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Miscellaneous - 315 SOUTH BRADFORD STREET 4/30/2018 (3)
DESIGN LAYOUT Smolak Farms �r/" 1 Food Establishment Pian Review Guide FOOD ESTABLISHMENT PLAN REVIEW APPLICATION IS TO BE COMPLETED BY THE OPERATOR AND SUBMITTED TO THE REGULATORY AUTHORITY—at least 60 days in advance before commencement of any food establishment planned openings TOWN OF NORTH ANDOVER, MA Regulatory Authority 1600 Osgood Street, Suite 2035,North Andover, MA 01845 Date: '__/671/J NEW -New construction,not yet built !/REMODEL -partial or major renovation of existing establishment CONVERSION—existing establishment that you are purchasing Name of Establishment: 5 K0 k,+/Y Corporate Name:--b PkOL, , :. 1=A-d_W 5- LLC- Category: Restaurant t/ 'Institution ,Daycare , Retail.Market . Other Fc-?_v,-a4 Establishment Address:_,315- c" j0)r, c O R i Phone: (at location if available) 7co 3� O E-mail Contacts: 6014 ��� A s i Name of Owner:_ . / t( ,ka e j Mailing Address: j{-� 12 P-# /fid Telephone:. ^' C901 Applicant's Name (if different than owner):^A,1�, Town of North Andover,Health Departnient,1b00 Osgood Street,Suite 2035, North Andover,MA 01845---Phone:978.688.9540--^-Fax:978.688.8476 Page 1 of 19 L. SMALL EQUIPMENT REQUIREMENTS 62. Please specify the number, location, and types of each of the following proposed for on site use: Slicers Cutting boards Can openers Mixers Floor mats Other .Y SFX�['IC fEXXXTcx�: STATEMENT: I hereby certify that the above information is correct, and I fully understand that any deviation from the above without prior permission from this Health Regulatory Office may nullify final approval. Signature (s) 114 Print: IsL• c` r wt c� 2 Owner(s) or responsible representative(s) 5ApprDate:A/C9 / /5- Approval oval of these plans and specifications by this Regulatory Authority does not indicate compliance with any other code,law or regulation that may be required--federal, state,or local. It further does not constitute endorsement or acceptance of the completed establishment (structure or equipment). A preconstruction inspection with equipment in place and a preopening inspection of the establishment will be necessary to determine if it complies with the local and state laws governing food service establishments. Page Last Updated: 1/29/2013 Town of North Andover,Health Department,1600 Osgood Street,Suite 2035, North Andover,MA 01845--Phone:978.688.9540--Fax:978.688.8476 Page 19 of 19 Sawyer, Susan From: smolakfarms@aol.com Sent: Monday,April 27, 2015 12:42 PM To: Sawyer, Susan Subject: Fwd: scan Attachments: Scan0006.pdf Hi Susan, Attached is the Food Establishment Plan Review Guide Application as requested. I have put a status report for the item you mentioned. Hand wash sink for the barn has been ordered. I will update you as things happen.. Michael Smolak I have noted the following items that need addressing before opening this year; Rear loading area - sliding door has gap at bottom where concrete has chipped -will be fixed by the hand man - floors are filthy in delivery bay; (as this area has not been made into a proper storage area, as discussed there will be no food kept in this area) ( if you wish to make this into a storage room it will need floors, walls and ceilings that comply with the code.) -this has been cleaned - gaps in various areas between the exterior walk-ins along the wall-will be filled by the handyman - Walk-in refrig. Floor is porous as the paint is worn; Old wooden pallets are directly on walk in floor. These absorb water and odors. Please attempt to pry them up and use non porous shelving that is 6 inches above the floor. (as the floor needs painting, this is a good time to remove these) -working on this Front and Kitchen - spec sheets for new display cooler-sent by email dirty build up under all equipment; (power wash) -all have been cleaned - curved coving is missing in kitchen area - paint worn on display fixtures; walls etc (must be nonporous)-painting being done or completed wall fan louver open; possibly in disrepair-fan has been fixed 1 VR5FRIOERA rOR MANUFA C TLIRER 4184 E. Conant St. Project AV Long Beach, CA 90808 Model# kifirAbo aIr Tel. 310-900-1000 Item#: Qty: Fax.310-900-1077 more durable,efficient,beautiful www.turboairinc.com Available W/H : Approval i TWO FUNCTIONS IN ONE REFRIGERATOR Model :TOM-W-50SB (Refrigerated Merchandiser+Refrigerated Top Display Case) clogo .. IlUIIIN�I(IIIIIIiIIII1111(IIIIlN� -. ___ _g111181gIIll = FE i4TURES & BENEFITS= o Modern design ■ Standard back-guard improves airflow By harmonizing curvature and rigidness,our modern style product designs are user-friendly while maintaining the highest product visibility and aesthetics.Glass front shield and side walls optimize the ■ Foamed with polyurethane, high-density cell merchandiser's display effects of fresh salads,sandwiches,desserts insulation (CFC Free) and beverages.Its elegant contemporary euro design will enhance any store application. ■ 300 series stainless steel interior standard LED lighting interior display system Brighter and longer lasting LED lights provide attractive,enhanced including back wall, shelves and deck pans illumination compared to fluorescents.It saves energy by producing less heat,while maximizing the visibility in the display area. ■ Perforated interior back wall and top for ■Designed to enhance impulsive sales improved airflow Ideal for eye-catching displays and convenient access with fast service in high traffic area. ■ Front air intake and rear air discharge ■ Environmentally friendly, efficient refrigeration ■ Recommended operating conditions system TOM models are designed to operate in an environment where tempera- Turbo Air's refrigerators are designed with oversized and balanced ture&humidity do not exceed 75°F and 55%respectively.Units should environmentally friendly R-1 34A(CFC Free)refrigeration.These include not be installed near HVAC vents,fans or doorways that will disrupt the air large evaporators and condensers for faster cooling and balanced curtain and compromise the function of the cabinet.Air curtain models will temperature throughout the cabinet. run most efficiently when completely loaded with product. ■ Non-peel, durable anti-rust coating on the exterior reduces fingerprints s vF..x a Tz T><t. 0 WA RAYTI' uI,— Intertek Intertek CU./FT. Crated L x D x H Model (Top/Bottom) HP AMPS Weight(lbs.) (inches) TOM-W-50SB 5.6/8.5 1/2 11 639 507/8 x 34 x 561/2 Ver.201501 M e Model :TOM-W-50SB PLAN VIEW ELECTRICAL DATA (unit:inch) Voltage 115/60/1 Plug Type rt NEMA 5-15P 507/8(1292.) Full Load Amperes 11 Compressor HP 1/2 Refrigerant R-134A E DIMENSIONAL DATA M Net Capacity cu.ft.(Top/Bottom) 5.6/8.5 M Ext.Length Overall in. 507/8(1292mm) Ext.Depth Overall in. 34(864mm) Ext.Height Overall in. 561/2(1435mm) TOP VIEW Interior Dimensions(LxDxH)(Top) 475/8 x 13 x 153/4 Interior Dimensions(LxDxH)(Bottom) 475/8 x 24 x 137/8 _507/8(1292mm) Net Weight lbs. 496 Gross Weight lbs. 639 Design and specifications subject to change without notice. Actual slipping weight may differ due to extra packing materials for product protection. � WARRANTY. Year Parts and Labor Warranty Additional 3 Year Warranty on Compressor ■ Simple plug-in installation o0 ■ Patented self-contained system,no plumbing required ■ Standard color comes in black only FRONT VIEW 34(864.1) 115/8 81/2 (295mm) (217mm) 131/8(333mm) 6(152mm) F ]37/8 E v (353nun) 7 241/8 00 (613mm) N r �_ N h SIDE VIEW Ver.201501 me�qq.. ■ Turbo Air:800-627-0032 ■ GK: 800-500-3519 ■ ` 'S 171js Warranty:800-381-7770 ■ AC: 888-900-1002 w�nnanry Intertek Intertek "�®a//, GERMRNFE II11IRaDianCc �/ - f ®�® CJKt,�N WORLD Blackburn, Lisa From: Sawyer, Susan Sent: Wednesday, April 15, 2015 9:11 AM To: megan@ppsllc-us.com; Grant, Michele Cc: Blackburn, Lisa Subject: Smolak Farm - walk in Attachments: 201504150832.pdf I am approving the installation of a new walk in cooler at Smolak Farms. Megan,the ice cream stand will open in a couple of weeks and the farm stand after that. I looked back at some of the inspections and also did a walk through.This is the list I came up with at this time. I can add to it if you have some thoughts. Susan I have noted the following items that need addressing before opening this year; Rear loading area -sliding door has gap at bottom where concrete has chipped -floors are filthy in delivery bay; (as this area has not been made into a proper storage area, as discussed there will be no food kept in this area) ( if you wish to make this into a storage room it will need floors, walls and ceilings that comply with the code.) -gaps in various areas between the exterior walk-ins along the wall -Walk-in refrig. Floor is porous as the paint is worn; Old wooden pallets are directly on walk in floor.These absorb water and odors. Please attempt to pry them up and use non porous shelving that is 6 inches above the floor. (as the floor needs painting,this is a good time to remove these) Front and Kitchen -spec sheets for new display cooler -dirty build up under all equipment; (power wash) -curved coving is missing in kitchen area - paint worn on display fixtures;walls etc(must be nonporous) -wall fan louver open; possibly in disrepair 1 Sawyer, Susan From: Sawyer, Susan Sent: Wednesday,April 15, 2015 1:12 PM To: smolakfarms@aol.com Subject: hand wash sink This unit is fine. Susan http://www.sustainablesupply.com/PolvJohn-PSW1-1000-HandStand-Portable-Sink-p/pswl-1OOO.htm Susan Sawyer Public Health Director Town of North Andover 1600 Osgood Street Suite 2035 North Andover,MA 01845 Phone 978.688.9540 Fax 978.688.8476 Email mailto:ssawyer@townofnorthandover.com Web www.TownofNorthAndover.com AC! I 1 PolyJohn PSW1-1000 HandStand Portable Hand Washing Sink, Single Station Page 1 of 2 r Home I My Account I Order Status I Contact Us I About Us ib Sustainable '4111 SUPPLY build.work green Live Chat Coil 888.207.3005 keyword or product# d1 X71; Qa jakoollm ftth Oft 1 ■ ■ . , Building Materials Home>Building Materials>Plumbing>Portable Hand Wash Stations&Hand Senitizer Stands> PolyJohn PSW7-1000 HandStand Portable Hand Washing Sink Adhesives&Sealants Air Filtration Qty: _ Ceiling Tiles Electronic Ballasts p�Y GJARFNnEO �Afea Fans&Ventilators SECURITY O)SECURE _ Contact Us for Floors,Mats,and Supplies <, .�. Oraln ho»Nlaw. - -__ eonv■"Iontwa Special V01ume Or :Q s :..7`•'.