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Miscellaneous - 25 COMMERCE WAY 4/30/2018 (2)
DYS& Fiber Optic Solutions for Industry PAUL F. BARRY JR. Manager of Operations and Manufacturing DYMEC, Inc. Tel: (978) 256-0025 27 Katrina Road Fax: (978) 256-1510 Chelmsford, MA 01824 e-mail: dymecpfb@aol.com 0 CERTIFICATE OF USE & OCCUPANCY TOWN OF NORTH ANDOVER Building Permit Number 122 8/11/09)^ Date: January 15, 2010 THIS CERTIFIES THAT THE BUILDING LOCATED ON 25 Commerce Way Unit #6 MAY BE OCCUPIED AS Tenant Fit Up — OSI Electronics IN ACCORDANCE WITH THE PROVISIONS OF THE MASSACHUSETTS STATE BUILDING CODE AND SUCH OTHER REGULATIONS AS MAY APPLY. Certificate Issued to: Eli Levine 25 Commerce Way North Andover MA 01845 Gerald Brown, Inspector of Buildings ./ t' m m m m m m CO) v m c FO C � CD OZ y 06 � 0. r c CL ? c y ato -0 o v CD CD 0 Q d CD mo CD O CD ca w �. c CD _a v � �CD i v CO) 'O Z CD 0 a O O � CD O CCD _C W Sc 0 O' -1 =• y Scor y = Q nO ECOco r ti 70s- d z CJ CL m b Nm C Cn 'V ?= y H -4 .Oyu n,► '.07 * O ..f CZ cn TI ' y O a of nC V J CD .i -o > fmm >0 2 a O 0. . 0 o o �. 0 O C d G cn N Q =0 CD cn W C tv CL ao 0m : m d• �4 ED Gqq� G: y ' .0.►� o M H n CS O H• C CL H ••� C O Cfl CA _C W Sc 0 O' -1 =• y Scor y = nO ECOco p ti 70s- d z CJ CL m Z Nm C 'V ?= y H -4 .Oyu n,► '.07 * O ..f CZ TI y O a of GO y CD .i -o > fmm >0 2 a . 0 C to O 0 O C d G N Q =0 CD W C =r .% : CL ao 0m : m 0 ..... CD O H ED ,om CL , y ' .0.►� o ty N H C d CS O �r : C CL H ••� C O Cfl CA =r H N O � 1 Ca O O CD to .-► C7 O 0 =r ® O CA Co ,.., CD =m H CD CD - o� RM: no: on)' � o �o c o � co WO m z 0 \ 94 Onq 0 9 O C CD \1 per. m C `; G O p 70s- d z oGa pGp Cil ce 0 z 0 \ 94 Onq 0 9 O C CD Project Number: Project Title: Project Location: Name of Building: Nature of Project: TOWN OF NORTH ANDOVER Final Design Affidavit 0905060 Alterations and modifications to existing space for OSI Electronics 25 Commerce Way, North Andover, MA 25 Commerce Way Alterations and modifications to existing space. In accordance with Section 116.0 Registered Architectural and Professional Engineering Services -Construction Control of the Massachusetts State Building Code, I, Gregory P. Smith Registration No. 8688 being a Registered PFefessional Engineef/Architect, HEREBY CERTIFY that I have prepared or directly supervised the preparation of all design plans, computations and specifications concerning: Entire Project _ Architectural XXXX Structural Mechanical Fire Protection Electrical Other (specify) FOR THE ABOVE-NAMED PROJECT, AND THAT SUCH PLANS, COMPUTATIONS AND SPECIFICATIONS MEET THE APPLICABLE PROVISIONS OF THE 780 CMR MASSACHUSETTS STATE BUILDING CODE, ALL ACCEPTABLE ENGINEERING PRACTICES AND APPLICABLE LAWS AND ORDINANCES FORITHE PROPOSED USE AND OCCUPANCY. I FURTHER CERTIFY THAT I HAVE PERFORMED THE NECESSARY PROFESSIONAL SERVICES AND EITHER MY REPRESENTATIVE OR I HAVE BEEN PRESENT ON THE CONSTRUCTION SITE ON A REGULAR AND PERIODIC BASIS TO DETERMINE THAT THE WORK HAS PROCEEDED IN ACCORDANCE WITH THE DOCUMENTS SUBMITTED FOR THE BUILDING PERMIT, AND SHALL BE RESPONSIBLE FOR THE FOLLOWING AS SPECIFIED IN SECTION 116.2.2 1. Review for conformance to the design concept, shop drawings, samples and other submittals which are submitted by the contractor in accordance with the requirements of the construction documents. 2. Review and approval of the quality control procedures for all code -required controlled materials. 3. Be present at intervals appropriate to the state of construction to become generally familiar with the progress and quality of the work and to determine, in general, if the work is being performed in a manner consistent with the construction documents. I AM SUBMITTING THIS FINAL REPORT AS TO THE SATISFACTORY COMPLETION AND READINESS OF THE PROJECT FOR OCCUPANCY. Signature and Stamp (no facsimile) SUBSCRIBED ANDSWORN TO BEFORE ME THIS DAY OF Iti 2010 MY COMMISSION EXPIRES S " NOTARY PUBLIC LINDA VANDEVOORDE Notary Public - New Hampshire My Commission Expires April 15, 201 HVAC .a SANITARY MCCABE ASSOCIATES Consulting Engineers ELECAL FRE PROTRIC cTI®N 75 GOODHUE ROAD, DERRY, NH 03038 Tel:(603) 437-2002 Fax:(603) 437-0123 January 12, 2010 Gerald Brown Inspector of Building Building Department 1600 Osgood St. North Andover, MA 01845 RE: OSI Electronics 1 st Floor Commerce Ave North Andover, MA MECHANICAL& ELECTRICAL FINAL AFFIDAVIT I certify that the HVAC and Electrical work associated with the OSI Electronics project is complete and that to the best of my knowledge, information, and belief the work was done in conformance with McCabe Associates Plans and Specifications and the provisions of the Massachusetts State Building Code and all other pertinent laws and ordinances. Steven Houle Engineer 75 Goodhue Road, Derry, NH Address January 12 2010 46743 Mass. Reg. No. OF NSSgC� 2 STEVE �'� R• o HOULE 140. 46143 O A LONA- 741013 Date..�bi p4w ....... �' MORTp i. 0", ,,.o 3? ° WN OF NORTH ANDOVER e X PERMIT FOR GAS INSTALLATION This certifies that ... r` -I ( ",: � c, -n./1 ....A ........ has permission for gas installation . ..,,�!(,l,C�✓i!�Q� ....... . in the buildings of ... &,,,A- 4. �'� '....�l•'�.PA ............... at.... North AndoMass. %%��ss. Feee.60 .�Q Lic. No.1 .c.1,Q.. � ... f i' . GAS INSPECTOR Check # SSI q( MASSACHUSETTS UNIFORM APPLICATION FOR ERMIT TO DO GASFITTING P.A fu or) UL� Mass. Date1 20 /6 Perm/it # Building Location Owner's Name C�/� 2. _ %%co ,),S- 66hIVOLL (,�J/�i Type of Occupancy CeH New n Renovation n Replacement ri✓ Plans Submitted: Yes ❑ No ❑ Installing Company Name Business Telephone Name of Licensed Plumber or Gasfitter Check one: Certificate p. -Corporation 0 Partnership ❑ Firm/Co. INSURANCE COVERAGE: I have a current liability insurance policy or its substantial equivalent which meets the requirements of MGL Ch. 142 Yes/0- No ❑ If you have checked yes, please indicate the type of coverage by checking the appropriate box_ A liability insurance policy 9�- '. Other type of indemnity ❑ Bond ❑ OWNER'S INSURANCE WAIVER: I am aware that the licensee does not have the insurance coverage required by Chapter 142 of the MGL, and that my signature on this permit application waives this requirement. Signature of Owner or Owner's Agent Owner ❑ Agent ❑ I hereby certify that all of the details and information I have submitted (or entered) in above application are true and accurate to the best of my knowledge and that all plumbing work and installations performed under the permit issued for this application will be in compliance with all pertinent provisio4of;atachusetts State Gas Code and Cha ter 142 of the General Laws. BYType' of Uc use_Title 4QPlumber EIMaster ed Plumber/Gasfitter City/Town ❑ Gasfitter ❑ Journeyman License Number APPROVED OFFICE USE ONLY Nr Date. /--?..4 ;." ..... TOWN OF NORTH ANDOVER • PERMIT FOR GAS INSTALLATION This certifies that ................................. has permission for gas installation ....... in the buildings of .................... at ......... . ........ G�y North Andover, Mass. Fee.'�� ..... Lic. No......'!..?. . .... .......... GAS INSOR Check# 112-2 - 7004 FIXTURES MASSACHUSETTS UNIFORM APPLICATION FOR PERMIT TO DO GAS FITTING City/Town: ±j t L O A nt/-L,r— MA. Date: ?l Permit# � J` Building Locationn„n nI e,r� P t ,a� Ur\,J j Owners Name: Q S� I Type of Occupancy: Commercial B/Educational ❑ Industrial ❑ Institutional ❑ Residential ❑ New: ❑ Alteration: ❑ Renovation: Q� Replacement: ❑ Plans Submitted: Yes ❑ No ❑ FIXTURES INSURANCE COVERAGE: I have a current liability insurance policy or its substantial equivalent which meets the requirements of MGL. Ch. 142 Yes No ❑ If you have checked Yes, please indicate the type of coverage by checking the appropriate box below. A liability insurance policy K]/Other type of indemnity ❑ Bond ❑ OWNER'S INSURANCE WAIVER: I am aware that the licensee does not have the insurance coverage required by Chapter 142 of the Massachusetts General Laws, and that my signature on this permit application waives this requirement. Check One Only Owner ❑ Agent ❑ Sianature of Owner or Owner's Aqent By checking this box ❑; I hereby certify that all of the details and information I have submitted (or entered) regarding this application are true and accurate to the best of my Knowledge and that all plumbing work and installations performed under the permit issues for tnis appimation win oe in compliance with all Pertinent provision of the Massachusetts State Plumbing Code and Chapter 142 of the General Laws. Type of License: By ❑ Plumber o 2;1 Title D Gs Fitter Sig ature of Licensed PI m r/Gas Fitter Waster City/Town ❑Journeyman License Number: 1 D 1 D APPROVED OFFICE USE ONLY ❑ LP Installer W W Y U W IX MM z t- QQ a z J W w z W w O IY E 0 I— D O W N Lu 0 m 0 a a H m W w X N> IY fn w 0 z w w O Z I- w 2 w 0 0 <W w o o ME U w U' J J J u_ 0 F= w w Z O m �- m D N a Q X w Q w m w Q> 0 z O O y w z > z z to _ a� 0 _ o o u. c� O = J O a 9 � � > > > O SUB BSMT. BASEMENT 1 FLOOR 2 FLOOR Vu FLOOR -4-FLOOR 51H FLOOR 6111 FLOOR 7 1H FLOOR 8 FLOOR Check One Only Certificate # Installing Company Name: PV CC -(.j corporation 1913 Address:)14 013aJc,l, , A City/Town:Plan c State: �i El Partnership Business Tel: Ltil L(.4 I'IS % Fax: ❑ Firm/Company Name of Licensed Plumber/Gas Fitter: M,C. h'12 n INSURANCE COVERAGE: I have a current liability insurance policy or its substantial equivalent which meets the requirements of MGL. Ch. 142 Yes No ❑ If you have checked Yes, please indicate the type of coverage by checking the appropriate box below. A liability insurance policy K]/Other type of indemnity ❑ Bond ❑ OWNER'S INSURANCE WAIVER: I am aware that the licensee does not have the insurance coverage required by Chapter 142 of the Massachusetts General Laws, and that my signature on this permit application waives this requirement. Check One Only Owner ❑ Agent ❑ Sianature of Owner or Owner's Aqent By checking this box ❑; I hereby certify that all of the details and information I have submitted (or entered) regarding this application are true and accurate to the best of my Knowledge and that all plumbing work and installations performed under the permit issues for tnis appimation win oe in compliance with all Pertinent provision of the Massachusetts State Plumbing Code and Chapter 142 of the General Laws. Type of License: By ❑ Plumber o 2;1 Title D Gs Fitter Sig ature of Licensed PI m r/Gas Fitter Waster City/Town ❑Journeyman License Number: 1 D 1 D APPROVED OFFICE USE ONLY ❑ LP Installer The Commonwealth of Massachusetts Department of Industrial Accidents Office of Investigations 600 Washington Street Boston, MA 02111 www mass.gov/dia Workers' Compensation Insurance Affidavit: Builders/Contractors/Electricians/Plumbers Applicant Information Please Print Legibly Name (Business/Organization/Individual):,A-CC i1! *-e A L Address: 11-/ 4 Dou, k a,, C - City/State/Zip:Mcgnc�_P-d--e,- FVlH 63)c3 Phone#:6o3 b6,? S/s� Are Y9u an employer? Check the appropriate box: 1. I am a employer with a_ 4. ❑ 1 am a general contractor and I employees (full and/or part-time).* have hired the sub -contractors 2. ❑ I am a sole proprietor or partner- listed on the attached sheet ship and have no employees These sub -contractors have working for me in any capacity. workers' comp. insurance. [No workers' comp. insurance 5• ❑ We are a corporation and its required.) officers have exercised their 3. ❑ I am a homeowner doing all work right of exemption per MGL myself. [No workers' comp. C. 152, § 1(4), and we have no insurance required.] t employees. [No workers' comp. Insurance required.] Type of project (required): 6. ❑ New construction 7. ❑ Remodeling 8. ❑ Demolition 9. ❑ Building addition 10. ❑ Electrical repairs or additions 11.❑ Plumbing repairs or additions 12.❑ Roof repairs 13. ❑ Other •u r ::i:y..a.cuc uue �u=c:' oux r, : MUSL WSO illi Olrt the Sectron below showing L,err p; or}:e;5 enmpensatroII policy information. t Homeowners who submit this affidavit indicating they are doing all work and then hire outside contractors must submit a new affidavit indicating such. #Contractors that check this box must attached an additional sheet showing the name of the sub -contractors and their workers' comp. policy information. I am an employer that is providing workers' compensation insurance for my employees. Below is the policy and job site information. Insurance Company Name: Policy # or Self -ins. Lic. #:-.(.:f P P0 '8_14 %D 1 Expiration Date: '3/,?/ 1- b Job Site Address: a -Y C r✓� M-er W V , ,'t City/State/Zip: IN_.a o rQ i y✓1aS S Attach a copy of the workers' compensation policy declaration page (showing the policy number and expiration date). Failure to secure coverage as required under Section 25A of MGL c. 152 can lead to the imposition of criminal penalties of a fine up to $1,500.00 and/or one-year imprisonment, as well as civil penalties in the form of a STOP WORK ORDER and a fine of up to $250.00 a day against the violator. Be advised that a copy of this statement may be forwarded to the Office of Investigations of the DIA for insurance coverage verification. I do hereby certify under the pains and penalties of perjury that the information provided above is true and correct Official use only. Do not write in this area, to be completed by city or town official City or Town: Permit/License # Issuing Authority (circle one): 1. Board of Health 2. Building Department 3. City/Town Clerk 6. Other Contact Person: R 4. Electrical Inspector 5. PIumbing Inspector Phone M Information and Instructions Massachusetts General Laws chapter 152 requires all employers to provide workers' compensation for their employees. Pursuant to this statute, an employee is defined as "...every person in the service of another under any contract of hire, express or implied, oral or written." An employer is defined as "an individual, partnership, association, corporation or other legal entity, or any two or more of the foregoing engaged in a joint enterprise, and including the legal representatives of a deceased employer, or the receiver or trustee of an individual, partnership, association or other legal entity, employing employees. However the owner of a dwelling house having not more than three apartments and who resides therein, or the occupant of the dwelling house of another who employs persons to do maintenance, construction or repair work on such dwelling house or on the grounds or building appurtenant thereto shall not because of such employment be deemed to be an employer." MGL chapter 152, §25C(6) also states that "every state or local licensing agency shall withhold the issuance or renewal of a license or permit to operate a business or to construct buildings in the commonwealth for any applicant who has not produced acceptable evidence of compliance with the insurance coverage required." Additionally, MGL chapter 152, §25C(7) states "Neither the commonwealth nor any of its political subdivisions shall enter into any contract for the performance of public work until acceptable evidence of compliance with the insurance requirements of this chapter have been presented to the contracting authority." Applicants Please fill out the workers' compensation affidavit completely, by checking the boxes that apply to your situation and, if necessary, supply sub-contractor(s) name(s), address(es) and phone number(s) along with their certificate(s) of insurance. Limited Liability Companies (LLC) or Limited Liability Partnerships (LLP) with. no employees other than the members or partners, are not required to carry workers' compensation insurance. If an LLC or LLP does have employees, a policy is required. Be advised that this affidavit may be submitted to the Department of Industrial Accidents for confirmation of insurance coverage. Also be sure to sign and date the affidavit. The affidavit should be returned to the city or town that the application for the pe—ariit or license is being requested, not the Department of Industrial Accidents. Should you have any questions regarding the law or if you are required to obtain a workers' compensation policy, please call the Department at the number listed below. Self-insured companies should enter their self-insurance license number on the appropriate line. City or Town Officials Please be sure that the affidavit is complete and printed legibly. The Department has provided a space at the bottom of the affidavit for you to fill out in the event the Office of Investigations has to contact you regarding the applicant. Please be sure to fill in the permit/license number which will be used as a reference number. In addition, an applicant that must submit multiple permit/license applications in any given year, need only submit one affidavit indicating current policy information (if necessary) and under "Job Site Address" the applicant should write "all locations in (city or town)." A copy of the affidavit that has been officially stamped or marked by the city or town may be provided to the applicant as proof that a valid affidavit is on file for future permits or licenses. A new affidavit must be filled out each year. Where a home owner or citizen is obtaining a license or permit not related to any business or commercial venture (i.e. a dog license or permit to bum leaves etc.) said person is NOT required to complete this affidavit. The Office of Investigations would like to thank you in advance for your cooperation and should you have any questions, please do not hesitate to give us a call. The Department's address, telephone and fax number: The Commonwealth of Massachusetts Department of Industrial Accidents Office of Investigations 600 Washington Street Boston, MA 02111 Tel. # 617-727-4900 ext 406 or 1-877-MASSAFE Revised 5-26-05 Fax # 617-72.7-7749 www.rmss.gov/dia CERTIFICATE OF LIABILITY INSURANCE OP ID BG O MALONEY ASSOCIATES, INC. 1650 Elm Street, Suite 501 Manchester NH 03101-1217 Phone:603-669-9700 Fax:603-626-5560 INSURED Accurate Air Inc. and J.A.S. Industries, Inc. d/b/a Accurate Air Mechanical Sys. 140 Bouchard Street Manchester NH 03103 DATE 05/18/09 THIS CERTIFICATE IS ISSUED AS A MATTER OF INFORMATION ONLY AND CONFERS NO RIGHTS UPON THE CERTIFICATE HOLDER. THIS CERTIFICATE DOES NOT AMEND, EXTEND OR ALTER THE COVERAGE AFFORDED BY THE POLICIES BELOW. INSURERS AFFORDING COVERAGE NAIC # INSURER ACincinnati Insurance Co. INSURER B: INSURER C' INSURER D: INSURER E'. .. THE POLICIES OF INSURANCE LISTED BELOW HAVE BEEN ISSUED TO THE INSURED NAMED ABOVE FOR THE POLICY PERIOD INDICATED. NOTWITHSTANDING SHOULD ANY OF THE ABOVE DESCRIBED POLICIES BE CANCELLED BEFORE THE EXPIRATION ANY REQUIREMENT, TERM OR CONDITION OF ANY CONTRACT OR OTHER DOCUMENT WITH RESPECT TO WHICH THIS CERTIFICATE MAY BE ISSUED OR MAY PERTAIN, THE INSURANCE AFFORDED BY THE POLICIES DESCRIBED HEREIN IS SUBJECT TO ALL THE TERMS. EXCLUSIONS AND CONDITIONS OF SUCH IMPOSE NO OBLIGATION OR LIABILITY OF ANY KIND UPON THE INSURER, ITS AGENTS OR POLICIES. AGGREGATE LIMITS SHOWN MAY HAVE BEEN REDUCED BY PAID CLAIMS. REPRES ATIVES. AUTHOR REPRESENTATIVE Y EFFECTIVE INUHD➢C POLICY NUMBER DA ECMMfDDIYYYY LTR YNSRCI TYPE OF INSURANCE PUL—Icy N DATE MMID�IWYY LIMITS ' GENERAL LIABILITY EACH OCCURRENCE S1,000,000 PREMISES (Ea occurence) $500,000 A I X COMMERCIAL GENERAL LIABILITY I CPP0824709 03/31/09 03/31/10 CLAIMS MADE X� OCCUR MED EXP (Any one person) $10,000 PERSONAL 8 ADV INJURY $1,000,000 X Per Proj . Aggr. . GENERAL AGGREGATE s2,000,000 PRODUCTS - COMPIOPAGG S2,000,000 ( GAGGREGATELIMITAPPLIESPER: X PRO - POLICY LOC JECT AUTOMOBILE LIABILITY COMBINED SINGLE LIMIT $ 1, 000,00009 A X ANY AUTO CPA08247 03/31/09 03/31/10 (Ea accident) i— I BODILY INJURY $ X ALL OWNED AUTOS i I (Per person) SCHEDULED AUTOS `BODILY INJURY $ j( HIREDAUTOS I X I NON -OWNED AUTOS (Preaccident) PROPERTY DAMAGE $ ' --i I (Per accident) j GARAGE LIABILITY I i AUTO ONLY_ EA ACCIDENT S ANY AUTOOTHER THAN EA AGC I S i AUTO ONLY: AGG $ I`f EXCESS I UMBRELLA LIABILITY i EACH OCCURRENCE s2,000,000 A ' iOCCUR CLAIMS MADE � CPP0824709 03/31/09 03/31/10 AGGREGATE r -- 's2,000,000 $ DEDUCTIBLE i $ RETENTION $ I ! $ WORKERS COMPENSATION ` X1TORY LtMtTS I ER ! _ AND EMPLOYERS' LIABILITY Y I N A ANY PROPRIETORIPARTNERIEXECUTIVE0 WC1921227 03/31/09 '. 03/31/10 E,L. EACH ACCIDENT 1$1,000,000 OFFICER/MEMBER EXCLUD I (Mandatory in NH) i E L. DISEASE - EA EM?LOYEE S 1 , 000 , 000 Ifes describe under I E.L. DISEASE - POLICY LIMIT I S 1 000 000 SPECIAL PROVISIONS below , , OTHER A Business Property �CPP0824709 03/31/09 03/31/10 $200,000 DESCRIPTION OF OPERATIONS I LOCATIONS I VEHICLES 1 EXCLUSIONS ADDED BY ENDORSEMENT I SPECIAL PROVISIONS Officers are included for Workers Compensation. riT.�3, a.iTil/.IY A. al 1R.1� - M1101MONWI\E1N ACORD 25 (2009/01) -" —. —,—...-... ......o... .--- -_ The ACORD name and logo are registered marks of ACORD SHOULD ANY OF THE ABOVE DESCRIBED POLICIES BE CANCELLED BEFORE THE EXPIRATION STA -006 DATE THEREOF, THE ISSUING INSURER WILL ENDEAVOR TO MAIL 10 DAYS WRITTEN NOTICE TO THE CERTIFICATE HOLDER NAMED TO THE LEFT, BUT FAILURE TO DO SO SHALL IMPOSE NO OBLIGATION OR LIABILITY OF ANY KIND UPON THE INSURER, ITS AGENTS OR State of Massachusetts REPRES ATIVES. AUTHOR REPRESENTATIVE ACORD 25 (2009/01) -" —. —,—...-... ......o... .--- -_ The ACORD name and logo are registered marks of ACORD Date. .q? . TOWN OF NORTH ANDOVER PERMIT FOR PLUMBING This certifies that.... .. 2� -t'..- has permission to perform% - -. x-�.�--:Q-�. �y . plumbing in the buildings of ........ ......... . at .�-��.�.. ��-tt--�_�-,� ,-�<Lf-,'-`J... orth Andover, Mass. PECTOR Fee, +C �. '.. Lic. No. (. `�.` Y. k�,.. ...... '.. ......... . P���V'S Check # 1,31 � �� . 'LUMBIMIP v 8277 MASSACHUSETTS UNIFORM APPLICATION FOR PERMIT TO DO PLUMBING (Type or pmt) NORTH ANDOVER, MASSACHUSETTS Building 'r. Owner L -L [— L� New Renovation 1 Replacement ❑ FIXTURES Date ,//" 2 -,o � Permit #t 2,-7 Amount Plans Submitted Yes No (Print or type) Installing Company Name of Licensed Plumber: Insurance Coverage: Indicate Liability insurance policy F D.?o I of insuranedcoverage by checki Other type of indemnity Check one: Certificate ❑ Corp. Partner. Firm/Co. appropriate box: Bond ❑ Insurance Waiver: I, the undersigned, have been made aware that the licensee of this application does not have any one of the above three insurance Signature Owner Agent I hereby certify that all of the details and information I have submitted (or entered) in above application are true and accurate to the best of my knowledge and that all plumbing work and installations perform ed Permit Issued for this application will be in compliance with all pertinent provisions of the Massac to o tt o} the General Laws. By:>Igmtur-eor xWens Ser Title Type of P mg License a City/Town icense Numoer Master El Journeyman APPROVED tomcE usE oNLY 01 Rr The Commonwealth of Massachusetts i Department of Industrial Accidents Office of Investigations 600 Washington Street Boston, MA -02111 www.massgov/dia Workers' Compensation Insurance Affidavit: Builders/Contractors/Electricians/Plumbers Applicant Information Please Print Legibly Name (Business/Organizationdndividual): Address: City/State/Zip:_ 6, o,1,5 -b� Phone #: 6,)3 �r Are you an employer? Check the appropriate bog: 1. ❑ I am a employer with 4. ❑ I am a general contractor and I employees (full and/or part-time).* have hired the sub -contractors 2. ❑ I am a sole proprietor or partner- listed on the attached sheet. I ship and have no employees These sub -contractors have working for in any capacity. [No workers' comp. insurance required.] 3. ❑ I am a homeowner doing all work myself. [No workers' comp. insurance required.] t workers' comp. insurance. 5. ❑ We are a corporation and its officers have exercised their right of exemption per MGL c. 152, §.l (4), and we have no employees. [No workers' comp. insurance required.] Type of project (required): 6. ❑ construction 7. gRemodeling 8. ❑ Demolition 9. ❑ Building addition 101-1 Electrical repairs or additions 11.❑ Plumbing repairs or additions 12.❑ Roof repairs 13.❑ Other +�r.y a ,ptmca.� fret checY.s oox #; —so tilt out the section below showing their workers' compensation policy information. Homeowners who submit this affidavit indicating they are doing all work and then hire outside contractors must submit a new affidavit indicating such.. lContractors that check this box must attached an additional sheet showing the name of the sub -contractors and their workers' comp. policy information. I am an employer that isproviding workers' compensation insurance for my employees Below is thepolicy and job site information. Insurance Company Name: J Policy # or Self4ns. Lic. Job Site Address: Expiration Date: City/State/Zip:. Attach a copy of the workers' compensation policy declaration page (showing the policy number and expiration date). Failure to secure coverage as required under Section 25A of MGL c. 152 can lead to the imposition of criminal penalties of a fine up to $1,500.00 and/or one-year imprisonment, as well as civil penalties in the form of a STOP WORK ORDER and a fine . of up to $250.00 a day against the violator. Be advised that a copy of this statement may be forwarded to the Office of Investigations of the DIA for insurance coverage verification. I do herel;y::ce�H05kunder the wins and penalties of perjury that the information provided above is true and correct Phone #: . 603 S �a Official use only. Do not write in this area, to be completed by city or town officiaL City or Town: Permit/License # x/10 Issuing Authority (circle one): 1. Board of Health 2. Building Department 3. City/Town Clerk 4. Electrical Inspector 5. Plumbing Inspector 6. Other Contact Person: Phone #: Information and Instructions � .( Massachusetts General Laws chapter 152 requires all employers to provide workers' compensation for their employees. Pursuant to this statute, an employee is defined as "...every person in the service of another under any contract of hire, express or implied, oral or written." An employer is defined as "an individual, partnership, association, corporation or other legal entity, or any two or more of the foregoing engaged in a joint enterprise, and including the legal representatives of a deceased employer, or the receiver or trustee of an individual, partnership, association or other legal entity, employing employees. However the owner of a dwelling house having not more than three apartments and who resides therein, or the occupant of the dwelling house of another who employs persons to do maintenance, construction or repair work on such dwelling house or on the grounds or building appurtenant thereto shall not because of such employment be deemed to be an employer." MGL chapter 152, §25C(6) also states that "every state or Iocal licensing agency shall withhold the issuance or renewal of a license or permit to operate a business or to. construct buildings in the commonwealth for any applicant who has not produced acceptable evidence of compliance with the insurance coverage required." Additionally, MGL chapter 152, §25C(7) states "Neither the commonwealth nor any of its political subdivisions shall enter into any contract for the performance of public work until acceptable evidence of compliance with the insurance requirements of this chapter have been presented to the contracting authority." Applicants Please fill out the workers' compensation affidavit completely, by checking the boxes that apply to your situation and, if necessary, supply sub -contractors) name(s), address(es) and phone number(s) along with their certificate(s) of insurance. Limited Liability Companies (LLC) or Limited Liability.Partnerships (LLP) with no employees other than the members or partners, are not required to carry workers' compensation insurance. If an LLC or LLP does have employees, a policy is required. Be advised that this affidavit may be submitted to the Department of Industrial Accidents for confirmation of insurance coverage. Also be sure to sign and date the affidavit. The affidavit should be returned to the city or town that the application for the permit or license is being requested, not the Department of Industrial Accidents. Should you have any questions regarding the law or if you are required to obtain a workers' compensation policy, please call the Department at the number listed below. Self-insured companies should enter their self-insurance license number on the appropriate line. _. City or Town Officials Please be sure that the affidavit is complete and printed legibly. The Department has provided a space at the bottom of the affidavit for you to fill out in the event the Office of Investigations has to contact you regarding the applicant. Please be sure to fill in the permit/license number which will be used as a reference number. In addition, an applicant that must submit multiple permittlicense applications in any given year, need only submit one affidavit indicating current policy information (if necessary) and under "Job Site Address" the applicant should write "all locations in (city or town)." A copy of the affidavit that has been officially stamped or marked by the city or town may be provided to the applicant as proof that a valid affidavit is on file for future permits or licenses. A new affidavit must be filled out each year. Where a home owner or citizen is obtaining a license or permit not related to any business or commercial venture (i.e. a dog license or permit to burn leaves etc.) said person is NOT required to complete this affidavit. The Office of Investigations would like to thank you in advance for your cooperation and should you have any questions, please do not hesitate to give us `a call. The Department's address, telephone and fax number: The Commonwealth of Massachusetts Department of Industrial Accidents. Office of Investigations 600 Washington. Street Boston, MA. 0.21.11. Tel. # 617-7274900 ext 4406 or 1-877-MASSAFE Fax # 617-72.7-7749 Revised 5 -26 -QS mrwm7.mass.govfdia O Date/ -.. 01. TOWN OF NORTH ANDOVER PERMIT FOR WIRING This certifies that ��'(hve.p . . ...................................... has permission to perform Z/7i.�I 17 ) ... V.r ......................... wiring in the building of.,,2 ..r -z-� .................. ..... .q.l .............. at.. Aoqh Andover, Mass. Fee ./.J .......... Lic. No. IR AL NSP 0OR: Check # 9084 -A. Commonwealth of Massachusetts Official Use only Department of Fire Services Permit No. U Occupancy and Fee Checked BOARD OF FIRE PREVENTION REGULATIONS [Rev. ]/07] (leave blank) APPLICATION FOR PERMIT TO PERFORM ELECTRICAL WORK All work to be performed in accordance with the Massachusetts Electrical Code (MC), 527 C R 12.00 (PLEASE PRINT IN INK OR TYPE ALL INFORMATION) Date: 7. �q 4 City or Town of. NORTH ANDOVER To the Inspector of ices: By this application the undersigned gives notice of his or her intention to perform the electrical work described below. Location (Street & Number) A Owner or Tenant 10 r-:tM N'l C.S Telephone No. -19919 Owner's Address Is this permit in conjunction with a building permit? Yes ❑ No (Check Appropriate Box) Purpose of Building R 1 0 Utility Authorization No. Existing Service Amps / Volts Overhead ❑ Undgrd ❑ No. of Meters New Service Amps / Volts Overhead ❑ Undgrd ❑ No. of Meters Number of Feeders and Ampacity Location and Nature of Proposed Electrical Work: Completion o the ollowin table maybe waived by the Inspector of Wires. No. of Recessed Luminaires No. of Ceil: Susp. (Paddle) Fans No. s Total Transformers KVA No. of Luminaire Outlets No. of Hot Tubs Generators KVA No. of Luminaires Swimming Pool Above ❑ In- ❑ rnd. rnd. o. o Emergency Lighting Battery Units No. of Receptacle Outlets No. of Oil Burners FIRE ALARMS I No. of Zones No. of Switches No. of Gas Burners No. of Detection and Initiating Devices No. of Ranges g No. of Air Cond. Total Tons No. of Alerting Devices No. of Waste Disposers Heat Pum Number Tons KW No. of Self -Contained Totals I Detection/Alerting Devices No. of Dishwashers Space/Area Heating KW Local ❑ Municipal El Other Connection No. of Dryers Heating Appliances KW Security Systems:* No. of Devices or Equivalent No. of Water Kms, No. of No. of Data Wiring: Heaters Signs Ballasts No. of Devices or Equivalent No. Hydromassage Bathtubs No. of Motors Total HP Telecommunications Wiring: No. of Devices or Equivalent OTHER: Attach additional detail if desired, or as required by the Inspector of Wires. Estimated Value of lectrica Work: (When required by municipal policy.) Work to Start: I Inspections to be requested in accordance with MEC Rule 10, and upon completion. INSURANCE COVERAGE: Unless waived by the owner, no permit for the performance of electrical work may issue unless the licensee provides proof of liability insurance including "completed operation" coverage or its substantial equivalent. The undersigned certifies that such cove a is in force, and has exhibited proof of same to the permit issuing office. CHECK ONE: INSURANCE ® BOND ❑ OTHER ❑ (Specify:) I certify, under the pains and penalties of perjury, that the information on this application is true and complete. FIRM NAME: S S Ll C LIC. NO.: Licensee:Signatu LIC. NO.: �-�} (If applicable, enter "exempt" in the licen a number line. Bus. Tel. No.•g2� W -!FPS 49 Address: Alt. Tel. No.:!! -- =fQ(pV *Per M.G.L c. 147, s. 57-61, security work requires Department of Public Safety "S" License: Lic. No. OWNER'S INSURANCE WAIVER: I am aware that the Licensee does not have the liability insurance coverage normally required by law. By my signature below, I hereby waive this requirement. I am the (check one)❑ owner ❑ owner's agcnt. Owner/Agent Signature Telephone No. PERMIT FEE. $ ll-dg-6�q On, ( 2 — ri>_co 1p-lt� s Mfirrcnt TOWN OF NORTH ANDOVER BUILDING DEPARTMENT(6JSTRUCTION APPLICATION TO CONSTRUCT REPAIR, RENOVATE, CHANGE THE USE OR OCCUPANCY OF, OR DEMOLISH ANY BUILDING OTHER THAN A ONE OR TWO FAMILY DWELLING s Section for Official Use OnI � � ��-,�1 _. .3 . 4 BUII,DI tG PERMIT NUMBER: DATE ISSUED: i�t73. / Z ,200 QQ SIGNATURE: Building Commissioner/IaTector of Buildings Date `n 1.1'Property Address: 1.2 Assessors Map and Parcel Number: / � �fJ � .Z S G D ..•.mac e � � { Ly�i� GLTv: Map Number Parcel Number 1.3 Zoning Information: 1.4 Property Dimensions: i Z Zarin District Proposed Use Lot Area Frontage ft 1.6 BUILDING SETBACKS (ft) t., Cc- -'VrG- rzCc , -X&ore7L,orL c•>o2K o Front Yard Side Yard Rear Yard Required Provide Required Provided Re red Provided 1.7 Water Supply M.GL.C.40. 54) 1.5. Flood Zone Information: 1.8 Sewerage Disposal System: Public ❑ Private ❑ Zone Outside Flood Zone 0 Municipal On Site Disposal System ❑ 0 r sy i fy 2.1 Owner of Record /& /�'%d.Ld 4G ast.y� �o /-�C . Z� rO'dj �/ % ���G�[.