^i" ( s Furniture and Furnishings gamk■wwatna. Government Pricing Questions?888.207.3005 Green Cleaning and NO FREE$HBPPING 2013 Janitorial on this item Grounds Maintenance 006 Retailer List Price:$729.00 Heating and Cooling _ $434 00 r AM101+ViG4IJIi1 Hand Dryers ■ High Efficiency Motors Weight(LBS):58 B.Ilt4n wh.;.far Made in:USA Insulation wy m.nauv dib t' --- -- - — Manufacturer:PolyJohn Lamps&Fixtures Mfg Part#:PSW1-1000 LED Lighting +Larger Photo Lockers Availability:Usually Ships in 7 to 9 Business Days s Paints and Coating .R+II Like Shan ------- Product Code:PSW1-1000 Plumbing Rainwater Harvesting Our customers also bought... 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International Shipping Track My Order Hand Dryers for Schools Home Inc.500 on Us Order History Industry Links Privacy&Security About Us Chat Account Tools Blog Legal Statement Press Room Shipping&Returns Shopping Cart Carbon Neutral Product Index Testimonials Help&FAQ Shipping Sitemap Gift Certificate k?A & Quotes Green Product Info Contact Us WaterSense Product Reviews rdR1NrR «1101 i - DMOVER £alcor+ GO., IC 60" , *9110" • FWe Accept: V� - _, � txsa.s 8 AayPa! ® McAfee Rights 7 SECURE * ®2015•Sustainable Supply Company,LLC All Rights Reserved-Bulk with Volusion 11586 Colony Row Broomfield,CO 80021-Phone:303.325.7938 http://www.sustainablesupply.com/PolyJohn-PS W 1-1000-HandStand-Portable-Sink-p/psw... 4/15/2015 • Manager Certification Training ARG Associates, LLC • Food Establishment Inspections Food Safety Services • Employee Training Programs lI Heard Drive • HACCP Plans and Services Ipswich, MA 01938 • Food Service Industry Consulting Plan Review Packai?e To: Brian LaGrasse CC: Sandra Starr From: Allen Gromko Date: Friday,April 25,2003 Establishment Name: Smolak Farms Part One: The Narrative 1. (no plan review package submitted) 2. Letter states floor will be"hosed down completely". If the floor is properly constructed and pitched to the central floor drain,then they may not need to have a mop sink,otherwise they would. j 3. No menu is provided. Can we assume only ice cream?No hot dogs,soda,etc? Part Two: The Drawing 1. Narrative says"Dip sinks, at each sliding window". I assume he means dipper wells with running water at each dipping cabinet. (?) V/ 2. I don't see any shelving for cases of cones,paper supplies,etc. KGs sow s(.elu:�� efiC. 3. The only hand wash sink is located in the far back corner of the room. I would like to see it relocated up front where the employees serving at the windows can easily use it. / A/10u\,\) S-K It f7-,v-t- -nie, l- ta.•.tzr V Part Three: Other questionstobservations 1. Does this operator plan to have soft serve ice NO or yogurt? If yes,do they understand the MA requirements for monthly lab testing and reporting? 2. Has Smolak Farms established an outside eating area with provisions for tables,covered trash receptacles,etc.? d 1'-- 3. Will North Andover require a Certified manager? There is no PHF. .� 4. How will the operator avoid"Bare Hand contact"(with cones)? May want to consider pre- wrapped cones. � 5. These places get buggy in the summer. All windows and doors should be screJned. Black light fly control would be desirable inside. Out side dumpsters and trash containers should be located away from customers.V" 6. I do not have Smolak Farms I my list to inspect. Is the farm stand/bakery OK? 7. When do they plan to open? Smolak Farms } 315 South Bradford Street North Andover, Massachusetts 01845 (978) 682-6332 - Stand IL (978) 687-4029- Tours &Activities (978) 688-8058 - Office www.smolakfarms.com The North Andover Board of Health 27 Charles Street North Andover, MA 01845 June 9, 2003 Dear Brian: In accord with our telephone conversation concerning the report from the consultant, these are the items we will incorporate into the plan: 1)The hand wash sink will be at the front corner of the area to allow quicker access for employees. 2) Since we have a floor drain we do not need a mop sink. 3) There will be covered trash containers outside. 4) There will be screens at the service windows. 5) There will be shelving for storage of supplies and food items. 6)There will be insect control both inside and outside. 7) The menu will consist of ice cream and frozen yogurt, both cones and dishes, frappes, sundaes and possibly snow cones. If you have any other concerns, please let us know of them. Thank you for your consideration. Singe I , H. Michael Smolak Jr. Smolak Farms 315 South Bradford Street North Andover, N` —Ansetts 01845 (978) 682- (978) 687-4029 - (978) 688 — www.sm( 101, April 10 2003 Sandy Starr Board of Health 27 Charles Street North Andover, MA 01845 RE: Ice Cream Stand Dear Sandy: Please find enclosed a plan for the Ice Cream Stand at SmolaK might remember, I started talking with Susan Ford about this quite a while ago as we a. sold ice cream of some sorts in the past. First of all, we are in the process of connecting to the town sewer and expect to be done within a month's time or sooner. The water from the ice cream area will be pumped into the grease trap and then pumped into our system into the sewer. I have enclosed a copy of the equipment that we have planned for thus far and will include anything else you suggest. We will, of course, have a hand wash sink, a triple basin sink, dip sinks at each of the sliding windows and a hot water heater. The refrigeration equipment will consist of a refrigerator, a walk in freezer, two 17 top dip cabinets with room for expansion, along with air conditioning. The floor will drain into a pump chamber and will be able to be hosed down and drained completely. The walls will be impervious panels and the ceiling will be washable as well. I have consulted with Paul Richardson of Richardson's Ice Cream and he has review- ed my plans and added suggestions. We will be using them as our supplier of ice cream and will not be making any ourselves. I have enclosed a check for$60 that your secretary has told me is the fee for reviewing the plan. If you have any questions, please call. Sincerely, v H. Michael Smolak Jr. Ice Cream Stand Needs Iem # Needed Cost Total Cost Site Notes Freezer 2 $2,758.00 $5,516.00 http://www.zesco.com 17 tops - price quoted by Richardson's NEW Frappe Mixer 1 $484.00 $484.00 http://www.sonicboom- 3 Spindles, 3 Speeds, 2 yr. csi.com/warmers.html Warranty NEW Frappe Cups 6 $4.75 $28.50 http://www.servu- NEW onfine.com/subpages/Produc ts.asp?dept=15&cat=204&gr Scoops 8 $12.30 $98.40 www.zesco.com NEW Spades 3 $11.00 $33.00 www.zesco.com NEW Fudge Warmer 1 $154.00 $154.00 http://www.sonicboom- NEW csi.com/warmers.html Topping/Syrup Canister 1 $215.25 $215.25 http://www.servu- NEW online.com/subpages/Produc ts.asp?dept=15&cat=202&gr Whipped Cream Dispenser 2 $62.00 $124.00 www.zesco.com NEW Holds 1 Qt. Napkin Dispensers 3 Walk-In Freezer 1 $1-8,000 www.zesco.com Nicky D Sanitizing Equipment Dip Well & Faucet 1 $78.00 $78.00 http://www.servu- online.com/subpages/Produc ts.asp?dept=15&cat=202&gr Dip Wells $54.00 $108.00 http://www.servu- online.com/subpages/Produc ts.asp?dept=15&cat=202&gr t Construction Costs 1 Michael Hot Water Heater 1 $475.00 $475.00 www.homedepot.com Tankless Gas Water Heater (built to replace 40 Back-Up Generator 1 $4,052.77 $4,052.77 http://www.coloradostandby 7000 Watt Gas Generator .com/catalog/default.php?cP 1 $3,101.27 $3,101.27 5500 Watt Gas Generator Smolak Farms 315 South Bradford Street North Andover, Massachusetts 01845 (508) 688-8058 - Office (508) 682-6332 - Stand April 18, 1996 Susan Ford North Andover Board of Health 146 Main St. North Andover, MA 01845 Dear Susan: As requested, here is a rendering of the set up of our farm stand and bakery operation. Since last year we have not altered the kitchen, walk-in freezer or cooler areas. We have changed the configuration of the sales area of the store, which is reflected in the drawing and list of equipment. The products added since last year are variations of our bakery products plus steamed hot dogs and soups in crock pots. If there are any suggestions you might make, we await hearing from you. Best Regards, P� H. Michael Smolak, Jr. HMS/clb t-U ------- . . . co 0—51------- cr <0 cc LL LL ui • Y <xo . .. ....... 0 z Cl) Ll cr Tt 4--t ............... T id_l 4 f T 'T i Nk 70T, _rT FARM STORE EQUIPMENT INVENTORY 1996 TYPE YR. OF PURCH. MODEL A 1 Apple Peeler-Corer '86 Pease P25 B 1 Ap le Polisher '48 Deck Type C 5 Bakery Racks '88 20 Shelf 0 2 Cash Registers '93 Samsun ER-4900 C- 2 Donut Robots '88 Belshaw F 1 Freezer '86 2 glass Door Upright �. 1 Jet Spray '89 2 Compartment 1 Jet Spray 190 Hot Chocolate X 1 Mixer '86 Hobart A-200 V 10 Muffin Pans '86 2 Dozen r 2 Ovens Blodgett '86 & '88 Convection 1, 2 Ovens Blodgett 196 Regular 1 Refrigerator '86 2 Glass Door Upright rJ 2 Scales 30# '86 & '88 Kubota LA-230 0 30 Sheet Pans '86 Full Size dO 10 Air Pots '95 & '96 (� 1 2 Gal. Bunn Coffee Maker '96 (� 1 3 Burner Coffee Maker 196 1 4 Slice Toaster '96 T 1 Star Hot Dog Steamer '96 0 3 Hamilton Beach Crock Pots (6 Qt.) '96 V 1 Traulsen Revolving Refrigerated Case '96 e H. Michael Smolak, Jr. ti 315 South Bradford Street North Andover, Massachusetts 01845 1P (617) 688-8058 August 11, 1985 Dear Members of The Board of Health, In speaking with Mr. Rimbach and other members of the Board of Health, I would like to let you know what I am doing concerning the farmstand I am constructing. Enclosed is a floorplan of the stance. I have designed the stand to be open from mid-August to Christmas. First, I am going to produce cider in our farmstand building, We haveconstructed the cider area in accord with the design the cider mill producer has given us as well as information given to us by the state. All of our cider will be sold retail at the s*and. The waste water will be simply wash water which will go through floor -to drains to a dry well which is already installed. Earlier in the year I spoke with Mike Graff and I told him I would check with the state about the dry well. I did 9-nd out from my brother John who spoke to DEQEand found there was no approval required. As a matter of convenience for our customers as well as ourselves we are renting a portable toilet. ,Ve also will be producing pies and donuts. The area for this will be smrrounded by nonporous walls, floor and ceiling. Baked products will be covered. I hope this sheds some light on what I am doing. I hope this will be successful for us as well as an asset to the town. Sincerely, .-r� H. Michael Smolak Jr. 57 l j 1 _ ! o UCN i r t 6 4-om-y e, i . t I I i- A r 11 ( � r I I ( I , i y ' ' August 12 , 1985 Mr. Gayton Osgood, Chairman Board of Health No.Andover,Mass . Dear Gayton I will be unable to attend the Monday Meeting because I am on vacation. I have read the material sent to me about the proposed farm stand at Smolak' s . It is my understanding that a food service permit has been applied for and that baked goods will be produced and sold in addition to the making of cider. I am definitely against the use of this stand which in my opinion is a whole new building, until the proper tests have been conducted and septic system has been installed. Ve truly yo , Edward . Scanlon Board ember ' August 12 , 1985 Mr. Gayton Osgood, Chairman Board of Health No.Andover,Mass . Dear Gayton I will be unable to attend the Monday Meeting because I am on vacation. --- I have read the material sent to me about the, proposed farm stand atrSmolak' s . It is my understanding that a food service permit has been applied for and that baked goods will be produced and sold in addition to the making of cider. I am definitely against the use of this stand which in my opinion is a whole i new building, until the proper tests have been . conducted and septic system has been installed. Very truly yours , Edward J. Scanlon Board Member i i s n �a µ 1 4 f ty�r A6 Iva f J RECEIVED JUN 0 2 2008 Smolak Farms LLC Pesticide Compliance Report 315 South Bradford Street TOHE G 1 DL'I 1Unrth Anrinvor MA niRA� tIF_;RLTri i�t:P:. Pesticide License # 19073 The following is a_ report for r 2OnLq Pesticide usea_ na_ on the C:herry Orchard. field number 23 & 24. included are the foiinwinn- 1) Field Plan and map 2) Spray schedules with field name. number, applicator, date of usage, reentry period. EPO registration number_ active innrer_iients brand name_ re entry time rate, total used, weather conditions & target pest Rl MCr)S /material safety data cheetsl Chemicals Used 2008: o0A��� CHATEAU C-O-C-S f"��A 11Ar�VAtIC IMIDAN INDAR PROWL H2 O 7=A! Report prepared by H Michael Smolak Jr 2006 NRCS Smolak Farms LLC Crop Field Plan American Chestnuts: Totals: 23 JTS Field 0.8ac 0.8ac Apples: 1 Bridle Path 8.3ac 17 Heritage Orchard 3.9ac 20 Hilltop Orchard 9.8ac 25 Berry Field 1 .9ac 23.9ac Blueberries: 11 Blueberry Field 2.9ac 2.9ac Q crri .. 5 Cherry Field 0.5ac 23 JTS Field 0.8ac 24 Pond Field 2.8ac 4.2ac Christmas Trees: 2 Second Hill 1.6ac 14 Lilac Field 3.Oac 18 Bog Field 1.8ac 2-5 Purgatory Field 1.4ac 27 Lower Bear Hill 3.6ac 11 .4ac Hayfields/Parking: 15 Main Pond Field 2.7ac 16 Front of House 1.Oac 26 Bear Hill 5.7ac 9.4ac Peaches Nectarines• 4 Newest Peach 1.6ac 7 Peach Orchard 3.4ac 5.Oac Pears: 6 Pear Orchard 0.6ac 0.6ac Pumpkins: 8 Barn Field 0.8ac 9 Greenhouse Field 0.7ac 10 Stand Field 1.6ac 12 Combined Fields 3.8ac 19 Old Peach Field 1.2ac 21 Old Standard 1 .4ac ac 1 s Flat Field 9.8ac 19 3ac _Rs_Qberries Currants Gooseberries• 13 Raspberry Field 1.0ac 1.0ac a flowers• 16 Front of House 0.6ac 0.6ac Strawberries: 3 Front Hill 2.6ac 2.6ac Tomatoes• 8 Barn Field 0.8ac 0.8ac Woodland: 2s Ridge Field 41.2ac 41.2ac "ggin •v^' t�-, r�.��. + t'�'=(. 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Leary 1 73 ^� , 19 �to (978)688-805x3 Farm Number I IF 1 {) II)/1 O(.n tfl)N fl .ua ✓+ �/ (/ �PE-.4��� �•.c� Q-7 g nlfl A•r.Uu. Nd mP .A1..r17.1 y/yr•.n� 1 nn I fl.•tl.r. 1�.1 (-•u{) Nn.ngC. ®1 unrf)C. I 1 7 .rn.f N...nr r � `>.io UI Au•.1 1 - U'.1)A 1 Illy In 4•.v.J�{ .fnrmOUgY Ul:el An.� - - IISUA I 1 //.rf•• I Ir.,rlr•.1 )r.r rl /.fIQ NpfP1 gel pcsl(s), spr. Jt USUa f� r llif 1� p. Srfr. ApplicJ prfs%ur C. galjonagc. wrn(j d w USDA T 11a9 /`�e'N'• ; 3.�y f l� OS{)A 1 US[)A' - ,r.1UQUO e c<ct, C jt C9 x _ I 1 x i x _ +i ! x I 1 I I I x l Smolak Farms LLC H. Michael Smolak Jr. Lic. # 19073 315South Bradford Street John R. Leary 33519 NorthAndover, MA 01845 (978)658-8058 Farm Number > e ) If f T) IU/LOCATION W,OA PCACHAC> 4,F,—? 8 Alllrhc ator Name ,idr>/Uay/YC Tri FPA 1?cy 17(1Str rC tCrf Crop. I Sue of Aro:r Total Anrouot Field Notes target Pest(S). 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Leary 33.519 NorthAndover, MA 0 1845 (978)688-8058 Farm Number C tteap,,e.�v 41 f ft-l() ID/LOCATION W,UA AItI N,c ator NamC ;Mo/!).ty/Yell, EPA Reg I /I !J I Rc•tilnCUtt1 CrU P. 1 Sue of Aw.r lolal ArnouUl Field Notes .argct pesl(s), spr;)y, ;utd (.erhtl(.1Pon IunC I Nullifier AClwe Inrlredrt'niS 1 (]rand N.,,ne } ntr InlCrvat;comm 1 Y odn hale Number � I 1 I 1 Y 1 IrC.rtcd Applied pressure, r3.i llona9C. wind & wCa fRF1) uSOn USDA USDA or Sde - -t - - - USDA ®i �t USOA t SOA I USDA x = x = x = x i X i ' 1 Smolak Farms LLC 315South Bradford Street H. Michael Smolak Jr. Lic. # 19073 NorthAndover, MA 01845 John R. Leary 33519 (978)688-8058 Farm Number f IE l i) IU/LOCA TIONpGAcHs-/ -*Lj-j npphcalor Name .Mu/U.ly/YC7rl EPA Rt,q I /I RCs1r+CICU Cro _ -- i c .- .iwl Certif+cat,on lune ; Nun+hCr 1 I i V Sue of ArC.t Ipl.)I Amount Field Notes target pCSI(S). Spray, Active In(jIV(J �nfS Banal N.,,nr• ! nlr Interval,Conan y 1 Irr.NCd A) hCU r Number + Y i odrt 1?afr• ?p P CSSvrC, q.k IIona9C. wind $ we;, t1;nn uSUn uSOn (AF 1) of Site -- - -._� ®� --USDA i ®� 11SDA W "USDA - ++ } 10011 ' x iLee Vr -11114 x = x = x = x = x = x I t - � x - I I` x ! I ( x x Smolak Farms LLC H. Michael Smolak Jr. Lac. # 19073 315South Bradford Street John R. Leary 33519 NorthAndover, MA 01845 (978)688-8058 Farm Number f IL 1 O IU/LOCA rl.ON uSUA --CD PEA.HA� *.L°4 e/ 7 U Ap;ilK atOr Nam( ,Mu/Oay/yCJri EPA Rcq f?rlllnetr�rf crop. i Sue of Awa Tolal Anrount Field Noles larget pest(s). Sprdye ;rnd (.CrUlrcatron /mit` Nu-iitw, i Aclrve In< rr•d rrv�lS C3r,rnd Ne.n I J c �f nir'y Inlerv.-1Ii cOnNTlOdrty ilai(` I TrCJiCd Appired presswc. gallonage. wind 8 weal Number Srte uSUn ( ®I USDA t/SOA USDA. -USOA ® 'l1SOA "USDA' - - I T- liwyi Olei j i Q I �JVV7 -114 x = t I -- 4)jc,.4-y- x = x = i x = I x = 1 i I x - x x Smotak Farms LLC H_ Michael Smolak Jr. Lic. # 19073 315South Bradford Street John R. Leary 33519 NorthAndover, MA 01845 (978)688-8058 Farm Number Pe Q /5, -t fe, Glut-f,F -e> �4& 3 f Ir1T) IUILOCATION USUn Altt>t,cator Name ,M„/Oay/year EPA (Ie( I - - --- -. - --- ------- - -- 1 I j t�csu+uc,l Crop. j S,n of n,c:, Total An,U,n,t Field Notes target pest(s). Spray( and CCrU I,Catum TunC i Number I Active 111o,vownls i f),amt N.nrne entry Interv.-tt;Commodity Hate Number �, ®i ([IF t) �i o, S,le i„.,tt.(1 i t f ed pressure. 9 Ilon g wind $, e,t A ph 11SDA - 1 USDA�� USOA USOA USDA W -OSOAI SOA' 't -- t -i ' - -- 2 . 1-7 SIM fd4,1 l ,?tz , ca x = 16, x x = t x = - I x = I' x _ j ! x = I � 1 I x x syngenta MATERIAL SAFETY DATA SHEET Syngenta Crop Protection, Inc. In Case of Emergency, Call Post Office Box 18300 1-800-888-8372 Greensboro, NC 27419 1. PRODUCT IDENTIFICATION Product Name: BRAVO WEATHERSTIK Product No.: A12531 B EPA Signal Word: Caution Active Ingredient(%): Chlorothalonil(54.0%) CAS No.: 1897-45-6 Chemical Name: Tetrachloroisophthalonitrile Chemical Class: Chlorinated Benzonitrile Fungicide EPA Registration Number(s): 50534-188-100 Section(s)Revised: 3, 12, 14 2. COMPOSITION/INFORMATION ON INGREDIENTS OSHA ACGIH NTP/IARC/OSHA Material PEL TLV Other Carcinogen Propylene Glycol Not Established Not Established 50 ppm TWA **** No Silica,amorphous 80 mg/m'/%Si02 TWA Not Established 6 mg/ml TWA** IARC 3 Chlorothalonil(54.0%) Not Established Not Established 0.1 mg/m'TWA *** IARC Group 2B ** recommended by NIOSH *** Syngenta Occupational Exposure Limit(OEL) **** Recommended by AIHA(American Industrial Hygiene Association) Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications. Syngenta Hazard Category: C,S 3. HAZARDS IDENTIFICATION Symptoms of Acute Exposure May cause eye,respiratory system and skin irritation. May cause contact dermatitis. May cause sensitization by skin contact. Hazardous Decomposition Products May decompose at high temperatures forming toxic gases. Physical Properties Appearance: Light gray liquid Odor: Slight Unusual Fire,Explosion and Reactivity Hazards During a fire,irritating and possibly toxic gases may be generated by thermal decomposition or combustion. 4. FIRST AID MEASURES Have the product container,label or Material Safety Data Sheet with you when calling Syngenta(800-888-8372),a poison contol center or doctor,or going for treatment. Ingestion: If swallowed: Call Syngenta(800-888-8372),a poison control center or doctor immediately for treatment Product Name: BRAVO WEATHERSTIK Page: 1 advice. Have the person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so after calling 800-888-8372 or by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Eye Contact: If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present,after 5 minutes,then continue rinsing eye.Call Syngenta(800-888-8372),a poison control center or doctor for treatment advice. Skin Contact: If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call Syngenta(800-888-8372),a poison control center or doctor for treatment advice. Inhalation: If inhaled: Move person to fresh air. If person is not breathing,call 911 or an ambulance,then give artificial respiration,preferably mouth-to-mouth if possible. Call Syngenta(800-888-8372),a poison control center or doctor for further treatment advice. Notes to Physician There is no specific antidote if this product is ingested. Treat symptomatically. Persons suffering a temporary allergic reaction may respond to treatment with antihistamines or steroid creams and/or systemic steroids. Medical Condition Likely to be Aggravated by Exposure None known. 5. FIRE FIGHTING MEASURES Fire and Explosion Flash Point(Test Method): Not Applicable Flammable Limits(%in Air): Lower: %Not Applicable Upper: %Not Applicable Autoignition Temperature: Not Applicable Flammability: Not Flammable Unusual Fire,Explosion and Reactivity Hazards During a fire,irritating and possibly toxic gases may be generated by thermal decomposition or combustion. In Case of Fire Use dry chemical,foam or CO2 extinguishing media. Wear full protective clothing and self-contained breathing apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire,smoke,fumes or products of combustion. Prevent use of contaminated buildings,area,and equipment until decontaminated. Water runoff can cause environmental damage. If water is used to fight fire,dike and collect runoff. 