✓d .c(QiJ e f%,;1/,0 i Name (Print) ,400 Jt r 1y GO . Address for Service /- 4-10 ;P 7-74/ 7- Sigr!�w Telephone 2.2 Authorized Agent Name Print Address for Service: 60 3- 6Z7- c,/r,03 Signature Telephone 3.1 Licensed Construction Supervisor Not Applicable ❑ �� �-v �// �e Nr t°_ fIP. �� LOi?//l'(/•o.y l•�4. /.�ti. �i� o�✓Q ySy Address License Number f� �% ��� �� /�-r-�r!%,r.•� Iva., �cQ •�-Gleet/Gi" SGL"/. censed Construction sor. Expiration Date,_ O a tgnature Telephone 3.2 Registered Home Improvement Contractor Not Applicable Company Name,. Registration Number Address Expiration Date Signature Telephone M X Z O 14 "I as Owner/Authorized Agent Hereby declare that the statements and information on the foregoing application are true and accurate, to the best of my knowledge and belief. Signed under the pains/and penalties of perjury Print Name �4 a Signature of Owner/Agent Date Item Estimated Cost (Dollars) to Completed by appli cant permit 1. Building A (a) Building Permit Fee Multiplier 2 Electrical v S o o (b) Estimated Total Cost of Construction from (6) 3 Plumbing 0, 4 . a Building Permit fee (a) x (b) ;L0 4 Mechanical (HVAC) 5 Fire Protection 6 Total (1+2+3+4+5) Check Number -'g Affi-, Pg ti RM '1`02 ' � 't, W `15 I 'N, x NO. OF STORIES SIZE BASEMENT OR SLAB SIZE OF FLOOR TIMBERS 2ND 3RD SPAN DEMENSIONS, OF SILLS DEMENSIONS OF POSTS DIMENSIONS OF GIRDERS HEIGHT OF FOUNDATION THICKNESS SIZE OF FOOTING x MATERIAL OF CHIMNEY IS BUILDING ON SOLID OR FILLED LAND IS BUILDING CONNECTED TO NATURAL GAS LINE 0 M ?T77'R a 1777 =2 SECTItSN 44 �SIEE;t Workers Compensation Insurance affidavit must be completed and submitted with this application. Failure to provide this affidavit will result in' issuance of the building permit. Signed affidavit Attached Yea ....... No ....... ❑ sEcrrorl s :1t>frta I n "J 1, > su�y �p/►r�t or r : �1� �envll�'taE;�CfE�3� 1iKF .�. ,i8.�Si►11'3L3:7L+rl.L•+?l�Ld? 5.1 Registered Architect.- rchitect:Name: Name: R�N X93 a Q Address - T ,F 4109 Signat l ^ Telephone Area of RWonsibility Name: Registration Number Address: Expiration Date Signature Total Not applicable ❑ Name: Registration Number Expiration Date Address . Signature Telephone Area of Responsibility Name Registration Number Expiration Date Address--, Signature Telephone Area of Responsibility Registration Number Expiration Date Name Address Signature Telephone Ae, II/ 1 0 . �y f Not Applicable ❑ Company Name: �a _az Responsible in Charge of Construction i New Construction ❑ Existing Building Repairs) ❑ Alterations(s) Addition ❑ Accessory Bldg. ❑ Demolition 0 ❑ Other ❑ Specify Brief Description of Proposed Work: 1.4— gin 'e OR /' �/� • c-L� eo"'O/ -Oy. . 9'30!) f� tel/ oY-' mye -e- srJ �G e Gcii'rLi '.d0 l40 -,"Z'd.0 ,o P C) e- o d►G P B Business BUILDING AREA EXISTING if applicable) PROPOSED Number of Floors or Stories Include Basement levels Floor Area per Floor s Total Area s Total Height (ft) Structural Structural Peer Review Yes ❑ No [�� SECTION 10a Owner Authorization - TO BE COMPLETED WHEN OWNERS AGENT OR CONTRACTOR APPLIES FOR BUILDING PERMIT ti .yP �. �r /ter®vcy G� ,as Owner of the subject property Hereby authorize A7, c 4a "O" 101f 1111m/ /&1x f"�! //'mac ''v.ti L� i LC to act on My behalf, in all matters relative two work authorized by this building permit application ZJ"? _"' 20/. Si o er Date USE GROUP Check as a livable CONSTRUCTION TYPE A Assembly ❑ A-1 ❑ A4 0 A-2 A-5 0 A-3 0 ❑ lA 113 *-**I— ❑ B Business 2A 2B 2C 0 0 ❑ C Educational ❑ F Factory 0 F-1 0 F-2 0 H High Hazard 0 3A 3B ❑ ❑ IInstitutional 0 I-1 ❑ 1-2 ❑ 1-3 0 M Mercantile ❑ 4 0 R residential 0 R-1 0 R-2 ❑ R-3 0 5A 5B ❑ ❑ S Storage 0 S-1 0 S-2 0 U Utility ❑ Specify: M Mixed Use 0 Specify: S Special Use 0 Specify: COMPLETE THIS SECTION IF EXISTING BUILDING UNDERGOING RENOVATIONS, ADDITIONS AND OR CHANGE IN USE Existing Use Group: Existing Hazard Index 780 CMR 34: Proposed Use Group: Proposed Hazard Index 780 CMR 34: BUILDING AREA EXISTING if applicable) PROPOSED Number of Floors or Stories Include Basement levels Floor Area per Floor s Total Area s Total Height (ft) Structural Structural Peer Review Yes ❑ No [�� SECTION 10a Owner Authorization - TO BE COMPLETED WHEN OWNERS AGENT OR CONTRACTOR APPLIES FOR BUILDING PERMIT ti .yP �. �r /ter®vcy G� ,as Owner of the subject property Hereby authorize A7, c 4a "O" 101f 1111m/ /&1x f"�! //'mac ''v.ti L� i LC to act on My behalf, in all matters relative two work authorized by this building permit application ZJ"? _"' 20/. Si o er Date CERTIFICATE OF USE &OCCUPANCY Building Permit Number, of N oath Andover J-,4_7AJQ2S-Q uNftl'G 6 / THIS CERTIFIES THAT THE BUILDING LOCATED ON Date a ommerce MAY BE OCCUPIED AS u pd cl u r l kj t o ' ACCORDANCE WITH THE PROVISIONS OF THE MASSACHUSETTS STATE BUILDING CODE AND SUCH OTHER REGULATIONS AS MAY APPLY. re. e .boa CERTIFICATE ISSUED TO ADDRESS .J2244yA,qeM—"04 CO /ai MjDDIS -sem ol C �'' Building Inspector 750 East Industrial Park Drive • Manchester, NH 03109 Kelly CQn4ruchon May 9, 2001 Mr. Bob Nicetta No. Andover Building Department 27 Charles Street No. Andover MA. 01845 Dear: Bob As a follow up to our conversation on May 9,2001 1 respectfully request that your department make changes to the Certificate of use & occupancy. Request # 1- Certificate of use & Occupancy for the Comfort food project was issued with the permit # as 57, and the unit # as 6. The date of 2/26/2001 is ok. Could you please reissue a new C of O, with the permit # as 20 and the unit # as 5. Date of issue 2126/2001. Request # 2 — Certificate of use & occupancy for the Innerstep project was issued with the permit # as 57 and the unit # as 6. This is correct, but the date needs to be changed to April 23,2001. Please call me with any questions. I can be reached at 1-603-627-4203. Thank you for all your help. Sincerely, ) Richard R Dalphond Project manager Kelly Construction Co. > Inc. FEB -2T-01 02:59 PM STEVE W KELLY 6220435 ` LMS - F USE &OCCUPANCY -North; Andover SEA T (mm rG�gY VAJ I ON §:�KeIN ACCORDANO 0=111��AtC I HU4MS NATE BUn DING COPE ANI SW 0 A 470) A,NAR is Building iI .02 c1mmcg, 0 A 470) A,NAR is Building iI .02 C/) m m cn U) 0 O �• N O QS, = -% m H * ® O y IS „„ C _. Z �� N y CD O .*"0 IE?.m•o0 m = p o CD ;; e d 'm Er CD CA zy R r� 4 0 .. CL r- C9� C/) CD 2 o y OO C cm CL y nu y 3 1 C/, O d y , cr cn CD CDa d �• V/ y CAI? `• O .••F iO m Q R -N -N CCD O CCDCD n v ® o Q C CDy� c y CO) CD mm n � bd CO) O C/)m y CD CD co O �c u fl.F dF R CO) • iz ter` C O (�► cn 0Ej c Q ., � arc• � n cn100 aGn x r ^ ro 0w� 07n ;o rd b n w- n gi Ap X a O, tri cn CD y -n O- tv 70d tTj ri I� 0 ( l 0=3 ol 9 0 c DYt6 Fiber Optic Solutions for Industry PAUL F. BARRY JR. Manager of Operations and Manufacturing DYMEC, Inc. Tel: (978) 256-0025 27 Katrina Road Fax: (978) 256-1510 Chelmsford, MA 01824 e-mail: dymecpfb@aol.com January 10, 2001 Fiber Optic Solutions for Industry Mr. D. Robert Nicetta Town of North Andover Building Commissioner 27 Charles Street North Andover, Ma. 01845 Re: Usage and business operation at 25 Commerce Way, bay #1. Dear Mr. Nicetta, Dymec Inc. 25 Commerce Road North Andover, MA 01845 Phone(978)688-8807 Fax(978)688-8771 www.dvmec.com Dymec Inc. designs and manufacturers fiber optic communication transceivers that are used in industrial, utility, and commercial applications. We are categorized as a very light electronics manufacturer utilizing printed circuit boards which are purchased from outside vendors, stuffed with electronic components, soldered, assembled, tested, and finally packaged for shipment to end users and customers. We currently employ 25 individuals with the hope of expanding to 50 over the next three to five years. Here is a breakdown of the departments and the number of people in each. • Manufacturing/Production 15 • Engineering 4 • Sales & Marketing 4 • Finance & H.R. 2 The building consists of 16,000 square feet of space broken down into the following areas. • Open manufacturing space • 600 sq foot wave soldering room • Caged stockroom/shipping/receiving areas • Open Sales & Administration space • Open Engineering space • 60 seating capacity break/lunch room • Conference room • Training room • 12 offices (12'x12') • 4 bathrooms The break/lunch room, which consists of the following: • (1) Refrigerator 0 (2) Microwave ovens 1 -o • (2) Vending machines • (1) Industrial coffee machine • (l) Bottled water dispenser We will also be storing several chemicals on site in OSHA approved fire and metal cabinets. Including a 55 -gallon drum (type 17E), that will be stored in a separate area clearly marked "hazardous waste area" to be reclaimed by Safety-Kleen of No. Andover. We will store less than 55 gallons and utilize less than 10 gallons per month of solvent based materials that are used for sealing our electronics, and in our ultrasonic cleaners for washing flux from boards after wave and hand soldering operations. The chemicals used for cleaning are not discharged through the sanitary lines. They are all reclaimed, documented and disposed of through a licensed hazardous waste company. All flammables and toxic materials will be stored in appropriate cabinets and containers in accordance with OSHA and proper manufacturing processes. • See attachment #1 for the exact details of the areas for storage of all chemicals. • See attachment 42 for the detailed listing of the types of chemicals being used with manufacturer's name, description, and average quantities to be stored or reclaimed. • See attachment #3 for material safety data sheets (MSDS) of all chemicals being stored on the premises. • See attachment #4 for contract with Safety-Kleen (NE), Inc. for our environmental hazardous waste reclaiming service. We also have a service agreement with Northside Carting Inc. of No. Andover for weekly dumpster pickup and service. The agreement includes two dumpsters behind the building at the bay#1 site. One will be a 4 cubic yard dumpster for trash with locks. The other will be an 8 cubic yard dumpster for corrugated materials with locks and slotted. We will also have a sign on the front left corner outside wall being installed by Bailey Sign of Westbrook, Maine. The sign will consist of one single face 5'x 13'6"x 5' aluminum framed wall sign with '/2" cut out sintra letters on surface, to read "DYMEC". If you need any further clarification or information, please don't hesitate to call. The Chelmsford telephone number is (978) 256-0025. Best regards, Paul F. Barry Jr. Manager of Operations and Manufacturing. 10'-0" gx a m m m N N 14'-0" o N N N O N < O O O < < C_ C Incoming test ° a N < < Gcn W N - isal sal isal - Ut cn � •�(ssy •yoaW a Cable Assy. m I —10'-11 3/8"--4 U-O��c ____= i Paul's Desk � N � CM 12-0" 11' 0" 11' 0" Mi 6-8 118 30'-0" en n 6 6" Ire, J 10'-T � n A `D 6-10" co o < 00 a Diff -A M Q i Potting . 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C_ C 'O C C C C C C C C C C C C C C C C C C Ccu cz •fl m C C Cca m U U U U O 0 U � O D U U U U U U U O p U O D U U U U U U U U � O w O w O D U U � O ' O p 0 O Om ( (O � Q O OD 6 O Om � (0 O O ( (6 O D06 O O O 0 (O O O OB O y a)a)a)a�ma)a)m a�a�ma� aaa as L a) �:2 w Z a) a)2 a)��������� m ii ii U- ii LL LL LL LL ii LL LL a E a, E R N N 0 m _ U m _ U m U m U m N m Q L" Q (n m (n m 0 m (n m@ (n Y Y Y Y-- U C U C 6 C N (6 _� (II � Z p W U W U W c� W U p E p E O p E W W W U U w W w w w O O O O a) m c m c UO _ t�0 (�9 (y0 U U V � N U (J U V U f0 i_ (6 � (0 i_ (d �_ / 0 0 0 2 2 E (n (n (n (n � �0 w6 � � �0 � � D U U U (i3 U (6 U (n L � L to L M M � 0.S Q) 06 a) N = O UUUU O O O O UUUUUUUUUU O O C L O O O O O (0 c��c� N O 00 _ C c m cu (D c—o c c c c _ U c V c U c .! •� O •` N O O O O O O L L L> a s O v 2 a) 2 a) 2 a) z>:E a) f0 m m m O --- O O 0 U U U U U U D >> Z (a m a) w CO m m m (pUUU O y O O O E t E (p (pQa c U O U 0 Uaaaaaa 0 L L L L L L N m N m N I--- r - U C L L L ++ : a) a) J J J J J J Z Z m Z �U, O �U, O Q O O — _ Q _Q Q _Q Q _Q Q M U Ca U M U CD U U L U t U •� •� E~ Z J J J U) U) W E E _ = a O L Q N = Cl) L C p O U a a) cn m O N L C: U O O w+ m Q) C LL w= L L °� L O ? is (O T `-) N _ L Q) L N � a w C UO^ (n /o/ a) u O° o ° o Y a) c C 'a O LL C-0 a) U) N ��20�� L L L fn mQ C T (n Q o Q' a •> M �oo(`')mo Q m T M T-0 m,co N O LLJ (D Q m LL � C O� (o 3 _ () N d (� U d N a�ifL--> .� � d L F- (D ((p � CO O W r W N T N T N Z () V N - c -p O N co M a) N O E a) a) N co coM 00 a) � � ~ N W N N O m Q Q U) Co O NT N = LL O = •E = + N � + Ch CJ \ L M U _ O < Q O LLL _cn W 3M 3,N1 General Offices MATERIAL SAFETY DATA SHEET 31,1 Censer St. Paul, vfN 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) 04-80 15323 Copyright, 1999, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. DIVISION: 3M SPECIALTY MATERIALS TRADE NAME: FC -77 FLUORINERT Brand Electronic Liquid ID NUMBER/U.P.C.: ISSUED: MAY 7, 1999 SUPERSEDES: FEBRUARY DOCUMENT: 10-3791-0 ZF-0002-0105-1 ZF-0002-0320-6 ZF-0002-4132-1 98-0204-0703-1 98-0211-1773-8 98-0211-3998-9 98-0211-5508-4 98-0211-7938-1 98-0211-8807-7 98-0211-8882-0 98-0211-9334-1 98-0212-1104-4 16, 1999 00-51135-09021-3 00-51135-02245-0 00-51135-02377-8 00-51135-02960-2 00-51135-10800-0 00-51135-10938-0 00-51135-10990-8 00-51135-11161-1 00-51135-45126-7 ZF-0O02-0106-9 ZF-0002-0389-1 98-0204-0701-5 98-0204-0704-9 98-0211-1774-6 98-0211-3999-7 98-0211-6447-4 98-0211-8800-2 98-0211-8875-4 98-0211-9333-3 98-0211-9371-3 1. INGREDIENT C.A.S. NO. PERCENT PERFLUORO COMPOUNDS, (PRIMARILY COMPOUNDS WITH 8 CARBONS) .......... 86508-42-1 100.0 00-51135-09020-6 00-51135-09022-0 00-51135-02246-7 00-51135-02378-5 00-51135-10269-5 00-51135-10930-4 00-51135-10986-1 00-51135-11150-4 00-51135-45000-0 NOTE: The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. FOR INDUSTRIAL USE ONLY. NOT INTENDED FOR USE AS A MEDICAL DEVICE OR DRUG. 2. PHYSICAL DATA BOILING POINT:. VAPOR PRESSURE: VAPOR DENSITY: EVAPORATION RATE: ............ SOLUBILITY IN WATER: ........ SP. GRAVITY: ............ PERCENT VOLATILE: ........... 90-107 C (Typical) ca. 42 mmHg Calc. a 2OC ca. 14 Air = 1 Calc. a 20C > 1.0 Butyl Acetate = 1 nil ca. 1.8 Water = 1 c a . 100 % Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately 3M General Offices 3M Center 04-80 St. Paul, V1\' 55144-1000 15324 1-800-364-3577 or (651) 737-6501 (24 hours) MATERIAL SAFETY DATA SHEET MSDS: FC -77 FLUORINERT Brand Electronic Liquid MAY 7, 1999 PAGE: 2 of 6 2. PHYSICAL DATA (continued) pH: ................... N/A VISCOSITY: .................. 0.8 centistokes at 20 C MELTING POINT.. .. N/A APPEARANCE AND ODOR: Colorless, odorless liquid. 3. FIRE AND EXPLOSION HAZARD DATA FLASH POINT:. ........ Setaflash None (SetaflashCC) FLAMMABLE LIMITS - LEL: ..... Nonflammable FLAMMABLE LIMITS - UEL: ..... Nonflammable AUTOIGNITION TEMPERATURE: ... Nonflammable EXTINGUISHING MEDIA: Nonflammable. SPECIAL FIRE FIGHTING PROCEDURES: When fire fighting conditions are severe and total thermal decomposition of the product is possible, wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. No unusual effects are anticipated during fire extinguishing operations. Avoid breathing the products and substances that may result from the thermal decomposition of the product or the other substances in the fire zone. Keep containers cool with water spray when exposed to fire to avoid rupture. UNUSUAL FIRE AND EXPLOSION HAZARDS: Exposure to extreme heat can give rise to thermal decomposition. See section 8, Health Hazard Data. NFPA HAZARD CODES: HEALTH: 1 FIRE: 0 REACTIVITY: 0 UNUSUAL REACTION HAZARD: none 4. REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY - MATERIALS TO AVOID: Finely divided active metals, Alkali and alkaline earth metals. HAZARDOUS POLYMERIZATION: Will Not Occur HAZARDOUS DECOMPOSITION PRODUCTS: See Health Hazard Data section. S. ENVIRONMENTAL INFORMATION SPILL RESPONSE: Observe precautions from other sections. In accordance with good industrial practice, provide exhaust ventilation for large spills or in confined spaces. Collect spilled material with an absorbent. Place in an approved container. RECOMMENDED DISPOSAL: As a disposal alternative, incinerate in the presence of a Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately 3M 3M General Offices 3M Center 04-80 St. Paul, N1\ 55144-1000 15325 1-900-364-3577 or (651) 737-6501 (24 hours) MATERIAL SAFETY DATA SHEET MSDS: FC -77 FLUORINERT Brand Electronic Liquid MAY 7, 1999 PAGE: 3 of 6 S. ENVIRONMENTAL INFORMATION (continued) combustible material in an industrial or commercial facility capable of handling halogenated waste. Reclaim if feasible. For information on product return, contact your distributor. ENVIRONMENTAL DATA: SUPPORTING DATA: Biodegradation: Chemical Oxygen Demand (COD): Nil 20 -Day Biochemical Oxygen Demand (BOD20): Nil Aquatic toxicity: Fathead minnow (Pimephales promelas) 96 -Hr. LL50: >1000 mg/L Water flea (Daphnia magna) 48 -Hr. EL50: >1500 mg/L REGULATORY INFORMATION: Volatile Organic Compounds: N/A. VOC Less H2O & Exempt Solvents: N/A. Since regulations vary, consult applicable regulations or authorities before disposal. U.S. Clean Water Act, Section 307, Toxic Pollutants = None. U.S. EPA Hazardous Waste Number = None (Not U.S. EPA Hazardous). The components of this product are in compliance with the chemical registration requirements of: TSCA, EINECS, CDSL, AICS, MITI. OTHER ENVIRONMENTAL INFORMATION: EPCRA 311/312 Reportable Quantity = Not Reportable. Transportation Information: Not regulated, all transportation modes.. This substance is resistant to biodegradation and is therefore likely to persist in the environment. This compound is completely fluorinated (perfluorinated), or it contains perfluorinated portions. Perfluoroalkyl groups resist degradation in most natural environments. This low -solubility substance has insignificant toxicity to aquatic organisms (Lowest LL50 or EL50 is >1000 mg/L). LL50 (Lethal Level) and EL50 are similar to LC50 and EC50, but tests the water phase from incompletely -miscible mixtures. Bioassays have been run on organisms from less than three phyla. Organisms from taxa that were not tested may show greater sensitivity. No data are available on the toxicity effects of this substance on wastewater treatment system organisms. EPCRA HAZARD CLASS: FIRE HAZARD: No PRESSURE: No REACTIVITY: No ACUTE: No CHRONIC: No 6. SUGGESTED FIRST AID EYE CONTACT: Immediately flush eyes with large amounts of water. Get immediate Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately 3M 3M General Offices 3M Center 04-80 St. Paul, MN 55144.1000 15326 1-800-364-3577 or(651)737-6501 (24 hours) MATERIAL SAFETY DATA SHEET MSDS: FC -77 FLUORINERT Brand Electronic Liquid MAY 7, 1999 PAGE: 4 of 6 6. SUGGESTED FIRST AID (continued) medical attention. SKIN CONTACT: Wash affected area with soap and water. INHALATION: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: No need for first aid is anticipated. OTHER FIRST AID: This product is not expected to be irritating to the eyes, skin or respiratory system at room temperature conditions. This assessment does not account for contaminants from product use. The suggested first aid measures are basic first aid measures for removal of foreign materials from the skin and/or eyes. 7. PRECAUTIONARY INFORMATION EYE PROTECTION: As a good industrial hygiene practice: Wear safety glasses with side shields. SKIN PROTECTION: Gloves are not required. VENTILATION PROTECTION: As a good industrial hygiene practice: For those situations where the fluid might be exposed to extreme overheating due to misuse or equipment failure, use with appropriate local exhaust ventilation sufficient to maintain levels of thermal decomposition products below their exposure guidelines (SEE SECTION 8). RESPIRATORY PROTECTION: Avoid prolonged breathing of vapors. If thermal decomposition occurs: Avoid breathing of thermal decomposition products. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: half -mask supplied air respirator, full -face supplied air respirator. PREVENTION OF ACCIDENTAL INGESTION: Not an expected route of exposure. RECOMMENDED STORAGE: Store under normal warehouse conditions. Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately 3M 311 General Offices 3M Center 04-80 St. Paul,,VIN 55144-1000 15327 1-900-364-3577 or (651) 737-6501 (24 hours) MATERIAL SAFETY DATA SHEET MSDS: FC -77 FLUORINERT Brand Electronic Liquid MAY 7, 1999 PAGE: 5 of 6 7. PRECAUTIONARY INFORMATION (continued) FIRE AND EXPLOSION AVOIDANCE: Nonflammable. OTHER PRECAUTIONARY INFORMATION: No smoking: Smoking while using this product can result in contamination of the tobacco and/or smoke and lead to the formation of the hazardous decomposition products mentioned in the Reactivity Data section of this MSDS. HMIS HAZARD RATINGS: HEALTH: 0 FLAMMABILITY: 0 REACTIVITY: 0 PERSONAL PROTECTION: X (See precautions, section 7.) EXPOSURE LIMITS INGREDIENTS VALUE UNIT TYPE AUTH SKINX PERFLUORO COMPOUNDS, (PRIMARILY COMPOUNDS WITH 8 CARBONS) .......... NONE NONE NONE NONE * SKIN NOTATION: Listed substances indicated with "Y" under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - AIHA: American Industrial Hygine Assoc. Workplace Environmental Exposure Level - NONE: None Established S. HEALTH HAZARD DATA EYE CONTACT: Contact with the eyes during product use is not expected to result in significant irritation. SKIN CONTACT: Contact with the skin during product use is not expected to result in significant irritation. INHALATION: Health effects from inhalation are not expected unless the product is over heated and decomposition occurs. IF SWALLOWED: Ingestion is not a likely route of exposure to this product. OTHER HEALTH HAZARD INFORMATION: If the product is exposed to extreme condition of heat from misuse or equipment failure, toxic decomposition products that include hydrogen fluoride and perfluoroisobutylene can occur. Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately 3M 3M General Offices MATERIAL SAFETY DATA SHEET 31N4 Center St. Paul, Y1\ 55144-1000 1-900-364-3577, or (651) 737-6501 (24 hours) MSDS: FC -77 FLUORINERT Brand Electronic Liquid MAY 7, 1999 8. HEALTH HAZARD DATA (continued) 04-80 15328 PAGE: 6 of 6 Hydrogen fluoride has an ACGIH threshold limit value of 3 parts per million parts of air, ppm, of fluoride as a ceiling limit and an OSHA PEL of 3 ppm of fluoride as an eight hour time -weighted average and 6 ppm of fluoride as a Short Term Exposure Limit. Perfluoroisobutylene has an ACGIH threshold limit value of 0.01 parts Per million parts of air as a ceiling limit or 0.082 milligrams per cubic meter as a ceiling limit. A 3M Product Toxicity Summary Sheet is available. EXPOSURE ROUTE SUMMARY OF TOXICITY FINDINGS Oral Dermal Eye Inhalation SECTION CHANGE DATES Practically Non -Toxic Minimally Irritating Practically Non -Irritating Practically Non -Toxic INGREDIENTS SECTION CHANGED SINCE FEBRUARY 16, 1999 ISSUE Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M General Offices 3M Center 04-80 St. Paul, MN 55144-1000 15329 1-800-364-3577 or (651) 737-6501 (24 hours) ********** THIS PACKET CONTAINS MSDS TEXTS FOR THE ********** FOLLOWING PURCHASE ORDERS: ********* **** 2674**** MATERIAL SAFETY DATA SHEET ALPHA METALS 1.300 Route 440 jersey City, NJ 07304 elephone: 201-434-6778 SECTION I - GENERAL INFORMATION :'RODUCT NAME 425 Thinner . NUMBER) ,CHEMICAL FAMILY Alcohol. J. 0. T HAZARD CLASS Flammable liquid. NUMBER: 199 REVISION: 10/31/94 SECTION II - HAZARDOUS INGREDIENTS INGREDIENTS CAS NUMBER WEIGHT - ---- ---- - ----- - - PERCENT Isopropyl Alcohol 67-63-0 100 ihis product is ------------- ---- - --- ;iazardous as defined n 29 CFR1910.1200. OSHA HAZARD -Eye irritant. SECTION III - PHYSICAL DATA :PUBLISHED or ESTIMATED VALUES) OSHA PEL ACGIH TLV 400 ppm 400 ppm Stel 500 ppm_ Stel 500 ppm SOILING POINT Deg. F. 180 SPECIFIC GRAVITY (H 0 = 1) 0.783 760 mm Hg)7 (@ 77 deg F) VAPOR PRESSURE 33 % VOLATILE by WEIGHT 100 (mm Hg AT 20 Deg. C.) VAPOR DENSITY (AIR= 1) 2.0 EVAPORATION RATE(BUAC = 2.3 1) :SOLUBILITY IN WATER Complete pH NA APPEARANCE AND ODOR Clear, colorless liquid, non -residual odor. SECTION IV - FIRE AND EXPLOSION HAZARD DATA r_STIMATED FLAMMABLE LIMITS (% By Volume in Air) LEL:2.0 UEL:12.0 ;-LASH POINT Deg. F. T.C.C. 54 EXTINGUISHING MEDIA Carbon dioxide or dry chemical. SPECIAL FIREFIGHTING Use NIOSH approved self-contained breathing apparatus PROCEDURES in enclosed area. UNUSUAL FIRE AND Vapors are heavier than air and may travel along EXPLOSION HAZARD ground. Never use welding torch on or near metal containers (even empty). SECTION V(a) - HEALTH HAZARD DATA (Symptoms/Effects of Overexposure) .Jii.:,LATTON: '-an cause nasai irritation, dizziness, nausea, headache. .;GEST:ON: Can cause gastrointestinal irritation, nausea, -,omitinc and diarrhea. Prolonged or repeated contact can cause de'attina and derma:i:is. Can cause severe irritation, wearing, ciurred -,rasion. 1iii inure eve tissue if not removed oromp:v. OGENS: done. SECTION V(b) - HEALTH HAZARD DATA (Emergency & First Aid Procedures) INHALATION If affected, remove individual to fresh air. If breathing is difficult, administer oxygen. Get medical attention. INGESTION Call physician or Poison Control Center immediately. DO NOT induce vomiting. Never give anything by mouth to an unconscious person. CONTACT Wash exposed area with soap and water. Remove contaminated clothing. ,,':YE CONTACT Flush eyes with large amount of water lifting upper and lower lids occasionally. Get prompt medical attention. SECTION VI - REACTIVITY DATA STABILITY CONDITIONS Heat, sparks and open flames. STABLE: X UNSTABLE: TO AVOID INCOMPATIBILITY Strong oxidizing agents. (Materials to Avoid) HAZARDOUS Carbon dioxide and carbon monoxide. DECOMPOSITION PRODUCTS IAZARDOUS POLYMERIZATION CONDITIONS TO NA VVILL OCCUR: WILL NOT OCCUR:X AVOID I SECTION VII - SPILL or LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL /S RELEASED OR SPILLED i,'! -LL SPT_LL. Absorb liquid: cn paper, -vermiculite, floor absorbent, or -::er absorbent _T.a erial ar:d transfer to hood. Ventilate area. .._ .G[. SPIT See section .1. 11ASTE DISPOSAL Destroy by approved incineration or deposit in approved landfill. Must be in accordance with Federal, State, and Local Laws and Regulation SECTION VIII - SPECIAL PROTECTION r;ESPIRATORY If threshold limit value is exceeded, use NIOSH approved respirator for organic vapors. EYEWEAR Chemical splash goggles in compliance with OSHA regulations are advised. Provide eye bath near work site. Always protect eyes. ::L0THING/GLOVES Wear resistant gloves such as rubber, neoprene or plastic. 1ENTILATION Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below TLVs. SECTION IX - SPECIAL PRECAUTIONS RECAUTIONS TO BE TAKEN IN HANDLING AND STORING Observe precautions for a flammable liquid. Keep container closed when not in use. Store away from ignition sources in cool dry area. Jse adequate ventilation. Read all container labeling. Use eye !protection. OTHER PRECAUTIONS: CONTAINERS: Since empty containers may retain product residues (vapor, liquid, or solid) all labeled hazard precautions must be observed. FOR INDUSTRIAL USE ONLY. KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. SECTION X - ADDITIONAL INFORMATION STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: (continued) LARGE SPILL: Ventilate area. Eliminate all ignition sources (flares, flames including pilot lights, electrical sparks), Persons not wearing protective equipment should be excluded from area of spill. Dike area of spill to prevent spreading. Pump liquid to salvage tank. Remaining liquid may be taken up clay or other absorbent material and shoveled into containers. ---------------------- REGULATORY INFORMATION ---------------------- Toxic Substance Control Act (TSCA) Status: All ingredients of this product are listed on the TSCA inventory. SARA TITLE III (Section 313): Components present in this product at a level which could require reporting under the statute are: None CALIFORNIA SCAQMD RULE 443.1 VOCS: Contains 782 grams/liter of Isopropyl Alcohol. CERCLA: If this product is accidentally spilled, it is not subject to any special reporting under the requirements of the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA). We recommend you contact local authorities to determine if there may be other local reporting requirements. SARA TITLE III (Sections 311/312): This product is classified into the following hazard categories; Immediate health. Delayed health. Fire. EMERGENCY TELEPHONE NUMBER CHEMTREC 1-800-424-9300 DAY or NIGHT The information contained herein is based on data considered accurate and is offered at no charge. No warranty is expressed or implied regarding the accuracy of this data. Liability is expressly disclaimed for loss or injury arising out of use of this information of the use of any materials designated. MATERIAL SAFETY DATA SHEET ALPHA METALS 600 Route 440 Jersey City, NJ 07304 Telephone: 201-434-6778 NUMBER: 587 REVISION: 02/22/97 SECTION I - GENERAL INFORMATION PRODUCT NAME 63Sn/37Pb Solder, Solid Bar or Wire (NUMBER) CHEMICAL FAMILY Inorganic Metals. D.O. T HAZARD CLASS Not regulated. SECTION II - HAZARDOUS INGREDIENTS INGREDIENTS CAS NUMBER WEIGHT OSHA PEL ACG/H TLV PERCENT Tin 7440-31-5 63 2.0 mg/cum 2.0 mg/cum Lead 7439-92_1 37 0.05 mg/cum _ 0.05 mgicum SECTION III - PHYSICAL DATA (PUBLISHED or ESTIMATED VALUES) BOILING POINT Deg. F. NA SPECIFIC GRAVITY (H 0 = I j NA (760 mm Hg) 1 VAPOR PRESSURE NA % VOLATILE by WEIGHT NA (mm Hg A T 20 Deg. C. ) VAPOR DENSITY (AIR= 1) NA EVAPORATION RATE NA SOLUBILITY IN WATER Insoluble pH NA APPEARANCE AND ODOR Silver-gray metal, odorless, solid bar or wire. SECTION IV - FIRE AND EXPLOSION HAZARD DATA ESTIMATED FLAMMABLE LIMITS (% By Volume in Air) LEL:NAUEL:NA FLASH POINT Deg. F. NA EXTINGUISHING MEDIA NA SPECIAL FIRE FIGHT/NG Use NIOSH/MSHA approved self-contained breathing PROCEDURES apparatus and full protective clothing if involved in a fire. UNUSUAL FIRE AND Moderate in the form of dust when exposed to heat EXPLOSION HAZARD or flame. When heated to high temperatures, lead emits highly toxic fumes. SECTION V(a) - HEALTH HAZARD DATA (Symptoms/Effects of Overexposure) LEAD: Exposure to high levels of airborne or ingested lead may produce Symptoms of anemia, insomnia, weakness, constipation, nausea and abdominal pain. Overexposure may cause damage to blood -forming, nervous, reproduc- tive, intestinal and urinary systems. For occupational exposure require- ments see 29 CFR 1910.1025 Lead Standard and its appendices. CHRONIC TOXICITY: Women of child bearing age should avoid exposure to Lead and its inorganic compounds due to post -natal effects. Lead can cause potential injury to a developing fetus and possible effects on re- production. For overexposure to TIN see Section X. LISTED CARCINOGENS: None of the metal elements of this product are confirmed as human carcinogens at this time by NTP, IARC, or OSHA. IARC classifies lead and some lead compounds as 23 carcinogens !possibly carcinogenic to humans). MEDICAL CONDITIONS POSSIBLY AGGRAVATED: See Section X. SECTION V(b) - HEALTH HAZARD DATA (Emergency & First Aid Procedures) INHALATION Lead: Excessive overexposure may result in an acute or chronic illness. If symptoms are present, the individual should be removed from exposure and a physician consulted. INGESTION Call a physician or Poison Control Center at once. SKIN CONTACT For hot metal burns, exposed area should be cooled with water and medical attention sought. After handling solid solder wire, bar, etc., wash thoroughly with soap and water. Dust, vapor and/or fume are not readily absorbed through the skin. EYE CONTACT Flush with water, contact a physician. Dust or fume may cause irritation. SECTION VI - REACTIVITY DATA STABILITY CONDITIONS NA STABLE: X UNSTABLE: TO AVOID INCOMPATIBILITY Oxidizing materials, acids, hydrogen peroxide >52%. (Materials to Avoid) HAZARDOUS Lead oxide and antimony oxide fume may be evolved at DECOMPOSITION temperatures greater than 1000 deg F (538 Q. PRODUCTS HAZARDOUS POLYMERIZATION CONDITIONS TO WILL OCCUR: WILL NOT OCCUR:X AVOID NA SECTION VII - SPILL or LEAK PROCEDURES STEPS TO BE TAKEN /N CASE MATERIAL IS RELEASED OR SPILLED Avoid inhalation of solder fume or dust. vacuuming or washing is recommended. Do not use dr_; sweeping or compressed air cleaning systems. WASTE DISPOSAL Scrap or waste solder should be recycled or stored in sealed containers for later disposal. Must be in accordance with Federal, State, and Local Laws and Regulation SECTION VIII - SPECIAL PROTECTION RESPIRATORY A NIOSH/MSHA approved dust/fume respirator should be worn where airborne exposures may exceed OSHA/ACGIH permissable air concen- trations. EYEWEAR Safety glasses and/or face protection is recommended for exposures to dust or splash of hot metal. CLOTHING/GLOVES Protective gloves should be worn to reduce burn exposure. Work clothes should be worn and laundered in accordance with current OSHA lead standards. VENTILATION Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below permissable air con- centrations. SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Food and drink should not be consumed or tobacco products used, nor cosmetics applied in areas where solder may be used. Always wash hands after handling solder and before eating, drinking or smoking. OTHER PRECAUTIONS: CONTAINERS: Since empty containers may retain product residues (vapor, liquid, or solid) all labeled hazard precautions must be observed. FOR INDUSTRIAL USE ONLY. KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. SECTION X - ADDITIONAL INFORMATION NOTES TO PHYSICIAN: Lead and its inorganic compounds are neurotoxins which may produce peripheral neuropathy. For an overview of the effects of lead expcsure, consult Occupational Safety and Health Administration Appendix A of Occupational Exposure to Lead (29CFR1910.1025). HEALTH HAZARD DATA: (continued) OVEREXPOSURE TO: TIN: Dust or fume may cause irritation of the skin, mucous membranes, and may result in a benign pneumoconiosis (stannosis). MEDICAL CONDITIONS POSSIBLY AGGRAVATED: Diseases of the blood and blood -forming organs, kidneys, nervous and possibly reproductive systems. ---------------------- REGULATORY INFORMATION ---------------------- California State Proposition 65: "WARNING! This product contains LEAD known to the State of California to cause cancer, birth defects or other reproductive harm." (See product label.) Toxic Substance Control Act (TSCA) Status: All ingredients of this product are listed on the TSCA inventory. SARA TITLE III (Section 313): Components that may be present in this product at a level which could require reporting under this statute are: Lead EMERGENCY TELEPHONE NUMBER CHEMTREC 1-800-424-9300 DAY or NIGHT The information contained herein is based on data considered accurate and is offered at no charge. No warranty is expressed or implied regarding the accuracy of this data. Liability is expressly disclaimed for loss or injury arising out of use of this information of the use of any materials designated. MATERIAL SAFETY DATA SHEET ALPHA METALS 600 Route 440 Jersey City, NJ 07304 Telephone: 201-434-6778 SECTION I - GENERAL INFORMATION NUMBER: 422 REVISION: 02/22/97 PRODUCT NAME Energized -Plus Rosin Core Solder (NUMBER) CHEM/CAL FAMILY Wire core solder D. 0. T HAZARD CLASS Not regulated SECTION II - HAZARDOUS INGREDIENTS INGREDIENTS CAS NUMBER WEIGHT OSHA PEL ACGIH TLV PERCENT Lead } Product contains 7439-92-1 * 0.05 mg/cum 0.05 mg/cum Tin one or more of 7440-31-5 2.0 mg/cum 2.0 mg/cum Silver } these metallic 7440-22-4 0.01 mg/cum 0.1 mg/cum Bismuth I elements in 7440-69-9 NE NE Antimony} varying 7440-36-0 0.5 mg/cum 0.5 mg/cum Indium percentages. 