6. ACCIDENTAL RELEASE MEASURES In Case of Spill or Leak Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water. Clean up spills immediately, observing precautions outlined in Section 8. Cover entire spill with absorbing material and place into compatible disposal container. Scrub area with hard water detergent(e.g. commercial products such as Tide,Joy,Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal container. Once all material is cleaned up and placed in a disposal container,seal container and arrange for disposition. 7. HANDLING AND STORAGE Store the material in a well-ventilated,secure area out of reach of children and domestic animals.Do not store food,beverages or tobacco products in the storage area.Prevent eating,drinking,tobacco use,and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR THE MANUFACTURE,FORMULATION,PACKAGING AND USE OF THIS PRODUCT. Product Name: BRAVO WEATHERSTIK Page: 2 FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL. Ingestion: Prevent eating,drinking,tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Eye Contact: Where eye contact is likely,use chemical splash goggles.Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Skin Contact: Where contact is likely,wear chemical-resistant(such as nitrile or butyl)gloves,coveralls,socks and chemical-resistant footwear.For overhead exposure,wear chemical-resistant headgear. Inhalation: A respirator is not normally required when handling this substance.Use effective engineering controls to comply with occupational exposure limits. In case of emergency spills,use a NIOSH approved respirator with any N,R,P or HE filter. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Light gray liquid Odor: Slight Melting Point: Not Applicable Boiling Point: 212°F Specific Gravity/Density: 1.34g/ml(water= 1) PH: 6.5-8.5 Solubility in H2O Chlorothalonil: 0.81mg/1 @ 77°F(25°C) Vapor Pressure Chlorothalonil: 5.7 x 10(-7)mmHg @ 77°F(25°C) 10. STABILITY AND REACTIVITY Stability: Stable under normal use and storage conditions. Hazardous Polymerization: Material is not known to polymerize. Conditions to Avoid: None known. Materials to Avoid: None known. Hazardous Decomposition Products: May decompose at high temperatures forming toxic gases. 11. TOXICOLOGICAL INFORMATION Acute Toxicity/Irritation Studies(Finished Product Ingestion: Practically Non-Toxic Oral(LD50 Rat) : 9,000 mg/kg body weight Dermal: Slightly Toxic Dermal(LD50 Rabbit) >2,000 mg/kg body weight Inhalation: Slightly Toxic Inhalation(LC50 Rat) >0.704 mg/I air-4 hours Eye Contact: Moderately Irritating(Rabbit) Skin Contact: Mildly Irritating(Rabbit) Skin Sensitization: A skin sensitizer. Reproductive/Developmental Effects Chlorothalonil: No evidence of adverse developmental effects in rabbit and rat studies. Chronic/Subchronic Toxicity Studies Chlorothalonil: In dogs, 1 years administration caused a significant decrease in body weight gain and increases in absolute liver and kidney weights. Product Name: BRAVO WEATHERSTIK Page: 3 Neurotoxicity: No evidence in regulatory studies. Carcinogenicity Chlorothalonil: No evidence of carcinogenicity in dogs after administration for up to one year. Treament related increases in the incidence of renal tubular adenoma and carcinoma were observed in rats and male mice. Squamous cell adenomas and carcinomas were also observed in the forestomach of both species. The forestomach tumors seen in rodent studies are not relevant to human health,as humans do not possess an anatomical equivalent of the rodent forestomach. The relevance of renal tumors to human health is unclear,although metabolism data suggest that the dog,a species that is resistant to chlorothalonil-induced renal injury,may be more representative of humans than the rat. IARC identifies chlorothalonil as a 213 carcinogen(possibly carcinogenic to humans). Other Toxicity Information Studies on rats and mice have suggested that technical chlorothalonil(97%),when fed at high levels in the diet,may have oncogenic potential to these laboratory animals. However,neither chlorothalonil nor its metabolites interact with DNA and thus are not mutagenic. Tumor formation has been related to a non-genotoxic mechanism of action for which threshold levels have been established in rats and mice. Comprehensive dietary and worker exposure studies have shown exposure levels for humans to be well below these threshold levels. In addition,surveillance of chlorothalonil plant workers for over twenty years has not demonstrated any increase in oncogenic potential to humans. Additional Toxicity Information: May cause irritation of the gastrointestinal tract following ingestion of large amounts. Mildly irritating to skin. Material rarely causes an allergic reaction. May be irritating to the respiratory tract. This is rarely observed. Material is not readily absorbed through intact skin. Toxicity of Other Components Propylene Glycol Reported to cause central nervous system depression(anesthesia,dizziness,confusion),headache and nausea. Also, eye irritation may occur with lacrimation but no residual discomfort or injury. Prolonged contact to skin may cause mild to moderate irritation and possible allergic reactions. Chronic dietary exposure caused kidney and liver injury in experimental animals. Silica,amorphous Dusts in high concentrations may cause skin,eye and respiratory tract irritation. Target Organs Active Ingredients Chlorothalonil: Lung,eye,kidney Inert Ingredients Propylene Glycol: CNS,skin,eye,kidney,liver Silica,amorphous: Skin,eye,respiratory tract 12. ECOLOGICAL INFORMATION Summary of Effects Chlorothalonil Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Eco-Acute Toxicity Chlorothalonil Green Algae 5-day EC50 190 ppb Invertebrates(Water Flea)48-hour EC50 70 ppb Fish(Rainbow Trout)96-hour LC50 47 ppb Fish(Bluegill Sunfish)96-hour LC50 26.3 ppb Product Name: BRAVO WEATHERSTIK Page: 4 . . ...__._..___ - I Birds(8-day dietary-Bobwhite Quail)LC50 5200 ppm Birds(8-day dietary-Mallard Duck)LC50> 10000 ppm Bees 48-hour LD50> 181 ug/bee Eco-Chronic Toxicity Chlorothalonil Bobwhite Quail Reproduction 21-week LOEL 250 ppm Mallard Duck Reproduction 19-week LOEL 100 ppm Fathead Minnow 168-day LOEC 6.5 ppb Environmental Fate Chlorothalonil: The information presented here is for the active ingredient,chlorothalonil. Low bioaccumulation potential. Not persistent in soil or water. Low mobility in soil. Sinks in water(after 24 h). 13. DISPOSAL CONSIDERATIONS Disposal Do not reuse product containers. Dispose of product containers,waste containers,and residues according to local,state,and federal health and environmental regulations. Characteristic Waste: Not Applicable Listed Waste: Not Applicable 14. TRANSPORT INFORMATION DOT Classification Ground Transport-NAFTA Non-Bulk: Not regulated by US DOT. Tank Truck: Proper Shipping Name: Environmentally Hazardous Substance,Liquid,N.O.S.(Chlorothalonil),Marine Pollutant Hazard Class or Division: Class 9 Identification Number: UN 3082 Packing Group: PG III Air Transport-NAFTA Not regulated by US DOT. B/L Freight Classification Fungicides,NOI,O/T Poison Comments Water Transport-International Proper Shipping Name: Environmentally Hazardous Substance,Liquid,N.O.S.(Chlorothalonil),Marine Pollutant Hazard Class or Division: Class 9 Identification Number: UN 3082 Packing Group: PG III IMDG EMS#: F-A, S-F Air Transport-International Proper Shipping Name: Environmentally Hazardous Substance,Liquid,N.O.S.(Chlorothalonil) Hazard Class or Division: Class 9 Identification Number: UN 3082 Packing Group: PG III Note: Max.inner packages 5 liters;Max.single packages 450 liters 15. REGULATORY INFORMATION EPCRA SARA Title III Classification Section 311/312 Hazard Classes: Acute Health Hazard Product Name: BRAVO WEATHERSTIK Page: 5 Chronic Health Hazard Section 313 Toxic Chemicals: Chlorothalonil (54.0%) (CAS No. 1897-45-6) California Proposition 65 Not Applicable CERCLA/SARA 302 Reportable Quantity(RQ) None RCRA Hazardous Waste Classification(40 CFR 261) Not Applicable TSCA Status Exempt from TSCA,subject to FIFRA 16. OTHER INFORMATION NFPA Hazard Ratings HMIS Hazard Ratings 0 Minimal Health: 2 Health: 2 1 Slight Flammability: 1 Flammability: 1 2 Moderate Instability: 0 Reactivity: 0 3 Serious 4 Extreme For non-emergency questions about this product call: 1-800-334-9481 Original Issued Date: 1/8/2001 Revision Date: 1/31/2007 Replaces: 12/2/2004 The information and recommendations contained herein are based upon data believed to be correct. However,no guarantee or warranty of any kind,expressed or implied,is made with respect to the information contained herein. RSVP# : Not Applicable End of MSDS Product Name: BRAVO WEATHERSTIK Page: 6 0 rm-O."Zo- Material Safety Data Sheet CHATEAU® Herbicide WDG This Material Safety Data Sheet (MSDS) serves different purposes than and DOES NOT REPLACE OR MODIFY THE EPA-APPROVED PRODUCT LABELING (attached to and accompanying the product container). This MSDS provides important health, safety, and environmental information for employers, employees, emergency responders and others handling large quantities of the product in activities generally other than product use, while the labeling provides that information specifically for product use in the ordinary course. Use, storage and disposal of pesticide products is regulated by the EPA under the authority of the Federal Insecticide, Fungicide, and Rodenticide Act(FIFRA)through the product labeling. All necessary and appropriate precautionary, use, and storage, and disposal information is set forth on that labeling. It is a violation of federal law to use a pesticide product in any manner not prescribed on the EPA-approved label. 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: CHATEAU® Herbicide WDG VC NUMBER(S): 1420 ITEM: 88608 SYNONYM(S): CHATEAU WDG Herbicide EPA REGISTRATION NUMBER: 59639-119 MANUFACTURER EMERGENCY TELEPHONE NUMBERS VALENT USA CORPORATION HEALTH EMERGENCY OR SPILL(24 hr): P.O. Box 8025 (800)892-0099 1600 Riviera Avenue, Suite 200 TRANSPORTATION (24 hr.): CHEMTREC Walnut Creek, CA 94596-8025 800 424-9300 or 202 483-7616 PRODUCT INFORMATION AGRICULTURAL PRODUCTS: (800)682-5368 PROFESSIONAL PRODUCTS: 800 898-2536 The current MSDS is available through our website or by calling the product information numbers listed above. (wm.valent.com) 2. COMPOSITION/INFORMATION ON INGREDIENTS hemical Name Wei ht1Percent ACGIH Exposure Limits OSHA Exposure Limits Flumioxazin(2-[7-fluoro-3,4-dihydro-3-oxo- 51 None None (2-propynyl)-2H-1,4-benzoxazi n-6-ylj- 5,6,7-tetrahydro-1 H-isoindole-1,3(2H)- ione 103361-09-7 Kaolin clay(1332-58-7) 16 2 mg/m'TWA(respirable fraction) 15 mg/m'TWA 5 m /m'TWA Others**(including particulates not j 32 10 mg/m'TWA(inhalable 15 mg/m'TWA(total dust);5 mg/m' otherwise classified)(No CAS#) particulate);3 mg/m'TWA TWA(respirable fraction) (respirable fraction Emergency Telephone: (800)892-0099 MSDS NO.: 0257 REVISION NUMBER: 2 REVISION DATE: 03/11/2005 CHATEAU® Herbicide WDG Page 2 of 8 Active Ingredient ** Other ingredients, which are maintained as trade secrets, are any substances other than an active ingredient contained in the product. Some of these may be hazardous, but their identity is withheld because they are considered trade secrets. The hazards associated with the other ingredients are addressed in this document. Specific information on other ingredients for the management of exposures, spills, or safety assessments can be obtained by a treating physician or nurse by calling 1-800-892-0099 at any time. 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW CAUTION • Harmful if inhaled or absorbed through skin. • Avoid breathing dust or spray mist. • Avoid contact with eyes, skin and clothing. • Keep out of reach of children. POTENTIAL HEALTH EFFECTS Acute Toxicity(Primary Routes of Exposure) Signs and Symptoms of Systemic Effects: No signs or symptoms occured in animals exposed to high oral or dermal doses of Flumioxazin Technical. Exposure to very high concentrations of Flumioxazin Technical in the air resulted in breathing difficulties, decreased activity and some changes in the tissues of the respiratory system. Acute Eye Contact: Based on an evaluation of the ingredients and/or similar products, this product may cause brief and/or minor eye irritation. The expected adverse health effects resulting from an exposure may include redness and possible swelling. Acute Skin Contact: Based on an evaluation of the ingredients and/or similar products, this product may cause brief and/or minor skin irritation. The expected adverse health effects resulting from an exposure may include redness and possibly some minor swelling. This product may be slightly toxic when absorbed through the skin. This product is not expected to cause allergic skin reactions. Acute Ingestion: Based on an evaluation of the ingredients and/or similar products,this product may be minimally toxic when ingested. Acute Inhalation: Based on an evaluation of the ingredients and/or similar products, this product is expected to be slightly toxic when inhaled. Exposure to high concentrations of dust may result in respiratory irritation. Signs and symptoms may include, but not be limited to, nasal discharge, sore throat, coughing and difficulty in breathing. Chronic Toxicity(including cancer): Repeated exposures to Flumioxazin Technical in animals have produced anemia and other blood formation changes, organ weight changes and changes in blood chemistry. Flumioxazin Technical did not produce cancer in life-time feeding studies in laboratory animals. Developmental Toxicity (birth defects): Birth defects were produced in the offspring of female rats exposed to Flumioxazin Technical. No effects were observed in rabbits. Reproductive Toxicity: Reproductive effects were observed in rats exposed to Flumioxazin Technical. Potentially Aggravated Medical Conditions: Individuals with anemia or preexisting diseases of the blood may have increased susceptibility to the toxicity of excessive exposures. For complete discussion of the toxicology data from which this evaluation was made, refer to Section 11. For Regulatory Information, refer to Section 15. Emergency Telephone: (800)892-0099 MSDS NO.: 0257 REVISION NUMBER: 2 REVISION DATE: 03/11/2005 CHATEAU® Herbicide WDG Page 3 of 8 4. FIRST AID MEASURES EMERGENCY NUMBER(800)892-0099 Have the product container or label with you when calling a poison control center or doctor, or going for treatment. You may also contact 1-800-892-0099 for emergency medical treatment information. EYE CONTACT: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. SKIN CONTACT: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. INGESTION: Call a poison control center or doctor immediately for treatment advice. Have a person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to an unconscious person. INHALATION: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advice. NOTES TO PHYSICIAN: None 5. FIRE FIGHTING MEASURES FLASH POINT: Not applicable AUTOIGNITION: No data available EXTINGUISHING MEDIA: Water fog, carbon dioxide, foam, dry chemical FLAMMABLE LIMITS IN AIR- LOWER(%): Not applicable FLAMMABLE LIMITS IN AIR-UPPER(%): Not applicable NFPA RATING: Health: 1 Flammability: 1 Reactivity: 0 Special: None (Least-0, Slight-1, Moderate-2, High-3, Extreme-4). These values are obtained using professional judgement. Values were not available in the guidelines or published evaluations prepared by the National Fire Protection Association, NFPA. FIRE FIGHTING INSTRUCTIONS: Products of combustion from fires involving this material may be toxic. Avoid breathing smoke and mists. Avoid personnel and equipment contact with fallout and runoff. Minimize the amount of water used for fire fighting. Do not enter any enclosed area without full protective equipment, including self-contained breathing equipment. Contain and isolate runoff and debris for proper disposal. Decontaminate personal protective equipment and fire fighting equipment before reuse. Read the entire document. HAZARDOUS COMBUSTION PRODUCTS: Normal combustion forms carbon dioxide,water vapor and may produce: Oxides of nitrogen. Combustion may produce toxic: Nitrogen compounds. Fluorine compounds. Incomplete combustion can produce carbon monoxide. Emergency Telephone: (800)892-0099 MSDS NO.: 0257 REVISION NUMBER: 2 REVISION DATE: 03/11/2005 i CHATEAU@ Herbicide WDG Page 4 of 8 6. ACCIDENTAL RELEASE MEASURES VALENT EMERGENCY PHONE NUMBER: (800)892-0099 CHEMTREC EMERGENCY PHONE NUMBER: (800)424-9300 OBSERVE PRECAUTIONS IN SECTION 8: PERSONAL PROTECTION Stop the source of the spill if safe to do so. Contain the spill to prevent further contamination of the soil, surface water, or ground water. For additional spill response information refer to the North American Emergency Response Guidebook. FOR SPILLS ON LAND: CONTAINMENT: Reduce airborne dust. Avoid runoff into storm sewers or other bodies of water. CLEANUP: Clean up spill immediately. Vacuum or sweep up material and place in a chemical waste container. Wash area with soap and water. Pick up wash liquid with additional absorbent and place in a chemical waste container. FOR SPILLS IN WATER: CONTAINMENT: This material will disperse or dissolve in water. Stop the source of the release. Contain and isolate to prevent further release into soil, surface water and ground water. CLEANUP: Clean up spill immediately.Absorb spill with inert material. Remove contaminated water for treatment or disposal. 7. HANDLING AND STORAGE END USER MUST READ AND OBSERVE ALL PRECAUTIONS ON PRODUCT LABEL. Keep pesticide in original container. Do not store or transport near food or feed. Do not contaminate food or feed. Do not put concentrate into food or drink containers. Do not dilute concentrate in food or drink containers. Store in a cool, dry place, out of direct sunlight. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION END USER MUST READ AND OBSERVE ALL PRECAUTIONS ON PRODUCT LABEL. EYES: Do not get this material in your eyes. Eye contact can be avoided by wearing protective eyewear. RESPIRATORY PROTECTION: Use this material only in well ventilated areas. Unless ventilation is adequate to keep airborne concentrations below recommended exposure standards, approved respiratory protection should be worn. SKIN PROTECTION: Avoid contact with skin or clothing. Skin contact should be minimized by wearing protective clothing including gloves. EXPOSURE LIMITS -See Section 2. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Granule COLOR: Light brown ODOR: Slight MELTING POINT: Not applicable BULK DENSITY: 0.49 g/cc(30.8 Ib./cu. ft.) VAPOR PRESSURE: Not applicable pH: 5.4 @ 25°C (11% suspension) CORROSION CHARACTERISTICS: Not corrosive to containers. Emergency Telephone: (800)892-0099 MSDS NO.: 0257 REVISION NUMBER: 2 REVISION DATE: 03/11/2005 CHATEAU® Herbicide WDG Page 5 of s SOLUBILITY: Dispersible in water 10. STABILITY AND REACTIVITY CHEMICAL STABILITY: This material is considered chemically and thermally stable. INCOMPATABILITY: May react with strong oxidizing agents, such as chlorates, nitrates, peroxides, etc. OXIDATION/REDUCTION PROPERTIES: Not an oxidizing or reducing agent. EXPLODABILITY: Not expected to be explosive. HAZARDOUS DECOMPOSITION PRODUCTS: No data available 11. TOXICOLOGICAL INFORMATION ACUTE (Product Specific Information): Eye Irritation: No product specific data available. Based on an evaluation of the ingredients and/or similar products, this product may cause brief and/or minor eye irritation. (Toxicity Category III) Skin Irritation: Based on an evaluation of the ingredients and/or similar products, this product may cause brief and/or minor skin irritation. (Toxicity Category IV) Oral Toxicity: No product specific data available. The oral LD50 in rats for a similar product is> 5,000 mg/kg. (Toxicity Category IV) Dermal Toxicity: No product specific data available. The dermal LD5o in rabbits for a similar product is>2000 mg/kg (Toxicity Category III) Inhalation Toxicity: No product specific data available. No rats died in a 4-hour inhalation study with a similar product at the maximum attainable concentration of 0.969 mg/l. (Toxicity Category III) Exposure to very high concentrations in the air resulted in breathing difficulties, decreased activity and some changes in the tissues of the respiratory system. Skin Sensitization: Based on an evaluation of the ingredients and/or similar products, this product is not expected to cause allergic skin reactions. TOXICITY OF FLUMIOXAZIN TECHNICAL SUBCHRONIC: Compound related effects of Flumioxazin Technical noted in rats following subchronic exposures at high dose levels were hematotoxicity including anemia, and increases in liver, spleen, heart, kidney and thyroid weights. In dogs, the effects produced at high dose levels included a slight prolongation