7440-74-6 NE 0.1 mg/cum Rosin 8050-09-7 1-4 i WEIGHT PERCENT: Composition of solder alloys vary widely therefore no weight percent or specific gravity is given. (See product label for composition.) Sensitizer, reduce exposure as low as possible. SECTION III - PHYSICAL DATA (PUBLISHED or ESTIMATED VALUES) BOILING POINT Deg. F. NA SPECIFIC GRAVITY (H20= 1) NA (760 mm Hg) (@ 77 deg F) VAPOR PRESSURE NA % VOLATILE by WEIGHT NA (mm Hg AT 20 Deg. C.) VAPOR DENSITY (AIR= 1) NA EVAPORATION RATE NA (BUAC = 1) SOLUBILITY IN WATER Insoluble pH NA APPEARANCE AND ODOR Silver-gray metal wire, odorless, various shapes and sizes. SECTION IV - FIRE AND EXPLOSION HAZARD DATA ESTIMATED FLAMMABLE LIMITS (% By Volume in Air) LEL: NA UEL: NA FLASH POINT Deg. F. NA EXTINGUISHING MEDIA NA SPECIAL FIREFIGHTING Use NIOSH approved self-contained breathing apparatus PROCEDURES and full protective clothing if involved in a fire. UNUSUAL FIRE AND When heated to high temperatures, lead emits highly EXPLOSION HAZARD toxic fumes. K, SECTION VW - HEALTH HAZARD DATA (Symptoms/Effects of Overexposure) INHALATION: Exposure to rosin fume may cause dizziness or headache. May also cause an allergic reaction such as rash or throat and respiratory irritation in a sensitive person. INGESTION: Essentially non -hazardous at room temperature. (NOT likely to occur.) SKIN: Molten core solder will cause burns. Repeated exposure to rosin fume may cause a skin rash. EYES: Molten rosin core flux will cause eye burns. Rosin fume can cause eye irritation. TOXICITY: See Section X. LISTED CARCINOGENS: None MEDICAL CONDITIONS POSSIBLY AGGRAVATED: Chemical hypersensitivity and diseases of the lungs. SECTION V(b) - HEALTH HAZARD DATA (Emergency & First Aid Procedures) INHALATION If rosin fume is inhaled when wire is heated to soldering temperatures, remove individual to fresh air. If breathing is difficult administer oxygen and consult a physician. INGESTION Call physician or Poison Control Center immediately. Never give anything by mouth to an unconscious person. SKIN CONTACT For burns cool with water and obtain medical aid. For rash, remove from exposure and consult a physician. EYE CONTACT For burns flush immediately with cool water and obtain medical aid. For fume irritation remove from exposure. SECTION VI - REACTIVITY DATA STABILITY CONDITIONS None STABLE: X UNSTABLE. TO AVOID INCOMPATIBILITY Oxidizing materials, strong acids. (Materials to Avoid) HAZARDOUS Thermal decomposition may produce CO, CO2, abietic DECOMPOSITION acid, aliphatic aldehydes, terpenes and other acids. PRODUCTS HAZARDOUS POLYMERIZATION CONDITIONS TO WILL OCCUR: WILL NOT OCCUR:X AVOID None SECTION VII - SPILL or LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Solid at room temperature. If in molten state allow to cool and solidify and then scrape up. WASTE DISPOSAL The alloy portion is reclaimable. Must be in accordance with Federal, State, and Local Laws and Regulation SECTION VIII - SPECIAL PROTECTION RESPIRATORY If threshold limit value is exceeded or ventilation is not adequate to remove smoke from the breathing zone, than a NIOSH/MSHA approved, cartridge type respirator should be worn. EYEWEAR When soldering use face shield or eye goggles. CLOTHING/GLOVES Not usually necessary. VENTILATION Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure levels below TI -Vs. SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING No special requirements for storage. Read all container labeling. Food and drink should not be consumed or tobacco products used, nor cosmetics applied in areas where core solders may be used. Always wash hands after handling core solder and before eating, drinking or smoking. OTHER PRECAUTIONS: CONTAINERS: Since empty containers may retain product residues (vapor, liquid, or solid) all labeled hazard precautions must be observed. FOR INDUSTRIAL USE ONLY. KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. SECTION X - ADDITIONAL INFORMATION NOTES TO PHYSICIAN: Lead and its inorganic compounds are neurotoxins which may produce peripheral neuropathy. For an overview of the effects of lead exposure, consult Occupational Safety and Health Administration Apprndix A of Occupational Exposure to Lead (29CFR1910.1025). HEALTH HAZARD DATA: (continued) LEAD TOXICITY: Molten solder alloys do not produce significant lead fume below 900 deg F. Exposure to high levels of airborne or ingested lead may produce symptoms of anemia, insomnia, weakness, constipation, nausea and abdominal pain. Overexposure may cause damage to blood -forming, nervus, reproductive, intestinal and urinary systems. For occupational exposure requirements see 29 CFR 1910.1025 Lead Standard and its appendices. Women of child bearing age should avoid exposure to lead and its inorganic compounds due to post -natal effects. Lead can cause potential injury to a developing fetus and possibly effect reproduction. TIN, SILVER, BISMUTH, ANTIMONY AND INDIUM TOXICITY: Overexposure to these elements is not expected. ---------------------- REGULATORY INFORMATION ---------------------- California State Proposition 65: "WARNING! This product contains LEAD known to the State of California to cause cancer, birth defects or other reproductive harm." Toxic Substance Control Act (TSCA) Status: All ingredients of this product are listed on the TSCA inventory. SARA TITLE III (Section 313): Components that may be present in this product at a level which could require reporting under the statute are: Lead - Silver - Antimony EMERGENCY TELEPHONE NUMBER CHEMTREC � 1-800-424-9300 DAY or NIGHT The information contained herein is based on data considered accurate and is offered at no charge. No warranty is expressed or implied regarding the accuracy of this data. Liability is expressly disclaimed for loss or injury arising out of use of this information of the use of any materials designated. 01/12/2001 18:51 5085874514 CAST COAT INC PAGE 05 CAST -COAT, INC. MATERIAL SAFETY DATA SREST MATERIAL NAME: CC3-1200 WHITE MFILLED PAGE 1 OF 4 TELEPHONE NUMBER: (5081 587-4502 FAX NUMBER: (508) 587-4514 ------------------------------------------------------------------------------------------- SECTION 1 GAMRAL INFORMATION --------------------------------------------- MANUFACTURER'S NAME: CAST -COAT, INC. ADDRESS: 354 WEST STREET, W. BRIDGEWATER, MA 02379 PROPER SHIPPING NAME(49CFR 172.101): NONE D.O.T. HAZARD NAME(49CFR 172.101): NONE D.O.T_ ID NO.(49CFR 172.101); NONE D.O.T. HAZARD CLASS(49CFR 172.101); NONE RCRA HAZARD CLASS(49CFR 172.101): NON HAZARDOUS E.P.A. PRIORITY POLLUTANTS(40CFR 122.53): NONE NFPA = NATIONAL FIRE PROTECTION ASSOCIATION: HEALTH (NFPA): 0 FLAMMABILITY (NFPA): 1 REACTIVITY (NFPA): 0 CAS NO: MIXTURE GENERIC DESCRIPTION: LIQUID SILICONE RUBBER ------------------------------------------------------------------------------------------- SECTION 2 HAZARDOUS INGREDIENTS ------------------------------------------------------------------------------------------- INGREDIENTS I TLV (UNITS) CASA 1. NONE 2. 3. 4 5. 6. ONLY THOSE INGREDIENTS LISTED IN THIS SECTION HAVE BEEN DETERMINED TO BE HAZARDOUS AS DEFINED IN 29 CFR 1910.1200. AN INGREDIENT WITH AN ASTERISK (*) IS ALSO LISTED IN 29 CFR 1910.1200(D)(4) AS KNOWN OR SUSPECTED CARCINOGEN. COMMENTS: NONE ------------------------------------------------------------------------------------------- SECTION 3 HEALTH HAZARD DATA ----------------------------------------------------------------------------------------- ORAL LD50: NONE ESTABLISHED DERMAL LD50: NONE ESTABLISHED SPI CLASS: NONE IRRITATION -SKIN: SLIGHT IRRITATION (RABBITS) IRRITATION -EYES: SLIGHT IRRITATION (RABBITS) SENSITIZATION: NONE TLV: NONE ESTABLISHED RESPIRATORY: NONE LIKELY UNLESS HEATED TO HIGH TEMPERATURE EFFECTS OF EXPOSURE: CONTACT WITH SKIN OR EYES MAY CAUSE TEMPORARY IRRITATION COMMENTS: NONE 01/12/2001 18:51 5085874514 CAST COAT INC PAGE 06 :._� . GST -COAT, INC. MATERIAL SAFETY DATA SHEET MF+TERIAL NAME: CC3-1200 WHITE UNFILLED PAGE 2 OF 4 ------------------------------------------------------------------------------------------- SECTION 4 3"RGENCY FIRST AID PROCEDURES ------------------------------------------------------------------------------------------- EYES: IMMEDIATELY FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN. SKIN: PROMPTLY WASH WITH SOAP AND WATER. ORAL: IF CONSCIOUS, GIVE LARGE QUANTITIES OF WATER OR MILK, INDUCE VOMITING. CALL A PHYSICIAN. COMMENTS: PROMPTLY REMOVE CONTAMINATED CLOTHING, WASH BEFORE REUSE. DESTROY CONTAMINATED LEATHER AND ABSORBENT SHOES. ------------------------------------------------------------------------------------------- SECTION 5 FIRS AND EXPLOSION DATA ------------------------------------------------------------------------------------------- FLASHPOINT: 435-F METHOD USED: TOC AUTOIGNITION TEMPERATURE: NOT DETERMINED FLAMMABILITY LIMITS IN AIR (LEL): NONE ESTABLISHED (UEL): NONE ESTABLISHED EXTINGUISHING MEDIA: CARBON DIOXIDE, FOAM, DRY CHEMICAL, WATER SPRAY. SP5C=�L =IRE FIGHTING PROCEDURES: USE SELF-CONTAINED BREATHING APPARATUS. UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE KNOWN TO CAST -COAT, INC. COMMENTS: NONE ------------------------------------------------------------------------------------------- SECTION 6 PHYSICAL DATA BOILING POINT 4) 760MM HG,�C: >100 SPECIFIC GRAVITY (4 25-C: 1.20 MELTING POINT: NOT APPLICABLE VAPOR PRESSURE wR 25'C,MMHG: <0.1 VAPOR DENSITY Q 25'C(AIR=1): >1 PERCENT VOLATILE BY VOLUME, EVAPORATION RATE (BUTYL ACETATE=1): <1 SOLUBILITY IN WATER, INSOLUBLE ODOR: BLAND ODOR APPEARANCE: LIQUID COLOR: WHITE COMMENTS: NONE NOTE: THE ABOVE INFORMATION IS NOT INTENDED FOR USE IN PREPARING PRODUCT SPECIFICATIONS. CONTACT CAST -COAT, INC. BEFORE WRITING SPECIFICATIONS. 01/12/2001 18:51 5085874514 CAST COAT INC PAGE 07 CAST -COAT, INC. MATERIAL SAFETY DATA SHBET MATERIAL NAME: CC3-1200 WHITE UNFILLED PAGE 3 OF 4 ------------------------------------------------------------------------------------------- SECTION 7 REACTIVITY DATA ------------------------------------------------------------------------------------------- STABILITY: STABLE INCOMPATABILITY (MATERIALS TO AVOID): STRONG OXIDIZING AGENTS CONDITIONS TO AVOID: NOT APPLICABLE HAZARDOUS DECOMPOSITION MATERIALS: CARBON MONOXIDE, CARBON DIOXIDE, SILICONE OXIDES. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR COMMENTS: NONE SECTION 8 SPILL, LEAK AND DISPOSAL PROCEDURES ------------------------------------------------------------------------------------------- STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: AVOID ALL PERSONAL CONTACT. TAKE UP WITH ABSORBENT MATERIAL. SHOVEL INTO CLOSABLE CONTAINERS. WEAR PROTECTIVE CLOTHING DURING CLEAN UP. PROTECTIVE EQUIPMENT EYES: WEAR PROTECTIVE EYEWEAR. SKIN: WEAR IMPERVIOUS GLOVES. WEAR APPROPRIATE EQUIPMENT TO PREVENT SKIN CONTACT. INHALATION: USING A NIOSH APPROVED RESPIRATOR SUITABLE FOR ORGANIC VAPORS, IS NOT NECESSARY WITH PROPER VENTILATION. WASTE DISPOSAL METHOD: CAST -COAT, INC. RECOMMENDS THAT ALL LOCAL, STATE, AND FEDERAL REGULATIONS CONCERNING HEALTH AND POLLUTION BE REVIEWED TO DETERMINE APPROPRIATE DISPOSAL PROCEDURE. COMMENTS: FOLLOWING GOOD HOUSEKEEPING PROCEDURES IS RECOMMENDED. 01112/.2001 18:51 5085874514 CAST COAT INC PAGE 08 CAST -COAT, INC. MATERIAL SAFETY DATA SHEET MATERIAL NAME: CC3-1200 WHITS UNFILLED SECTION 9 ROUTINE HANDLING PRECAUTIONS PAGE 4 OF 4 PROTECTIVE EQUIPMENT - EYES: WEAR PROTECTIVE EYEWEAR. PROTECTIVE CLOTHING - SKIN*: WEAR GLOVES IMPERVIOUS TO THIS MATERIAL. WEAR APPROPRIATE EQUIPMENT TO PREVENT SKIN CONTACT. INHALATION: USING NIOSH APPROVED RESPIRATOR SUITABLE FOR ORGANIC VAPORS, IS NOT REQUIRED WITH PROPER VENTILATION. LOCAL EXHAUST: RECOMMENDED MECHANICAL (GENERAL): RECOMMENDED COMMENTS: USE GOOD HOUSEKEEPING PROCEDURES. THESE PRECAUTIONS ARE FOR ROOM TEMPERATURE HANDLING, USE AT ELEVATED TEMPERATURE MAY REQUIRE ADDED PRECAU'-IONS. * GOOD PRACTICE REQUIRES THAT GROSS AMOUNTS OF ANY CHEMICAL BE REMOVED FROM THE SKIN AS SOON AS PRACTICAL, ESPECIALLY BEFORE EATING OR SMOKING. ------------------------------------------------------------------------------------------- SECTION 10 SPECIAL PRECAUTIONS ------------------------------------------------------------------------------------------- PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: STORE IN COOL, DRY AREA IN CLOSED CONTAINERS. OTHER PRECAUTIONS: NONE COMMENTS: NONE THESE DATA ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT AS A PRODUCT SPECIFICATION. NO WARRANTY, EITHER EXPRESSED OR IMPLIED, IS HEREBY MADE. THE RECOMMENDED INDUSTRIAL HYGIENE AND SAFE HANDLING PROCEDURES ARE BELIEVED TO BE GENERALLY APPLICABLE. HOWEVER, EACH USER SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE INTENDED USE Pai'D DETERMINE WHETHER THEY ARE APPROPRIATE. PREPARED BY: R.S. LOTHROP TITLE: TECHNICAL DIRFCTOR LAST REVISION DATE: 01/05/01 PREVIOUS REVISION DATE: 02/11/99 DATE: Jan 12, 2001 -01/1/2001 16:39 5085874514 CAST COAT INC PAGE 06 CAST -COAT, INC. XKTERIAL SAFETY DATA SHIRT MATERIAL NAME: H-23 CATALYST PAGE 1 OF 4 TELEPHONE NUMBER: (508) 587-4502 FAX NUMBER. (508) 587-4514 ------------------------------------------------------------------------------------------- SECTION 1 GENERAL INFORMATION ------------------------------------------------------------------------------------------- MANUFACTURER'S NAME: CAST -COAT, INC. ADDRESS: 354 WEST STREET, W. BRIDGEWATER, MA 02379 PROPER SHIPPING NAME(49CFR 172.101): NONE D.O.T. HAZARD NAME(49CFR 172.101): NONE D.O.T. ID NO.(49CFR 172.101): NONE D.O.T. HAZARD CLASS(49CFR 172.101): NON -HAZARDOUS RCRA HAZARD CLASS(49CFR 172.101): NONE E.P.A. PRIORITY POLLUTANTS(40CFR 122.53): NOT AVAILABLE NFPA = NATIONAL FIRE PROTECTION ASSOCIATION: HEALTH (NFPA): 0 FLAMMABILITY (NFPA): 1 REACTIVITY (NFPA): 0 CAS NO: MIXTURE GENERIC DESCRIPTION: LIQUID SILICONE RUBBER CATALYST ------------------------------------------------------------------------------------------- SECTION 2 HAZARDOUS INGREDIENTS ------------------------------------------------------------------------------------------- 7NGREDIENTS $ TLV (UNITS) CAS 1, NONE 3. 4. 5. 6. ONLY THOSE INGREDIENTS LISTED IN THIS SECTION HAVE BEEN DETERMINED TO BE HAZARDOUS AS DEFINED IN 29 CFR 1910.1200. AN INGREDIENT WITH AN ASTERISK (*) IS ALSO LISTED IN 29 CFR 1910.1200(D)(4) AS Y"NOWN OR SUSPECTED CARCINOGEN. COMMENTS: NONE ------------------------------------------------------------------- ------ SECTION 3 HEALTH HAZARD DATA ------------------------------------------------------------------------------------------* ORAL LD50; NONE ESTABLISHED DERMAL LD50: NONE ESTABLISHED SPI CLASS: NONE IRRITATION -SKIN: SLIGHT IRRITATION (RABBITS) IRRITATION -EYES: SLIGHT IRRITATION (RABBITS) SENSITIZATION: NONE TLV: NONE ESTABLISHED RESPIRATORY: NONE LIKELY UNLESS HEATED TO HIGH TEMPERATURE EFFECTS OF EXPOSURE: CONTACT WITH SKIN OR EYES MAY CAUSE TEMPORARY IRRITATION COKM2NTS : NONE "01/12/2001 18:39 5085874514 CAST COAT INC PAGE 07 CAST -COAT, INC. MATERIAL SAFETY DATA SHEET MATERIAL NAME: H-23 CATALYST PAGE 2 OF 4 ------------------------------------------------------------------------------------------- SECTION 4 EMERGENCY FIRST AID PROCEDURES EYES: IMMEDIATELY FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN. SKIN: PROMPTLY WASH WITH SOAP AND WATER. ORAL: IF CONSCIOUS, GIVE LARGE QUANTITIES OF WATER OR MILK, INDUCE VOMITING. CALL A PHYSICIAN. COMMENTS: PROMPTLY REMOVE CONTAMINATED CLOTHING, WASH BEFORE REUSE. DESTROY CONTAMINATE LEATHER AND ABSORBENT SHOSS. ------------------------------------------------------------------------------------------- SECTION 5 FIRE AND EXPL08ION DATA ------------------------------------------------------------------------------------------- ?LASHPOINT 495'F METHOD USED: TOC AUTOIGNITION TEMPERATURE: NOT DETERMINED FLAMMABILITY LIMITS IN AIR (LEL): NONE ESTABLISHED (UEL) NONE ESTABLISHED EXTINGUISHING MEDIA: CARBON DIOXIDE, FOAM, DRY CHEMICAL, WATER SPRAY, SPECIAL FIRE FIGHTING PROCEDURES: USE SELF-CONTAINED BREATHING APPARATUS. UNUSUAL FIRE AND EX?LOSION HAZARDS: NONE KNOWN TO CAST -COAT, INC. CC`,MSNTS : NONE --------------------------------------------------------------------------- SECTION 6 PHYSICAL DATA BOILING POINT Q^ 760MM 14G,'C: >100 SPECIFIC GRAVITY @ 25'C: 1.45 MELTING POINT: NOT APPLICABLE VAPOR PRESSURE @ 25-C,MMEG: <0.1 VAPOR DENSITY 4 25-C(AIR=1): >1 PERCENT VOLATILE BY VOLUME, t: <1 EVAPORATION RATE (BUTYL ACETATE=1); <1 SOLUBILITY IN WATER, INSOLUBLE ODOR: METALLIC APPEARANCE: LIQUID COLOR: BLUE CONIIVtENTS : NONE NOTE: THE ABOVE INFORMATION IS NOT INTENDED FOR USE IN PREPARING PRODUCT SPECIFICATIONS. CONTACT CAST -COAT, INC. BEFORE WRITING SPECIFICATIONS. '01/1212001 18:39 5065874514 CAST COAT INC PAGE 08 CAST -COAT, INC. MATERIAL SAPBTY DATA SHEET MATERIAL NAME: H-23 CATALYST PAGE 3 OF 4 ------------------------------------------------------------------------------------------- SECTION 7 REACTIVITY DATA ------------------------------------------------------------------------------------------- STABILITY: STABLE INCOMPATABILITY (MATERIALS TO AVOID): STRONG OXIDIZING AGENTS CONDITIONS TO AVOID: NOT APPLICABLE HAZARDOUS DECOMPOSITION MATERIALS: CARBON MONOXIDE, CARBON DIOXIDE, SILICONE OXIDES. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR COMMENTS: NONE -------------------------------------------------------------------------------------- SECTION B SPILL, LEAK AND DISPOSAL PROCEDURES ------------------------------------------------------------------------------------------- STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: AVOID ALL PERSONAL CONTACT. TAKE UP WITH ABSORBENT MATERIAL. SHOVEL INTO CLOSABLE CONTAINERS. WEAR PROTECTIVE CLOTHING DURING CLEAN UP. PRCTECTIVE-0UIPMENT EYES: WEAR SPLASH PROOF, CHEMICAL GOGGLES. SKIN: WEAR IMPERVIOUS GLOVES. WEAR APPROPRIATE EQUIPMENT TO PREVENT SKIN CONTA-C7... INHALATION: USE NIOSH APPROVED RESPIRATOR SUITABLE FOR ORGANIC VAPORS, IF REQUIRED. WASTE DISPOSAL METHOD: CAST -COAT, INC. RECOMMENDS THAT ALL LOCAL, STATE, AND FEDERAL REGULATIONS CONCERNING HEALTH AND POLLUTION BE REVIEWED TO DETERMINE APPROPRIATE DISPOSAL PROCEDURES. COMMENTS: NONE '01/127 2001 18:39 5085874514 CAST COAT INC PAGE 09 CAST -COAT, INC. MATERIAL SAFETY DATA SHBBT MATERIAL NAME: H-23 CATALYST PAGE 4 OF 4 ------------------------------------------------------------------------------------------- SECTION 9 ROUTINE HANDLING PRECAUTIONS PROTECTIVE EQUIPMENT - EYES WEAR SPLASH PROOF, CHEMICAL GOGGLES. PROTECTIVE CLOTHING - SKIN•: WEAR GLOVES AND CLOTHING IMPERVIOUS TO THIS MATERIAL. INFALATION: WEAR FULL FACE NIOSH APPROVED RESPIRATOR IN ABSENCE OF VENTILATION. VENTILATION LOCAL EXHAUST: NOT REQUIRED MECHANICAL (GENERAL): RECOMMENDED SUITABLE RESPIRATOR: NIOSH APPROVED FULL FACE RESPIRATOR SUITABLE FOR ORGANIC VAPORS COMMENTS: '.NONE THESE PRECAUTIONS ARE FOR ROOM TEMPERATURE HANDLING, USE AT ELEVATED TEMPERATURE MAY REQUIRE ADDED PRECAUTIONS. * GOOD PRACTICE REQUIRES THAT GROSS AMOUNTS OF ANY CHEMICAL BE REMOVED FROM THE SKIN AS SOON AS PRACTICAL, ESPECIALLY BEFORE EATING OR SMOKING. ------------------------------------------------------------------------------------------- SECTION 10 SPECIAL PRECAUTIONS --------------------------------------- - - - - -- PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: STORE IN COOL, DRY AREA IN CLOSED CONTAINERS. OTHER PRECAUTIONS: NONE COMMENTS: NONE THESE DATA ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT AS A PRODUCT SPECIFICATION. NO WARRANTY, EITHER EXPRESSED OR IMPLIED, IS HEREBY MADE. THE RECOMMENDED INDUSTRIAL HYGIENE AND SAFE HANDLING PROCEDURES ARE BELIEVED TO BE GENERALLY APPLICABLE. HOWEVER, EACH USER SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE INTENDED USE AND DETERMINE WHETHER THEY ARE APPROPRIATE. PREPARED BY: R.S. LOTHROP TITLE: TECHNICAL DIRECTOR LAST REVISION DATE: 01/05/01 PREVIOUS REVISION DATE: 01/05/00 DATE: Jan 12, 2001 CAST -COAT, INC. MATERIAL SAFETY DATA SHEET MATERIAL NAME: CC3-1291 PRIMER PAGE 1 OF 4 TELEPHONE NUMBER: (508)5�7-4502 FAX NUMBER: (508) J87-4514 ---------------------------------------�y�lt;+sM1fr-'_•--------------_------......-......-_-.- SECTION 1 GENERAL INFORMATION ------------------------------------------------------------------------------------------- MANUFACTURER'S NAME: CAST -COAT, INC. ADDRESS: 354 WEST STREET, W. BRIDGEWATER, MA 02379 PROPER SHIPPING NAME(49CFR 172.101): FLAMMABLE LIQUID N.O.S. D.O.T. HAZARD NAME(49CFR 172.101): LIQUID PRIMER D.O.T. ID NO.(49CFR 172.101): UN 1993 D.O.T_ HAZARD CLASS(49CFR 172.101): 3 RCRA HAZARD CLASS(49CFR 172.101): PACKING GROUP III E.P.A. PRIORITY POLLUTANTS(40CFR 122.53): NOT AVAILABLE NFPA z NATIONAL FIRE PROTECTION ASSOCIATION: HEALTH (NFPA): 2 FLAMMABILITY (NFPA): 3 REACTIVITY (NFPA): 0 CAS N0: MIXTURE GENERIC DESCRIPTION: LIQUID RTV SILICONE PRIMER ------------------------------------------------------------------------------------------- SECTION Z HAZARDOUS INGREDIENTS ------------------------------------------------------------------------------------------- INGREDIENTS t TLV (UNITS) CAS 1, ACETONE 25 - 4S 1000 67-64-1 2. TOLUENE 10 - 30 100 108-88-3 3. ISOPROPYL ALCOHOL 15 - 40 400 67-63-0 4- 5. 6. ONLY THOSE INGREDIENTS LISTED IN THIS SECTION HAVE BEEN DETERMINED TO BE HAZARDOUS AS DEFINED IN 29 CFR 1910.1200. AN INGREDIENT WITH AN ASTERISK (}) IS ALSO LISTED IN 29 CFR 1910.1200(D)(4) AS KNOWN OR SUSPECTED CARCINOGEN. COMMENTS: NONE ------------------------------------------------------------------------------------------- SECTION 3 HEALTH HAZARD DATA --------------------------------------7---------------------------------------------------- ORAL LD50: NOT DETERMINED DERMAL LD50: NOT DETERMINED SPI CLASS: NONE IRRITATION -SKIN: DRYING OF SKIN AND ALLERGIC REACTION IRRITATION -EYES: MAY CAUSE IRRITATION SENSITIZATION: MODERATE SENSITIZER TLV: 200 PPM RESPIRATORY: EXCESS INHALATION CAUSES HEADACHES, DIZZINESS, NAUSEA EFFECTS OF EXPOSURE: CONTACT WITH SKIN OR EYES MAY CAUSE TEMPORARY IRRITATION COMMENTS: NONE TO 39Cd ONI lCOO 1SCO VTSVL39309 TS:8T T00Z/ZT/T0 01112/2001 18:51 5085874514 CAST COAT INC PAGE 02 CAST -COAT, INC. MATERIAL SAFETY DATA SHEET MATERIAL NAME: CC3-1291 PRIMER PAGE 2 OF 4 ------------------------------------------------------------------------------------------- SECTION 4 EMERGENCY FIRST AID PROCEDURES ------------------------------------------------------ EYES: IMMEDIATELY FLUSH EYES WITH WATER FOR AT LEAST 30 MINUTES. PROMPT MEDICAL ATTENTION IS ESSENTIAL. SKIN: PROMPTLY WASH WITH SOAP AND WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN IF NECESSARY. ORAL: IF CONSCIOUS, GIVE LARGE QUANTITIES OF WATER OR MILK, INDUCE VOMITING, CALL A PHYSICIAN. COMMENTS: PROMPTLY REMOVE CONTAMINATED CLOTHING, WASH BEFORE REUSE. DESTROY CONTAMINATED LEATHER AND ABSORBENT SHOES. ------------------------------------------------------------------------------------------- SECTION 5 FIRE AND EXPLOSION DATA ------------------------------------------------------------------------------------------- FLASHPOINT: 56'F METHOD USED: TCC AUTOIGNITION TEMPERATURE: NONE ESTABLISHED FLAMMABILITY LIMITS IN AIR (LEL): 2.5 (UEL): 11.0 EXTINGUISHING MEDIA: CARBON DIOXIDE, FOAM, DRY CHEMICAL, WATER SPRAY. SPECIAL FIRE FIGHTING PROCEDURES: USE SELF-CONTAINED BREATHING APPARATUS. UNUSUAL FIRE AND EXPLOSION HAZARDS: VAPOR FORMS EXPLOSIVE MIXTURE WITH AIR. COMMENTS: NONE --------------------------------------------------------------- SECTION 6 PHYSICAL DATA ------------------------------------------------------------------------------------------- BOILING POINT @ 760MM HG,�C: 160'F SPECIFIC GRAVITY @ 25-C: 0.85 MELTING POINT: NOT AVAILABLE VAPOR PRESSURE @ 25-C,MMHG: NOT AVAILABLE VAPOR DENSITY Q 25'C(AIR=i): 2.0 PERCENT VOLATILE BY VOLUME, k: 71 EVAPORATION RATE (BUTYL ACETATEx1): NOT AVAILABLE SOLUBILITY IN WATER, $: MODERATE ODOR: PUNGENT APPEARANCE: CLEAR LIQUID COLOR: COLORLESS COMMENTS: NONE NOTE: THE ABOVE INFORMATION IS NOT INTENDED FOR USE IN PREPARING PRODUCT SPECIFICATIONS. CONTACT CAST -COAT, INC. BEFORE WRITING SPECIFICATIONS. 01/12/2001 18:51 5065874514 CAST COAT INC PAGE 03 CAST -COAT, INC. MATERIAL SAFETY DATA SHEET MATERIAL NAME: CC3-1291 PRIMER PAGE 3 OF 4 ------------------------------------------------------------------------------------------- SECTION 7 REACTIVITY DATA ------------------------------------------------------------------------------------------- STABILITY: STABLE INCOMPATABILITY (MATERIALS TO AVOID): STRONG OXIDIZING AGENTS CONDITIONS TO AVOID: HEAT, SPARKS, OPEN FLAME HAZARDOUS DECOMPOSITION MATERIALS: THERMAL DECOMPOSITION MAY PRODUCE CARBON DIOXIDE, SILICONE OXIDES HAZARDOUS POLYMERIZATION: WILL NOT OCCUR COMMENTS: NONE SECTION 8 SPILL, LEAK AND DISPOSAL PROCEDURES ------------------------------------------------------------------------------------------- STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: AVOID ALL PERSONAL CONTACT_ TAKE UP WITH ABSORBENT MATERIAL, SHOVEL INTO CLOSABLE CONTAINERS. WEAR PROTECTIVE CLOTHING DURING CLEAN UP. PROTECTIVE EQUIPMENT EYES: WEAR SPLASH PROOF, CHEMICAL GOGGLES. SKIN: WEAR IMPERVIOUS GLOVES, WEAR APPROPRIATE EQUIPMENT TO PREVENT SKIN CONTACT. INHALATION: USE NIOSH APPROVED RESPIRATOR SUITABLE FOR ORGANIC VAPORS, IF REQUIRED. WASTE DISPOSAL METHOD: CAST -COAT, INC. RECOMMENDS THAT ALL LOCAL, STATE, AND FEDERAL REGULATIONS CONCERNING HEALTH AND POLLUTION BE REVIEWED TO DETERMINE APPROPRIATE DISPOSAL PROCEDURES. COMMENTS: NONE 01/12/2001 18:51 5085874514 CAST COAT INC PAGE 04 y CAST -COAT, INC. MATERIAL SAFETY DATA SHEET MATERIAL NAME: CC3-1291 PRIMER PAGE 4 OF 4 ------------------------------------------------------------------------------------------- SECTION 9 ROUTINE HANDLING PRECAUTIONS ------------------------------------------------------------------------------------------- PROTECTIVE EQUIPMENT - EYES: WEAR SPLASH PROOF, CHEMICAL GOGGLES. DO NOT WEAR CONTACT LENSES. PROTECTIVE CLOTHING - SKIN*: WEAR GLOVES AND CLOTHING IMPERVIOUS TO THIS MATERIAL. INHALATION: WEAR FULL FACE NIOSH APPROVED RESPIRATOR IN ABSENCE OF VENTILATION. VENTILATION LOCAL EXHAUST: RECOMMENDED MECHANICAL (GENERAL): RECOMMENDED SUITABLE RESPIRATOR: NIOSH APPROVED FULL FACE RESPIRATOR SUITABLE FOR ORGANIC VAPORS. COMMENTS: NONE THESE PRECAUTIONS ARE FOR ROOM TEMPERATURE HANDLING,USE AT ELEVATED TEMPERATURE MAY REQUIRE ADDED PRECAUTIONS. *GOOD PRACTICE REQUIRES THAT GROSS AMOUNTS OF ANY CHEMICAL BE REMOVED FROM THE SKIN AS SOON AS PRACTICAL, ESPECIALLY BEFORE EATING OR SMOKING. ------------------------------------------------------------------------------------------- SECTION 10 SPECIAL PRECAUTIONS ------------------------------------------------------------------------------------------- PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: STORE IN COOL, DRY AREA IN CLOSED CONTAINERS AWAY FROM HEAT, SPARKS AND OPEN FLAME OTHER PRECAUTIONS: NONE COMMENTS: NONE THESE DATA ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT AS A PRODUCT SPECIFICATION. NO WARRANTY, EITHER EXPRESSED OR IMPLIED, IS HEREBY MADE. THE RECOMMENDED INDUSTRIAL HYGIENE AND SAFE HANDLING PROCEDURES ARE BELIEVED TO BE GENERALLY APPLICABLE. HOWEVER, EACH USER SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE INTENDED USE AND DETERMINE WHETHER THEY ARE APPROPRIATE. PREPARED BY: R.S. LOTHROP TITLE: TECHNICAL DIRECTOR LAST REVISION DATE: 01/05/01 PREVIOUS REVISION DATE: 02/11/99 DATE: Jan 12, 2001 ,@?.:/12/p2001 18:39 5085874514 CAST COAT INC PAGE 02 CAST -COAT, INC. MATERIAL SAFETY DATA SHEET MATERIAL NAME: H-34 HARDENER PAGE 1 OF 4 TELEPHONE NUMBER: (508) 587-4502 FAX NUMBER: (508) 581-4514 ---------------------------------------------------------------------- SECTION 1 GENERAL INFORMATION MANUFACTURER'S NAME: CAST -COAT, INC. ADDRESS: 354 WEST STREET, W. BRIDGEWATER, MA 02379 PROPER SHIPPING NAME(49CFR 172.101): CORROSIVE LIQUID N.O.S. D.O.T. HAZARD NAME(49CFR 172.101): LIQUID HARDENER D.O.T. ID N0.(49CFR 172.101): UN 1760 D.O.T. HAZARD CLASS(49CFR 172.101): 8 RCRA HAZARD CLASS(49CFR 172.101): PACKING GROUP III E.P.A. PRIORITY POLLUTANTS(40CFR 122.53): NOT AVAILABLE NFPA = NATIONAL FIRE PROTECTION ASSOCIATION: HEALTH (NFPA): 2 FLAMMABILITY (NFPA): 1 REACTIVITY (NFPA): 0 CAS NO: MIXTURE GENERIC DESCRIPTION: LIQUID EPDXY HARDENER ------------- SECTION 2 HAZARDOUS INGRZD13NTS -- -- -------- ----- -------------- -- ---- - -� T --- - INGREDIENTS+V (UNITS) CAS' 1 2-PYROLIDONE 1-20 NOT DETERMINED 616-45-5 ?. 4,4 -METHYLENE DiANILINE 35-85 NOT DETERMINED 101-77-9 3, 4. 5. 6. 8. ONLY THOSE INGREDIENTS LISTED IN THIS SECTION HAVE BEEN DETERMINED TO BE HAZARDOUS A5 DEFINED IN 29 CFR 1910.1200. AN INGREDIENT WITH AN ASTERISK (*) IS ALSO LISTED IN 29 CFR 1910.1200(D)(4) AS KNOWN OR SUSPECTED CARCINOGEN. CO[yLMENTS_NONE------------------------------------------------------------------- -- SECTION 3 HEALTH HAZARD DATA ORAL LD50: -2140-3990 MG/KG (RATS) DERMAL LD50 560 MG/KG (RABBITS) TLV: NONE ESTABLISHED IRRITATION -SKIN: SHORT SINGLE EXPOSURE MAY CAUSE SKIN BURNS IRRITATION -EYES: MAY CAUSE SEVERE IRRITATION WITH CORNEA INJURY WHICH MAY RESULT IN PERMANENT IMPAIRMENT OF VISION, EVEN BLINDNESS INHALATION: EXCESSIVE EXPOSURE MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT. INGESTION: MAY CAUSE GASTROINTESTINAL IRRITATION OR ULCERATION. MAY CAUSE BURINS OF THE MOUTH AND THROAT. SEVERE ABDOMINAL PAIN. SENSITIZATION: MAY CAUSE SENSITIZATION OR ASTHMA IN SUSCEPTIBLE PERSONS. COMMENTS: NONE Q_1/12t2001 16:39 5065674514 CAST COAT INC PAGE 03 CAST -COAT, INC. MATERIAL SAFETY DATA SHEET MATERIAL NAME: H-34 HARDENER PAGE 2 OF 4 ---------------------------------------------------------------------------------- SECTION 4 EMERGENCY FIRST AID PROCEDURES ------------------------------- EYES: IMMEDIATE AND CONTINUOUS IRRIGATION WITH WATER FOR AT LEAST 30 MINUTES IS IMPERATIVE. CONTACT PHYSICIAN IMMEDIATELY. SKIN: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 1S MINUTES. IMMEDIATELY REMOVE CONTAMINATED CLOTHING. CONTACT PHYSICIAN. INHALATION: IMMEDIATELY REMOVE TO FRESH AIR. CONTACT PHYSICIAN IF EFFECTS OCCUR. ORAL: DO NOT INDUCE VOMITING. GIVE LAR03 AMOUNTS OF MILK OR 2 oz. OF VINEGAR. CONTACT PHYSICIAN IMMEDIATELY. GIVE SALINE CATHARTIC. COMMENTS: PROMPTLY REMOVE CONTAMINATED CLOTHING, WASH BEFORE REUSE. DESTROY CONTAMINATED LEATHER AND ABSORBENT SHOES. ---------------------------------------------------------------------------------- SECTION 5 FIRE AND EXPLOSION DATA FLASHPOINT 168'C (335'F) - METHOD USED: CLEVELAND OPEN CUP AUTOIGNITION TEMPERATURE: 3601C (680'F) FLAMMABILITY LIMITS IN AIR (LEL): NOT DETERMINED (UEL): NOT DETERMINED EXTINGUISHING MEDIA: WATER, FOG, ALCOHOL FOAM, CO2, DRY CHEMICAL SPECIAL FIRE FIGHTING PROCEDURES: USE FULL PROTECTIVE CLOTHING AND A POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS UNUSUAL FIRE AND EXPLOSION HAZARDS! DECOMPOSITION PRODUCTS MAY BE TOXIC COMMENTS: NONE ---------------------------------------------------------------------- SECTION 6 PHYSICAL DATA ----------------------------------- BOILING POINT 9 760MM HG,'C: >220'C SPECIFIC GRAVITY 13 25'C: 0.989 - 0.995 MELTING POINT: NONE VAPOR PRESSURE � 25'C,MM14G: < 1 ® 20'C VAPOR DENSITY 4 25'C(AIR=1): 7.6 PERCENT VOLATILE BY VOLUME, V: 0 EVAPORATION RATE (BUTYL ACETATE=1): < 0.001 SOLUBILITY IN WATER, %: MIXES COMPLETELY ODOR: AMMONIA ODOR APPEARANCE: LIQUID COLOR: WATER WHITE COMMENTS: NONE NOTE: THE ABOVE INFORMATION IS NOT INTENDED FOR USE IN PREPARING PRODUCT SPECIFICATIONS. CONTACT CAST -COAT, INC. BEFORE WRITING SPECIFICATIONS. @ /12/2001 16:39 5085874514 CAST COAT INC PAGE 04 CAST -COAT, INC. MATERIAL SAFETY DATA SHEET MATERIAL NAME: H-34 HARDENER PAGE 3 OF 4 ---------------------------------------------------------------------------------- SECTION 7 REACTIVITY DATA ---------------------------------------------------------------------------------- STABILITY: STABLE INCOMPATABILITY (MATERIALS TO AVOID): STRONG MINERAL ACIDS CONDITIONS TO AVOID: CAN AUTOIGNITE IN AIR AT APPROXIMATELY 360'C. HAZARDOUS DECOMPOSITION MATERIALS: NITROGEN OXIDE, CARBON MONOXIDE, CARBON DIOXIDE WHEN BURNED. :iAZARDOUS POLYMERIZATION: WILL NOT OCCUR COMMENTS: NONE SECTION 8 SPILL, LEAK AND DISPOSAL PROCEDURES ---------------------------------------------------------------------------------- S7_EPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: LARGE SPILLS - DIKE AND PUMP INTO APPROPRIATE CONTAINERS SMALL SPILLS - DILUTE WITH WATER AND RECOVER OR USE NONCOMBUSTIBLE ABSORBENT MATERIAL/SAND AND SHOVEL INTO SUITABLE CONTAINERS. PROTECTIVE EQUIPMENT EYES: WEAR SPLASH PROOF CHEMICAL GOGGLES SKIN: WEAR PROTECTIVE CLOTHING IMPERVIOUS TO THIS MATERIAL INHALATION: WEAR FUEL FACE NIOSH APPROVED RESPIRATOR WASTE DISPOSAL METHOD: CAST -COAT, INC. RECOMMENDS THAT ALL LOCAL, STATE, AND FEDERAL REGULATIONS CONCERNING HEALTH AND POLLUTION BE REVIEWED TO DETERMINE APPROPRIATE DISPOSAL PROCEDURES. COMMENTS: NONE 01/12/2001 18:39 5065874514 CAST COAT INC PAGE 05 CAST -COAT, INC. MATERIAL SAFETY DATA SHEET MATERIAL NAME: H-34 HARDENER PAGE 4 OF 4 ---------------------------------------------------------------------------------- SECTION 9 ROUTINE HANDLING PRECAUTIONS ---------------------------------------------------------------------------------- PROTECTIVE EQUIPMENT - EYES: WEAR SPLASH PROOF GOGGLES PROTECTIVE CLOTHING - SKIN*: WEAR PROTECTIVE CLOTHING IMPERVIOUS TO THIS MATERIAL INHALATION: WEAR FULL FACE RESPIRATOR IN ABSENCE OF VENTILATION VENTILATION LOCAL EXHAUST: PREFERRED MECHANICAL (GENERAL): RECOMMENDED SUITABLE RESPIRATOR: NIOSH APPROVED FULL FACE RESPIRATOR COMMENTS: NONE THESE PRECAUTIONS ARE FOR ROOM TEMPERATURE HANDLING, USE AT ELEVATED TEMPERATURE MAY REQUIRE ADDED PRECAUTIONS- * RECAUTIONS_ * GOOD PRACTICE REQUIRES THAT GROSS AMOUNTS OF ANY CHEMICAL BE REMOVED FROM THE SKIN AS SOON AS PRACTICAL, ESPECIALLY BEFORE EATING OR SMOKING. ---------------------------------------------------------------------------------- SECTION 10 SPECIAL PRECAUTIONS ---------------------------------------------------------------------------------- PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: STORE IN A COOL, DRY AREA IN A CLOSED CONTAINER. AVOID SKIN CONTACT AND INHALATION OF VAPORS. OTHER PRECAUTIONS: GROUND ALL TRANSFER EQUIPMENT. HOLD BULK STORAGE UNDER A NITROGEN BLANKET. THIS PRODUCT SHOULD NOT COME IN CONTACT WITH•'COPPER OR COPPER -BEARING ALLOYS. COMMENTS: NONE THESE DATA ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT AS A PRODUCT SPECIFICATION. NO WARRANTY, EITHER EXPRESSED OR IMPLIED, IS HEREBY MADE. THE RECOMMENDED INDUSTRIAL HYGIENE AND SAFE HANDLING PROCEDURES ARE BELIEVED TO BE GENERALLY APPLICABLE. HOWEVER, EACH USER SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE INTENDED USE AND DETERMINE WHETHER THEY ARE APPROPRIATE_ PREPARED BY: R.S. LOTHROP TITLE: TECHNICAL DIRECTOR LAST REVISION DATE: 01/08/01 PREVIOUS REVISION DATE: 01/05/00 DATE: Jan 12, 2001 P. ,o WNIVW)Ni(S INC. MSDS#0704 (, IOC I: ('11FNIICAL PRODUCT AND COMPANY INFORMATION n,n:un Wdress: cater Driyc Product Information: 800 -TECH -401 I:tncrgcncy: (Chcnuttc) 800-424-9300 (. ustonter Service: 800-64i-1244 Revision Date: October 6. 