in activated partial thromboplastin time, increased cholesterol and phospholipid, elevated alkaline phosphatase, increased liver weights and histological changes in the liver. The lowest no-observable-effect-level (NOEL) in subchronic studies was 30 ppm in the three-month toxicity study in rats. CHRONIC/CARCINOGENICITY: In a one year dog feeding study, Flumioxazin Technical produced treatment-related changes in blood chemistry and increased liver weights at 100 and 1000 mg/kg/day. Minimal treatment-related histological changes were noted in the livers of animals in the 1000 mg/kg/day group. Based on these data the NOEL is 10 mg/kg/day. Dietary administration of Flumioxazin Technical for 18 months produced liver changes in mice of the 3000 and 7000 ppm groups. There was no evidence of any treatment-related oncogenic effect. The NOEL for this study is 300 ppm. Dietary administration of Flumioxazin Technical for 24 months produced anemia and chronic nephropathy in rats of the 500 and 1000 ppm groups. The anemia lasted throughout the treatment period, however, it was not progressive nor aplastic in nature. No evidence of an oncogenic effect was observed. The NOEL for this study is 50 ppm. Emergency Telephone: (800)892-0099 MSDS NO.: 0257 REVISION NUMBER: 2 REVISION DATE: 03/11/2005 CHATEAU® Herbicide WDG Page s of 8 DEVELOPMENTAL TOXICITY: Flumioxazin Technical produces developmental toxicity in rats in the absence of maternal toxicity at doses of 30 mg/kg/day by the oral route and 300 mg/kg/day by the dermal route. The developmental effects noted consisted primarily of decreased number of live fetuses and fetal weights, cardiovascular abnormalities, wavy ribs and decreased number of ossified sacrococcygeal vertebral bodies. The developmental NOEL in the rat oral and dermal developmental toxicity studies were 10 and 100 mg/kg/day, respectively. The response in rabbits was very different from that in rats. No developmental toxicity was noted in rabbits at doses up to 3000 mg/kg/day, a dose well above the maternal NOEL of 1000 mg/kg/day. REPRODUCTION: Reproductive toxicity was observed in F1 males, P1 females and F1 females at 300 ppm Flumioxazin Technical, the highest dose tested and a dose that also produced signs of systemic toxicity. Toxicity was also observed in the F1 and F2 offspring at doses of 200 ppm and greater. MUTAGENICITY: Flumioxazin Technical was not mutagenic in most in vitro assays: gene mutation and a chromosome aberration assay in the absence of metabolic activation. In three in vivo assays, chromosome aberration, unscheduled DNA synthesis and micronucleus assay, Flumioxazin Technical was not mutagenic. The only positive response was observed in the in vitro chromosome aberration assay in the presence of metabolic activation. Overall, Flumioxazin Technical does not present a genetic hazard. For a summary of the potential for adverse health effects from exposure to this product, refer to Section 3. For information regarding regulations pertaining to this product, refer to Section 15. 12. ECOLOGICAL INFORMATION AVIAN TOXICITY: Flumioxazin Technical is practically non-toxic to avian species. The following results were obtained from studies with Flumioxazin Technical: Oral LD5o bobwhite quail: greater than 2250 mg/kg; Dietary LC5o bobwhite quail: greater than 5620 ppm; Dietary LC5o mallard duck: greater than 5620 ppm. No reproductive effects were observed in bobwhite quail exposed to 500 ppm Flumioxazin Technical in the diet. In mallard ducks, a slight, but not statistically significant reduction in hatchlings and 14-day old survivors was observed. Based on a possible, slight effect on egg production at 500 ppm, the NOEL for this study was 250 ppm. AQUATIC ORGANISM TOXICITY:Flumioxazin Technical is slightly to moderately toxic to freshwater fish; moderately toxic to freshwater invertebrates; moderately toxic to estuarine/marine fish and moderately to highly toxic estuarine/marine invertebrates, based on the following tests: 96-hour LC5o rainbow trout: 2.3 mg/I; 96-hour LC5o bluegill sunfish: greater than 21 mg/I; 48-hour LC5o Daphnia magna: 5.5 mg/I; 96-hour LC50sheepshead minnow: greater than 4.7 mg/I; 96-hour(shell deposition) EC5oeastern oyster: 2.8 mg/I; 96-hour LC50mysid shrimp: 0.23 mg/I; Fish early life-stage(rainbow trout): MATC>7.7 pg/I, <16 pg/I; Chronic toxicity(mysid shrimp): MATC >15 pg/I, <27 pg/I; Chronic toxicity(Daphnia magna): MATC >52 pg/I, <99 pg/I. OTHER NON-TARGET ORGANISM TOXICITY: Flumioxazin Technical is practically non-toxic to bees. The acute contact LC50 in bees was greater than 105 pg/bee. Emergency Telephone: (800)892-0099 MSDS NO.: 0257 REVISION NUMBER: 2 REVISION DATE: 03/11/2005 CHATEAU® Herbicide WDG Page 7 of 8 13. DISPOSAL CONSIDERATIONS END USERS MUST DISPOSE OF ANY UNUSED PRODUCT AS PER THE LABEL RECOMMENDATIONS. DISPOSAL METHODS: Check government regulations and local authorities for approved disposal of this material. Dispose in accordance with applicable laws and regulations. 14. TRANSPORT INFORMATION DOT(ground)SHIPPING NAME: Compounds,weed killing, dry, non-regulated DOT TECHNICAL SHIPPING NAME: Flumioxazin 51% Solid DOT REPORTABLE QUANTITY(RQ): None UN/NA NUMBER: Not applicable HAZARD CLASS: Not applicable REMARKS: None EXEMPTION REQUIREMENT: None 15. REGULATORY INFORMATION REGULATIONS UNDER FIFRA: All pesticides are governed under FIFRA(Federal Insecticide, Fungicide, and Rodenticide Act). Therefore, the regulations presented below are pertinent only when handled outside of the normal use and applications of pesticides. This includes waste streams resulting from manufacturing/formulation facilities, spills or misuse of products, and storage of large quantities of products containing hazardous or extremely hazardous substances. OTHER U.S. FEDERAL REGULATIONS: CWA Section 311: No data Chemical Name SARA 313 Chemicals SARA Section 302 CERCLA Reportable Quantity RQ Flumioxazin(2-[7-fluoro-3,4-dihydro- Not listed Not listed None oxo-4-(2-propynyl)-2H-1,4- benzoxazin-6-yl]-4,5,6,7-tetrahydro- 1 H-isoindole-1,3(2H)-dione) 103361-09-7 Kaolin clay 1332-58-7 Not listed Not listed None Others"(including particulates not Not listed Not listed None otherwise classified)(No CAS# SARA (311, 312): Immediate Health: Yes Chronic Health: Yes Fire: No Sudden Pressure: No Reactivity: No STATE REGULATIONS: Each state may promulgate standards more stringent than the federal government. This section cannot encompass an inclusive list of all state regulations. Therefore, the user should consult state or local authorities. The state regulations reviewed include: California Proposition 65, California Directors List of Hazardous Substances, Massachusetts Right to Know, Michigan Critical Materials List, New Jersey Right to Know, Pennsylvania Right to Know, Rhode Island Right to Know and the Minnesota Hazardous Substance list. For Washington State Right to Know, see Section 2 for Exposure Limit information. For Louisiana Right to Know refer to SARA information listed under U.S. Regulations above. Emergency Telephone: (800)892-0099 MSDS NO.: 0257 REVISION NUMBER: 2 REVISION DATE: 03/11/2005 CHATEAU@ Herbicide WDG Page 8 of 8 Chemical NameMI-Critical Materials List MA Fight To Know NJ Ri ht To Know Kaolin clay 1332-58-7 Present Chemical Name PA Right To Know RI Right To Know MN Hazardous Substance Kaolin clay(1332-58-7) Present Toxic Present(includes inert or nuisance dust California Proposition 65: Not listed CANADIAN REGULATIONS: WHMIS Hazard Class: Not determined For information regarding potential adverse health effects from exposure to this product, refer to Sections 3 and 11. 16. OTHER INFORMATION REASON FOR ISSUE: Product uses a kaolin clay without silica quartz or titanium dioxide. MSDS updated to exclude these ingredients. MSDS NO.: 0257 REVISION NUMBER: 2 REVISION DATE: 03/11/2005 SUPERCEDES DATE: 09/14/2004 THE INFORMATION IN THIS MSDS IS BASED ON DATA AVAILABLE TO US AS OF THE REVISION DATE GIVEN HEREIN, AND BELIEVED TO BE CORRECT. CONTACT VALENT USA CORPORATON TO CONFIRM IF YOU HAVE THE MOST CURRENT MSDS. JUDGEMENTS AS TO THE SUITABILITY OF INFORMATION HEREIN FOR THE INDIVIDUAL'S OWN USE OR PURPOSES ARE NECESSARILY THE INDIVIDUAL'S OWN RESPONSIBILITY.ALTHOUGH REASONABLE CARE HAS BEEN TAKEN IN THE PREPARATION OF SUCH INFORMATION, VALENT EXTENDS NO WARRANTIES, MAKES NO REPRESENTATIONS, AND ASSUMES NO RESPONSIBILITY AS TO THE ACCURACY OR SUITABILITY OF SUCH INFORMATION FOR APPLICATION TO THE INDIVIDUAL'S PURPOSES OR THE CONSEQUENCES OF ITS USE. Emergency Telephone: (800)892-0099 MSDS NO.: 0257 REVISION NUMBER: 2 REVISION DATE: 03/11/2005 P MATERIAL SAFETY DATA SHEET C-O-C-S®WDG FOR CHEMICAL EMERGENCY,SPILL,LEAK,FIRE,EXPOSURE OR ACCIDENT,CALL CHEMTREC-DAY OR NIGHT 1-800-424-9300 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION FORMULATED FOR: LOVELAND PRODUCTS,INC. 24-Hour Emergency Phone: 1-800-424-9300 P.O.Box 1286-Greeley,CO 80632-1286 Medical Emergencies: 1-800-301-7976 U.S..Coast Guard National Response Center:1-800424-8802 PRODUCT NAME: IC=O-C-S®WDG CHEMICAL NAME: Copper,in the form of Copper Oxychloride Sulfate CHEMICAL FAMILY: Fungicide EPA REG.NO.: 34704-326 MSDS Number: 000326-07-LPI MSDS Revisions: Sections 1 and 16 Date of Issue: 09/14/07 Supersedes: 07/07/04 2. HAZARDS IDENTIFICATION SUMMARY KEEP OUT OF REACH OF CHILDREN—WARNING-AVISO—Si usted no entiende la etiqueta,busque a alguien para que se la explique a usted en detaile (If you do not understand the label, find someone to explain it to you in detail.) Causes substantial but temporary eye injury. Harmful if swallowed,inhaled,or absorbed through skin.Do not get in eyes,on skin,or on clothing.Avoid breathing dust(vapor or spray mist).Prolonged or frequently repeated skin contact may cause allergic reaction in some individuals. This product is grayish blue-green granular powder with virtually no odor. 3. COMPOSITION,INFORMATION ON INGREDIENTS Chemical Ingredients: Percentage by Weight: CAS No. TLV(Units) Copper Oxychloride* 74.80 1332-65-6 and not listed Basic Copper Sulfate* 14.20 1344-73-6 not listed Inert Ingredients 11.00 4. FIRST AID MEASURES If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes.Remove contact lenses,if present,after the first 5 minutes,then continue rinsing eye.Call a poison control center or doctor for treatment advice. If swallowed: Call a poison control center or doctor immediately for treatment advice.Have