1997 Product Identification u CHEMASK Product Code: CN,I I. CMi. CIf'IS •:(`110V2-: CODII'OSII'ION/IN'FORMATION ON INGREDIENTS ',uuct In-'redient Information CAS# Wt. %o Range unrcnc cnnllsion (latex) mixture 90.0-9i.0 ;inul ldirhiocarhtrmtt[c 136-23-2 1 0-i.0 mixture I.0 -i.0 nnu7iu tc:ucr 7732-18-5 urun,l 67-56-1 1.0-3.8 it:u,iunl dioxide 13463-67-7 0.1-1.0 l'iintcthvl quinoline homopolymer 26780-96-I 0.1-1.0 \nunnniunt ItydrOxidC 1336-21-6 0.1-1.0 '4'(' ION 3: HAZARD IDENTIFICATION u;crecncc Overview: Opaque, pink. viscous mild ammoniacal odor. This product is nonflammable. Liquid will irritate eyes and skin under repeated or prolonged \pwmrr. ISrcathing high concentrations of product vapor may produce drowsiness and a headache. .,olc,ilial I Icallh Effects: +111. \mnionia vapors ofthis product are irritating and can cause pain. tearing. reddening and swelling accompanied by a stinging sensation. omact causes skin irritation. nccstton: I larIll l'ul if swallowed. Irritating to mouth, throat and stomach. Latex may solidify in intestinal tract. cn;,tiun: 1 kirnttul il' inhaled. Highconcentrations of vapors in immediate area can displace oxygen and can cause irritation of mouth. nose, throat and mucus nnr;uus. kccp people away from such vapors without self-contained breathing apparatus. Medical Conditions Aggravated by Exposure: Lung. skin, eve. :i i `TION 4: FIRST AID MEASURES hnnx•diately (lush with plenty of water. After initial Flushing. remove ally contact lasses and continue Ilushing lot- at least 15 minutes. Have eyes anti tcsied by medical personnel if irritation develops or persists. n, ;h skin \\ ith soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persist. Wash clothing separately before reuse. ucc ,tion 1l stcallowcd. do not induce vomiting. Get medical attention IMMEDIATELY. Keep head below knees to minimize chance of aspirating material into the ones. \0 Cl civic anything by mouth to an unconscious person. nit;llmion: Iccnwve to li'csh air. If not breathing, give artificial respiration. If breathing is difficult. give oxygen. (yet medical attention. ;h:('IION 5: FIRE FIGHTING -MEASURES List( Poinii None to boiling (TCC) LEL/UEL: Not established (% by volume in air) I1112uishin \lalia: llsc alcohol foam. carbon dioxide. or water spray when fighting tires involving this material. Instructions: As in any tire. wear self-contained breathing apparatus (pressure -demand. INISHVNIOSH approved or equivalent) and full protective t 1 ION 6: ACCIDENTAL RELEASE N'IEASURES _-- nfiis: phut oll Icak if possible and safe to do so. Wear self-contained breathing apparatus and appropriate personal protective equipment. Allow latex to dry. 1a1,c un Mid place in a chemical waste container for proper disposal. Do not flush to sewer. Avoid runoff into storm sewers and ditches which lead to waterways. n,;ut ~alts: ticrapc up dried latex,. then place in a chemical waste container for proper disposal. �V( TION 7: 11ANDLIN'G AND STORAGE rid mnloneetl or repeated contact with eyes, skin, and clothing. Wash hands before eating. Use with adequate yentiletion. Avoid breathing product vapor or , ,uu not reuse this container. Store in a cool dry place away irons heat. sparks and flame. Keep container closet) when not in use. Do not store in direct ,in„_ht. i LEA' OUT OF REACH OF CHILDREN. :I:('I'ION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION I \:posurc ( iuidclines: ill-:\II('A1, NA.NIF ACGiI-i TWA OSHA PEL ACGIH STEL I, i,olvrnc cnutlsion NA NA NA rucuu,i 200 ppm 200 ppni 250 ppm nnrnnunt in droxidc 25 ppm NA 50 ppttt auiunt ,lin idc 10 nt'a/tut' Irl/i nia/m" NA ik :ionic PI"al.tICCS: Good 2Cneral ventilation should be sufticialt to control airborne levels. Local exhaust \altilation may be necessary to control any air nl;unmants to within thcir'fLVs during the use of this product. Wear safety glasses with side shields (or _,oLLlcs) and rubber or other chemically resistant gloves .urn h;tnulin_ Ihis material. I' \ ;Ind Ilii\•IIS Codcs: NFP.\ IIiIIIS I ;:unin;uiilin 0 0 0 0 runnal I'mtcclion 11 Pa',e I o1' 2 A, a n k 111% ITRONICS INC. NISDS#0704 -.IU TION 9: PHYSICAL AND CHEMICAL PROPERTIES `!n,.ical StatC: Opaque. pink liquid Solubility in Water: Dispersible ,dor: :Mild. anunonia like Specific Gravity: .90 (Water=l) ,:11001' Pl'CSSnrC: 760 nun Ha .ii! I OOC Evaporation Rate: >1 q,or I elisity: 0.63 (Butyl acetate=l): I "' I Color: pink ne Point: 11) 100 initial Viscosity: 15,000 cps (Approximately) ALC1' :nt \ olatilc: ; [IN weight Melting Point: NA QVC HON 10: STABILITY AND CHEMICAL PROPERTIES hii it - I his product is stable. Conditions to Avoid: Do not spray near open flames. red hot surfaces or other sources of ignition. r,nnmatihilit Do not mix with powdered alkali and alkaline earth metals or strong oxidizing agents. ':,niucts 01 Uccomposition: Thermal decomposition may release carbon monoxide. carbon dioxide and incompletely burned hydrocarbons. k-lydous I'olvmcrization: Will not occur Conditions to Avoid: NA ,;IJ PION 11: TOXICOLOGICAL INFORMATION nh;ll;uinn: Ingestion: Icih;uuil LC50/rats 64.000ppm/41irs Methanol LD50 5,628 mg/kg :icer Inionnation: No ingredients listed as human carcinogens by NTP or IARC '-4 (TION 12: ECOLOGICAL INFORMATION I% ironntcnral Impact Information Environmental Impact Data -id run0lI' into dorm sewers and ditches which lead to (percent by weight) ,11c1%\;l%` \\ MCI runoit'can cause environmental damage. CFC 11.019. VOC 3.1% HCFC (1019" HFC 0.0% IC_ulations require reporting spills of this material that Cl. SON. 0.0'9, ODP 0.00 .wl(i rc;tch any surface waters. The toll free number for Iii Guard National Response Center is: Igor more information call: `1111-a 21-�I)t112 1-800-645-5244 (:(TION 13: DISPOSAL CONSIDERATIONS )i:posc of in accordance with all federal. state and local regulations. Water runoff can cause environmental damage. :.( TION 14: TRANSPORTATION INFORMATION Caning Compound Not Regulated -wnd: t (caning Compound Not Regulated ;i:( TION 15: REGI L.ATORY INFORMATION ,I ("11ON' I'. SUPPLIER NOTIFICATION 1 his ow(Im:1 contains the following toxic chemicals subject to the reporting requirements of Section 313 ol'the Emergency I'lanning and Community Right -To -Know heroical \'ante CAS# Wt. % Range cihan"l 67-56-1 1.0-3.8 1i> mlhrmation should be included on all MSDSs copied and distributed for this material N!C SI BS f \LACES CONTROL ACT (TSCA). II ingredients of (his product are listed on the TSCA Inventory. �I(( FION 16: OTHER INFORMATION �nnal ventilation Ibr standard manufacturing practices is usually adequate. Local exhaust should be used when large amounts are released. 1 ! RI:X(:S: 29 CFR 1910.1200 40 CFR 300-700 ANSI 2400.1-1993 \1IOSI-I RTECS provided by CHEM -BANK by SILVERPLATTER 411dC to Occupational Exposure Values 1996 the hcsi of our knmvledge. the information contained herein is accurate. However, all materials may present unknown hazards and should be used with caution. ti pmiicuiai. improper use of our products and their inappropriate combination with other products and substances may produce harmful results which cannot be luicip❑ted. I incl determination of the suitability of any material is the sole responsibility of the user. Although certain hazards are described herein, we cannot narantCe that these are the only hazards that may exist. 11age 2 of 2 d .lk (Sl llV'.dTR0 NlCS INC. MSDS#0408 �i ( TION I: CHEMICAL PRODUCT AND COMPANY INFORMATION oln! ury \ddress: I Cohh ('enter Drive Product Information: 800 -TECH -401 Emergency: (Chemtrec) 800-424-9300 Customer Service: 300-645-i244 Revision Date: October n. 1997 Product Identification I STATIC FREE" PLAST-N-CLAS" (Formerly Static Free SD -7 Plast-N-Glas) 1'roduct Code: ES1668 4'( PION 2: COMPOSITION. INFORMATION ON INGREDIENTS hcmic;rl \arae CAS4 Wt. "fig Range 1, onireu .tatcr 7732-18-5 50.0-95.0 moon I ;Ji :oliol 67-63-0 1.0-20.0 74-98-6 1.0-20.0 -'ohnia!tc 75-23-5 1.0 ?0.0 i'n,lt\ lcnc '-!I.\ CIA n-hutvl ether 5131-66-8/15821-83-7 1.0-210.0 ufacautt 68412-54-4 0.I-10.0 \ntutatic :rvent 68308-67-8 0.01-10.0 r ranee NA 0.01-10.0 \lonocthanola!ttilie 141-43-5 0.01-10.0 77 -TION 3: HAZARD IDENTIFICATION mer_encv Overview: Clear. colorless liquid with clean. fresh odor. This product is not flammable. quid will irritate eves and skin under repeated or prolonged exposure. Breathing high concentrations of product vapor may produce drowsiness and a headache. i'fuential Health Effects: - es I.iquid. aerosols and vapors of this product are irritating and can cause pain, tearing. reddening and swelling accompanied by a stinging sensation. in: t.,mtact,:ausesskin irritation. uee,tiun: I Iminful if swallowed. Irritating to mouth. throat and stomach. Vlay cause vomitinS. mwilation: I larntfid if inhaled. High concentrations of vapors in immediate area can displace oxygen and can cause dizziness. unconsciousness, and even death with "m1cr exposure. Deep people away from such vapors without self-contained breathing apparatus. !:xistina Vledical Conditions Aggravated by Exposure: Skin. eve. -lJ l ION 4: FIRST AID MEASURES linntcdiate!v flush with plenty of water. .After initial flushing, remove any contact lenses and continue flushing for at least li minutes. Have eyes mine[( ,utd tested by medical personnel if irritation develops or persists. ,1,m: \•N;tsh skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persist. Wash clothing separately before reuse. neestion: �w allowing less than an ounce will not cause significant harm. For larger amounts. do not induce vomiting. 'out give one or two glasses of water to drink And _ct inttnediate medical attention. !nnalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult. give oxygen. Get medical attention. :.V( CION FIRE FIGHTING MEASURES 'A Haim: Proiection: Nonflammable (< 18 inches) LEL: UEL: Not established (",�" by volume in air) uneuishing Media: Use alcohol foam, carbon dioxide. or water spray when fighting tires involving this material. !v ' iehtins Instructions: As in anv tire. wear self-contained breathing apparatus (pressure -demand. MSHA/NIOSH approved or equivalent) and full protective ,,V( VION 6: ACCIDENTAL RELEASE MEASURES ;!rec Spills: Shut off leak if possible and safe to do so. Wear self-contained breathing apparatus and appropriate personal protective equipment. Absorb spill with nc. material te.g_. dry sand or earth). then place in a chemical waste container for proper disposal. Do not flush to sewer. Avoid runoff into storm sewers and eLc> which lead to waterways. ,11[.111,11[.111 Shills: Absorb spill with inert material (e.. dry sand or earth). then place in a chemical waste container For proper disposal. ,P:("IION ?: IIANDLING AND STORAGE \t,id pmlon.ted or repeated contact with eyes. skin. and clothing. Wash hands before eating. Use with adequate ventilation. Avoid breathing product vapor or jim. Do not reuse this container. Store in a cool dry place away from heat, sparks and Harte. Keep container closed when not in use. Do not store in direct •.un!isht. I VIA' 01 A' OF REACH OF CHILDREN. QFC CION 8: EXPOSURE CONTROLS/PERSONNEL PROTECTION \postrrc t uidelines: III:MICAl. NAME ACG III TWA OSHA PEL ACGIH STEL :nrup I alcohol 400 ppm 400 ppm 500 ppm Propylene t il\ col n- ether NA NA NA \ r!;,I I\eicnic Practices: Good general ventilation should be sufficient to control airborne levels. Local exhaust ventilation may be necessary to control any air iamin;uns to within their FEVs during the use of this product. Wear satcty .asses with side shields (or goggles) and rubber or other chemically resistant gloves kt!en lmndliiiL this material. I P \ ;!nil I1\ -IIS Codes: NFPA 11MIS '!ciltlt I I artit in 0 t anal I'micction 13 I'a,c I of 2 w, /-, , Ni R) ( IIF*kIT1Z0NiCS INC. MSDS#0908 lAA'10N 9: I'IiYSICALAND CHEMICAL PROPERTIES 'hs sical `;tate: Opaque white toam Solubility in water:> 90% by wt. ,trn- Floral tra^rance Specific Gravity: 0.95 (liquid only) %tl 't. _0� (liquid) (Water=l) rn r I'rc .ore: (:\ir =1) Evaporation Rate: >1 nm 1I, a OF (Butyl acetate= 1) wor Uensitx: I u. b81- Viscosity: I (Approximates ) ''r -1 1 Percent Volatile: > Wlo (Approximately) • line I' pint: ' (' F (liquid only) Meltiniz Point: NA I ( TION 10: STABILITY .AND REACTIVITY 75 k.g; ;i)ilin - I his product is stable. Conditions to Avoid: Do not spray near open flames. red hot surfaces or other sources of ignition. ,:om atihiiit\ : Do not mix strong oxidizing agents. v ,uucts nt I)ccomposition: Thermal decomposition may release carbon monoxide. carbon dioxide and incompletely burned hydrocarbons. :varduus Pnlvmerization: Will not occur Conditions to Avoid: NA 4 ( TION I i s TOXICOLOGICAL INFORMATION Halation: Ingestion: Lcyxopvl alcohol LD50/rats 16,000 ppm/4hrs Isopropyl alcohol LD50/rats 5045 mg/kg Propylene glycol n -butyl ether* LD50/rats 3,300 mg/kg m. '10mic11e 1%C01n-hutylether LD50/rabbits 3100 mg/ke Eve: nrnp -1 ; icohol 500 mg 'VILD Isopropyl alcohol 10 mg MOD Intormation received from manufacturer. :n,;er Information: No ingredients listed as human carcinoeens by NTP or IARC -i,t I ION 12: ECOLOGICAL INFORMATION n%ironmental Impact information Environmental Impact Data oid runott into storm sewers and ditches which lead to (percent by weight) t,: i %\ a\ s. \Garcr runoff can cause environmental damage. CFC 0.0% VOC 11.1% :I -PORTING HCFC u.0% HFC 0.0% rCLnlatluns require reporting spills of this material that CI. Solv. 0.0% ODP 0.00 ni,i rrtcit any surface waters. The toll tree number for OM Guard Nationai Response C.nter is: For more information call: -NOO-424-SN02 1-800-645-5244 -I:("I 10\ 13: DISPOSAL CONSIDERATIONS �,nosc ,u in accordance with all federal, state and local regulations. Water runoff can cause environmental damase. i ( 110\ 14: TRANSPORTATION INFORMATION "•` Sub. Pkg. Hazard Pka. Max. wnin . \lame UN Number Class Risk Group Label Instr. Quantity \cro,uis nonlianunable m.o.s. UN 1950 2.2 NA NA Nonflammable 203 75 k.g; Gas Y203 30 kg und: ( 1111sumerComnodity NA ORM-D NA NA ORM-D Pkg. 173.306 ()RNI-D 1uth. -t.( 1 iO` la: REGULATORY iNFORNIATION (. F10N ,13 SUPPLIER NOTIFICATION product contains the following toxic chemicals subject to the reporting requirements of Section 313 of the Emereencv I'lanning and Community Right -To -Know I 11N, (40 CFR :72). .nn• inliam:tion should be included on all MSDSs copied and distributed for this material. t\I( SI BS FANC'E-S CONTROL ACT (TSCA). •.;I utercdicnts of this product are listed on the TSCA Inventory. T( TION 16: O'I'LIER INFORMATION Immdnct is a Level I aerosol. Do not puncture or incinerate containers. Normal ventilation for standard manufacturing practices is usually adequate. Local Haust shi old he used when large amounts are released. I;i:RI'N( I'S: 29 CFR 1910.1200 40 CFR 300-700 ANSI Z400. t-1993 NIOSH RTECS provided by CHEM -BANK by SiLVERPLATTER Guide to Occupational Exposure Values 1996 (hc hest if mir knowledge, the information contained herein is accurate. However. all materials may present unknown hazards and should be used with caution. n:uticular unproper use ofour products and their inappropriate combination with other products and substances may produce harmful results which cannot be -!tiopnicd. final determination of the suitability of anv material is the sole responsibility of the user. Although certain hazards are described herein, we cannot ar:intcc that these arc the only hazards that may exist. Paue 2 of 2 CNEMTRONICS -- E -SERIES FREEZ-IT ANTISTAT OSU COLLEGE OF BIOLOGICAL SCIENCES MSDS FILE CHEMTRONICS -- E -SERIES FREEZ-IT ANTISTAT MATERIAL SAFETY DATA SHEET NSN: 685000F036288 Manufacturer's CAGE: 21267 Part No. Indicator: A Part Number/Trade Name: E -SERIES FREEZ-IT ANTISTAT General Information Company's Name: CHEMTRONICS INC Company's Street: 8125 COBB CTR DR Company's City: KENNESAW Company's State: GA Company's Country: US Company's Zip Code: 30144 Company's Emerg Ph 4: 800-645-5244/800-832-4401 Company's Info Ph T: 404-424-4888/404-424-4267 FAX Record No. For Safety Entry: 001 Tot Safety Entries This Stk4: 001 Status: SE Date MSDS Prepared: 01JAiN91 Safety Data Review Date: 25AUG94 MSDS Preparer's Name: M WATKINS Preparer's Company: CHEMTRONICS INC Preparer's St Or P. 0. Box: 8125 COBB CTR DR Preparer's City: KENNESAW Preparer's State: GA Preparer's Zip Code: 30 N4 MSDS Serial Number: BTVQL Ingredients/Identity Information ----------------- Proprietary: NO Ingredient: CHLORODIFLUOROMETHANE, FREON 22, MONOCHLORODIFLUOROMETHANE Ingredient Sequence Number: 01 NIOSH (RTECS) Number: PA6390000 CAS Number: 75-45-6 OSHA PEL: 1000 PPM ACGIH TLV: 3540 MG/CUM Other Recommended Limit: 1000 PPM Proprietary: NO Page 1 of 5 http://ww-w.biose... /CHEMTRONICS%20--%20E-SERIES%20FREEZ-IT%20ANTISTAT.ht 1/12/01 - CHEMTRONICS -- E -SERIES FREEZ-IT ANTISTAT Page 2 of 5 Ingredient: METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS Ingredient Sequence Number: 02 NIOSH (RTECS) Number: PC 1400000 CAS Number: 67-56-1 OSHA PEL: 200 PPM ACGIH TLV: 250 PPM Other Recommended Limit: 200 PPM Physical/Chemical Characteristics Appearance And Odor: CLEAR, COLORLESS, LIQUIFIED GAS W/SLIGHT ETHEREAL ODOR Boiling Point: -41AF Vapor Pressure (MM Hg/70 F): 151 PSIG Vapor Density (Air --I): 3.03 Specific Gravity: 1.19 Evaporation Rate And Ref. (BU AC=1): <1 Solubility In Water: 0.3% Fire and Explosion Hazard Data Flash Point: NONE Flash Point Method: TOC Extinguishing Media: NONFLAMMABLE Special Fire Fighting Proc: SCBA MAY BE REQUIRED IF CONTAINERS RUPTURE & CONTENTS ARE RELEASED UNDER FIRE CONDITIONS. ADDITION OF EXCESS WATER 0.2% WILL FORM A FLAMMABLE SUPERNANT LAYER- Unusual AYER Unusual Fire And Expl Hazrds: PRESSURIZED AEROSOL CONTAINERS MAY VENT, RUPTURE/EXPLODE & ADD TO FLYING & FALLING DEBRIS. DECOMPOSITION MAY OCCUR Reactivity Data Stability: YES Cond To Avoid (Stability): OPEN FLAMES Materials To Avoid: HOT SURFACES, ALKALI & ALKALINE EARTH METALS -POWDERED ALUMINUM, ZINC, BERYLLIUM, MAGNESIUM, RED HOT SURFACES Hazardous Decomp Products: HYDROCHLORIC, HYDROFLUORIC ACIDS & CARBONYL HALIDES. Hazardous Poly Occur: NO ----------------------------------------------------------------------- Health Hazard Data http://www.biosc.../CHEMTRONICS%20--%20E-SERIES%20FREEZ-IT%20ANTISTAT.ht 1/12/01 CHEMTRONICS -- E -SERIES FREEZ-IT ANTISTAT Page 3 of 5 LD50-LC50 Mixture: ORAL LD 50 (RAT): 5,620 MG/KG (SEE SUPP Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: INHALATION: BREATHING HIGH CONCENTRATIONS OF IRRITATION MAY OCCUR LIQUID CONTACT CAN CAUSE FROSTBITE. EYES: CONTACT MAY CAUSE SEVERE DAMAGE & BLINDNESS. LIQUID CONTAIN METHANOL, AN EYE IRRITANT. LIQUID CONTACT CAN CAUSE FROSTBITE. Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: NONE Signs/Symptoms Of Overexp: IRRITATION, DEFATTING, LIGHT-HEADEDNESS, GIDDINESS, SHORTNESS OF BREATH, NARCOSIS, UNCONSCIOUSNESS, REDDENING, NAUSEA. VOMITING Med Cond Aggravated By Exp: CARDIOVASCULAR DISEASE. Emergency/First Aid Proc: INHALATION: REMOVE TO FRESH AIR IF NOT FLUSH W/WATER INGESTION: DON'T INDUCE VOMITING AS THE HAZARD OF ASPIRATING THE MATERIAL INTO THE LUNGS IS A GREATER HAZARD THAN ALLOWING IT TO PASS THROUGH THE INTESTINAL TRACT. EYES: FLUSH W/WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. (SEE SUPP) Precautions for Safe Handling and Use Steps If Mad Released/Spill: VENTILATE AREA. REMOVE OPEN FLAMES/OTHER IGNITION SOURCES. COLLECT PRODUCT W/ABSORBENT MATERIAL & PLACE IN CLOSED STEEL DRUMS FOR PROPER DISPOSAL. Waste Disposal Method: DONT PUNCTUREANCINERATE AEROSOL CANS. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. Precautions-Handling/Storing: DONT STORE NEAR SOURCES OF HEAT, DIRECT SUNLIGHT/WHERE TEMPS EXCEED 120F. DONT PUNCTURE/DAMAGE CONTAINERS. ROTATE STOCK. Control Measures Respiratory Protection: GOOD VENTILATION Ventilation: ADEQUATE AS NEEDED TO COMPLY W/TLV. LOCAL EXHAUST WHEN LARGE "f CHEMTRONICS -- E -SERIES FREEZ-IT ANTISTAT Page 4 of 5 AMOUNTS ARE RELEASED. MECHANICAL TO BE USED IN LOW PLACES. Protective Gloves: BUTYL Eye Protection: CHEMICAL SPLASH GOGGLES Other Protective Equipment: EYE BATH & PROTECTIVE CLOTHES Suppl. Safety & Health Data: ORAL LD 50 IS FOR METHYL ALCOHOL. NOTE TO PHYSICIAN: BECAUSE OF THE POSSIBLE RISK OF ELICITING CARDIAC DYSRYTfUvUAS, CATECHOLINAMINES DRUGS, SUCH AS EPINEPHRINE, SHOULD BE USED ONLY AS A LAST RESORT IN LIFE THREATENING EMERGENCIES. Transportation Data Disposal Data Label Data Label Required: YES Technical Review Date: 25AUG94 Label Date: 25AUG94 Label Status: F Common Name: FREEZ IT ANTISTAT Chronic Hazard: YES Signal Word: DANGER! Acute Health Hazard -Severe: X Contact Hazard -Severe: X Fire Hazard -None: X Reactivity Hazard -None: X Special Hazard Precautions: INHALATION: BREATHING HIGH CONCENTRATIONS OF IRRITATION MAY OCCUR LIQUID CONTACT CAN CAUSE FROSTBITE. EYES: CONTACT MAY CAUSE SEVERE DAMAGE & BLINDNESS. LIQUID CONTAIN METHANOL, AN EYE IRRITANT. LIQUID CONTACT CAN CAUSE FROSTBITE. TARGET ORGANS: HEART, SKIN & EYES. N/K Protect Eye: Y Protect Skin: Y Protect Respiratory: Y Label Name: CHEMTRONICS INC Label Street: 8125 COBB CTR DR Label City: KENNESAW Label State: GA http://www.biosc.../CHEMTRONICS%20--%20E-SERIES%20FREEZ-IT%20ANTISTAT.ht 1/12/01 CHEMTRONICS -- E -SERIES FREEZ-IT ANTISTAT Page 5 of 5 Label Zip Code: 30144 Label Country: US Label Emergency Number: 800-645-5244/800-832-4401 Year Procured: UNK URL for this msds http://siri.org. If you wish to change, add to, or delete information in this archive please sent updates to dan@siri.org. httn://www.biosc.../CHEMTRONICS%20--%20E-SERIES%20FREEZ-IT%20ANTTl�TAT ht 1/12/01 OT FORMATTED FOR USEISALE IN THE STATE OF CALIFORNIA J'MiSEAL DIVISION/CHASE CORPORATION HUMISEAL TYPE: 1B15 MATERIAL SAFETY DATA SHEET uNUFACTURER'S NAME: HUMISEAL :NERAL INFORMATION:718-932-0800 a: (7i8) 932-4345 1ERGENCY;CHEMTREC:800-424-9300, ONLY IN THE EVENT OF CHEMICAL EMERGENCIES :7OLVING A SPILL, LEAK, FIRE, EXPOSURE, OR ACCIDENT INVOLVING CHEMICALS. %DRESS: 26-60 Brooklyn Queens Expressway West, Woodside, NY 11377 ZMICAL NAME AND SYNONYMS: Acrylic Conformal Coating ,ADE NAME AND SYNONYMS: HUMISEAL 1315 ,.TE OF REVISION: October 8, 1998 ' ARED BY: Jim Lawrenc ,.RA:This product contains toxic chemicals listed in section 3A subject to .e reporting requirements of section 313 of the Emergency Planning & mmunity Right -To -{now Act of 1986 and 40 CFR 372 (SARA).TSCA:A11 the .emical components are TSCA listed. :IR: Not/Appi. 'ATES RIGHT -TO KNOW LAWS: 100% of all chemical ingredients are listed in ction 3 0` +:is MSDS. -•formation indicated as proprietary will be :leased to a physician or appropriate authority in an emergency.+ ',C:592 grams per liter. IIS/NFPA:Health 3 Fire 3 Reactivity 0 :TREMELY HAZARDOUS SUBST. LIST (TPQ): Does not apply. TIPPING CLASS: UN 1263, Paint, Flammable Liquid ATERIAL WT.% ACGIH TLV c�ior. 3A (Sara RQ) .luene (1% SARA) ?thyl Ethyl Ketone (1% SARA) action 3B .rylic Polymer TWA:PPM/Mg?erM3 STEL;PPM/Mg?erM3 47-53 100/377 565/565 13-18 200/590 885/885 32-38 AILING POINT: 180 F. kPOR PRESSURE (mm Hg) : 45.4 . XPOR DENSITY (AIR = 1): 4.0 ?ECIFIC GRAVITY (H2O=1): .88. 9RCENT VOLATILE BY VOLUME (%): 63-67. 37 REV. 11124/98 N/E 108-88-3 78-93-3 Prop. :)T FORMATTED FOR USEISALE IN THE STATE OF CALIFORNIA ?MISEAL DIVISION/CHASE CORPORATION HUMISEAL TYPE: 1B15 GESTION: DO NOT INDIICE VCbETING. If vomiting occurs spontaneously, keep ad below hips to prevent aspiration of liquid into lungs. GET MEDICAL 'TENTION IM MEDIATELY : %TE TO PHYSICIAN: If more than 2 ml/kg has been ingested, and vomiting has. occurred, emesis should be induced with supervision. Keep victim's head :low hips to prevent aspiration. If symptoms such as loss of gag reflex, '-vulsions or unconsciousness occur before emesis, gastric varge using a cuffed endotracheal tube should be considered. ACTION LEVEL: -/L Hippuric Acid level in urine (sampled at end of workday). ABILITY (choose one):( )UNSTABLE (X) STABLE. HDITIONS TO AVOID: Not Applicable 'COMPATIBILITY (MATERIALS TO AVOID): Avoid contact with strong oxidizing ents. ZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide, Carbon Dioxide. ZARDOUS POLYMERIZATION (choose one): ()M.AY OCCUR (X)WILL NOT OCCUR. NDITIONS TO AVOID: Not Applicable EPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:Absorb with inert aerial (sand, vermiculite, etc.) Large spills may be scooped up with non- arking tools. Remove sources of ignition. Provide ventilation and/or ,atar,r Nrot=ction. ZTE DISPOSAL. METHOD:Disposal of HumiSeal products requires strict moliance with local, state and federal regulations pertaining to sposing hazardous waste materials. Contact the appropriate environmental ,encies. RA Waste 110./RQ: Toluene; U220/1000Lbs., MEK;U159/5000lbs.CERCLA: uene;10001bs.,MEK;5000lbs ASPIRATORY PROTECTION (SPECIFY TYPE): aspirator -organic vapor type if TLV is exceeded(NIOSH approved). ;NTILATION:LOCAL EXHAUST: Yes. ;CHANICAL (GENERAL): Explosion proof. 'ECTAL: Designed and maintained to provide volume and patterned to prevent .00r. . .HER: Concentration in excess of TLV or PEL. tOTECTIVE GLOVES: Impervious to chemical and petroleum(BUNA-N,Solvex etc.). 'E PROTECTION: Chemical type goggles must be worn. .HER PROTECTIVE EQUIPMENT: Prevent contact to workers as required. IECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep away from heat, )arks and open flames. Store at ambient temperature. Ground to protect =om static charge.Keep container closed.Use adequate ventilation. 37 REV. 11/24/98 . N HUHISEAL DIVISION/CHASE CORPORATION HUHISEAL TYPE: THINNER 503 MATERIAL SAFETY DATA SHEEP }{At4 ICTURER'S NAME: HUHISEAL GENERAL iNFORNATIOX:718-932-0800 PAY; (718) 932-4345 EMERGENCY;CEEHTREC:800-424-9300, ONLY IN THE EVENT OF CHEMICAL EMERGENCIES INVOLVING SPILL, LEAK, FIRE, .EXPOSURE, OR ACCIDENT INVOLVING CHEMICALS. ADDRESS: 26-60 Brooklyn Queens Zxpressway West, Woodside, NY 11377 CZMCAL HAMS AND SYBORYMS: Solvent Solution TRADE XAMB AND SYNOHYMs: HUHISEAL THINNER 503 DAT? Op REVISION: January 13, 1993 SARA:This product contains toxic cbnicals listed in section 31 subiect to the reporting requirements of section 313 of the Emergency Planning & Cosmunity ' : Right-To-K,ncw Act of 1986 and 40 CFR 372 (SARA).TSCA:All the chemical components are TSCA listed. CAIR: Not/APpl. PROPOSITION 65: Certain raw materials used in making this product may contain trace amounts of materials as impurities which are regulated by California Proposition 65. STATES RIGHT -TO KNOW LAWS: 100% of all chemical ingredients are listed in section 3 of this RSDS. Information indicated as proprietary will be released to a physician or appropriate authority in an emergency. S.C.A.Q.m.: voC 848 grams per liter. ID{IS/HFPA:Health 3 Fire 3 Reactivity 0 EXTREMELY HASARDOUS SUBST. LIST (TPQ): Does not apply. SBTPpLNG CLASS: UN 1263, Paint, Flammable Liquid MATERIAL ACGIH TLV CAS N0. Section 3A(Sara RQ) TWA:PPN/MgPerH3 STEL;PPH/HgPerN3 Toluene(tt SARA) 55-75 100/377 108-88-3 565/565 Methyl Ethyl Ketone 25-45 200/590 78-93-3 (I% SARA) , 885/885 Section 3B BOILING POINT: 180 F. VAPOR PRESSM(u Hg): 45.4 .VAPOR DENSITY (AIR = 1): 4.0 SPECIFIC GRAVITY (H2O=1): .85 -PERCENT VOLATILE BY VOL M (t): 100.E7APORATIOH RATE (BUAC= 1): 3.62 SOLUBILITY IN WATER: Negligible - less than 0.1 percent.APPEARANCE AND ODOR: Water clear, low viscosity liquid, aromatic odor. FLASH POINT (METHOD USED): 30 F (Tag Closed Cup).FLAHWU LIMITS: LEL: 1.6 DEL: 11.2 EXTIXGUISMG MEDIA: Foam, carbon dioxide and dry chemical. SPECIAL FIRE FIGHTING PROCEDURES: Fight as a flaamable liquid fire; wear self contained breathing apparatus. UNUSUAL FIRE AND EIPLASION WARDS: Vapor is flammable and beavier than air and may travel to source of ignition and flashback. ROUTES OF ENTRY: SKIN: Yes. INHALATION: Yes. INGESTION: Yes. EFFECTS OF OVEREIPOM" : EYES: Short tern contact say result in slight eye irritation and con junctivitis.Prolonged contact with liquid rn can result in corneal bus.Eigh vapor concentrations>approx. IOOOPPH are irritating to the eyes. SKIN: Prolonged and repeated liquid contact can cause defatting and drying of the skin, which may result in skin irritation and dermatitis.Derxal12 (50)(Rabbits).>2000ag/Kg.Skin absorption may add significantly to exposure. I'l MAISEAI.TYPE: THINNER 503 i?IHAL.;TION: Causes cent_ai nervous systam dearession. Klld 2xposur3 causes dizziness, headache, 'reakness,aausea,atc..Aora savera axposures,greater .han approx. i000PP4, nav cause respirator depression, convulsions and eatl.Card iac arrhythmias, including fatal ventricular fibrillation, may occur.lhl- rat LCuo: 4000PP}f/4 hrs. Olfactory detection level is 50 PPM. However, sense of shell is dulled by continuous exposure, so unsatisfactory as a means of detection. INGESTION: Koderately toxic, LD(50) (rats): 5g/kq. LD(Lo)(?mmanI:50mq/kq. Causes burnino sensation in aouth and stomach and is likely to produce sysptoms similar ose Described for inhalation. 4ore serious hazard posed by voditing after swelling resulting in aspiration(breath inq) of vonitas into lungs-wftich may result in cheucal pneumonitis and pulmonary edeiajheiarrhage,and say be fatal CIRCIMUICITY: 71his product is not listed by the National Toxicology Progra' the international Agenc-i for Research on Cancer or the Occupational Safety and Health ldninistration. E} MENCY AND FIRST AD PROCEDURES: Eves: Mush with ,rater for 15 minutes while holding ayelids open.Get medical attentlon. Skin: Flush with water while refovinq contaainated clothing and shoes, follow by iashinq with soap and water. Do not reuse clothing or shoes until properly cleared. if irritation persists, get medical attention. inhalation:Remove victim to fresh air and provide oxygen if breathing is difficilt.Give artificial respiration if not breathinq.Get medical atteition. Ingestion: DO moT DiDUC.. 7OMIfiLYG. If vomiting occurs spontaneously, keep Sea.; Below hsps to ;rsvent aspiration of '-igl,:id into lungs._at aedica'_ attent'.en irmediataly. NOTE TO PHYSICL� : If Yore than 2 ml/kg has been ingested, and voaiti,c has not occurred, esesis should be induced with supervision. Keep victia`s head below hips to prevent aspiration. If symptoms such as loss of caq reflex, convulsions or unconsciousness occur before emesis, gastric lavage usino a cuffed endotracheal gibe should be cons idered.1C..'i0M LEVEL: 4g/L Hippurlc Acid level in prine(saapled at and of woryday). . kZILITY. ;L2",: ` , VHS-MLL ' ,') ST.CELZ. V 1VOID. Not DP1_.i 3b1'e INCC*jTiBILITY (m,.v_vRIM_s To k1OID): Avoid contact ,lith strong oxidizing agents. HALIARDOGS DECOMPOSITION PRODCCI`S: Ca -r'.= Aoncxide, carbon Dioxide.HA2,9MS POLYKERIMTIGN (choose one): (;HAY CCCUR (X)'WILL NOT OCCUR. CONDITIONS TO VOID: Not applicable ST'PS ib HE :'AM IN GLEE 1kT7_RL.1.L iS MBASED OR SPILLED: Absorb with inert cataria: ;sand, veraiculite, etc.) Wrge spills xav be scooped up with non-soarkinq tools. Remove sources of ignition. ?rovide ventilation and/or reSplr3tOC'� ''"vT0L2Ct!On . '++ASTE DISPOSAL ITMOD: Disposal of rumiseal products reT'.:=res strict CO3p,,,nCe wi:2 !OCal, State and"federal regulations pertaini:q to disposing hazardous waste asserials. Contact the apprcpriata environmental agencies. RC?1k Waste No./RQ: Toluene; U220/10001bs., !� t; 01:4l5000ibs.CERCLA: Toiueae;lGCOlbs.,rlr.';SCOOlbs R?SPIRATGRY PMECTICA (SHCIFY TYPE): Respirator -organic vapor tfpe if TLV is exceeded(NION approved). VENT111TION:LM-1 EISAUST: Yes.}+.ECSANiCAL (GENLRIL): "..plosion proof .SPECIAL: Designed and saintained to provide volume and patterned to prevent vapor. OTBi.R: Concent,ation in excess of TLV or PPL: PROTECTIVE GLGVFS: iYoerrious to chetical and petroleum(BUNA-N, Solve% etc.). TfE' MTECTIOii: Chemical type goggl2s must be :tern. •OTM PEOTF vE EQUIPKM., Pre,,,ant contact to workers as re(T,:ired. P.R?CAGTIONS TO BE MM IN HANDLLNG AND STORING: Keep a!Jay fron heat, sparks and oper,, flares. Store at ambient taaperatlre. Ground to protect fro% static cbarge.Kee9 container closed.Ose adequate ventilation. It n. ,..111 Material Jaiety uata sheet :r No. 1 702 SILITE RTV SILICONE --CLEAR, WHITE AND RED Page- 6 t I,ITE RTV SILICONE --CLEAR, WHITE AND RED Last revised 5/24/95 :;(:TION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION temical family Silicones n,ral information: When cured, these products are not hazardous. they cure by reactin.,z with .111Itshheric moisture to slowly give off acetic acid. the same substance as in vinegar acetic acid vapor .n ne an irritant. u�ufacturer EMERGENCY INFORMATION \\' hI VCON Emergency telephone number i:rniicott street (CHEMTREC) (800) 424-9300 ntvcrs. MA 01923 Other Calls: (508) 777-1100 ;,:CTION 2: COMPOSITION/INFORMATION ON INGREDIENTS Is CONs'trrur-_�vrs Exposure limits Weight ACGIH OSHA Other M'IMIent Abbr. Cas No. Percent TLV PEL Limits it% lu iacctoxysilane 17689779 1-5 IOPPM N/E N/E e:ih\hriacetoxysilane 4253343 1-5 IOPPM N/E N/E :\ "" n,c:u s the "threshold Limit value exposure (eight-hour. time -weighted average. unless otherwise noted) as established by the ,et ic;ui :mlicrrnce of governmental industrial hy-ienists. " s'TEU' indicates a short-term exposure limit. "PE -L" indicates the 11 \ I'Vnnissihle I:Xposurc Limit. "n/e" indicates that no exposure limit has been established. An asterisk (") indicates a hose idcntm is a trade secret of our supplier and unknown to us. "(710N 3: HAZARDS IDENTIFICATION aercency Overview I<<nce. ph\'sical form. odor: White/clear/red paste with vinegar odor. 'A UTION! Eve. Skin and respiratory irritant. Avoid eye contact. May be harmful if swallowed. 'lential health effects: :•inmry routes of exposure: Ill Contact Skin Absorption steins of acute overexposure: ,in: 'tlllcrtic irritation. Eye Contact Inhalation Ingestion XXX XXX cs: acetic acid vapor given off during cure can cause eye irritation in poorly ventilated areas. nhalation: Ill\ irritate upper respiratory tract. I'_- est u,ntltls consumed due to carelessness during normal operations should not cause injury. Ingestion of r ; ;u�tounrs may cause discomfort. ivtatertat )atety uata )neer , in No. 1702 SILITE RTV SILICONE --CLEAR, WHITE AND RED Page- 7 iTccts Ot'Chronic Overexposure: ledical Conditions Which May Be Aggravated By Exposure: ,n)c reported ircino(enicity - OSHA regulated: ACGIH: National Toxicology Program: International Agency for Research on Cancer: Cancer - suspect constituent(s): NONE I)er ; i rests: �;u:) available. .a`f ION 4: FIRST AID MEASURES irs( aid for eves: lush with water for 15 minutes. Obtain medical attention. irst aid for skin: \'1pe offand flush with water first aid for inhalation: move to iresh air. Obtain immediate medical attention. Wsl air for ingestion: himn immediate medical attention. i:CTION 5: FIRE FI( xtin;,ruishing media: aicr Carbon Dioxide XX XXX Dry Chemical Foam XXX XXX ❑tsh Point (F): >250 Method: Tag closed cup ,mosive limits in air-- Lower: N/D Upper: N/D Alcohol Foam aerial lirefrahtlna procedures: wear self-contained breathing apparatus and protective clothing. *water fog. uusual fire and explosion hazards: I;i\ emitacrid smoke and irritating fumes. kizardous products of combustion: clic acid: oxides of carbon. Possibly fine particulate silica on complete combustion. Formaldehyde. ,TTION G: ACCIDENTAL RELEASE MEASURES :)ill Control: n gree spills. ventilate area. Wear the appropriate personal protective equipment. untaill ill ent: suitable absorbent material. Icanuh: Crapc up spill and place in moisture -proof containers. Scrub areas of large spills with detergent and water rrnuwe vine(ar odor. :)cciai urocedures: Iviateriai,3aiety uata 3iieet ,In No. 1702 SILITE RTV SILICONE --CLEAR, WHITE AND RED Page- 8 41CTiON 7: HANDLING AND STORAGE iandling precautions: ;ir;lscs acctic acid on contact with moisture or water vapor. Use with good ventilation. Avoid excessive of acetic acid vapor. Provide appropriate ventilation/respiratory protection against ,:composition products (see section 10) during welding/flame cutting operations and to protect against .!isancC dust during sanding/grinding of cured product. !andlin., precautions: .ore in a scaled container below 90f. i:CTiON 8: EXPOSURE CONTROLS/PERSONAL PROTECTION '1L'IIICO1,11I? controls ^Ildatlon: srlrticient ventilation to maintain exposure levels below tiv. General area ventilation is usually e�luatc: in confined areas or for high-volume uses of the silicones, local exhaust is recommended. Cher engineering controls: ivc emergency shower and eye wash available. •rsonal protective equipment ,, c ,Ind face protection: Ik2ty �-'lasses with side shields. Xul protection: n111 sleeves and other protective clothing as required to prevent skin contact. csniralory protection: rorcerive `Tear needed in well -ventilated areas. A niosh-approved acid vapor respirator my be required hcunrly ventilated areas. i•:CTION 9: PHYSICAL AND CHEMICAL PROPERTIES ;rccific uravity: 1.04 letting, point(F) N/D :Igor Pressure (mmHg): N/D AT 77 F Inc f<-yranis/liter): <70 rcent volatile by volume <5 •rcent solids by weight >95 pilin!( point (F) >300 :lpor density (air=1) : >1 \:Iporntion rate (butyl acetate =1): <1 :debility in water: NEGLIGIBLE solution or slurry in water): N/D FICTION 10: STABILITY AND REACTIVITY ;lis product is chemically stable. azardous polynlerization will not occur urlditions to avoid: Ir ;n- moisture causes acetic acid vapors to form. im inpatible materials: ron_ OXiclizin' agents. Material Ijatety uata jheet :iri No. 1702 SILITE RTV SILICONE --CLEAR, WHITE AND RED Page- 9 hazardous decomposition products: :'tic acid: oxides of carbon. Possibly fine particulate silica on complete combustion. Formaldehyde. ,nitlitions of hazardous polymerization: ;o applicable. :';CTION 11: TOXICOLOGICAL INFORMATION cute oral effects: - _•Ol K,\ h): No data available. _,aha available. :Lite dermal effects )��0 1 RABBIT): No data available. data available. cute inhalation effects: '�O (IZAT): No data available. 0 data available '.'e irritation: Mata available uhchronic Effects :,nc• known. hronic effects „nc known. .u-cinoaenicity, teratogenicity, and mutagenicity: 0ne known. ',,icouruical information on hazardous chemical constituents of this product: ustituent Oral LD50 Dermal LD50 Inhalation LC50 (rat) (rabbit) (rat, 4 hours) hvltriacetoxysilane n/d n/d n/d icthvitriacetoxvsilane 2060 mg/kg n/d n/d i,.CTION 12: ECOLOGICAL INFORMATION cotoxicity: tiara available t(ibility and persistence: Environmental fate: „ dam available. No data available. :NOTION 13: DISPOSAL CONSIDERATIONS v'asic mana-ement recommendations: )isnosc ole in accordance with federal, state, and local regulations. d-- CTION 14: TRANSPORT INFORMATION 'raper shipping name: Non-regulated material 'ethnical name: i/crit ciass: None 11 i'c Coll Material Safety Data Sheet ':irl No. 1702 SILITE RTV SILICONE --CLEAR, WHITE AND RED Page- 10 number: N/A packing group: N/A IMDG Page no. N/A ncr,cncv response guide no. N/A .-CTION IS: REGULATORY INFORMATION i Federal Regulations ';C'A: ,-11 in<<redients of this product are listed, or are exempt from listing, on the tsca inventory. nc hollowing RCRA code(s) applies to this material if it becomes waste: None c2uiatory status of hazardous chemical constituents of this product: Extremely Toxic Cercla TSCA 12b Export u 1,MLICIlt Hazardous* Chemical** RQ(lbs) Notification 1.0triacetoxysilane NO NO NO NOT REQUIRED iclhvltriacetoxvsilane NO NO NO NOT REQUIRED on,nit the appropriate regulations for emergency planning and release reporting requirements for substances on the sara section I , \ucmciv hazardous substances list. ui smiiccs for which the "toxic chemical" column is marked "yes" are on the sara section 313 list of toxic chemicals. for which nw): be required. Consult the appropriate regulations for specific requirements. ::ossification of the material for SARA section 312 hazardous materials inventory reporting: .nunediate health hazard .mnoian re�-ulations +1I-hN11S hazard class(es): D2B I omponcnts of this product are on the domestic substances list. t�:CTION 16: OTHER INFORMATION l hazardous Materials Information System (HMIS) ratings: i health Flammability Reactivity 'f 0 nim nianon ano reconunendattons in this document are based on the best intormation available to us at the time of preparation. r mai<c no other warranty. express or implied. as to its correctness or completeness. or as to the results of reliance on this u;ncm. JNJ Industries, Inc. 195 E. Main Street, Suite 303 Milford, MA 01757 Phone (800) 554-9994*Fax (508) 478-5290 HAZARD RATING 4 = Extreme 3 = High 2 = Moderate 1 = Non -Toxic, Slight 0 = Insignificant --------------------- Fire 3 Toxicity 2 0 Reactivit 0 S ecial .MATERIAL SAFETY DATA SHEET MATERIAL GlobalTechT"I CODE HEY Isopropyl Alcohol, 70% �ARDCLASS IPA/DI Flammable Liquid , ORMULA DATE ISSUED NA CHEMICALNAMEORSYNONYMS 7/11196 2 -Propanol USP Isopropyl Alcohol USP Water DI I - APPROXIMATE COMPOSITIONAL INFORMATION APPROX. WEIGHT % 70 30 II - PHYSICAL PROPERTY INFORMATION TWA/TLV 400 ppm TWA NE 'PEARANCE; ODOR; pH VISCOSITY Water Clear Liquid pH=7 NA ELTING/FREEZING POINT BOILING POINT VAPOR DENSITY (Air) = 1) -88.50C F.P. 179°F (82°C) 2.07 LUBILITY IN WATER Vii° VhLATtLc:m,,.A,oW Complete �, ..,...�.,,...-c...,..,. lete b .0 C.:i::a`....sv.�i:�.:iir:i7l�) p 100% . 33 ECIFIC GRAVITY (Water -=I) EVAPORATION RATE (Butyl Acetate = 1) 0.88 2.88 III - FIRE AND EXPLOSION HAZARD INFORMATION ASH POINT AUTO IGNITION TEMP LOWER EXPLOSION LIMIT % UPPER EXPLOSION LIMIT F (17° C, TCC) Will Not Occur NA NA TINGUISHING MEDIA X Foam _ "Alcohol" Foam X CO, X Dry Chemical X Water Spray Other :CIAL FIRE FIGHTING PROCEDURES Use water spray to cool containers and to prevent flammable vapor from escaping. Water may be ineffective on direct flame, but can be used to flush spills from ignition or disperse vapor JSUAL FIRE AND EXPLOSION HAZARDS Liquid is invisible and flammable, vapors may travel in low areas to ignition source IV - HEALTH HAZARD INFORMATION 'OMMENDED WORK PLACE EXPOSURE LIMITS 500 ppm STEL OSHA & ACGIH 'ECTS OF OVEREXPOSURE Inhalation: May cause mild irritation to nose, throat or above TLV -headache Eye Contact: Slight to moderate irritation, may cause corneal injury Skin Contact: Prolonged contact results in skin drying Ingestion: May cause vomiting, diarrhea, drowsiness, cramps RGENCY AND FIRST AID PROCEDURES Inhalation: Move subject to fresh air, give artificial respiration if breathing has stopped Eve or Skin Contact: Flush with large amount of water. Contact Physician. Remove contaminated clothing and wash before reus, Ingestion: If patient is conscious Give two classes of water/milk ind inrinrn vnmitin 7 r... ,,,,: .._ __ R , A �OCTITE CORPORATION ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (8601, 571-5100 MATERIAL SAFETY DATA SHEET 738- Act_vator 05/01/98 Page 01 of 05 _._EMICAL PRODUCT AND COMPAN`f __DENTI ICA77-,N em i`ac. 20263 =--duce 'F-ine: Activator _ 3•'PJS_ T IO�i, IN, ON=NGRED=jj7S ^ed e _s Ati No. -"ter aNE 1�2-82-5 50-55 Aldehyde -aniline condensate 68411-20-1 30-35 TSOPRCPYL ALCOHOL 67-63-0 15-20 -f:;anccopper compound 13395-16-9 J.O1-0.1 -_,-edients which have exposure _imits ._-,CC.9;iTW;V =?r' is �,'�v'1, HER Jr_ S TL_V, JJ) -._-- _-NE =_ 0 Ocm TWA 50,J ppm TWA None 1640 ma. /M3 1600 mg/M3 ALCOHOL 100 ppm 'TWA v_f'D_ pom TWA 400 ppm TWA 983 mg/m3 980 mg/m3 DuPont AEL Doper comoou^d _,_ 0.2ma/m3fume Cu 0.1mc/7:3 T�JA gone ma/M3 dust Cu 1 mg/i 3 d'wst - csu _ L__ai is =7 ACGL. OSHA _.r ed -en. S L V'!,(_ .---• __'_•— :''.JV ZDom 0, Dom 050 mg/M3 2000 mg; ?3 :_LCOHOL 00ycm SOC oom 1230mg/m3 122"S- mg/7:3 ___ ZAK.DS IDENTIFICATION f_:ma f v Routes of Entry: :::.igns and Symptoms E�c�osure Existing Conditions A,_tgravated by Exposure: CTIT� CORPORATION gym. :!o. . Severe eve irritant. Sk-n irritant. n,alation irritates nose and throat. Ingestion may irritate digestive tract and cause nausea, vomiting, and diarr-.ea. Aspiration of material into the lungs can cause chemical pneumonitis, Sv-_Ch can be fatal_• Heptane and lSopropano'_: Inhalation, ingestion, eye and skin contact. Dizziness, anesthesia, unconsciousness. Heptane: Preexisting skin conditions, heart ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MAT ERI..L SAFETY DATA SHEET 20263 05/01/98 Page 02 of 05 .. �jAEARDS IDENTIFICATION (continued) conditions, respiratory disorders. Isoprocancl: Skin, eve, and _rescJratory disorders. Literature Referenced Carcinogen -n .redients Target Organ. and Ot; er Hea_-.. 2i=ecus NTP IARC OSHA CNS IRR NO NO NO _de,;de-aniline condensate No Data NO NO NO �OP�GPYL ALCOHOL ALG CNS IRR NO N/A NO �--7anccopper compound BLO IRR KID LIQ✓ ------------------------------------------------------------------------------- NO NO NO _ IDl_ acle O B_(DCC -RR -- -L- an- - _1`J _,_ ver -RST AID MEASURES -esc-on: :-_ _3nt3Ct: _..- zn=act. IRE 77GHTING MEASURES ALG All ----_,en CNS Central nervc Z sys_em KID Kidney Do not -i-duce vomiting. Keec_ i..di ai dual calm. Obtain medical attention. Remove to -fresh a-_ _ i 1p_c-s persist, obtain medical attention. Wash +i th soap and water. Flus-. at _east 15 mJnu—s : =_-. __er. Obtain medical attention. -_ash Point: 250E Me-.hcd. S -imated -.- --mended — -suing Agents: Carbon dioxide, =cam, dry r ne-, _ec-a- -refighting - .._edUres : Not a-iai_able : _�rdous Products formed ___ or Thermal Decomp Irri=acing organic vapers _re Jr _ _. _o,._on Hazards: Vapor may travel cpns_derGp_e .._s-Gnce _o source i I --on and flash bac :. e L_mi ,s by volume in air)Lower b.; volume in air)Upper ICTITE CORPORATION _ -n. Bi o . . 1.1' Herr -ane 2.0 Isopropyl aicchol 6.7s Heptane 12.7< Isopropyl aicoho- ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET 20263 . =.CCIDENTAL RELEASE MEASURES 05/01/98 Page 03 of 05 ;.s be taken in case G s�.p 1. o ._ ___ or i..a..• la_ntain good ventilation. Avoid ignition sources. Soak up remainder in an inert absorbent and store in a closed container until distiosal. a A a AND'LING AND STORAGE _.e Storage:Store below 100oF in a tightly closed container away from oxidizing materials and sources of iGnitiOn. n - Loctite Customer Service 1-800-243-4814 for shelf life information) ^-g: Keee away from flame. Avoid prolonged breathing of vapors. Avoid skin or -,-e`contact. 7:iPOSURE CONTROLS, PERSONAL PROTECTION - Safety glasses or goggles. _--• Rubber or plastic gloves. -at-o Sufficient to maintain vapor concentration below TLV. =ra r'J NOL available See Section 2 for Exposure Limi_s. _STCAL AND CHEMICAL PROPERTIES _.a_ance: Amber liquid Alipncltic 122oF -• Does not apply i -.. Water. TuT,iSC ipie ---_ r3,_ty 0. 094 :ic iomcol::_^.0 �- lod G.�, 3E 84�i 645.1 Qr amS per i,. �.er - =Cess.___.Estimated: 35 mm at 68oF Not available ac I e a_... `. Po `/:.Teri za �_c- W___ not occur C c a__w__„_rong Oxidizers, s_rz= ac=:s or gases, selected a -.=pec p2rO Y' 'des, ac' d ....__c `=s, acid ar'_il ldrideS alkali metals, ammc^_ia. --- -- to ?vola: Not available CORPORATION 05/01/98 ROCKY ;ILL, CONNECTIC'T 06067 EMERGENCY PHONE: (860) 571-5100 ,-__IERIAL SAFETY DATA SWEET 'pace 04 of 05 _... 2026:; BILITY AND REACTIVIT`i (continued) ;a-ardous Decomposition rOu cts (non -thermal): None __._)XICOLOGICAL INFORMATION See Section 3. _'07C•GICAL INFCRMATIONi No data available _ =., _)SAL CONS IDERAT!OMS emmended methods of s csa1: Incinerate following EFA and local regulations. -_ - _.�_�fdous Waste :=Cer D001 - Hazardous waste per 4007R 26..2;. -R=.NSPORTAT ION I�iFORMATION �? ..FR =-2) nes`i_ Ground 'Transport __ ce Shipping Name: Consumer Commodity (Not more than one liter); Flammable Iiquids, n.o.s., (Contains hectane and isooropanci) (More than one lite -1 �aSS or on: ORM-D (Not more than one Class 3, Packing Group IT (More =_^an one liter) =uent-=_�ation Number: None (Not more than one Lter',; UN 1993 (More than one liter) Iarine Pollutant: None roper Shipping Name: Flammable liquid, n.o.s. (Contains heptane and isopropanol) _ass or Division: Class 3, Fucking Group IT or =D Number. UN 1993 _A -CRY TNFORNI_.TION _ ee3 -on 65 'dFOR.i1 TION NFP"A(R) Code: _.. Hazard: I - - __-- -_ORP3RAT _0N :7TE ER INFORMATION .eac`_vity Hazard: oeci is Hazard: HMIS (R) Code: iealth Hazard: :lammability Hazard: .reactivity Hazards: rsonal Protection: No Preposition 65 chemicals are known to be oresenr. I ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: ;360; 571-5100 MATERIAL SAFETY DATA SHEET 0 Does not apply 1 3 0 See Section 8. 05/01/98 Page 05.of 05 (continued) FPA is a registered trademark of the National Fire Protection Assn. is a registered trademark of the National Pais.- and Coatings Assn. By: Stephen Repetto Research Chemist; Safety,Health&Regulatory Affairs Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 hone: (860) 571-5100 :.ilio Date: August 06, 1996. 0013 " ,n - ,r)Q fl. - O LOCTITE CORPORATION 01/16/00 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 384 OUTPUT EFD 25 ML SYR 20286 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Item No.. 4 Product Ty pe: Tough Acrylic 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Aluminum hydroxide, hydrated 21645-51-2 60-65 Heterocyclic methacrylate 2455-24-5 15-20 Hydroxyalkyl methacrylate 27813-02-1 5-10 Synthetic Rubber 126904-15-2 5-10 CUMENE HYDROPEROXIDE* 80-15-9 1-3 SACCHARIN 81-07-2 1-3 * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) Aluminum hydroxide, hydrated 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 respir. Hydroxyalkyl methacrylate None None 1 ppm TWA 3 ppm STEL Exposure Limits (STEL) P_CGIH OSHA Ingredients (TLV) (PEL) 3. HAZARDS IDENTIFICATION Toxicity: Severe eye irritant. Moderate skin irritant. Possible inhalation irritant. May be harmful if swallowed. May cause kidney or liver damage. Primary Routes of Entry: Eye, skin, inhalation, ingestion. Signs and Symptoms of Exposure: May cause severe dermatitis on prolonged contact in sensitive individuals. Existing Conditions Aggravated by Exposure: None known LOCTITE CORPORATION 01/16/00 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Item No.: 20286 3. HAZARDS IDENTIFICATION (continued) Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Aluminum hydroxide, hydrated IRR LUN RES NO NO NO Heterocyclic methacrylate ALG IRR NO NO NO Hydroxyalkyl methacrylate ALG IRR NO NO NO Synthetic Rubber No Data NO NO NO CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO SACCHARIN ------------------------------------------------------------------------------- NTO YES 2B NO Abbreviations 23 Possibly carcinogenic to humans ALG Allergen CNS Central nervous system COR Corrosive IRR Irritant LUN Lung MUT Mutagen NTO No Target Organs RES Respiratory 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. obtain medical attention. Inhalation: Does not apply Skin Contact: wash with soap and water. Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200°F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Special Firefighting Procedures: Not available Hazardous Products formed by Fire or Thermal Decomp Irritating organic vapors Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower Not available (% by volume in air)Upper Not available LOCTITE CORPORATION 01/16/00 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 05 Item No.: 20286 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Scrape up as much as possible. Residues may be cleaned with solvent. Store in a partly filled, closed container until disposal. 7. HANDLING AND STORAGE Safi Storage: Store below 100°F (Contact Loctite Customer Service 1-800-243-4874 for shelf life information) Handling: Avoid prolonged skin contact. Keep away from eyes. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eves: Safety glasses or goggles. Skin: Impermeable gloves recommended for prolonged or frequent use. Ventilation: Does not apply Respiratory Not available See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Odor: Boiling Point: pH: Solubility in Water: Specific Gravity volatile Organic Compound (EPA Method 24) Vapor Pressure: Vapor Density: Evaporation Rate (Ether = 1) White paste Mild More than 300°F Does not apply Slight Approximately 1.0 26.6%; 266 grams per liter Less than 10mm at 80°F Not available Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur incompatibility: None Conditions to Avoid: Not available Hazardous Decomposition Products (non -thermal): None LOCTITE CORPORATION ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Item No.: 20286 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 01/16/00 Page 04 of 05. Estimated oral LD50 more than 5000 mg/kg. Estimated dermal LD50 more than 2000 mg/kg. No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None 15. REGULATORY INFORMATION CA Proposition 65: WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. propylene oxide, acetaldehyde, dioxane 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: Fire Hazard: Reactivity Hazard: Specific Hazard: LOCTITE CORPORATION Item No.: 16. OTHER INFORMATION Estimated HMIS(R) Code: Health Hazard: Flammability Hazard: Reactivity Hazards: Personal Protection: This product contains Saccharin. No Prop65 hazard warning is necessary if this product is used as reasonably anticipated. 2 1 1 Does not apply ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET 20286 2 1 1 See Section 8. 01/16/00 Page 05 of 05 (continued) NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist- Safety,Health&Regulatory Affairs Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: January 27, 1999 Revision: 0028 .1# application assistance . browse catalog . distributor locator . datasheets . what's ne8v about Loctite . contact loctite . literature . Loctite world wide . search . home I. PRODUCT IDENTIFICATION PRODUCT NAME: Removable Threadlocker 242 ITEM NUMBERS: FAnaerobic5 42 4231. 24241 PRODUCT TYPE:-- II. COMPOSITION Ingredients SPolyygggl1lyycol dimethacrylate ACCHARINI oleate CUMENE HYDROPEROXIDE* METHYL ALCOHOL* SILICA, AMORPHOUS TREATED N N-Dialkyltoluidines TITANIUM DIOXIDE Y UA 1A SHEET CAS No. % 25852-47-5 60-65 9004-96-0 25-30 81-07-2 3-5 80-15-9 -3 67-56-1 Not available 112945-52-5 1-3 613-48-9 0.1-1 13463-67-7 0.1-0.5 Fax: (203)'571.-5495--, * This component is listed as a SARA Section 313 Toxic Chemical. III. CHEMICAL AND PHYSICAL PROPERTIES Vapor Pressure; Vapor Density; Solubility More than 200°F in Water: Specific Gravity; 1 Boiling Point: Volatile Organic Compound (EPA Method 24) EPporation Rate i ther = 1) Not available ppearance: Does not apply Blue Odor: liquid Mild Less than 5mm at Not available Slight 1.1 at 75°F More than 300°F 80°F 13.3%; 146 grams per liter IV. FLAMMABILITY AND EXPLOSIVE PROPERTIES Flash Point: Estimated NFPA Code: More than 200°F Health Hazard: 1 Fire Hazard: Reactiyit Hazard: i Specific Hiazard: Estimated HMIS Code: Does not apply Health Hazard: 1 Flammability Hazard: 1 Reactivity Hazard: 1 Personal Protection: Explosive Limits: See Section X. lommended by volume in air Lower by volume in air Upper Not available Not available Extinguishingg Aggents: Hazardous Carbon dioxide, pro ducis Formed Method: Tag Closed Cup foam, dry chemical 1CT NO.: 242 5� 1 X95 Dy Fire or Thermal Decomp Irritating organic vapors; oxides of carbon. Unusual Fire or Explosion Hazards: None Compressed Gases: None Pressure at Room Temp.: Does not apply V. SPILL OR LEAK AND DISPOSAL PROCEDURES Steps to be taken in case of spill or leak: Soak up in an inert absorbent. Store in a partly Recommended methods filled, closed container until disposal. of disposal: Incinerate following EPA and local regulations. VI. STORAGE AND HANDLING PROCEDURES Safe Storage: (Contact Loctite Customer Handling: II. SHIPPING REGULATIONS DOT (49 CFR 172) Domestic GroundTransport Proper Shipping Name: Hazard Class or Division: Identification Number: Marine Pollutant: Store below 100°F. AvoidCprolonged4ski87contact. Keeplawaynfromaeyes. Unrestricted Unrestricted None None ?09 --••+-. . v:1 .� ill Vll �... ILVJJ J/1-.JiVli 1'!il1. lt: �%�f J/1-J40J MATERIAL SAFETY DATA SHEET Page 2 of 3 Product Name: Removable Threadlocker 242 Item No.: 24205, 24231, 24241 VII. SHIPPING REGULATIONS (continued) IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: Nina VIII. REACTIVITY DATA -Stability: HazardousPPolymerization: Willlnot occur. Hazardous Decomposition Products (non -thermal): None Incompatability: one IX. EMERGENCY TREATMENT PROCEDURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention Inhalation: Does not appy -Skin Contact: Wash thoroughly with soap and water Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. X. PERSONAL PROTECTION Eyes: Skin; Ventilation: XI, HEALTH HAZARD DATA Toxicity: Primary Routes of Entry: Signs and Symptoms of Exposure: Existing Conditions Aggravated by Exposure: Safety glasses or goggles. Neoprene, rubber, or butyl rubber gloves. Does not apply Mild eye irritant Oral LD50 more than 10000 mg/4. Dermal LD50 more than 5000 . Eye, skin contact. May cause dermatitis on prolonged contact in sensitive individuals None known Expposure Limits (TWA) Ingredients RV (SEA) OTHER COR METHYL ALCOHOL 200ppm TWA skin 200ppm TWA skin None Irritant SILICA AMORPHOUS TREATED TITANIbM 262 m /m3 skin 10 mg7m3 TWA 262 mg/m3 skin 6 m9 /m3 TWA None NER DIOXIDE 10 mg/m3 dust 15�m33rdust None mg Exposure Limits (STEL) Ingredients RV (PEA) METHYL ALCOHOL 250 pp skin 328 250 pp skin mg skin 325 mg skin Ingredients for which no Exposure Limits have been established listed above. are not Literature Referenced Ingredients Target Organ and Other Health Effects Carcinogen NTP IARC OSHA Polyglycol dimethacrylate ALG IRR 0 NO Pol 1 col oleate yg y SACCHARIN IRR NO NO NO CUMENE HYDROPEROXIDE No Data ALG CNS COR IRR MUT NOS NO NO NO 'METHYL ALCOHOL SILICA, AMORPHOUJ TREATED N N-Dialkyltolui ines EYE IRR MET NER NUI NO NO/ NO NOA NO TITANIUM DIOXIDE ------------------------------------------------------------------------------- No Data IRR NUI NO NO NO Abbreviations N/A ALG Not Applicable Allergen 2B Possibly carcinogenic to humans COR Corrosive CNS EYE Central nervous system Eyes IRR Irritant MET Metabolic MUT NUI Mutagen Nuisance dust NER Nervous System nin � A J[Yf LI'ID A lli J(7r rage 3 Ot 3 Item No.: Name: Removable Threadlocker 242 24205, 24231, 2424 XII. REGULATORY COMPLIANCE CA Proposition 65: This product contains Saccharin. No prop65 hazard warning is necessary if this product is used as reasonably anticipated. XIII. PREPARATION INFORMATION Prepared By: Stephen Repetto Title: Research Chemist Environmental Health & Safety Coppan Loctite Corp 1601 Tr Br Cr, Rocky Hill CT 0667 Marn5 :Phone: (203) 571-5106 evision Date: anuary 03, 1995 Revision: 0028 211 i `.A ' OWRIYChemical Products MATERIAL SAFETY DATA SHEET SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME CIRCALOK 6701 ACi % _ ?RODUCT USE/CLASS :. ENCAPSULANT, PART A\ DATE PRINTED: 07/16/99 _DEFERENCE f ormerly LORD CORPORATION EMERGENCY TELEPHONE: 814 763-2345 CHEMICAL PRODUCTS DIVISION 24 HOURS A DAY 2000 WEST GRANDVIEW BLVD ERIE, PA 16514 INFORMATION TELEPHONE 814 868-3611 ?REPARE DATE: 09/21/98 PREVIOUS MSDS REVISION DATE: 06/26/97 SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS Wt Exposure LessGuidelines AGiH— Chemical Name CAS Number Than TWACISTEL TWAOICeillUnitslSkin Platinum complex Proprietary 0.1% N.E. N.E. N.E. N.E. N.E. - Not Established, S - Skin Designation, C - Ceiling SECTION 3 - HAZARDS IDENTIFICATION *** EMERGENCY OVERVIEW ***: Clear, viscous Liquid, with No odor. May cause skin and eye irritation. May cause allergic skin reaction. EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation: EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation. May rause dermatitis. Contains a trace amount of platinum complex that may cause skin sensitization. EFFECTS OF OVEREXPOSURE - INHALATION: No inhalation hazard expected during normal workplace use. EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed. Ingestion is not an expected route of entry in industrial or commercial uses. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: This product contains methylpolysiloxanes which can generate formaldehyde at approximately 300 degrees F (150 C) and above, in atmospheres which contain oxygen. Formaldeheyde is a skin and respiratory sensitizer, eye and throat irritant, acute toxicant, and potential cancer hazard. Workplace exposure (Continued on Page 2) 99029T1A080 Product: CIRCALOK 6701 A, Prepare Date: 09/21/98 Page 3 SECTION 6 - ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Avoid breathing vapors. Use self-contained breathing equipment. Notify appropriate authorities if necessary. Contain and remove with inert absorbent material. Avoid contact. Keep non-essential personnel away from spill area. Before attempting cleanup, refer to hazard caution information in other sections of the MSDS form. SECTION 7 - HANDLING AND STORAGE :HANDLING: Keep closure tight and container upright to prevent leakage. -lash thoroughly after handling. Avoid breathing of vapor or spray mists. Do not handle until all safety precautions have been read and understood. Do not weld or flame -cut an empty drum. Use with adequate ventilation. STORAGE: Store only in well -ventilated areas. Keep from freezing. Keep container closed when not in use. SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Sufficient ventilation in pattern and volume should De provided in order to maintain air contaminant levels below recommended exposure limits. RESPIRATORY PROTECTION: Respiratory protection is not required under =ormal working conditions where adequate ventilation is present. SKIN PROTECTION: Use neoprene, nitrile, or rubber gloves to prevent skin contact. EYE PROTECTION: Use safety eyewear including safety glasses with side shields and chemical goggles where splashing may occur. OTHER PROTECTIVE EQUIPMENT: Use disposable or impervious clothing if work clothing contamination is likely. Remove and wash contaminated clothing oefore reuse. HYGIENIC PRACTICES: Wash hands before eating, smoking, or using toilet Z acility. Do not smoke in any chemical handling or storage area. Food or beverages should not be consumed anywhere this product is handled or stored. Wash thoroughly after handling. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES BOILING RANGE : N.A. VAPOR DENSITY Is heavier than air APPEARANCE : Clear, viscous ODOR THRESHOLD : N.D. (Continued on Page 4) Product: CIRCALOK 6701 A, Prepare Date: 09/21/98 SECTION 14 - TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME: NOT REGULATED DOT HAZARD CLASS: NONE DOT UN/NA NUMBER: NONE Page 5 EMERGENCY RESPONSE GUIDE NUMBER: NONE PACKING GROUP : NONE SECTION 15 - REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: AS FOLLOWS - DSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: ----------- CHEMICAL NAME ----------- CAS NUMBER WT % IS LESS THAN NONE TOXIC SUBSTANCES CONTROL ACT: INVENTORY STATUS The chemical substances in this product are on the TSCA Section 8 Inventory. INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled ?roduct Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: No information available. SECTION 16 - OTHER INFORMATION HMIS RATINGS - HEALTH: 1* FLAMMABILITY: 1 REACTIVITY: 0 * - Indicates a chronic hazard; see Section 3 REASON FOR REVISION: Revised Section 3; Chronic hazards VOLATILE ORGANIC COMPOUNDS (Calculated) : 0.00 lbs/gal, 0 grams/ltr (Continued on Page 6) Poduts� ANAORDMATERIAL SAFETY DATA SHEET SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : CIRCALOK 6701 B PRODUCT USE/CLASS :,.,ENCAPSULANT,�PARTB DATE PRINTED: 07/16/99 REFERENCE : formerly' - CORD CORPORATION EMERGENCY TELEPHONE: 814 763-2345 =MICAL PRODUCTS DIVISION 24 HOURS A DAY :000 WEST GRANDVIEW BLVD ERIE, PA 16514 INFORMATION TELEPHONE 814 868-3611 PREPARE DATE: 09/21/98 PREVIOUS MSDS REVISION DATE: 06/26/97 SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS Wt Exposure Guidelines Less ACGIH I OSHA Chemical Name CAS Number Than TWA STEL TWA ICeil Units ISkin This product is not considered hazardous as defined by 29 CFR 1910.1200 (OSHA Hazard Communication Standard). N.E. - Not Established, S - Skin Designation, C - Ceiling SECTION 3 - HAZARDS IDENTIFICATION ** EMERGENCY OVERVIEW ***: Clear Liquid, with No odor. May cause skin nd eye irritation. 'IFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: rause dermatitis. IFFECTS OF OVEREXPOSURE - INHALATION: formal workplace use. May cause skin irritation. May No inhalation hazard expected during EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed. Ingestion is aot an expected route of entry in industrial or commercial uses. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: This product contains ,iethylpolysiloxanes which can generate formaldehyde at approximately 300 iegrees F (150 C) and above, in atmospheres which contain oxygen. ,ormaldeheyde is a skin and respiratory sensitizer, eye and throat (Continued on Page 2) 99029=080 A Product: CIRCALOK 6701 B, Prepare Date: 09/21/98 SECTION 6 - ACCIDENTAL RELEASE MEASURES Page 3 STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Avoid breathing vapors. Use self-contained breathing equipment. Notify appropriate authorities if necessary. Contain and remove with inert absorbent. material. Avoid contact. Keep non-essential personnel away from spill area. Before attempting cleanup, refer to hazard caution information in Other sections of the MSDS form. SECTION 7 - HANDLING AND STORAGE HANDLING: Keep closure tight and container upright to prevent leakage. ,Dash thoroughly after handling. Avoid breathing of vapor or spray mists. Do not handle until all safety precautions have been read and understood. Do not weld or flame -cut an empty drum. Use with adequate ventilation. STORAGE: Store only in well -ventilated areas. Keep from freezing. Keep container closed when not in use. SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Sufficient ventilation in pattern and volume should e provided in order to maintain air contaminant- levels below recommended exposure limits. RESPIRATORY PROTECTION: Respiratory protection is not required under normal working conditions where adequate ventilation is present. SKIN PROTECTION: Use neoprene, nitrile, or rubber gloves to prevent skin contact. EYE PROTECTION: Use safety eyewear including safety glasses with side Shields and chemical goggles where splashing may occur. OTHER PROTECTIVE EQUIPMENT: Use disposable or impervious clothing if work clothing contamination is likely. Remove and wash contaminated clothing before reuse. HYGIENIC PRACTICES: Wash hands before eating, smoking, or using toilet facility. Do not smoke in any chemical handling or storage area. Food or beverages should not be consumed anywhere this product is handled or stored. Wash thoroughly after handling. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES BOILING RANGE : N.A. VAPOR DENSITY : Is heavier than air APPEARANCE : Clear ODOR THRESHOLD : N.D. (Continued on Page 4) •' 1 a Product: CIRCALOK 6701 B, Prepare Date: 09/21/98 SECTION 14 - TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME: NOT REGULATED DOT HAZARD CLASS: NONE DOT UN/NA NUMBER: NONE Page 5 EMERGENCY RESPONSE GUIDE NUMBER: NONE PACKING GROUP SECTION 15 - REGULATORY INFORMATION J.S. FEDERAL REGULATIONS: AS FOLLOWS - : NONE DSHA: Non -hazardous by definition of Hazard Communication Standard (29 CFR X910.1200) 3ARA SECTION 313: -his product contains the following substances subject to the reporting -equirements of Section 313 of Title III of the Superfund Amendments and I eauthorization Act of 1986 and 40 CFR Part 372: ----------- CHEMICAL NAME ----------- CAS NUMBER WT o IS LESS THAN .vONE TOXIC SUBSTANCES CONTROL ACT: `NVENTORY STATUS 7.he chemical substances in this product are on the TSCA Section 8 _nventory. INTERNATIONAL REGULATIONS: AS FOLLOWS - :ANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled ?roduct Regulations except for use of the 16 headings. �ANADIAN WHMIS CLASS: No information available. SECTION 16 - OTHER INFORMATION .iMIS RATINGS - HEALTH: 1* FLAMMABILITY: 1 REACTIVITY: 0 - Indicates a chronic hazard; see Section 3 REASON FOR REVISION: Product name change VOLATILE ORGANIC COMPOUNDS (Calculated) : 0.00 lbs/gal, 0 grams/ltr (Continued on Page 6) ;. '.