a person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor.Do not give anything by mouth to an unconscious person. If on skin or clothing: Take off contaminated clothing.Rinse skin immediately with plenty of water for 15-20 minutes.Call a poison control center or doctor for treatment advices. If inhaled: Move person to fresh air. If person is not breathing,call 911 or an ambulance,then give artificial respiration,preferably mouth-to-mouth,if possible.Call a poison control center or doctor for further treatment advice. FOR A MEDICAL EMERGENCY INVOLVING THIS PRODUCT CALL:1-800-301-7976.Have the product container or label with you when calling a poison control center or doctor,or going for treatment. S. FIRE FIGHTING MEASURES FLASH POINT(°F/Test Method): Not applicable FLAMMABLE LIMITS(LEL&UEL): Not applicable EXTINGUISHING MEDIA: Use medium appropriate to surrounding fire.Dry chemical,carbon dioxide,foam,water spray or fog. HAZARDOUS COMBUSTION PRODUCTS: Oxides of sulfur,oxides of copper,hydrogen chloride,chlorine-containing compounds,and other unknown hazardous material may be formed in a fire situation. SPECIAL FIRE FIGHTING PROCEDURES: If water is used to fight fire or cool containers,contain run-off by diking to prevent contamination of water supplies.Avoid breathing smoke.Wear self-contained breathing apparatus and full protective gear. UNUSUAL FIRE AND EXPLOSION HAZARDS: Dusts may form explosive mixtures with air;avoid using heavy water streams. b. AGGIDENIALRELEA MEASURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Avoid breathing dusts. If liquid, dike and absorb with sand, cat litter or commercial absorbent and transfer to an approved chemical container. If dry material, cover to prevent dispersal. Sweep up dry spills and transfer to an approved chemical container.Wash the spill area with water containing a strong detergent, absorb with cat litter or other absorbent material, sweep up and place in a chemical container. Flush the area with water to remove any residue.Check local,state and federal regulations for proper disposal. CAUTION: Keep spills and cleaning runoff out of municipal sewers and open bodies of water. 7. HANDLING AND STORAGE HANDLING: Wash hands before eating,drinking,chewing gum,using tobacco or using the toilet.Remove clothing immediately if pesticide gets inside.Then wash thoroughly and put on clean clothing.Remove PPE after handling this product.Wash the outside of gloves before removing.As soon as possible,wash thoroughly and change into clean clothing. STORAGE: Keep out of reach of children and animals.Store in original containers only.Store in a cool,dry place and avoid excessive heat.Carefully open containers.After partial use,fold and roll bags,clamp and close tightly.Do not contaminate other pesticides,fertilizers,water,food or feed by storage or disposal. PAGE 1 OF 3 MATERIAL SAFETY DATA SHEET C-0-C-SO WDG 8. EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: When handlers use closed systems,enclosed cabs,or aircraft in a manner that meets with requirements listed in the Worker Protection Standard(WPS)for agricultural pesticides[40CFR 170.240(d)(4-6)],the handler PPE requirements may be reduced or modified as specified in the WPS. RESPIRATORY PROTECTION: Not normally required.If vapors or dusts exceed acceptable levels,wear a NIOSH approved pesticide respirator. EYE PROTECTION: Chemical goggles or shielded safety glasses. SKIN PROTECTION: Wear protective clothing:long-sleeved shirts and pants,hat,rubber boots with socks. Wear rubber or chemical- resistant gloves. OSHA PEL 8 hr TWA ACGIH TLV-TWA Nuisance Particulates 15 mg/m3(total dust) not established Personal Protective Equipment:Applicators and other handlers must wear:long-sleeved shirt and long pants,chemical-resistant gloves,shoes plus socks,and protective eyewear.Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product's concentrate.Do not reuse them.Follow manufacturer's instructions for cleaning and maintaining PPE. If no such instructions for washables,use detergent and hot water.Keep and wash PPE separately from other laundry. 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE AND ODOR: Grayish blue-green granular powder with virtually no odor. SOLUBILITY: Disperses with minimal agitation SPECIFIC GRAVITY(Water=1): 0.48-0.64 g/ml BULK DENSITY: 30-40 lbs/ft3 pH: Not applicable VAPOR PRESSURE: Not applicable BOILING POINT: Not applicable PERCENT VOLATILE(by volume): Not applicable EVAPORATION RATE: Not applicable Note: These physical data are typical values based on material tested but may vary from sample to sample. Typical values should not be construed as a guaranteed analysis of any specific lot or as specification items. 10. STABILITY AND HF:ACTIVIIY STABILITY: Stable CONDITIONS TO AVOID: Excessive heat. INCOMPATIBILITY: Strong oxidizers and acids. HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of sulfur,oxides of copper,hydrogen chloride,chlorine-containing compounds,and other unknown hazardous material may be formed in a fire situation. HAZARDOUS POLYMERIZATION:Will not occur. 11. TOXICOLOGICAL INFORMATION Acute Oral LDso(rat):1131 mg/kg Acute Dermal LD6o(rabbit): >2000 mg/kg Eye Irritation(rabbit): Causes substantial but temporary eye injury. Skin Irritation(rabbit): Causes mild irritation Inhalation LCSo(rat)): 1.29 mg/L(4 HR) Skin Sensitization(guinea pig):Not established. Carcinogenic Potential: None listed in OSHA,NTP,IARC or ACGIH 12. F-(;ULQGI(;AL INFORMATION This product is toxic to fish and aquatic organisms.For terrestrial uses,do not apply directly to water,or to areas where surface water is present or to intertidal areas below the mean high water mark. Drift and runoff from treated areas may be hazardous to fish and aquatic organisms in adjacent aquatic sites.Do not allow rinsate from cleaning of equipment or disposed material to enter surface or ground water. 13. DISPOSAL CONSIDERATIONS Do not reuse empty bag.Completely empty bag into application equipment.Then dispose of empty bag in a sanitary landfill or by incineration,or,if allowed by State and local authorities,by burning. If burned,stay out of smoke.Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. 14. TRANSPORT INFORMATION DOT Shipping Description: NOT REGULATED BY USDOT. U.S.Surface Freight Classification:INSECTICIDES OR FUNGICIDES,INSECT OR ANIMAL REPELLENTS;NOI;OTHER THAN POISON(NMFC 102120;CLASS:60) 15. REGULATORY INFORMATION NFPA&HMIS Hazard Ratings: NFPA HMIS 2 Health 0 Least 2 Health 0 Flammability 1 Slight 0 Flammability 0 Instability 2 Moderate 0 Reactivity 3 High H PPE 4 Severe PAGE 2 OF 3 s MATERIAL SAFETY DATA SHEET C-0-C-SO WDG SARA Title III Hazard Category: Immediate Y Fire N Sudden Release of Pressure N Delayed N Reactive N Reportable Quantity(RQ)under U.S.CERCLA: Not listed SARA,Title 111,Section 313: Copper Compounds 50%(CAS:1332-65-6 and.1344-73-6) RCRA Waste Code: Not listed CA Proposition 65: Not listed 16. OTHER INFORMATION MSDS STATUS: Sections 1 and 16 revised PREPARED BY: Registrations and Regulatory Affairs REVIEWED BY: Environmental/Regulatory Services ®C-0-C-S is a registered trademark of Loveland Products,Inc. `Metallic Copper Equivalent: 50.0% Product of Mexico Disclaimer and Limitation of Liability: This data sheet was developed from information on the constituent materials identified herein and does not relate to the use of such materials in combination with any other material or process. No warranty is expressed or implied with respect to the completeness or ongoing accuracy of the information contained in this data sheet,and LOVELAND PRODUCTS,Inc.disclaims all liability for reliance on such.information. This data sheet is not a guarantee of safety. Users are responsible for ensuring that they have all current information necessary to safely use the product described by this data sheet for their specific purpose. PAGE 3OF3 Page 1 of 1GRAMOXONE_EXT-R_A11_ ZENECA, INC. 1800 Concord Pike Wilmington, DE 19897 Phone (24 hr.) Technical: (302) 886-3000Medical: (800) 327-8633Chemtrec: (800) 424-9300 Reference No: 3967 Issue Date: 11/16/95 Rev. : D --------------------------------------------------------------------------- SECTION 1 NAME & HAZARD SUMMARY --------------------------------------------------------------------------- Material name: GRAMOXONE(R) EXTRA Hazard summary (as defined by OSHA Hazard Comm. Std., 29 CFR 1910.1200) : Physical hazards: None Health hazards: Corrosive (skin), irritant (eye, respiratory passages) , inhalation (TLV) , toxic (oral) Read the entire MSDS for a more thorough evaluation of the hazards. --------------------------------------------------------------------------- ***SECTION 2 INGREDIENTS --------------------------------------------------------------------------- OSHA PEL -------------------------------------------- ------------------------------ Paraquat dichloride (CAS 1910-42-5) 37 0.5 mg/m^3, resp. fract., skin Emetic 0.05 Not listed Inert ingredients 63 Not listed -------------------------------------------- ------------------------------ Ingredients not precisely identified are proprietary or nonhazardous. Values are not product specifications. --------------------------------------------------------------------------- SECTION 3 PHYSICAL DATA --------------------------------------------------------------------------- Appearance and odor: Blue-green liquid with strong, pungent odor from an added stenching agent. Boiling point: 212F, 100C (due to water) Vapor pressure (mm Hg at 25C) : 23.7 (due to water), paraquat has negligible vapor pressure. Vapor density (air = 1) : No data Solubility in water: Very soluble pH: 5 (5% solution) Specific gravity: 1.12 % Volatile by volume: 61.0 --------------------------------------------------------------------------- SECTION 4 FIRE AND EXPLOSION HAZARD DATA --------------------------------------------------------------------------- ***Flash point: Does not flash Autoignition temperature: >625C Flammable limits (STP) : No data Extinguishing media: Not applicable. Use media suitable for surroundin fire. Minimize use of water to avoid environmental contamination. Special fire fighting protective equipment: Self-contained breathing apparatus with full facepiece and protective clothing if involved in a fire of other materials. Unusual fire and explosion hazards: Possible toxic smoke, vapors, fallout and runoff water can result from