�R13 P oducts' MATERIAL SAFETY DATA SHEET SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION =RODUCT NAME CIRCALOK 6731 ?RODUCT USE/CLASS SILICONE CATALYST DATE PRINTED: 07/16/99 .-EFERENCE : formerly SC -29 f-f� CORD CORPORATION EMERGENCY TELEPHONE: 814 763-2345 =MICAL PRODUCTS DIVISION 24 HOURS A DAY ).00O WEST GRANDVIEW BLVD ERIE, PA 16514 INFORMATION TELEPHONE 814 868-3611 REPARE DATE: 04/19/99 PREVIOUS MSDS REVISION DATE: 09/04/98 SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS Wt % Exposure Guidelines Less ACGIH OSHA TWA Chemical Name CAS Number IThan TWA ISTEL I Cei11Units ISkin Tin catalyst Proprietary 100% 0.1 N.E. 0.1 N.E. mg/m3 S N.E. - Not Established, S - Skin Designation, C - Ceiling SECTION 3 - HAZARDS IDENTIFICATION ** EMERGENCY OVERVIEW ***: Clear to yellow Liquid, with Sweet mild odor. :armful if absorbed through skin. May cause skin and eye irritation. May rause respiratory tract irritation. EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause severe eye irritation on :ontact, with conjunctivitis and potential corneal injury if not promptly ind adequately treated. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May be absorbed through the skin _n harmful amounts. May cause skin irritation. May cause dermatitis. EFFECTS OF OVEREXPOSURE - INHALATION: May cause respiratory tract irritation. May cause headache and nausea. EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed. Ingestion is aot an expected route of entry in industrial or commercial uses. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause liver or kidney iamage. Chronic skin contact may cause dermatitis. (Continued on Page 2) 99028T19180 Product: CIRCALOK 6731, Prepare Date: 04/19/99 SECTION 6 - ACCIDENTAL RELEASE MEASURES Page 3 STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Avoid breathing rapors. Use self-contained breathing equipment. Notify appropriate authorities if necessary. Contain and remove with inert absorbent Material. Avoid contact. Keep non-essential personnel away from spill area. Before attempting cleanup, refer to hazard caution information in Dther sections of the MSDS form. SECTION 7 - HANDLING AND STORAGE L LADLING: Keep closure tight and container upright to prevent leakage. lash thoroughly after handling. Avoid breathing of vapor or spray mists. jo not handle until all safety precautions have been read and understood. :se with adequate ventilation. 3TORAGE: Store only in well -ventilated areas. Keep from freezing. Keep :ontainer closed when not in use. SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Sufficient ventilation in pattern and volume should .e provided in order to maintain air contaminant levels below recommended exposure limits. ZESPIRATORY PROTECTION: Use a NIOSH/MSHA approved chemical/mechanical =filter respirator designed to remove a combination of particulates and :rganic vapor if occupational limits are exceeded. For emergency situations, confined space use, or other conditions where exposure limits :lay be greatly exceeded, use an approved air -supplied respirator. Observe )SHA regulations (29CFR 1910.134) for respirator use. SKIN PROTECTION: Use neoprene, nitrile, or rubber gloves to prevent skin =tact. EYE PROTECTION: Use safety eyewear including safety glasses with side Shields and chemical goggles where splashing may occur. ETHER PROTECTIVE EQUIPMENT: Use disposable or impervious clothing if work _7lothing contamination is likely. Remove and wash contaminated clothing before reuse. HYGIENIC PRACTICES: Wash hands before eating, smoking, or using toilet `acility. Do not smoke in any chemical handling or storage area. Food or Beverages should not be consumed anywhere this product is handled or Stored. Wash thoroughly after handling. (Continued on Page 4) Product: CIRCALOK 6731, Prepare Date: 04/19/99 SECTION 14 - TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME: NOT REGULATED DOT HAZARD CLASS: NONE DOT UN/NA NUMBER: NONE Page 5 EMERGENCY RESPONSE GUIDE NUMBER: NONE PACKING GROUP SECTION 15 - REGULATORY INFORMATION J.S. FEDERAL REGULATIONS: AS FOLLOWS - : NONE )SHA: Hazardous by definition of Hazard Communication Standard (29 CFR 910.1200) 3ARA SECTION 313: ,his product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and eauthcrizat_on Act of 1986 and 40 CFR Part 372: ----------- CHEMICAL NAME ----------- CAS NUMBER WT % IS LESS THAN i ONE 'OXIC SUBSTANCES CONTROL ACT: :NVENTORY STATUS ,he chemical substances in this product are on the TSCA Section 8 nventory. :NTERNATIONAL REGULATIONS: AS FOLLOWS - ;ANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. 'ANADIAN WHMIS CLASS: D2A, D2B SECTION 16 - OTHER INFORMATION ISIS RATINGS - HEALTH: 2* FLAMMABILITY: 1 REACTIVITY: 0 r - Indicates a chronic hazard; see Section 3 REASON FOR REVISION: Revised MSDS Format 70LATILE ORGANIC COMPOUNDS (Calculated) : 0.00 lbs/gal, 0 grams/ltr (Continued on Page 6) U ;z_ . 10000 RCMP oducts MATERIAL SAFETY DATA SHEET SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : CIRCALOK kLD-8BLACK PRODUCT USE/CLASS : SILICONE RESIN DATE PRINTED: 07/16/99 REFERENCE : formerly S-1200 ac LORD CORPORATION EMERGENCY TELEPHONE: 814 763-2345 CHEMICAL PRODUCTS DIVISION 24 HOURS A DAY 2000 WEST GRANDVIEW BLVD ERIE, PA 16514 INFORMATION TELEPHONE 814 868-3611 PREPARE DATE: 07/16/99 PREVIOUS MSDS REVISION DATE: 08/21/96 SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS Wt % , Exposure Guidelines Less ACGIH OSHA Chemical Name CAS Number Than TWA STEL TWA Ceil Units Skin This product is not considered hazardous as defined by 29 CFR 1910.1200 (OSHA Hazard Communication Standard). N.E. - Not Established, S - Skin Designation, C - Ceiling SECTION 3 - HAZARDS IDENTIFICATION *** EMERGENCY OVERVIEW ***: Black Liquid, with No odor. Low hazard for asual industrial or commercial handling. EFFECTS OF OVEREXPOSURE - EYE CONTACT: Eye contact may cause slight irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: No hazard expected in normal industrial use. EFFECTS OF OVEREXPOSURE - INHALATION: No inhalation hazard expected during normal workplace use. EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed. Ingestion is not an expected route of entry in industrial or commercial uses. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: None expected under normal working conditions. (Continued on Page 2) 99009T1A209 Product: CIRCALOK 6708 BLACK, Prepare Date: 07/16/99 Page 3 SECTION 6 - ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Avoid breathina vapors. Notify appropriate authorities if necessary. Contain and remove 11ith inert absorbent material. Avoid contact. Keep non-essential personnel away from spill area. Before attempting cleanup, refer to hazard Laution information in other sections of the MSDS form. SECTION 7 - HANDLING AND STORAGE :HANDLING: Keep closure tight and container upright to prevent leakage. Avoid skin and eye contact. Wash thoroughly after handling. Do not handle ,ntil all safety precautions have been read and understood. Empty :ontainers should not be re -used. Use with adequate ventilation. 3TORAGE: Store only in well -ventilated areas. Keep container closed when :got in use. SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Provide adequate general ventilation where this product is used. RESPIRATORY PROTECTION: Respiratory protection is not required under normal working conditions where adequate ventilation_ is present. SKIN PROTECTION: Use neoprene, nitrile, or rubber gloves to prevent skin contact. EYE PROTECTION: Use safety eyewear including safety glasses with side shields and chemical goggles where splashing may occur. DTHER PROTECTIVE EQUIPMENT: Remove and wash contaminated clothing before reuse. HYGIENIC PRACTICES: Wash hands before eating, smoking, or using toilet facility. Do not smoke in any chemical handling or storage area. Food or oeverages should not be consumed anywhere this product is handled or stored. Wash thoroughly after handling. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES BOILING RANGE : N.A. VAPOR DENSITY : Is heavier than air APPEARANCE : Black ODOR THRESHOLD : N.D. PHYSICAL STATE : Liquid EVAPORATION RATE: Is slower than Ether ODOR : No DENSITY, LB/GAL : 13.81 SOLUBILITY IN H2O : Insoluble SPECIFIC GRAVITY: 1.66 (Continued on Page 4) Product: CIRCALOK 6708 BLACK, Prepare Date: 07/16/99 SECTION 14 - TRANSPORTATION INFORMATION DOT HAZARD CLASS: NONE DOT UN/NA NUMBER: NONE Page 5 EMERGENCY RESPONSE GUIDE NUMBER: NONE PACKING GROUP SECTION 15 - REGULATORY INFORMATION T.S. FEDERAL REGULATIONS: AS FOLLOWS - : NONE ')SHA: Non -hazardous by definition of Hazard Communication Standard (29 CFR 910.1200) SARA SECTION 313: .his product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Zeauthorization Act of 1986 and 40 CFR Part 372: ----------- CHEMICAL NAME ----------- CAS NUMBER WT % IS LESS THAN TONE =IC SUBSTANCES CONTROL ACT: :NVENTORY STATUS -he chemical substances in this product are on the TSCA Section 8 Inventory. INTERNATIONAL REGULATIONS: AS FOLLOWS - :ANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled .3roduct Regulations except for use of the 16 headings. :ANADIAN WHMIS CLASS: No information available. SECTION 16 - OTHER INFORMATION :MIS RATINGS - HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0 ZEASON FOR REVISION: Revised Product Name ;OLATILE ORGANIC COMPOUNDS (Calculated) : 0.00 lbs/gal, 0 grams/ltr LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined (Continued on Page 6) 4 Friday 12 of Jan 2001, LORD CORP 8148603999->1 978 256 1510 Page 7 of 11 Page 1 of 5 1.01;?I:)MATERIAL SAFETY DATA SHEET 11 SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name Oroduct UseiC ass LORD E-301 BLACK EPDXY RESIN LORD CORPORATION CHEMICAL PRODUCTS DIVISION 2000 WEST GRANDVIEW BLVD ERIE, PA 16514 EFFECTIVE DATE: 10/18/1999 INFORMATION TELEPHONE: 814 868-3611 TRANSPORTATION EMERGENCY CALL C H EMTREC: 800424-9300 NON -TRANSPORTATION EMERGENCY: 814 763-2345 SUPERCEDES DATE: 10/22/1997 SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS Number Weight %, ACGIH TLV -TWA ACGIH TLV -STEL OSHA PEL- TWA OSHA PEL-i CEILING Units Skin Less Than Epoxy resin Proprietary 35 % N.E. N.E. N.E. N.E. Resin 68609-97- 2 2.0% N.E. N.E. N.E. N.E. Carbon black 1333-06-4 1.0% 3.5 N.E. 3.5 N.E. mg/m3 Crystalline silica 14808-60- 7 1.0% G.1 N.E. 10 N.E. mg/m3 N.E. - Not Established, S - Skin Designation, C - Ceiling i SECTION 3 - HAZARDS IDENTIFICATION "' EMERGENCY OVERVIEW " : Viscous, black Paste, with No odor, May cause skin and eye irritation. May cause allergic skin reaction. May cause respiratory tract irritation. EFFECTS OF OVEREXPOSURE -EYE CONTACT: May cause eye irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May be absorbed through the skin in harmful amounts. May cause skin irritation. May cause skin sensitization. May cause dermatitis. EFFECTS OF OVEREXPOSURE - INHALATION: May cause respiratory tract irritation. EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed. Ingestion is not an expected route of entry in industrial or commercial uses. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause skin sensitization. Prolonged exposure to the silica - containing sanding dust of this product could cause long-term lung damage. Crystalline silica is classified by IARC as a known human carcinogen as a dust No exposure is expected during application of the product; possible exposure exists if the dried/cured product is sanded. Chronic skin contact may cause dermatitis. IARC has designated carbon black as Group 2B - inadequate evidence for carcinogenicity in humans, but sufficient evidence in experimental animals 1/12/2001 Friday 12 of Jan 2001, LORD CORP 8148603999->1 978 256 1510 Page 8 of 11 Page 2 of 5 PRIMARY ROUTE(S) OF ENTRY: Skin Contact. Inhalation, Ingestion, Eye Contact 11 SECTION 4 - FIRST AID MEASURES FIRST AID- EYE CONTACT: Flush eyes immediately with large amount of water for at least 15 minutes holding eyelids open while flushing. Get prompt medical attention. FIRST AID - SKIN CONTACT: Flush contaminated skin vvith large amounts of water while removing contaminated clothing. Wash affected skin areas with soap and water. Get medical attention if symptoms occur. FIRST AID - INHALATION: Move person to fresh air. Restore and support continued breathing. If breathing is difficult, give oxygen. Get immediate medical attention. FIRST AID - INGESTION: if swallowed, do not induce vomiting. Give victim one or two glasses of water or milk. Call a physician or poison control center immediately for further instructions. Never give anything by mouth to an unconscious person. SECTION 5 - FIRE FIGHTING MEASURES FLASH POINT: >2100F, 94C (SetaI Closed Cup) AUTOIGNITION TEMPERATURE: N.D. LOWER EXPLOSIVE LIMIT (°;): Not Applicable UPPER EXPLOSIVE LIMIT (%): Not Applicable OSHA FLAMMABILITY CLASSIFICATION: COMBUSTIBLE LIQUID -CLASS ill EXTINGUISHING MEDIA: Carbon Dioxide. Dry Chemical, Foam, Water Fog UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. Closed containers may rupture when exposed to extreme heat. Use water spray to keep fire exposed containers cool. SPECIAL FIREFIGHTING PROCEDURES: Wear full firefighting protective clothing, including self-contained breathing apparatus (SCBA). If water is used, fog nozzles are preferable. During a fire, irritating and/or toxic gases and particulate may be generated by thermal decomposition or combustion. SECTION 6 - ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Avoid breathing vapors. Notify appropriate authorities if necessary. Avoid contact. Use appropriate respiratory protection for large spills or spills in confined area. Keep non- essential personnel away from spill area. Scoop spilled material into an appropriate container for proper disposal. (If necessary, use inert absorbent material to aid in containing the spill). SECTION 7 -HANDLING AND STORAGE HANDLING: Keep closure tight and container upright to prevent leakage. Avoid skin and eye contact. Wash thoroughly after handling. Do not handle until all safety precautions have been read and understood. Empty containers should not be re -used. Use with adequate ventilation. STORAGE: Store only in well -ventilated areas. Keep container closed when not in use. SECTION 8 -EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Sufficient ventilation in pattern and volume should be provided in order to maintain air contaminant levels below recommended exposure limits. 1/1212001 Friday 12 of Jan 2001, LORD CORP 8148603999->1 978 256 1510 Page 9 of it Page 3 of 5 RESPIRATORY PROTECTION: Use a NIOSH/MSHA approved air -purifying organic vapor respirator if occupational limits are exceeded. For emergency situations, confined space use, or other conditions where exposure limits may be greatly exceeded, use an approved air -supplied respirator. Observe OSHA regulations (29CFR 1910.134) for respirator use. SKIN PROTECTION: Use neoprene, nitrile, or rubber gloves to prevent skin contact. EYE PROTECTION: Use safety eyewear including safety glasses with side shields and chemical goggles where splashing may occur. OTHER PROTECTIVE EQUIPMENT: Use disposable or impervious clothing if work clothing contamination is likely. Remove and wash contaminated clothing before reuse. HYGIENIC PRACTICES: Wash hands before eating, smoking, or using toilet facility. Food or beverages should not be consumed anywhere this product is handled or stored. Wash thoroughly after handling. 11 SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES BOILING RANGE: N.A - N.A F APPEARANCE: Viscous, black PHYSICAL STATE: Paste ODOR: No SOLUBILITY IN H2O: Insoluble FREEZE POINT: N.D. VOLATILE BY WEIGHT: 0.4% VAPOR PRESSURE: N. D. COEFFICIENT OF WATER/OIL DISTRIBUTION: N. D. (See section 16 for abbreviation legend) VAPOR DENSITY: Heavier than Air EVAPORATION RATE: Slower than Ether DENSITY, LBIGL: 17.32 SPECIFIC GRAVITY: 2.08 pH: N.A. ODOR THRESHOLD: N.D. VOLATILE BY VOLUME: 1.0% 11 SECTION 10 - STABILITY AND REACTIVITY CONDITIONS TO AVOID: Hich temperatures. INCOMPATIBILITY: Amines, acids, water, hydroxyl, or active hydrogen compounds. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, aldehydes. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur under normal conditions. STABILITY: Product is stable under normal storage conditions. SECTION 11 -TOXICOLOGICAL INFORMATION PRODUCT LD50 (ORAL) No Data (DERMAL) No Data PRODUCT LC50 No Data SECTION 12 - ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: No Information. il SECTION 13 -DISPOSAL CONSIDERATIONS 1/12/2001 4 . " Friday 12 of Jan 2001, LORD CORP 8148603999—>1 978 256 1510 Page 10 of 11 Page 4 of 5 DISPOSAL METHOD: Disposal should be done in accordance with Federal (40CFR Part 261), state and local environmental control regulations. If waste is determined to be hazardous, use licensed hazardous waste transporter and disposal facility. SECTION 14 -TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME: NOT REGULATED DOT HAZARD CLASS: NONE DOT UN/NA NUMBER: NONE PACKING GROUP: NONE EMERGENCY RESPONSE GUIDE NUMBER: NONE SECTION 15 - REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA HAZARDOUS BY DEFINITION OF HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: NONE TOXIC SUBSTANCES CONTROL ACT: INVENTORY STATUS The chemical substances in this product are on the TSCA Section 8 Inventory. EXPORT NOTIFICATION This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: CHEMICAL NAME CAS NUMBER Resin 68609-97-2 lEpoxy resin Proprietary INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings. CANADIAN WHMIS CLASS: D2A, D26 11 SECTION 16 -OTHER INFORMATION �I HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0 - Indicates a chronic hazard; see Section 3 REASON FOR REVISION: Computer System Upgrade VOLATILE ORGANIC COMPOUNDS (Calculated) : 0.08 lbs/gal, 9 grams/Itr LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined 1/12/2001 Friday 12 of Jan 2001, LORD CORP 8148603999->1 978 256 1510 Page it of 11 99015T00054 DISCLAIMER Page 5 of 5 The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this material. It is the responsibility of the user to comply with all applicable federal, state and local laws and regulations. 1/12/2001 Friday 12 of Jan 2001, LORD CORP 8148603999—>1 978 256 1510 Page 1 of 11 Chemical ��► Products A Division of Lord Corporation To: Dick Nunes Date: 01/12/2001 Fax Number: 9782561510 Dear Customer: CERTIFIEO 150 9001 G6-9000 s�A From: Hartman, Sherry L Pages: 11 Return Fax: 814-860-3709 Attached are the Material Safety Data Sheet (MSDS) form(s) for the Lord product(s) that you have recently ordered. NOTE: In the interest of providing the most accurate health and safety information on our products, a new MSDS system with enhanced reporting capabilities is now being utilized. The enclosed MSDS(s) may vary from past MSDS in content and appearance. Be advised, however, that the product itself has not been changed. Please compare the enclosed MSDS(s) with any prior version to ensure that you have the latest health/safety information on our products. Material Safety Data Sheets are an essential part of hazard communication and employee information and training programs required of employers under the OSHA Hazard Communication Standard (29 CFR 1910.1200), and as such, should be forwarded to those individuals in your organization responsible for safety, health and environmental practices and compliance. Additionally, the information should be provided to employees, customers, and contractors so that they will be fully informed of the safety, health, and environmental protection measures when working with the product(s). Feel free to copy this Material Safety Data Sheet as need be, while maintaining a master copy for your files. If you have any questions or require additional information on the storage, handling, or disposal of these product(s), please contact us. Sincerely, Joyce R. Nestor Product Safety Administrator Regulatory Compliance Department Lord RT7.pdf-,Lord E-301.pdf If all pages are not received clearly, call (814) 868-3611, Ext. 3407 Proprietary Notice The documents accompanying this facsimile transmission may contain information from Lord Corporation, which is proprietary or privileged. Such information is intended only for the use of the individual or entity named on this transmission sheet. If you are not the intended recipient, please be aware that any disclosure, copying, distribution or use of the contents of this Friday 12 of Jan 2001, LORD CORP 8148603999—>1 978 256 1510 Page 2 of 11 Page 1 of 5 � MATERIAL SAFETY DATA SHEET .11 SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 11 Product Name: Product Use/Class: LORD RT -7 EPDXY HARDENER LORD CORPORATION CHEMICAL PRODUCTS DIVISION 2000 WEST GRANDVIEW BLVD ERIE, PA 16514 EFFECTIVE DATE: 12/14/1999 INFORMATION TELEPHONE: 814 868-3611 TRANSPORTATION EMERGENCY CALL CHEMTREC: 800424-9300 NON -TRANSPORTATION EMERGENCY: 814 763-2345 SUPERCEDES DATE: 11/23/1999 SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS Number Weight % ACGIH TLV -TWA ACGIH TLV -STEL OSHA PEL-TWA OSHA PEL- CEILING Units Skin Less Than Polyoxypropylenediamine 9046-10-0 45% N.E. N.E. N.E. N.E. Amine compound Proprietary 45% N.E. N.E. IN.E. N.E. Triethanolamine 102-71-6 10 % 5 N.E. N.E. N.E. mg/m3 Piperazine 110-85-0 3.0% N.E. N.E. N.E. N.E. Amine curing agent 31326-29- 1 2.0% N.E. N.E. N.E. N.E. Bisphenol A 80-05-7 12.0% 1N.E, IN.F. JN.E. N.E. N.E. - Not Established, S - Skin Designation, C - Ceiling 11 SECTION 3 - HAZARDS IDENTIFICATION **' EMERGENCY OVERVIEW **°: Amber Liquid, with Mild ammoniacal odor. Harmful if inhaled. Harmful if absorbed through skin. May cause skin and eye burns. May cause allergic skin reaction. Causes respiratory tract irritation. EFFECTS OF OVEREXPOSURE- EYE CONTACT: May cause severe eye irritation on contact, with conjunctivitis and potential corneal injury if not promptly and adequately treated. May be corrosive to eyes; contact may cause eye burns. Eye contact may cause severe eye damage, including vision disturbances, corneal damage, and blindness. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May be absorbed through the skin in harmful amounts. May be corrosive to skin, contact may cause skin burns. May cause skin sensitization. May cause dermatitis. EFFECTS OF OVEREXPOSURE -INHALATION: Possible irritation of the respiratory system can occur causing a variety of symptoms such as dryness of the throat, tightness of the chest, and shortness of breath. May cause headache and nausea. Vapors may cause irritation of nose, throat, and upper respiratory tract. Inhalation may cause temporary blurring of vision. May cause respiratory sensitization. May cause lung damage. May cause nervous system depression. 1112/2001 Friday 12 of Jan 2001, LORD CORP 8148603999->1 978 256 1510 Page 3 of 11 Page 2 of 5 EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed. Ingestion is not an expected route of entry in industrial or commercial uses. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause conjunctivitis or other adverse eye effects. May cause skin sensitization. May cause liver or kidney damage. May cause long-term lung damage. Chronic skin contact may cause dermatitis. PRIMARY ROUTE(S) OF ENTRY: Skin Contact. Skin Absorption, Inhalation, Ingestion, Eye Contact 11 SECTION 4 - FIRST AID MEASURES FIRST AID- EYE CONTACT: Flush eyes immediately with large amount of water for at least 15 minutes holding eyelids open while flushing. Get prompt medical attention. FIRST AID - SKIN CONTACT: Flush contaminated skin with large amounts of water while removing contaminated clothing. Wash affected skin areas with soap and water. Get medical attention if symptoms occur. FIRST AID - INHALATION: Move person to fresh air. Restore and support continued breathing. If breathing is difficult, give oxygen. Get immediate medical attention. FIRST AID - INGESTION: If swallowed, do not induce vomiting. Give victim one or two glasses of water or milk. Call a physician or poison control center immediately for further instructions. Never give anything by mouth to an unconscious person. SECTION 5 - FIRE FIGHTING MEASURES FLASH POINT: > 200F. 94C (Setaflash Closed Cup) AUTOIGNITION TEMPERATURE: N.D. LOWER EXPLOSIVE LIMIT (%): Not Applicable UPPER EXPLOSIVE LIMIT MY Not Applicable OSHA FLAMMABILITY CLASSIFICATION: COMBUSTIBLE LIQUID- CLASS IIIB EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam, Water Fog UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. Closed containers may rupture when exposed to extreme heat. Use water spray to keep fire exposed containers cool. SPECIAL FIREFIGHTING PROCEDURES: Wear full firefighting protective clothing, including self-contained breathing apparatus (SCBA). If water is used, fog nozzles are preferable. During a fire, irritating and/or toxic gases and particulate may be generated by thermal decomposition or combustion. 11 SECTION 6 -ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Keep non-essential personnel a safe distance away from the spill area. Avoid breathing vapors. Use self-contained breathing equipment. Notify appropriate authorities if necessary. Avoid contact. Before attempting cleanup, refer to hazard caution information in other sections of the MSDS form. Scoop spilled material into an appropriate container for proper disposal. (If necessary, use inert absorbent material to aid in containing the spill). 11 SECTION 7 - HANDLING AND STORAGE HANDLING: Keep closure tight and container upright to prevent leakage. Avoid skin and eye contact. Wash thoroughly after handling. Avoid breathing of vapor or spray mists. Do not handle until all safety precautions have been read and understood. Empty containers should not be re -used. Use with adequate ventilation. STORAGE: Store only in well -ventilated areas. Keep container closed when not in use. 1/12/2001 Friday 12 of Jan 2001, LORD CORP 8148603999->1 978 256 1510 Page 4 of 11 Page 3 of 5 SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Sufficient ventilation in pattern and volume should be provided in order to maintain air contaminant levels below recommended exposure limits. RESPIRATORY PROTECTION: Use a NIOSH/MSHA approved air -purifying organic vapor respirator if occupational limits are exceeded. For emergency situations, confined space use, or other conditions where exposure limits may be greatly exceeded, use an approved air -supplied respirator. Observe OSHA regulations (29CFR 1910.134) for respirator use. SKIN PROTECTION: Use neoprene, nitrile, or rubber gloves to prevent skin contact. EYE PROTECTION: Use safety eyewear including safety glasses with side shields and chemical goggles where splashing may occur. OTHER PROTECTIVE EQUIPMENT: Remove and wash contaminated clothing before reuse. HYGIENIC PRACTICES: Wash hands before eating, smoking, or using toilet facility. Food or beverages should not be consumed anywhere this product is handled or stored. Wash thoroughly after handling. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES BOILING RANGE: 290 - 680 F VAPOR DENSITY: Heavier than Air APPEARANCE: Amber EVAPORATION RATE: Slower than Ether PHYSICAL STATE: Liquid DENSITY, LB/GL: 8.19 ODOR: Mild ammoniacal SPECIFIC GRAVITY: 0.98 SOLUBILITY IN H2O: Insoluble pH: N.A. FREEZE POINT: N.D. ODOR THRESHOLD: N.D. VOLATILE BY WEIGHT: 0.0% VOLATILE BY VOLUME: 0.0% VAPOR PRESSURE: N.D. COEFFICIENT OF WATER/OIL DISTRIBUTION: N.D. (See section 16 for abbreviation legend) CONDITIONS TO AVOID: High temperatures. INCOMPATIBILITY: Strong acids, bases, and strong oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, organic or inorganic nitrogen compounds including traces of hydrogen cyanide. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur under normal conditions STABILITY: Product is stable under normal storage conditions. 11 SECTION 11 -TOXICOLOGICAL INFORMATION PRODUCT LD50 (ORAL) No Data (DERMAL) No Data PRODUCT LC50 No Data 1/12/2001 Friday 12 of Jan 2001, LORD CORP 8148603999->1 978 256 1510 Page 5 of 11 Page 4 of 5 SECTION 12 - ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: No Information. SECTION 13 -DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Disposal should be done in accordance with Federal (40CFR Part 261), state and local environmental control regulations. If waste is determined to be hazardous, use licensed hazardous waste transporter and disposal facility. SECTION 14 -TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME: CORROSIVE LIQUIDS,NOS DOT HAZARD CLASS: 8 DOT UN1NA NUMBER: UN1760 PACKING GROUP: III EMERGENCY RESPONSE GUIDE NUMBER: 154 SECTION 15 - REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA: HAZARDOUS BY DEFINITION OF HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: CHEMICAL NAME CAS NUMBER WT % IS LESS THAN Bisphenol A 80-05-7 2.0% TOXIC SUBSTANCES CONTROL ACT: INVENTORY STATUS The chemical substances in this product are on the TSCA Section 8 Inventory. EXPORT NOTIFICATION This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: CHEMICAL NAME CAS NUMBER Amine compound Proprietary INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings. CANADIAN WHMIS CLASS: No Information 11 SECTION 16 -OTHER INFORMATION HMIS RATINGS - HEALTH: 2` FLAMMABILITY: 2 REACTIVITY: 1 - Indicates a chronic hazard; see Section 3 1/12/2001 11 . , t Friday 12 of Jan 2001, LORD CORP 8148603999->l 978 256 1510 Page 6 of 11 REASON FOR REVISION: Revised Section 3 VOLATILE ORGANIC COMPOUNDS (Calculated): 0.00 lbs/gal, 0 gramslltr LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined 99016T00004L DISCLAIMER Page 5 of 5 The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this material. It is the responsibility of the user to comply with all applicable federal, state and local laws and regulations. 1/12/2001 -- � LAST CHANGE: 1/15/90 ��URER'S NAME: COMPANY EMERRENCY TELEPHONE NO. 913-384'325 NORTH BRANCH ST iNFORMAT1UN TELEPHONE NO. 312-943-830 �O IL 60622 ____________________________________________________________________________ SECTI[}N 3 ~- PRODUCT IMFORMATIOt\j ---------------------------------------------------------------------------- T CODE: RE182 NAME: SCREEN INK RETARDER - H M I S C O D E S HEALTH - 1 T CLASS: SOLVENT' FLAMMABILITY - 2 REACTIVITY - 0 ___________________________________________________________________________ SECTION 2 -- HAZARDOUS ING%U1ENTS -----------------------------------,----',----------------------------------- 4L NAME; |PERCENTIOCCUPATIDHAL EXPOSURE LIMITS | VAPOR NAME; | BY | | FRESCUR; IBER |WEIGHT | TLV PEL | IN mwHg ------------------------------------------------------------------------ /LENE 0-YC0- METHYL ETHER; 100 100pPn 100pFM 1.36 0 20 METHYL ETHER; | | | V4-8 1 1STEL-150 PPM | | ! � | | --------------------------------------------------------------------------- SECTION Z -~ PHYSICAL DATA ----------------- --- ----- -_- -- -- ' ------------------------------------------- G POINT: 356 F VAPOR DENSITY: HEPVTER THAN Alw ATION RATE: SLOWER THAN ETHER PERCENT VDV.ATILF BY u[40MQ1/»)t 960.00 g/} [�.0o Jbygal WEIGHT PER GALLON: 8.00 LDS -----------------------------------------------'--------------'----------- SECTIDN 4 -- FIRE AND EXPLOSION HAZARD DATA ------ ----------- ------- --------- -_--___-__-_---_'__---__-_--_---_-_-_-_--- ABJLITY CLASSIFICATION; OSHA: SHA CLASSIFICATION: Class 1Il4 Combustible Liquid; DOT CLASSIFICATION: ambustible Liquid ABILITY CLASSIFICATION: DOT: FPA RATING: H`1 F-'2 R -C, POINT: 67 F (YCC) EXPLOSIVE LEVEL: Dt Established, GUI5H2NG MEDIA: oam- CO2- Dry Chemical- Water Spray. AL FIRE AND EXPLOSION HAZARDS: solate from heat, electrical equipment, spa"kg, and oRen flame. Ciosed ontainers may explode when exposed to extreme heat. . AL FIREFIGHTING PROCEDURES: 'ater ma)/ be ineffective but may be used to cool containers. The use of .elf - contained breathing app,ratus is recommended for fire fighters' PCOMMENTS: //A ___________________________________________________________________________ SECTIUN 5 -- HEALTH HAZARD DATA '__--- __---____--- ________________------ __--- __----- ---- ---- ---- -------- __--- :TS OF OVEREXPOSURr -iquid,vapor or mints may cause eye irritation. Skin contact may cause rrzcaciThis his mmueria� may ne ahsnroen through ) the ���n- nnmlu`/u.` nay cause raspiratory tract irritation or nervous system Hisonders such as .eadaches, dizzines, and fatigue' Ingestion may cause gastroinrPstins/ iract irritation and signs o4 nervnwn system depression. Reports have insociated repeated and prolonged occupational overexposure to solvent6 niLm permanent brain and nervmus system damage. Intentional misuse b/ !pliberatslv �nnce��ra�in�` *M� innelinq tne contents may be narmfo! nr h� effe�ts of t�is m�t�r��l. )RY R0UTE(s) OF ENTRY: }ermal (Contact/Absorption) - tnha:tation --;ErNICY AND FIRSTAID r.,:Sz V<IN CONTACT: Wash with Soap and water, contact physician if irritation ersists EYE CONTACT: FluSh well With �unnzng water fur a minimum of 15 /inute��, contact phy�iclan if irritatiqn p�r��sts' DvHAL��TIO�4: Remove to resh air, restore brea�hing� contact physician. INGESTION:; Contact '�ys�cian Or Poison Control �enter immeU:�Atp1y. � COPIMENTS: J/A '--------------------------------------------------------------- ------- -----...... ---- S)E:CT1ON 6 -- REACTIVITY DATA . .. ....... .... .............. ... ..... ....... .... LITY: �table- TIONS TO AW�"U: /e,�at, sparks and open flame. /PATIOILITY (WITH �trong o�idizing agents' �DOUG DECOMPOSITION PRODUCTS):: .arbon Monoxide, Carbon Dioxide and other no:ious gases. zDOUS PULYMERIZATlUN. !ill not occur. � COMMENTS; �/A ..................... ...... .......... _................ ........ SECTI�N � TO BE TAKEf-.1 IN CASE MATEk1AL IS RELEASED OR SPILLED-.- �Pmnxe all sources of ignition. Vent1lAte area. Avoid vapors. �cmLain release, and remove with inert atjsorbent: Avoid ccmtmct. Usp `on -sparking tools to Place material in for dxsposil. � DISPOSAL METHOU: }i�pose of in accordance with with applicable local, county, state, and �ederaI regulatinn!:". < COMMENTS: VA ---------------------------------------------------------------------------' SE[TTON 8 -- SPECIAL PROTECTION Tr\1FOR11qT7[QN '--------------------------------------------------------------------------- �RATORY PROTECTION-. �f vapor concertration exceeds thR TLV I isted in tion JJNJO9H :tpAroweg respirator wi�h cirganzc chem1cal Contact �afety supply 4(:)r thp appropriatr- resp1rafor. [LATlONs -�s required to keep the vapor (-.,qncentr,-,kti(,,)n 0P.1mw tr)e TL\/ n sectIon [I, - �TIVE 8LOVES: Jse neoprene, nitrile or other glovms resistant tn solvents listed in 3ecticin lIContact a reputablm supply rnmpany +pr af)proprz��e J1ovFd . *-. �FQTE�CT)ON: Use splash -proof gogg�es or safe�y giass�s. Contact a reputable �af�ty sup r,ly ccm}r,any for appropriate eye prote,ctiInn . � PROTECTI0�� Solvent resistant aprnns and o.f: an eye wash Are recommenned. Smoke in designated cmly. 2W%C ��AC�lCES: Wash with soap anU water befOre eating2 smoking ur using toile� faci}ities, -F, 'ATE OF LAST CHANGE: 1/22/92 MATERIAL SAFETY DATA SHEET DATE PRINTEED: ACE 131 MSDS No. 0702 210 192 !ANUFACTURER'S NAME: ?AZDAR COMPANY EMERGENCY TELEPHONE NO. 800-424-9300 087 N NORTH BRANCH ST INFORMATION TELEPHONE N0. 312-943-8338 ',gICAGO IL 60622 ----------------------------...---------------..-......-----------------------....-- SECTION 1 -- PRODUCT INFORMATION .....------------------------------------------------------------------------------- CD:ERNL :RADE NAME: ER -000 SERIES EPDXY RESIN INK XEALTX C 0 D. ZS - 'RODUCT CLASS: EPDXY ENAMEL, AMINE CATALIZED FL MMAB11LITY 2 'RODUCT GROUP: XER 'ETROLEUM DISTILLATE; ,ROMATIC HYDROCARBON MIXTURE; 'AS #: 64742-94-5 SUBJECT TO REPORTING REQUIREMENT OF SECTION 313 OF TITLE III OF SARA (40 CFR PART 372) 15-30 NOT ESTABLISHED 500PPH 5 @ 100 F --------------......-------------------------------------- SECTION 3 -- PHYSICAL DATA ------------------------------------------------------------------------------------ 'OILING RANGE: 360 DEG. F - 395 DEG. F VAPOR DENSITY: HEAVIER THAN AIR 'VAPORATIDN RATE: SLOWER THAN ETHER SEE SECTION I FOR VOC DATA. SEE SECTION I FOR WEIGHT PER GAL. DATA ------------------------------------------------------------------------------------- SECTION 4 -- FIRE AND EXPLOSION HAZARD DATA ------------------------------------------------------------------------------------ FLAMMABILITY CLASSIFICATION: Combustible Liquid Class II OTHER C91111ENTS: Combustible Liquid FLASH POINT: Lowest flashing component Hi -Sol 15 140 Deg. F TCC LOWER EXPLOSIVE LEVEL: I EXTINGUISHING MEDIA: Foam, CO2, Dry Chemical UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. Isolate from heat electrical equipment, sparks, and open flame. Closed containers may explode when ex osed to extreme heat. Do not apply to hot surfaces. Water spray mey pbe ineffective. Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion exposed to extreme heat. If water is used, fog nozzles are preferable. SPECIAL FIREFIGHTING PROCEDURES: N/A VC/ al VOCI VOC $ VOC wt/ e1 VOC $ VOC VOL ER3D1� l,I. 0 I/ Ib/388 VOL ERD12C gOC 11.5 393 1b/383 ER170 8.6 516 4.3 59 ER 71 8.6 516 4.3 59 ER177 7.8 462 3.9 53 .0 0 .0 0 ------------------------------------------------------------------------------------ SECTION 2 -- HAZARDOUS INGREDIENTS ................................----------........-----------------------------..... HEMICAL NAME; PERCENT EXPOSURE LIMITS 'OMMON NAME; By I JOCCUPArIONAL PRESSURE 'AS NUMBER WEIGHT TLV PEL IN mmHg ---------------------- 2-BUTOXYETHANOL'------------------ 11-21 ---------------- ------ --------- 25PPM 25PPH---- --- 10.6,@,20C--- 20C--- -LYCOL MONOBUTYL ATHER; 1 -AS #: 111.76.2 (Skin) 'ETROLEUM DISTILLATE; ,ROMATIC HYDROCARBON MIXTURE; 'AS #: 64742-94-5 SUBJECT TO REPORTING REQUIREMENT OF SECTION 313 OF TITLE III OF SARA (40 CFR PART 372) 15-30 NOT ESTABLISHED 500PPH 5 @ 100 F --------------......-------------------------------------- SECTION 3 -- PHYSICAL DATA ------------------------------------------------------------------------------------ 'OILING RANGE: 360 DEG. F - 395 DEG. F VAPOR DENSITY: HEAVIER THAN AIR 'VAPORATIDN RATE: SLOWER THAN ETHER SEE SECTION I FOR VOC DATA. SEE SECTION I FOR WEIGHT PER GAL. DATA ------------------------------------------------------------------------------------- SECTION 4 -- FIRE AND EXPLOSION HAZARD DATA ------------------------------------------------------------------------------------ FLAMMABILITY CLASSIFICATION: Combustible Liquid Class II OTHER C91111ENTS: Combustible Liquid FLASH POINT: Lowest flashing component Hi -Sol 15 140 Deg. F TCC LOWER EXPLOSIVE LEVEL: I EXTINGUISHING MEDIA: Foam, CO2, Dry Chemical UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. Isolate from heat electrical equipment, sparks, and open flame. Closed containers may explode when ex osed to extreme heat. Do not apply to hot surfaces. Water spray mey pbe ineffective. Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion exposed to extreme heat. If water is used, fog nozzles are preferable. SPECIAL FIREFIGHTING PROCEDURES: N/A 'RODUCT CODE ERNL NAZDAR COMPANY PAGE 2 OF 3 ------------------------------------------------------------------------------------ SECTION S -- HEALTH HAZARD DATA -----------------------------•--------------------------------.......--------------- EFFECTS OF OVEREXPOSURE: Inhalation: Anesthetic. Irritation of the respiratory tract or acute nervous system depression characterized by headache, dizziness, staggering gait, confusion, unconsciousness or coma. Skin or eye contact: Primary irritation. Repeated and prolonged overexposure by inhalation or skin absorption may cause kidney, liver, and blood damage. MEDICAL CONDITIONS PRONE TO AGGRAVATE BY EXPOSURE: N/A PRIMARY ROUTE(S) OF ENTRY: Dermal, inhalation and ingestion. EMERGENCY AND FIRST AID PROCEDURES: Fumes: Remove from exposure. Restore breathing.Keep warm and quiet. Notify, a physician. Splash (Eyes): Flush immeiately wi�h copious Quantities of running water for at Ieast IS minutes. Take rQ a physician for definitive medic�tI treatment. Splash (Skin: Remove with soap and water. Remove contaminated clothing. Do not induce vomiting if swallowed. ------------------------------------------------------------------------------------ SECTION 6 -- REACITIVITY DATA ------------------------------------------------------------------------------------ STABILITY: Stable CONDITIONS TO AVOID: N/A INCOMPAATIBILITY (WITH MATERIALS): Tf ZARDOUS DECOMPOSITION PRODUCTS: Hay produce hazardous fumes when heated to decomposition as in welding. Fumes may contain carbon monoxide and oxides of nitrogen. HAZARDOUS POLYMERIZATION: Will not occur. ------------------------------------------------------------------------------------ SECTION 7 -- SPILL OR LEAK PROCEDURES ------------------------------------------------------------------------------------ STE?S TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition (flames, hot surfaces, and electrical, static or frictional sparks). Avoid breathing vaors. Ventilate area. Remove with inert, absorbent and non -sparking toopls- WASTE DISPOSAL METHOD: Dispose o in accordance with applicable local, county, state and federal regulations. Do not incinerate closed containers. ------------------------------------------------------------------------------------ SECTION 8 -- SPECIAL PROTECTION INFORMATION ----------------------------------------------..--...---------.-...----------------- RESPIRATORY PROTECTION: If vapor concentration exceeds the TLV Iisted in Section II, use NIOSH ap roved respiratory with organic chemical cartridge. Consult a reputable Sa ety Supply company for proper respirator selection. VENTILATION: Provide general dilution or local exhaust ventilation in volume and pattern to keep TLV of most hazardous ingredient in Section II below acceptable limit, LEL in Section IV below stared limit, and to remove decomposition products during welding or flame cutting on surfaces coated with this product. PROTECTIVE GLOVES: Solvent resistant gloves required for prolonged or repeated contact. EYE PROTECTION: t PRODUCT CODE ERVL NAZDAR COMPANY, PAGE 3 OF 3 .- Use safety eyewear designed to protect against splash of liquids.- -.. --- OTHER PROTECTION: Prevent prolonged skin contact with contaminated clothing. HYGIENIC PRACTICES: Wash with soap and water before eating, smoking, or using toilet facilities. ------------------------------------------------------------------------------------- SECTION 9 -- SPECIAL PRECAUTIONS .------------------------------------------------------------------------------------ PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Do not store above I20 degrees F. Store Iar a quantities in buildings designed for storage of NFPA Class II combos Ible liquids. OTHER PRECAUTIONS: Do nor take internally. Containers should be grounded wen pouring. Avoid free fall of liquids in excess of a few Inches. Do not flame cut, braze, or weld without MSHA or NIOSH approved respirator or appropriate ventilation. ..............................................................................------- SECTION 10 -- DISCLOSURE ------------------------------------------------------------------------------------ DISCLOSURE INFORMATION: The information and recommendatlons contained herein are based upon data believed to be correct. However no guarantee or warranty of any kind expressed or implied is made with respect to the information contained herein. UhiKJ UIV DATE OF LAST CHANGE: 1/15/90 MANUFACTURER'S NAME: MATERIAL SAFETY DATA SHEET DATE PRINTED: 2I OF 3 MSDS No. 6$70 NAZDAR COMPANY EMERGENCY TELEPHONE NO. 800-424.9300 1087 N NORTH BRANCH ST INFoRMATIoN TELEPHONE N0. 312-943-8338 CHICAGO IL 60622 ------------------------------------------------------------------------------------- SECTION 1 -- PRODUCT INFORMATION ------------------------------------------------------------------------------------- PRODUCT CODE: ER176 TRADE NAME: CATALYST HRP.4LTSH C 0 D -EIS PRODUCT CLASS: MODIFIED POLYAMINE FL MMAIBILrTY VZTY _ 3 PRODUCT GROUP: ER ---------------------------------------------------------------------------••-------- SECTION 2 -- HAZARDOUS INGREDIENTS CHEMICAL -NAME;---- ----- - - -PERCENT-1 OCCUPATIONAL -EXPOSURE LIMITS I VAPOR----------------------------- COMMON APOR- COMMON NAME;PRESSURE CAS NUMBER WEIGHT TLV PEI, I IN mmHg - - * ETHYLENE GLYCOL ETHYL ETHER; 18 5PPM 200PPM - 14MM @-20C- + 2-ETHOXYETHANOL; I 110-80-5 I I * XYLENE - CAS #: IJ30-20-7 * METHYL ISOBUTYL KETONE CAS #: 108-10-1 * SUBJECT TO REPORTING REQUIREMENT SECT (40 CFRIPART 33 OF 72}E III OF 18 1 I00PFM STEL-15OPPM 28 STEL: 75PPPM 100PPM 5.1 @ 20C 50PPM 116MM @ 20C ---------------------------------.:-------------------------------------------------- SECTION 3 -- PHYSICAL DATA BOILING RANGE. 241 -DEG. F - 313 -DEG. -F VAPOR DENSITY HEAVIER TXAN AIR - - -- �_: EVAPORATION RATE: SLOWER THAN ETHER PERCENT VOLATILE BY VOLUME: 628 VOC: 524,40 b 4WEIGHT PER GALLON: 8.11 LBS --------:37----gal---------------------------------•-------.--....----------.. SECTION 4 -- FIRE AND EXPLOSION HAZARD DATA ---------------------------------------------------•••------------.........-.----.... FLAMMABILITY CLASSIFICATION: Flammable Liquid Class IC OTHER COMMENTS: Flammable Liquid FLASH POINT: Lowest flashing component Methyl Isobutyl Ketone 73 Deg. F TCC LOWER EXPLOSIVE LEVEL: I EXTINGUISHING MEDIA: Foam, CO2, Dry Chemical UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. Isolate from heat electrical equipment, sparks, and open fame. Closed contai ers may explode when exposed to extreme heat. Do not ap Iy to hot sur aces. Water spray may be ineffective. Water may a used to cool closed containers to prevent pressure buildup and possible autoignition or explosion exposed to extreme heat. If water is used, fog nozzles are preferable. SPECIAL FIREFIGHTING PROCEDURES: N/A GRRS�UN PkODUCT CODE ER176 NAZDAR COMPANY PAGE 2 OF 3 -•-------------------- .............-...-------------- SECTIONS -• HEALTH HAZARD DATA ..................................................................................... EFFECTS OF OVEREXPOSURE: Inhalation: Anesthetic. Irritation of the respiratory tract or acute nervous system depression characterized by headache, dizziness, staggering gait, confusion, unconsciousness or coma. Skin or eye contact: Primary irritation. MEDICAL CONDITIONS PRONE TO AGGRAVATE BY EXPOSURE: N/A PRIMARY ROUTE(S) OF ENTRY: Dermal, inhalation and ingestion. EMERGENCY AND FIRST AID PROCEDURES: Fumes: Remove from exposure. Restore breathi. Keep wa and quiet. Notify a physician. Splash (Eyes): Flush immengglately with copious quantities of running water for at least 15 minutes. Take tp a physician for definitive medical treatment. Splash (Skin): Remove with soap and water. Remove contaminated clothing. Do not induce vomiting if swallowed. ------------------------------------------------------------------------------------- SECTION 6 -- REACITIVITY DATA ------------------------------------------------------------------------------------- STABILITY: Stable CONDITIONS TO AVOID: N/A INCOMPATIBILITY (WITH MATERIALS): HAZARDOUS DECOMPOSITION PRODUCTS: May produce hazardous fumes when heated to decomposition as in welding. Fumes may contain carbon monoxide and oxides of nitrogen. HAZARDOUS POLYMERIZATION: Will not occur. ------------------------------------------------------------------------------------- SECTION 7 -- SPILL OR LEAK PROCEDURES ------------------------------------------------------------------------------------- STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition (flames, hot surfaces, and electrical, static or frictional sparks). Avoid breathing vaors. Ventilate area. Remove with inert, absorbent and non -sparking tools. WASTE DISPOSAL METHOD: Dispose of in accordance with appjicable local, county, state and federal regulations. Do not incinerate closed containers. ------------------------------------------------------------------------------------- SECTION 8 -- SPECIAL PROTECTION INFORMATION ------------------------------------------------------------------------------------- RESPIRATORY PROTECTION: If vapor concentration exceeds the TLV listed in Section Il, -use NIOSH approved respiratory with organic chemical cartridge. Consult a reputable Safety Supply company for proper respirator selection. VENTILATION: Provide general dila ion or local exhaust ventilation in volume and pattern to keep LV of most nazardous ingredient in Section II below acceptable limit, LEL in Sect'on IV be ow stated limit, and to remove decomposition products during welding or lame cutting on surfaces coated with this product. PROTECTIVE GLOVES: Solvent resistant gloves required for prolonged or repeated contact. EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids. lU GARSTON INC. TEL No.5086574622 Nov 17,93 10:53 N0.006 P.11 PRODUCT CODE ER176 NAZDAR COMPANY OTHER PROTECTION: Prevent prolonged skin contact with contaminated clothing. HYGIENIC PRACTICES: Wash with soap and water before eating, smoking, or using toilet facilities. PAGE 3 OF 3 ------------------------------------------------------------------------------------- SECTION 9 -- SPECIAL PRECAUTIONS ..................................................................................... PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Do not store above 120 degpees F. Store large quantities in buildings designed for storage of NFPA Class IC flammable liquids. OTHER PRECAUTIONS: Do not take internally. Containers should be grounded when pouring. Avoid free fall of liquids in excess of a few inches. Do not flame cut, braze, or we d without KSHA or NIOSH approved respirator or appropriate ventilation. ------------------------------------------------------------------------------------- SECTION 10 -- DISCLOSURE ------------------------------------------------------------------------------------- DISCLOSURE INFORMATION: The information and recommendations contained herein are based upon data believed to be correct. However no guarantee or warranty of any kind gxpressed or Implied is made with respect to the information contained erein. St. Paul, Minnesota 55144-1000 1-800-364-3577 or (612) 737-6501 (24 hours) Copyright, 1998, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. ;ION: ADHESIVES DIVISION ___ NAME: .TCH-WELD (TM) 2216 B/A Parte Gray Epoxy Adhesive MBER/U.P.C.: 2216-4130-1 00-21200-20353-4 2216-6830-4 - - - 2216-9530-7 00-21200-20361-9 D: March 23, 1998 .SEDES: November 25, 1997 ENT: 10-3167-3 62-2216-5930-3 - - - 62-2216-8530-8 00-21200-20360-2 ------------------------------------------------------------------------ INGREDIENT C.A.S. NO. PERCENT ------------------------------------------------------------------------ RESIN ............................. 25068-38-6 70.0 - 80.0 N .................................. 1332-58-7 20.0 - 30.0 components of this product are in compliance with the chemical ification requirements of TSCA. All applicable chemical redients in this material are listed on the European Inventory of sting Chemical Substances (EINECS), or are exempt polymers whose .omers are listed on EINECS. s Base (Mfg. EC -2216) used with SCOTCH -WELD 2216 B/A Part A Gray Ay Adhesive; (Mfg. EC -2217 -- MSDS DOC #1031749). ------------------------------------------------------------------------ PHYSICAL DATA ------------------------------------------------------------------- ---- NG POINT: ................. N/A PRESSURE: ................ N/A DENSITY: ................. N/A RATION RATE :.............. N/A ILITY IN WATER:........... nil FIC GRAVITY: .............. 1.330 Water=l NT VOLATILE: .............. 0.06 1 by wt ASTM ............I ............. N/A SITY:..................... 75000 - 150000 centipoise NG POINT: ................. N/D ------------------------------------------------------------------------ viations: N/D - Not Determined N/A - Not Applicable CA - Approximately SCOTCH -WELD (TM) 2216 B/A Part B Gray Epoxy Adhesive 23, 1999 PAGE 2 ------------------------------------------------------------------------ PHYSICAL DATA (continued) ------------------------------------------------------------------------ RANCE AND ODOR: amy paste, off-white, very slight epoxy odor. ------------------------------------------------------------------------ FIRE AND EXPLOSION HAZARD DATA ------------------------------------------------------------------------ POINT:.................... N/A ABLE LIMITS - LEL:........ N/A ABLE LIMITS - UEL:........ N/A ;NITION TEMPERATURE:...... N/D IUISHING MEDIA: or, Carbon dioxide, Dry chemical, Foam AL FIRE FIGHTING PROCEDURES: full protective clothing, including helmet, self-contained, hive pressure or pressure demand breathing apparatus, bunker coat pants, bands around arms, waist and legs, face mask, and :ective covering for exposed areas of the head. AL FIRE AND EXPLOSION HAZARDS: known. HAZARD CODES: HEALTH: 1 FIRE: 0 REACTIVITY: 1 UNUSUAL REACTION HAZARD: none ------------------------------------------------------------------------ 3EACTIVITY DATA ------------------------------------------------------------------------ !ITY: Stable ATIBILITY - MATERIALS/CONDITIONS TO AVOID: Dng Acids, Strong Oxidizing Agents. Heat is generated during v. Do not cure a mass larger than 50 grams in a confined space to rent a premature reaction (exotherm) with production of intense and smoke. DOUS POLYMERIZATION: Hazardous polymerization will not occur. DOUS DECOMPOSITION PRODUCTS: Don Monoxide and Carbon Dioxide, Aldehydes, Ketones, Hydrocarbons, c Vapors, Gases or Particulates. ------------------------------------------------------------------------ viations: N/D - Not Determined N/A - Not Applicable CA - Approximately SCOTCH -WELD (TM) 2215 B/A Part B Gray Epoxy Adhesive 23, 1998 PAGE 4 ------------------------------------------------------------------------- PRECAUTIONARY INFORMATION ------------------------------------------------------------------------- ?ROTECTION: )id eye contact. Wear vented goggles. Wear safety glasses with ie shields. PROTECTION: ;id skin contact. Wear appropriate gloves when handling this serial. A pair of gloves made from the following material(s) are .ommended: polyethylene/ethylene vinyl alcohol. iMENDED VENTILATION: ;vide appropriate local exhaust for grinding, cutting or sanding -ed material. Curing ovens must be exhausted to outdoors or to a .table emission control device. Use in a well -ventilated area. If iaust ventilation is not adequate, use appropriate respiratory otection. RATORY PROTECTION: :id breathing of vapors created during the cure cycle. Avoid :aching of dust created by cutting, sanding or grinding. Select : of the following NIOSH approved respirators based on airborne _centration of contaminants and in accordance with OSHA :ulations: half -mask dust respirator. :NTION OF ACCIDENTAL INGESTION: not eat, drink or smoke when using this product. Wash exposed as thoroughly with soap and water. Do not ingest. '.MENDED STORAGE: :re away from heat. Keep out of the reach of children. AND EXPLOSION AVOIDANCE: :p container tightly closed. EXPOSURE LIMITS DIENT VALUE UNIT TYPE AUTH SKIN* RESIN .......................... NONE NONE NONE NONE N ............................... 2 MG/M3 TWA ACGIH respirable dust N ............................... 10 MG/M3 TWA OSHA .N NOTATION: Listed substances indicated with 'Y' under SKIN refer to ;otential contribution to the overall exposure by the cutaneous route ding mucous membrane and eye, either by airborne or, more particularly, -rect contact with the substance. Vehicles can alter skin absorption. :E OF EXPOSURE LIMIT DATA: ;IH: American Conference of Governmental Industrial Hygienists ------------------------------------------------------------------------- >_viations: N/D - Not Determined N/A - Not Applicable CA - Approximately > . P SCOTCH -WELD (TM) 2216 B/A Part B Gray Epoxy Adhesive 23, 1998 PAGE 5 EXPOSURE LIMITS (continued) :DIENT VALUE UNIT TYPE AUTH SKIN* ------------------------------------------------------------------------ A: Occupational Safety and Health Administration None Established ------------------------------------------------------------------------ HEALTH HAZARD DATA ONTACT: orate Lye Irritation: signs/symptoms can include redness, swelling, n, tearing, and hazy vision. ors from heated material may cause eye irritation. t created by cutting, grinding, sanding, or machining may cause irritation. CONTACT: ergic Skin Reaction: signs/symptoms can include redness, swelling, stering, and itching. i Skin Irritation: signs/symptoms can include redness, swelling, itching. .AT I ON: itation (upper respiratory): signs/symptoms can include soreness --he nose and throat, coughing and sneezing. ors of heated material may cause respiratory system irritation. from cutting, grinding, sanding or machining may cause itation of the respiratory system. ALLOWED: estion may cause: Irritation of Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and blood in feces. HEALTH HAZARD INFORMATION: osure to this material in normal storage and handling has not been orted to cause significant adverse health effects. However, under :nal processing conditions, e.g. grinding or heating, this product release fumes and vapors of variable composition based on cific process conditions. These process releases may produce itation or any of the health effects listed above when the ssions are present at elevated concentrations. Use with ropriate local exhaust ventilation. -------------------------------------------------------- --------------- ,viations: N/D - Not Determined N/A - Not Applicable CA - Approximately SCOTCH -WELD (TM) 2216 B/A Part B Gray Epoxy Adhesive 23, 1998 PAGE 6 ------------------------------------------------------------------------ ON CHANGE DATES ------------------------------------------------------------------------- DIENTS SECTION CHANGED SINCE November 25, 1997 ISSUE ------------------------------------------------------------------------ viations: N/D - Not Determined N/A - Not Applicable CA - Approximately aformation in this Material Safety Data Sheet (MSDS) is believed to rrect as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR ED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF ANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF RMANCE OR USAGE OF TRADE. User is responsible for determining er the 3M product is fit for a particular purpose and suitable for s method of use or application. Given the variety of factors that ffect the use and application of a 3M product, some of which are ely within the user's knowledge and control, it is essential that ser evaluate the 3M product to determine whether it is fit for a cular purpose and suitable for user's method of use or application. ovides information in electronic form as a service to its customers. o the remote possibility that electronic transfer may have resulted rors, omissions or alterations in this information, 3M makes no osentations as to its completeness or accuracy. In addition, mation obtained from a database may not be as current as the mation in the MSDS available directly from 3M. TRA -BOND F113SC HIGH Tg and ROOM TEMPERATURE CURING FIBER-OPTIC EPDXY ADHESIVE DESCRIPTION: TRA -BOND F113SC is a room temperature curing, high Tg and low viscosity adhesive formulated for terminating ALL TYPES of fiber optic connectors. It has also been used for bonding LED displays, lenses and other optical components. TRA -BOND F113SC provides both high bond strength as well as low stress connections with no pistoning. This two part system can be cured overnight at room temperature or as quickly as 15 minutes at 90°C and is provided in a dark blue color to allow for easy polishing. PROPERTY TYPICAL VALUES Color, resin Clear hardener Dark Blue mixed Dark Blue Specific gravity, mixed 1.1 Viscosity, cps, mixed (after mixing) @ 25°C 1,250 Operating temperature range, °C -60 tc920 Hardness, Shore D 83 Mix ratio, parts by weight, Resin/Hardener 100/30 Lap shear, alum to alum, psi 1 hour @ 65°C 3900 24 hours @ 25°C 2700 Glass transition (Tg), °C, ultimate 95 Water absorption, % 0.98 VOC, grams/I 1.91 Coefficient of expansion, cm/cm/°C above Tg 1.91e-4 below Tg 7.57e-5 POT LIFE 25 grams 35 minutes CURE SCHEDULE WORKING LIFE 25 grams 1 hour 18 hours @ 25°C or 1 hour @ 65°C or 15 minutes @ 90°C for one drop application Sufficient cure is developed for polishing connectors in 15 minutes at 65°C, when higher cure temperatures are possible. TRA -BOND F113SC will complete its cure at room temperature with no pistoning. PRINT DATE : 01/27/99 REVISION DATE: 11/28/97 REV: 131 TRA -CON, INC. 45 Wiggins Avenue, Bedford, MA 01730 800-TRA-CON1 (800-872-2661) Tel. (781) 275-6363 FAX (781) 275-9249 QAF-1067 Rev A TRA -BOND F113SC APPLICATION DIRECTIONS (1) Carefully clean and dry all surfaces to be bonded. (2) Remove clamp and thoroughly mix the TRA -BOND F113SC epoxy adhesive system components in the handy BI PAX mixing -dispenser package until color is uniform throughout. (3) Apply this completely mixed adhesive to the prepared surfaces, and gently press these surfaces together. Contact pressure is adequate for strong, reliable bonds -- however maintain contact until adhesive is completely cured. EXPIRATION DATE TRA -CON resin products are marked with an expiration date at the time of manufacture which is similar to the the dating system used for most perishable materials such as foodstuffs, photographic films, pharmaceuticals and most reactive products. This date is marked "Use Before" which indicates that the product will yield its best properties when mixed and cured before the date shown. The expiration date should be monitored to ensure that inventory levels are replenished in adequate time to avoid unnecessary interruptions in the manufacturing process. STORAGE AND HANDLING CONDITIONS The expiration date is based upon dry storage conditions at or below 80°F (27°C) in the original, sealed and unopened containers. Contents may separate during storage. Resin or hardener in bulk containers (e.g. quarts, gallons) should be thoroughly mixed prior to combining them to obtain all the benefits of the properties designed into the formulation. STORAGE TEMPERATURE Some ingredients in this formulation may crystallize whe returning the product back to room temperature will not al cycle of 125°F for 30 minutes prior to mixing the resin and the product to its best condition. Crystallized epoxy comb and should be redissolved prior to use for best results. i subjected to low temperature storage. Merely itays redissolve the crystals and a gentle warming hardener components may be necessary to return onents do not react as well as liquid components WARNING: THIS MATERIAL IS SOLD FOR INDUSTRIAL USE ONLY Uncured epoxy adhesives - consisting of resin and hardener components - may cause dermatitis, skin sensitization or other allergic responses. Prevent all contact with skin and eyes. If contact occurs, flush immediately with plenty of water (get prompt medical attention for eyes). Keep away from heat and open flame. KEEP OUT OF REACH OF CHILDREN. Immediately clean up any spills that may occur. TRA -CON, INC. MAKES NO EXPRESS OR IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS OR OTHERWISE with respect to its products. In addition, while the information contained herein is believed to be reliable, no warranty is expressed or implied regarding the accuracy of the data or the results to be obtained from the use thereof. All recommendations or suggestions for use are made without guartanee inasmuch as conditions of use are beyond our control. The properties given are TYPICAL VALUES and are not intended for use in preparing specifications. Users should make their own tests to determine the suitability of this product for their own purposes. PRINT DATE : 01/27/99 REVISION DATE: 11/28/97 REV: B1 TRA -CON, INC. 45 Wiggins Avenue, Bedford, MA 01730 800 -TRA -CONI (800-872-2661) Tel. (781) 275-6363 FAX (781) 275-9249 QAF-1057 Rev A a TRA—CON THE A©HES: WJE SOURCE MATERIAL SAFETY DATA SHEET DATE: 8/27/98 H HEALTH F FLAMMABILITY R REACTVITY 0 P PROTECTION See Section VIII SECTION I MANUFACTURER'S NAME TRA-CON, INC. C OMPANY TELEPHONE NUMBER (781) 275-6363 EMERGENCY TELEPHONE NUMBER CHEMTREC (800) 424-9300 ADDRESS (Number, Street, City, State and ZIP Code) 46 WIGGINS AVENUE BEDFORD MA 01730 CHEMICAL NAME AND SYNONYMS: Epoxy Adhesive Resin TRADE NAME: TRA-BOND F113SC RESIN CHEMICAL FAMILY: Bis-A-Epichlorohydrin Epoxide FORMULA: Mixture (All ingredients listed in Federal TSCA Inventory) HAZARD LABEL REQUIRED? CARCINOGEN: NONE MUTAGEN: NONE NEI jROTOXIN:7 NONE TERATOGEN: NONE OTHER: NONE SECTION II - HAZARDOUS INGREDIENTS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES CAS # % TLV mg/m3 ppm Phenol,4,4'-(1-methylethylidene)bis-, polymer with (chloromethyl) oxirane Other ingredients (if any) per OSHA 1910.1200 (g)(2)()(c)(1) which may compose less than 1% of the composition, and/or which are non-hazardous or not listed on the Masachusetts Hazardous Substance List. SARA Title III, Section 313: not listed NE=Not Established 025068-38-6 up 80-100 to 20 NE NE SECTION 111- PHYSICAL DATA BOILING POINT(°F) > 350 SPECIFIC GRAVITY (H2O=1) 1.3 VAPOR PRESSURE (mm Hg.) @ 77°F < 1 PERCENT VOLATILE BY VOLUME (%) < 0.2 VAPOR DENSITY (air=1) > 1 EVAPORATION RATE (BuAC=1) low SOLUBILITY IN WATER low APPEARANCE AND ODOR: Light amber liquid, mild odor. SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASHPOINT (Method Used) : > 200°F(COC) FLAMMABLE LIMITS: N/AV LEL: N/A UEL: N/A EXTINGUISHING MEDIA: Dry chemicals, chemical foam, carbon dioxide, water. SPECIAL FIRE FIGHTING PROCEDURES: Avoid breathing smoke. Addition of water may reduce flame intensity. UNUSUAL FIRE AND EXPLOSION HAZARDS: Toxic gases may be liberated; handle as combustible; store in a cool place. TRA -CON, INC. MAKES NO EXPRESS OR IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS OR OTHERWISE WITH RESPECT TO ITS PRODUCTS. The information contained herein is based on MSDS information supplied by the Manufacturers and/or Vendors of the components listed and is believed to be reliable, however no guarantee or warranty is expressed or implied regarding the accuracy of the data or the results to be obtained from the use thereof. All recommendations or suggestions for use are made without guarantee inasmuch as conditions of use are beyond our control. Users should determine the suitability of this product for their own purposes. Rev B QAF-1068 Rev TRA -BOND F113SC HARDENER 1 SECTION V - HEALTH HAZARD DATA °\ EXPOSURE LIMITS: Ingestion LD50 (rats) > 500 mg/kg; Dermal LD50 > 1400 mg/kg. TLV -TWA 1 ppm. EFFECTS OF OVEREXPOSURE: Repeated contact or breathing of vapors may cause irritation; material is also a strong sensitizer. Eye and skin contact may cause transient irritation. EMERGENCY AND FIRST AID PROCEDURES EYES: Flush with water, get medical attention. SKIN: Wash with soap and water; remove contaminated clothing. INHALATION: Remove to fresh air. INGESTION: No known antidote but give milk or water; do NOT induce vomitting if swallowed; get medical attention. PRIMARY ENTRY ROUTE: Skin, eyes, inhalation. CCl�TIANI \/1 �CA/�TI\/ITV 1'\ATA TRA -CON, INC. MAKES NO EXPRESS OR IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS OR OTHERWISE WITH RESPECT TO ITS PRODUCTS. The information contained herein is based on MSDS information supplied by the Manufacturers and/or Vendors of the components listed and is believed to be reliable, however no guarantee or warranty is expressed or implied regarding the accuracy of the data or the results to be obtained from the use thereof. All recommendations or suggestions for use are made without guarantee inasmuch as conditions of use are beyond our control. Users should determine the suitability of this product for their own purposes. Rev B OAF -1058 Rev A TRA—CON THE ADFiESVE SOURCE MATERIAL SAFETY DATA SHEET DATE: 8/27/98 H HEALTH 3 F FLAMMABILITY R REACTVITY 0 P PROTECTION See Section VIII SECTION I MANUFACTURER'S NAME TRA -CON, INC. COMPANY TELEPHONE NUMBER (781) 275-6363 EMERGENCY TELEPHONE NUMBER CHEMTREC (800) 424-9300 ADDRESS (Number, Street, City, State and ZIP Code) 45 WIGGINS AVENUE BEDFORD MA 01730 CHEMICAL NAME AND SYNONYMS: Epoxy Adhesive Coreactant TRADE NAME: TRA -BOND F113SC HARDENER CHEMICAL FAMILY: Aliphatic Polyamine Mixture FORMULA: Mixture (All ingredients listed in Federal TSCA Inventory) HAZARD LABEL REQUIRED? CARCINOGEN: NONE MUTAGEN: NONE NFt ROTOXIN: NONE TERATOGEN: NONE OTHER: NONE SECTION II - HAZARDOUS INGREDIENTS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES CAS # % TLV mg/m3 ppm Benzenemethanol,4-amino-a,a-bis(4-aminophenyl)-, reaction products with aniline Diethylene triamine 1-propanamine,3,3'-(oxybis(2,1--ethanediyloxy))bis- Phenol, 4,4'-(1-methylethylidene)bis-,polymer with N,N'-bis(2-aminnoethy1)-1,2- ethanediamine and (chloromethyl) oxirane Other ingredients (if any) per OSHA 1910.1200 (g)(2)()(c)(1) which may compose less than 1 % of the composition, and/or which are non -hazardous or not listed on the Masachusetts Hazardous Substance List. SARA Title 111, Section 313: not listed NE=Not Established 068389-46-8 000111-40-0 004246-51-9 038294-69-8 up 1-2 10-30 40-60 5-25 to 20 NE NE 4.2 1 NE NE NE NE „ SECTION ill - PHYSICAL DATA BOILING POINT(°F) > 300 SPECIFIC GRAVITY (H2O=1) 1.0 VAPOR PRESSURE (mm Hg.) @ 77°F < 1 PERCENT VOLATILE BY VOLUME (%) < 1 VAPOR DENSITY (air=1) > 2 EVAPORATION RATE (BuAc=1) low SOLUBILITY IN WATER partial APPEARANCE AND ODOR: Blue, low viscosity liquid, ammoniacal odor. SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASHPOINT (Method Used) : > 200°F(setaflash) FLAMMABLE LIMITS: N/AV LEL: N/A UEL: N/A EXTINGUISHING MEDIA: Dry chemicals, chemical foam, carbon dioxide, water. SPECIAL FIRE FIGHTING PROCEDURES: Avoid breathing smoke. Addition of water may reduce flame intensity. UNUSUAL FIRE AND EXPLOSION HAZARDS: Toxic gases may be liberated; handle as combustible; store in a cool place. TRA -CON, INC. MAKES NO EXPRESS OR IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS OR OTHERWISE WITH RESPECT TO ITS PRODUCTS. The information contained herein is based on MSDS information supplied by the Manufacturers and/or Vendors of the components listed and is believed to be reliable, however no guarantee or warranty is expressed or implied regarding the accuracy of the data or the results to be obtained from the use thereof. All recommendations or suggestions for use are made without guarantee inasmuch as conditions of use are beyond our control. Users should determine the suitability of this product for their own purposes. Rev B QAF-1068 Rev TRA-BOND F113SC RESIN ti• SECTION V - HEALTH HAZARD DATA EXPOSURE LIMITS: LD50 (rats) > 4 grams/kg. EFFECTS OF OVEREXPOSURE: Repeated contact or breathing of vapors may cause irritation; material is also a strong sensitizer. Eye and skin contact may cause transient irritation. EMERGENCY AND FIRST AID PROCEDURES EYES: Flush with water, get medical attention. SKIN: Wash with soap and water; remove contaminated clothing. INHALATION: Remove to fresh air. INGESTION: No known antidote but give milk or water; induce vomittina if large amount swallowed. PRIMARY ENTRY ROUTE: Skin, eyes, inhalation. SECTION VI - REACTIVITY DATA UNSTABLE CONDITIONS TO AVOID: Avoid uncontrolled excess heating over long STABILITY periods; avoid uncontrolled amine reactions. STABLE X INCOMPATIBILITY: Strong acids and bases, strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, aldehydes, phenol. MAY OCCUR coNDlrloNs Toavolo: High temperatures, strong acids; certain organic HAZARDOUS metallic acids. WILL NOT OCCUR X POLYMERIZATION SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Prevent skin and eye contact. Soak up in absorbent material or scrape up and transfer to disposal container. Wipe up remaining resdue with solvents observing solvent flammab'lity rRutmons or use detergents WASTE DISPOSAL METHOD: Dispose of as hazardous waste according to local, state and federal regulations. Disposal method can be land burial or chemical SECTION VIII -SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (specify type): Air supplied or organic canister, mask in confined areas. LOCAL EXHAUST: Recommended SPECIAL: N/A VENTILATION MECHANICAL (General): Recommended OTHER: N/A PROTECTIVE GLOVES: Rubber or plastic disposable EYE PROTECTION: Safety glasses or goggles OTHER PROTECTIVE EQUIPMENT: As required to prevent all body contact; eye or bath and/or safety shower SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING & STORAGE: OTHER PRECAUTIONS: Store in cool place in closed containers. TRA -CON, INC. MAKES NO EXPRESS OR IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS OR OTHERWISE WITH RESPECT TO ITS PRODUCTS. The information contained herein is based on MSDS information supplied by the Manufacturers and/or Vendors of the components listed and is believed to be reliable, however no guarantee or warranty is expressed or implied regarding the accuracy of the data or the results to be obtained from the use thereof. All recommendations or suggestions for use are made without guarantee inasmuch as conditions of use are beyond our control. Users should determine the suitability of this product for their own purposes. Rev B QAF-1058 Rev A tr�crivE oaTE 02n 874,3 t:laiao CA&ide ugea� mb coamer or rdcipieal of this )AIDS to study it carefn* to become aware of and tmdesataad 0 husnrde associated .with the Product. The reader should consider coasuldog reference works or individuabi who in ezperes in vwa'ation. to6mWV, and }u4 PNve&dM as neeareary or appropriate to use and uodeeetand the date coataloed is"MSUS. To Ptomose sde htwdlag. each customer or recipiut tboutd: (I) mdly its tmplyeas. ateau, contractars and otthers whom it hat, .v or believes will use. this msserW or the Ieforma6tt4 ill tmc MSDS and aay other inkri adon rtepardug hazards or sadeq; C4 firaish two same infammafm to each of its customers far the product; and (3) regeust its customers to notify their ampk7- eec. cusomera, and other users of the prodw of this intbavtatim. I. IDENTIFICATION PRODUCT NAME: ACETONE CHEMICAL NAME: Acetone CHEMICAL FAMILY: Ketones FORMULA: CH3COCH3 MOLECULAR WEIGHT: 58.08 SYNONYMS: Dimethyl Ketone, 1-Propanone, Dimethyl Ketal CAS P AND NAME. 67-841 2-Propanono II. PHYSICAL DATA BOILING POINT. 760 mm Ng: 56.29 C (133.32 F) SPECIFIC GRAVITY(H20 — 1): 0.7916 at 20120 C FREEZING POINT: -98.54C (-141.77F) VAPOR PRESSURE AT 20'C. 184 mmHg Copyright 1998, Caws Carbide. EM MGENCY PHONE NUMBERS: I -800 -UCC -HELP (NUN BER AVAILABLE AT ALL TLUS) OR (304) 744-3487 ID&I CHENWAU DoE & INGACL gIAs 25 COMMERCIAL, STREET • MEDFORM MA.0215S PHONE (617) 391-0090 FAX (617) 395-1014 PRODUCT NAME: ACETONE PAGE 2 IV. EIRE AND EXPLOSION HAZARD DATA FLASH POINT: OF t-18 C1 Tag Closed Cup ASTM 0 56 FLAMMABLE LIMITS IN AIR LOWER; 2.15 % by volume: UPPER: 12.0 EXTINGUISHING MEDIA- Apply alcohol -type or ell -purpose -type foam try manufacturer's recommended techniques for large fires. Use Carbon dioxide or dry chemical rnedis for small fires, SPECIAL FIRE FIGHTING PROCEDURES; Use water spray to cool tire-ertposed containers and sirueturee- Use remote spray monitors or flght fit* from behind shields, Use water spray to disperse Vapors; re -ignition Is possible. Use self-contalned breathing epparatua and protective clothing. UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapors form from thio product and may travel or be moved by air currents and ignited by pilot lights, other flames, smoking, sparks, heaters, eieetrlosi VAPOR DENSITY (AIR = 11: 2.0 EVAPORATION RATE (8UtyI Acetate = 1): 14.4 SOLUBILITY IN WATER by wt: compista at 20 C APPEARANCE: Tranepatent colorless ODOR: Mint PHYSICAL STATE: Liquid PERCENT VOLATILES Iby weight): 100 III. INGREDIENTS 96 MATERIAL 99-100 Acetone CAS# EXPOSURE LIMIT 07-64.1 See Section V IV. EIRE AND EXPLOSION HAZARD DATA FLASH POINT: OF t-18 C1 Tag Closed Cup ASTM 0 56 FLAMMABLE LIMITS IN AIR LOWER; 2.15 % by volume: UPPER: 12.0 EXTINGUISHING MEDIA- Apply alcohol -type or ell -purpose -type foam try manufacturer's recommended techniques for large fires. Use Carbon dioxide or dry chemical rnedis for small fires, SPECIAL FIRE FIGHTING PROCEDURES; Use water spray to cool tire-ertposed containers and sirueturee- Use remote spray monitors or flght fit* from behind shields, Use water spray to disperse Vapors; re -ignition Is possible. Use self-contalned breathing epparatua and protective clothing. UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapors form from thio product and may travel or be moved by air currents and ignited by pilot lights, other flames, smoking, sparks, heaters, eieetrlosi PRODUCT NAME: ACETONE equipment, static discharges or other ignition Sources at locations distant from product handling polnt. Vapors from thle materlal may Bettie In low or confined areas or travel a long distance to an Ignition source and flash back explosively, This materiel may produce 8 floating fire hazard. Static Ignition hazard can result from handling and wee. Eseotrically bond end ground all containers and equipment before transfer or use of material. Use proper bonding and grounding during product transfer ea described in National Fife Protection Association Document NEPA 77. See 'Other Precautions" in Section IX, V. HEALTH HAZARD DATA EXPOSURE LIMfT(S): Acetone: 750 ppm TWA, OSHA 1000 ppm STEL. OSHA 600 ppm TWA. ACGIH 750 ppm STEL, ACGIH EFFECTS OF ACUTE OVEREXPOSURE: SWALLOWING; slightly toxic. Headache, nausea, vomiting, dizzineec, and drowsiness may occur_ Aopiration Into the lungs may occur during ingestion or vomiting. resulting in lung injury. SKIN ABSORPTION: No evidence of harmful effectr, from available information. INHALATION: Vapors are Irritating ano may cause a stinging anc itching senaaticn in the eyes, ocee and throat. coughing, exceeeive blinking, tear production, nausea and possibly vomiting, High vapor concentrations may result in headache, nausea, weakness, dizziness; Incoordination and eventually unconsciousness. SKIN CONTACT: Brief contact is not irritating. Prdonyod or ropeated punted may cause defetting and drying of the skln, EYE CONTACT: Cauaee severe Irritation, experienced as discomfort or pain, excess blinking and tear production, with markso excess rednaaa and swelling of the conjunctiva, Corneal injury may occur. EFFECTS OF REPEATED OVEREXPOSURE: No sovorae effects enticipaied from available Information. OTHER HEALTH HAZARDS: None ovrrontly known. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE. Skin contact may aggrevate an existing dormetitis, ADDITIONAL TOXICITY INFORMATION: Development of cataraote hes been reported in laboratory animals aftor prolonged repeated akin exposure 10 acetone. PAGE 3 PRODUCT NAME: ACETONE PAGE 4 EMERGENCY AND FIRST AID PROCEDURES: SWALLOWING: If patient is fully conscious, give two pleases of water. DO NOT INDUCE VOMITING. Obtain medical attention. SKIN: Remove Contaminated clothing. Wash skin with soap and water. Obtain medical attention If Irritation persists. Wash clothing before reuse. INHALATION: Remove to 1rech air. Give sniflclal r8spiratlon it not breathing, If breathing is dffflcult, oxygen may be given by quellfled personnel. Obtain medical attention, EYES: Immediately flush eyes with water and continue washing for at lodst IS minutes. DO NOT remove contact lenses, If worn. Obtain medical attention vritllout delay, preferably from an ophthalmologist. NOTES TO PHYSICIAN: Aspirated sestone may cause severe lung damage and present a significant hazard. Stomach contenta should be evacuated Quickly in a manner which avoids aspiration. Otherwise, trsetment of overexposure is directed at the Control of eYntptoms and the Cllnleel condition of the patient. No specific entldote is known. VI. REACTIVITY DATA STABILITY: Stable CONDITIONS TO AVOID: Contact with excessive heat, open flame. sDarke, or ignition sources. INCOMPATIBILITY (materials tO avoid): Strong oxidizing agents. Nitric acid. Alkalfea. HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS: Burning can produae the following products: Carbon monoxide andlar carbon dioxide. Carbon monoxide is highly toxic if Inhaled; carbon dioxiae in sufficient concentrations can act ae an saphywiant. HAZARDOUS POLYMERIZATION: WIII Not occur CONDITIONS TO AVOID: None known. VII. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Extingulsh and do not turn on any ignition source until the area it determined to be free from fire or explosion hazard. Weer aultable protective equipment. Smell Wile can be flushed with large amounts of water: lar9er spills should PRODUCT NAME: ACETONE PAGE 5 De cogeotsd for disposal. Observe government regulations. WASTE DISPOSAL METHOD: Incinerate in a furnace where permitted under Federal, State, and local regulations. Vill. SPECIAL PROTECTION INFORMATION RESPIRATORY PPOTECTION: Use self-contained breathing apparatus in high vapor Concentrations. VENTILATION: General lmechanical) room vontiletion it expected to be satisfactory where this product is stored and handled In closed equipment. Special, local ventilation is needed at pointe where vapors can be expected to escape to the workplace air. PROTECTIVE GLOVES: Butyl EYE PROTECTION: Monogogglee OTHER PROTECTIVE EQUIPMENT: Eve Beth, Safety Shower IX. SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: DANDER! EXTREMELY FLAMMABLE. HARMFUL IF INHALED. CAUSES EYE IRRITA i rOM. ASPIRATION MAY CAUSE LUNG DAMAGE. MAY CAUSE DIZZINESS AND DROWSFNESS. Keep away from heat, sparks and flame. Avoid oreatntng vapor, Avoid contact with eyes. Do not swallow. Keep container closed. Use with ade4uate ventilation. Vapor forms frim this product and rney travel or be moved by sir currents and ignftad by pilot lights, other :'lames, smoking, sparks, heaters, electrical equipment, static discharges or other ignition sources at locations distant from product handling point end may flashback explosively. Weah thoroughly after handling. FOR INDUSTRY USE ONLY OTHER PRECA,LITIONS: Vapors may settle in low or confined areas, or travel s long distanoe to an ignition source and flash back explogivsly. ADDITIONAL INFORMATION: There may be addltlonaf product safety Information on (Ns product, which may be obteined by calling your Union Carbide Corporation Seise or Customer Service Contact. PRODUCT NAME: ACETONE PAGE 6 PROCESS HAZARD: Sudden release of hot organic chemical vapors or mists from Procne$ equipment operating at elevated temperature and pressure, or sudden ingress of air Into hot equipment under a vacuum, may result in ignitiere without the presence of obvious ignition souses. Published 'autoignition' or '►gnition' ternParature values cannot be treated as safe operating temosratumn in chemical processes without analysis of the actual process conditions. Any use of this product in elevated•temporature processes should be thoroughly evelueted to establish and maintain safe operating conditions. Further information is available in a technical bulletin entitled "Ignition Hazards of Organic Chemical vapors,' X. REGULATORY INFORMATION STATUS ON SUBSTANCE LISTS: The concentrations shown are mWnrum or ceiling levels (weight %) to be used for calculations for regulations. Trade :Secreta are Indicated by "TS". FEDERAL EPA Comprehensive Environmontel Response Compensation, and Liablilty Act of 1980 (CERCLA) requires notification of the National Response Canter of release of quandties of Hazardous Substances equal to or greater than the reportable quarnitiess ACiel in 40 CFR 302.4. Cortiponents pree3011 in this praduot at a levai which could reauire reporting under the statute are: UPPER SOUND CHEMICAL CAS NUMBER CONCENTRATION % Acetone 67.64-1 100 Methanol 67.56.1 0.025 Formaldehyde 60-00-0 0.002 Acetic Aole 84-18.7 0,002 Propior,aldehyCe 123.38.6 0.002 Benzene 71.43-2 0.0005 Superfund Amendments and Reauthorization Act of 1986 (SAAAJ Title Ifs rsqulres emergency planning bated on Threshold Planning Quantities ('rPOs) and release reporting based on Reportable Quantities (RQs) in 40 CFR 366 (used for SARA 202, 304, 311 and 312). Components present in thie product et a level which could require reporting under the statute are- " NONE Superfund ArnertGments and ReautRorization Act Of 1988 (SARA) Title III requires submission of annual reports of release of toxic chemicals that appear ip 40 CFR 872 (for SAFIA 313). This; information must be Included In ail MSOSe that are copied and distributed for this material, COmponants present in this product at a fevel which could require reporting under the statute are: UPPER BOUND CHEMICAL CAS NUMBER CONCENTRATION % Thio product does not contain toxic aherniaaie at levels which require reporting under the statute. PRODUCT NAME: ACETONE Toxic Substances Control Act (TSCA) STATUS: All components of this product are on the TSCA Inventory or ere exempt from TSCA Inventory requimments. CALIFORNIA Proposition 66 STATE RIGHT -TO -KNOW Thi& product contains trace levels of BENZENi: and FORMALDEIRYOE, known to the Stats of California to cause cancer, See Maesechusetts lifting for amounts. MASSACHUSETTS Right -To -Know. Substance List (MSL) Hazardous Substances and Extraordinarily Hazardous Substances on the MSL must be identiflea wnen present in products. Cornponente present in this product at a level which could require reporting under the statute are: EXTRAORDINARILY HAZARDOUS SUBSTANCES ( .> 0.0001%) UPPER BOUND CHEMICAL CAS NUMBER CONCENTRATION sib Formaldehyde 50.00-0 0.002 8emene 71.43.2 0,0005 HAZARDOUS SUBSTANCES ( => t%) UPPER BOUND CHEMICAL Cas NUMBER CONCENTRATION % Acetone 67-64-1 100 PENNSYLVANIA Right -to -Know, Hazardous Subatanoe List Hatardoua Substances and Sp®oial Hazardous Subetanees on the List must be identified when present in produets. Components present in this product at a level which could raQuire reporting under the statute are: HAZAADCUS SUBSTANCES ( => 1%1 UPPER BOUND CHEMICAL CAS NUMBER CONCENTRATION % Acetone 67-84.1 100 CALIFORNIA SCAOMD RULE 443.1 VOC'S: YOC 790 qA; Vapor pressure 184 mm Hg ® 20 C OTHER REGULATORY INFORMATION: NEW YORK STATE BULK STORAGE REGULATIONS (S NYCRR Parte 555-698) This product Is covered by 8 NYCRR for Bulk Storage and Release Reporting and Response. Tschnloal guidance and recommended practices are as follo.ra; MATERIALS OF CONSTRUCTION Suitable materiels of construction are; Steel, stainless gteei, aluminum, baked phenolic lined eteei, galvanized steel Matorials not to be used: Copper and copper alloys. Plastics, including polyvinyl Chloride and polyatnylene, STORAGE SYSTEM DESIGN Design should comply with applicable Industry, Federal, and local codes for a Clens 1B Aammable liquid with regerdo to mechanical, sleatricat, safety and health components. Should also comply with NYSIDEC Chemical Bulk Storage regulation@ Parte 598.1 - 598.3 and 698.5 (for existing tanks) or Parte 588.1 PAGE 7 PRODUCT NAME: ACETONE no S99-10 Ifor new or substantially modified conks). CONDITIONS FOR STORAGE Store at normal ambient temperatures. INSPECTION AND MAINTENANCE A testing/inspection proaram which ensures structural integrity and proper system operation should be established. Inspectlon and maintenance procedurse and tasting of "UIPment should comply with NY8IDEC regulations Parts 598.8 to $88.10. TRANSFER AND UNLOADING These operations should Comply with NYS/DEC regulations. Part 598.4. EPA HAZARD CATIGORIES: IMMEDIATE HEALTH, DELAYED HEALTH, FIRE NOTE .... The opinlons expressed herein are those of tau&"fled experts within Union Carbide. We believe that the Information oonteined herein is current ae of the date of this Material Safety Data Sheet. Since the use of this information and the conditions of the use of the product ate not under She Control of Union CerDlde, it Is the user's obligation to determine ccnaitions of Rafe use of the product. REVISED SECTIONS: Section III . Ingredients Section V • Health He2ard pats Section Y1 - Reactivity Data Section VII - Spill or Look Procedures Section IX - Special Precautions PRODUCT: 11212 SeCdOrl X • Regulatory Data F NUMBER: C0302J PAGE 8 UNION CARBIDE CORPORATION MATERIAL SAFETY DATA SHEET Product Name: ISOPROPANOL ANHYDROUS Effective Date: 11/01/1999 MSDS#: 1194 Page 1 of 14 Union Carbide urges each customer or recipient of this MSDS to study it carefully to become aware of and understand the hazards associated with the product. The reader should consider consulting reference works or individuals who are experts in ventilation, toxicology, and fire prevention, as necessary or appropriate to use and understand the data contained in this MSDS. To promote safe handling, each customer or recipient should: 1) Notify its employees, agents, contractors and others whom it knows or believes will use this material of the Information in this MSDS and any other information regarding hazards or safety, 2) Furnish this same information to each of its customers for the product; and 3) Request its customers to notify their employees, customers, and other users of the product of this information. 11. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 1 1.1 IDENTIFICATION Product Name ISOPROPANOL ANHYDROUS Chemical Name lsopropyl Alcohol Chemical Family Alcohols Formula (CH3)2 CHOH Synonym ISOPROPANOL, ANHYDROUS, USP, ISOPROPANOL, ANHYDROUS SEMI- Phone It at CONDUCTOR GRAI3E, dimethyl carbinol, 2 -Propanol 39i O� J / r 1.2 COMPANY IDENTIFICATION Union Carbide Corporation 39 Old Ridgebury Road Danbury, CT 06817-0001 1.3 EMERGENCY TELEPHONE NUMBER Post-ito Fax Note 7671 Date// C/ #oes� To /i C/ From r rO �y - Co./Dept. G / Co. Phone It at Phone A 39i O� J / Fax # J Fax 4 24 hours a day: 1 -800 -UCC -HELP (1-304-744-3487) Number for non -emergency questions concerning MSDS (732) 563-5522 Additional information on this product may be obtained by calling the Union Carbide Corporation Customer Service Center at 1-800-568-4000. Copyright 1999, Union Carbide. MATERIAL SAFETY DATA SHEET Product Name: ISOPROPANOL ANHYDROUS Effective Date: 11101/1999 MSDS#: 1194 Page 3 of 14 Skin Absorption Exposure to small quantities is not expected to cause adverse health effects. Widespread or prolonged exposure may result in the absorption of harmful amounts of material, particularly in infants, leading to signs and symptoms as described for swallowing. Swallowing Slightly toxic. May cause dizziness, faintness, drowsiness, decreased awareness and responsiveness, lack of coordination, abdominal discomfort, nausea, vomiting and -diarrhea. Chronic Prolonged or Repeated Overexposure Effects of Repeated Overexposure Prolonged or repeated skin exposure may cause defatting of the skin. Other Effects of Overexposure gone currently known. Medical Conditions Aggravated by Exposure Skin. contact may aggravate an existing dermatitis_ 3.3 POTENTIAL ENVIRONMENTAL EFFECTS See Section 12 for Ecological Information, 14. FIRST AID PROCEDURES 4.1 INHALATION Remove to fresh air. Give artificial respiration if not breathing. If breathing is difficult, oxygen may be given by qualified personnel. Obtain medical attention. 4.2 EYE CONTACT Immediately flush eyes with water and continue washing for several minutes. Remove contact lenses, if worn. Obtain medical attention 4.3 SKIN CONTACT Remove contaminated clothing. Wash skin with soap and water. If irritation persists or if contact has been prolonged, obtain medical attention. 4.4 SWALLOWING If patient is fully conscious, give two glasses of water. Induce vomiting. This should be done only by medical or experienced first-aid personnel. Obtain medical attention. 4.5 NOTES TO PHYSICIAN There is no specific antidote. Treatment of overexposure should be directed at the control of symptoms and the clinical condition of the patient. MATERIAL SAFETY DATA SHEET Product Name: ISOPROPANOL ANHYDROUS Effective Date: 11/0111999 MSDS#: 1194 Page 5 of 14 5.7 HAZARDOUS COMBUSTION PRODUCTS Burning can produce the following products: Carbon monoxide and/or carbon dioxide. Carbon monoxide is highly toxic if inhaled; carbon dioxide in sufficient concentrations can act as an asphyxiant. Is. ACCIDENTAL RELEASE MEASURES 1 Steps to be taken if Material is Released or Spilled: Extinguish and do not turn on any ignition source until the area is determined to be free from fire or explosion hazard. Small spills can be flushed with large amounts of water, larger spills should be collected for disposal. Personal Precautions: Avoid contact with eyes. Wear suitable protective equipment. 17. HANDLING AND STORAGE 7.1 HANDLING General Handling Keep away from heat, sparks and flame. Avoid contact with eyes. Keep container closed. Use with adequate ventilation. Vapor forms from this product and may travel or be moved by air currents and ignited by pilot lights, other flames, smoking, sparks, heaters, electrical equipment, static discharges or other ignition sources at locations distant from product handling point and may flash back explosively. Wash thoroughly after handling. FOR INDUSTRY USE ONLY. Ventilation General (mechanical) room ventilation is expected .to be satisfactory where this product is stored and handled in closed equipment. Special, local ventilation is needed at points where vapors can be expected to escape to the workplace air. Other Precautions Vapor may settle in low or confined areas, or travel a long distance to an ignition source and flash back explosively. 7.2 STORAGE No information currently available. 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION MATERIAL SAFETY DATA SHEET Product Name: ISOPROPANOL ANHYDROUS Effective Date: 11101/1999 MSDS#: 1194 Page 7 of 14 PROCESS HAZARD: Sudden release of hot organic chemical vapors or mists from process equipment operating at elevated temperature and pressure, or sudden ingress of air into hot equipment under a vacuum, .may result in ignitions without the presence of obvious ignition sources. Published "autoignition" or'Ignitlon" temperature values cannot be treated as safe operating temperatures in chemical processes without analysis of the actual. process conditions. Any use of this product in elevated -temperature processes should be thoroughly evaluated to establish and maintain safe operating conditions. Further information is available in a technical bulletin entitled "ignition Hazards of Organic Chemical Vapors! 19. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Appearance: Transparent colorless pH: Not currently available. Solubility in Water (by weight): 20 "C 100% Odor: Slight ethanol/acetone-like - - Flash Point- Closed Cup: Tag ClosedjCup ASTM D 56 12 °C 530F Flash Point -Open Cup: Tag Open Cup ASTM D 1310 17"C 63 °F Percent Volatiles: 100 Wt% Molecular Weight: 60.10 glmol Liquid Density: 20 °C 6.5475 g/cm3 Boiling Point (760 mmHg):. 82.30C 180.10F Freezing Point: -89 °C -127 OF Specific Gravity (H20 =1): 0,787 20 "C 120 °C Vapor Pressure at 20°C: 4.4 kPa 33 mmHg Vapor Density (air =1): 2.1 Evaporation Rate (Butyl Acetate =1): 2.9 Melting Point: Not applicable. MATERIAL SAFETY DATA SHEET Product Name: ISOPROPANOL_ ANHYDROUS Effective Date: 11/01/1999 MSDS#: 1194 Page 9 of 14 Mortality: 0112 Major. Signs: prostration Gross Pathology: lungs, kidneys and liver discolored Inhalation: dynamic generation of vapor Exposure Time 8 h 12004 ppm Rabbit Mortality: 8/12 Major Signs: prostration Gross Pathology: lungs, kidneys and liver discolored Inhalation: dynamic generation of vapor Exposure Time 8 h 8000 ppm Rabbit Mortality: 0112 } Major Signs: prostration Gross Pathology: lungs, kidneys and liver discolored Inhalation: static generation of vapor Exposure Time 4 h Rabbit Room temperature " Mortality: 616 Major Signs: lacrimation, loss of coordination, prostration Gross Pathology: lungs discolored Inhalation: static generation of vapor Exposure Time 1 h Rabbit Room temperature Mortality: 016 Major Signs: lacrimation, loss of coordination, prostration Gross Pathology: lungs discolored IRRITATION Skin: Rabbit 24 hr uncovered no irritation Eye: Rabbit 0.02 ml moderate corneal injury SIGNIFICANT DATA WITH POSSIBLE RELEVANCE TO HUMANS MATERIAL SAFETY DATA SHEET Product Name: ISOPROPANOL ANHYDROUS Effective Date: 11/01/1999 MSDS#: 1194 Page 11 of 14 THOD (measured) 2.30 mg/mg THOD (calculated) 2.40 mg/mg OctanollWater Partition Coefficient - Measured: 0.14 113. DISPOSAL CONSIDERATIONS 13.1 WASTE DISPOSAL METHOD Incinerate in a furnace where permitted under Federal, State, and local regulations. Dispose in accordance with all applicable Federal, State, and local environmental regulations. Empty containers should be recycled or disposed of through•aO approved waste management facility. 13.2 DISPOSAL CONSIDERATIONS At very low concentrations in water, this product is biodegradable in a biological wastewater treatment plant. Disposal methods identified are for the product as sold. For proper disposal of used material, an assessment must be completed to determine the proper and permissible waste management options permissible under applicable rules, regulations and/or laws governing your location. 114. TRANSPORT INFORMATION 14,1 U.S. D.O.T. NON -BULK Proper Shipping Name: ISOPROPANOL ID Number: UN1219 Hazard .Class : 3 Packing Group: PG II BULK Proper Shipping Name: ISOPROPANOL ID Number: UN1219 Hazard Class: 3 Packing Group: PG II This Information is not intended to convey all specifrc regulatory or operational requirementslinformation relating to this product. Additional transportation system information can be obtained through an authorized sales or customer service representative. tt is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. MATERIAL SAFETY DATA SHEET Product Name: ISOPROPANOL ANHYDROUS Effective Date: 11/01/1999 MSDS#: 1194 Page 13 of 14 The component of this product is on the EINECS inventory. CEPA - DOMESTIC SUBSTANCES LIST (DSL) The component of this product is on the DSL. 15.2 STATE/LOCAL PENNSYLVANIA (WORKER AND C0144MUNnY RIGHT -TO -KNOW ACT) This product is subject to the Worker and Community Right -to -Know Act. The following components of this product are at levels which could require identification in the MSDS; Component CAS # Amount Isopropanol 67-63-0 <= 100.0000% MASSACHUSETTS (HAZARDOUS SUBSTANCES DISCLOSURE BY EMPLOYERS) The following components of this product appear on the Massachusetts Substance List and are present at levels which could require identification in the NtSDS: Component CAS # Amount lsopropanol 67-63-0 <= 100.0000% CALIFORNIA PROPOSITION 65 (SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986) This product contains no listed substances known to the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute. CALIFORNIA SCAQMD_ RULE 443.1 (SOUTH COAST AIRQUALITY MANAGEMENT DISTRICT RULE 443.1 LABELING OF MATERIALS CONTAINING ORGANIC SOLVENTS VOC: 785 g/l Vapor pressure 33 mmHg @ 20° C This section provides selected regulatory Information on this product including its components. This is not intended to Include all regulations. tt Is the responsibility of the user to know and comply with all applicable rules, regulations and laws relating to the product being used. 16. OTHER INFORMATION r January 8, 2001 AZ91 safetq,ween Mr. Paul Barry Dymec 27 Katrina Road Chelmsford, MA 01824 Regarding: Waste Disposal Services Dear Mr. Barry: Thank you for considering Safety-Kleen for your environmental needs. We welcome the opportunity to contribute to the success of safely and effectively managing all your hazardous waste requirements. Safety-Kleen understands and has responded to the unique needs of hazardous waste generator's in today's competitive economy: Certificate of Assurance and Indemnification: Without fault of the customer, if a spill or accident should occur while a customer's waste is in our possession, including ground or water pollution, Safety-Kleen's financial strength and assets will be there to pay the cost to clean it up. Safety-Kleen pursues a "zero defect" strategy: Minimizing risk by ensuring full compliance with appropriate regulations at the state, local and federal levels is only the beginning. Facilities are put through a demanding, almost continual audit process to make certain that operations are within regulatory guideline. Employees receive ongoing safety and compliance training to ensure that technical skills and expertise remain current with — or a step ahead of -- ever- changing environmental rules. A network of more than 200 service locations: This assures local convenience and cost- effectiveness; no matter how remote a location. Access to a full range of recycling options and advanced treatment technologies enables Safety-Kleen to be your single source for secure, responsible environmental services. The following pages contain a competitive, pricing proposal that is prepared in response to our conversation on January 8, 2000. Please do not hesitate to contact me at (603) 431-2924 with any questions or concerns regarding this proposal. Sincerely, Todd Berry Technical Sates Representative Cc: J. Howard, SK TCSR SAFETY -KEEN (NE), INC. Company Name: Dymec Safety-Kleen January 8, 2001 Pricing Proposal ..,... n.u. �.ti.�.........�.u.�...�...�.� .,.�.,....r.�M.......M..�... w�...�_rt��....�u..d.....�.�..�,��.,�.rm.....,._...n..r.......�A�,.._......w�.�.�..�_.���, Description Quantity Unit of Price Measure DISPOSAL lsopropanoUWater TBD 55 gallon $120.00 Waste Transportation Charge for Waste Removal I One drum $100.00 MATERIALS 55 Gallon Steel Drum Each 55 gallon $35.00 TRANSPORTATION* Delivery Charge for Materials I Each Flat Fee $50.00 Waste Transportation Charge for Waste Removal I One Flat Fee 1 $100.00 *The delivery charge for the empty 55 gallon drum(s) will be waived if coordinated with a waste pick-up. Company Name: Dymec Safety -Ween January 8, 2001 Important Information Regarding This Quotation • Disposal price is contingent upon completion and review of a waste profile. • If a material received from a generating location deviates from the specifications detailed on the waste profile, Safety-Kleen will research alternative solutions, if necessary. Those alternative solutions will be offered and may require a price adjustment. If the price adjustment is unacceptable, the material will be returned to the generating location at the customer's expense. • The information contained in this proposal, including, but not limited to pricing, is considered confidential and proprietary and is to be used solely by the customers of Safety-Kleen in response to bid solicitations. Any copying, faxing or otherwise communicating this information, to any third party other than existing and potential customers of Safety-Kleen, for purposes other than securing business for Safety-Kleen is strictly prohibited. • Due to the current price of fuel, a fuel surcharge may apply to the shipment. • Safety-Kleen's Master Services Agreement must be executed prior to the start of the project. This agreement was created as an equitable arrangement to satisfy the particular needs of all parties and was specifically designed for the type of work involved in this quotation. Bid submission should not in any way be interpreted as acceptance by Safety-Kleen of any terms included or referenced within any request for quotation and Safety-Kleen shall not be bound by them. • Federal, state and local taxes and fees have not been included in this quotation. The customer will be responsible for all applicable taxes. • All waste must be in DOT shippable containers. 3