fires depending on extent of combustion and presence of other combustible materials. Contaminated buildings, areas, and equipment must be properly decontaminated before reuse. --------------------------------------------------------------------------- SECTION 5 REACTIVITY DATA --------------------------------------------------------------------------- Stability: Decomposes at 300C. Stable for four (4) years at 25C in http://www.autorain.com/N4SDS_Sheets/570.txt 12/30/' Page 2 o) polyethylene. Incompatibility: Corrosive to most metals, e.g. iron, zinc, aluminum and causes stress cracking in some plastics. Hydrolyzes in alkaline media. This product reacts with aluminum to produce hydrogen gas. Do not mix or store in containers or systems made of aluminum or having aluminum fittings. Hazardous decomposition products: Combustion products of dry material: Carbon dioxide, carbon monoxide, chlorine, hydrogen chloride, possible trace amounts of phosgene, nitrogen oxides, ammonia, and other toxic and noxious fumes. Hazardous polymerization: Does not occur. --------------------------------------------------------------------------- SECTION 6 HEALTH HAZARD ASSESSMENT --------------------------------------------------------------------------- General: The health hazard assessment is based on the results of animal toxicity testing and reports of accidental human exposures. Ingestion: The acute oral toxicity of a 43.5% formulation of paraquat dichloride is 265 mg/kg for male rats and 175 mg/kg for female rats expressed as paraquat dichloride. An emetic is included in the formulation to induce vomiting. Signs and symptoms following ingestion include burning sensations, ulcerations of the mouth, tongue, pharynx and esophagus; vomiting, retching, and diarrhea may then ensue. A 1 to 3 week period of progressive kidney failure, liver complications, and pulmonary insufficiency may follow. Death is usually due to respiratory failure secondary to pulmonary fibrosis. Eye contact: Severe acute inflammatory changes may be the result of eye contact, reaching maximum effect in 12 to 24 hours. Surfactants tend to potentiate effects that develop after eye contact; the effects represent chemical burns. Although the eye injury may appear to be extensive, a slow but complete recovery usually occurs. Skin contact: Repeated and/or prolonged skin contact with the concentrated product can cause skin damage, including erythema, edema, and ulceration. Repeated and/or prolonged skin contact with the spray dilution may cause mild skin irritation. Contact of concentrated paraquat solutions with finger and toe nails may result in cracking and shedding; normal regrowth follows. Skin absorption: The intact skin is an effective barrier to paraquat. Paraquat penetrates intact human skin very slowly at a rate of less that 0.5% in 24 hours. Penetration is faster through injured or damaged skin. Prolonged contact with the concentrate can damage skin and lead to poisoning. Lung, kidney and liver injuries can ensue, followed by renal an pulmonary insufficiency. Death ensues after respiratory failure. The dermal toxicity in rabbit following a 24-hour skin exposure to a 43.5% formulation of paraquat dichloride is 83.9 mg/kg expressed as paraquat dichloride. A single application of this product is considered "moderately toxic" by skin absorption. Inhalation: Paraquat is not volatile; therefore, exposure to paraquat vapor is not applicable. The odor of this product is not paraquat; it is an added odorant intended to deter ingestion of the product. Prolonged inhalation or overexposure to aerosolized paraquat can cause irritation of the upper respiratory tract mucosa, as evidenced by a burning sensation, nose bleeds, and sore throat. These symptoms remit on cessation of exposure. Systemic toxicity is unlikely to develop following inhalation because typical spray droplets are not likely to be of respirable size. Effects of overexposure: The greatest hazards of paraquat exposure exist when the concentrated product (i.e. undiluted) is swallowed or allowed to remain in contact with the skin for a prolonged period. These circumstances can result in systemic poisoning which is severe, progressive, and frequently terminates in irreversible lung damage and death. The concentrated product can cause adverse local effects on eyes, skin, and nails. These problems are not normally seen with spray dilutions. Excessive exposure to spray mist can cause upper respiratory tract irritation. First aid procedures: CALL ZENECA'S EMERGENCY INFORMATION NETWORK AT 1-800-F-A-S-T-M-E-D (327-8633) . If a known exposure occurs or poisoning http://www.autorain.com/MSDS_Sheets/570.txt 12/30/ Page 3 o) is suspected, do not wait for symptoms to develop. Immediately start the recommended procedures below and simultaneously contact a Poison Control Center, a physician or the nearest hospital. IMMEDIATE TREATMENT IS ESSENTIAL. Skin: Remove contaminated clothing and footwear. Wash skin thoroughly with plenty of soap and water. Get medical attention. Eyes: Immediately wash eyes with plenty of water for at least 15 minutes. Get medical attention. Ingestion: Give one or more glasses of water to drink and induce vomiting by sticking finger down throat. Repeat until vomit is clear. GET IMMEDIATE MEDICAL ATTENTION. If bentonite, activated charcoal or fuller's earth is available, administer it until it appears in the stool. Inhalation: Spray mists may be caught in the upper respiratory tract and cause irritation and, potentially, nose bleeds. Treat symptomatically. Move victim to fresh air or get away from spray mist and get immediate medical attention. The odor of this product is not paraquat; it is an added odorant intended to deter ingestion of this product. Note to Physician: There is no effective antidote for oral paraquat poisoning. Prompt treatment is essential following ingestion. Paraquat is inactivated by its tight bonding to clay. Absorption can be reduced by administering adsorbents such as bentonite, activated charcoal or fuller's earth. A cathartic should also be given. Do not administer oxygen; oxygen potentiates the toxicity of paraquat. In selected cases of paraquat poisoning, hemoperfusion and hemodialysis may be considered. For further questions on medical treatment, call the Zeneca Emergency Information Network at 1-800-F-A-S-T-M-E-D (327-8633) . --------------------------------------------------------------------------- SECTION 7 SPILL OR LEAK PROCEDURES --------------------------------------------------------------------------- Steps to be taken in case material is released or spilled: Wear ey protection, protective clothing and respiratory protection during cleanup. Mix with a generous amount of clay or clay-containing soil and shovel into waste container. Untreated spilled material can dry to a highly irritating dust. For chemical emergency: spill, leak, fire, exposure or accident call CHEMTREC 1-800-424-9300. Disposal method: Do not contaminate waterways, streams or ponds when cleaning equipment or disposing of waste. Although paraquat is not a RCRA hazardous waste, it is recommended that the waste be disposed of in a facility permitted for hazardous waste. Container disposal: Empty container retains product residue. Triple rinse, or equivalent, empty container, return rinse water to dilution mixture, and dispose of dilution mixture as a hazardous waste. Do not reuse container. Offer it for recycling or reconditioning, or puncture and dispose of in properly permitted landfil. --------------------------------------------------------------------------- SECTION 8 SPEOIAL PROTECTION INFORMATION --------------------------------------------------------------------------- TLV(R) or suggested control value: Paraquat dichloride: The ACGIH TLV is 0.1 mg/m^3 (respirable fraction) , 0.5 mg/m^3 (total dust) as an 8-hour time weighted average. The OSHA PEL is 0.5 mg/m^3 (respirable fraction) as an 8-hour time-weighted average with a skin notation. Zeneca Inc. operates its facilities so that exposures to paraquat dichloride total dust do not exceed 0.5 mg/m^3 8-hour TWA, or 0.1 mg/m^3 respirable dust. Emetic: Zeneca Inc. operates its facilities so that exposure to the emetic does not exceed 0.02 mg/m^3. Ventilation: This product is intended for use outdoors where engineering controls are not necessary. If use conditions are different (e.g. product reformulation or repackaging) , use ventilation adequate to maintain safe levels. Respiratory protection (specify type) : For mixing, loading, or applying material, use a dust/mist filtering respirator (MSHA/NIOSH approval number prefix TC-21C) . http://www.autorain.com/MSDS_Sheets/570.txt 12/30/ Page 4 o+. ***Protective clothing: This product is FIFRA regulated. Refer to product labeling for required end-user personal protection equipment. Prevent skin contact. Applicators must wear coveralls or long-sleeved shirt and long pants, waterproof gloves, chemical-resistant footwear plus socks, protective eyewear, chemical-resistant headgear for overhead exposure, chemical-resistant apron when cleaning equipment, mixing, or loading, dust/mist filtering respirator (MSHA/NIOSH approval number prefix TC-21C) . Mixer and loaders of concentrate should wear coveralls over long-sleeved shirt and long pants, waterproof gloves, chemical resistant foot wear plus socks, chemical resistent headgear and chemical resistant apron. Remove any contaminated clothing promptly. Zeneca Inc.-conducted ASTM permeation tests using PVC gloves (0.2 mm thickness) and showed no breakthrough of the product after eight hours of testing. Eye protection: Protective eyewear. Other protective equipment: Eyewash station and safety shower near work area. -------------------------------------------------------------------------- SECTION 9 SPECIAL PRECAUTIONS OR OTHER COMMENTS --------------------------------------------------------------------------- Precautions to be taken in handling or storing: Store above 32F in original well-marked containers away from feed or food. Material is toxic to wildlife. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans, or public waters unless this product is specifically identified and addressed in a National Pollutant Discharge Elimination System (NPDES) permit. Users should wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing. Do not enter treated areas without protective clothing for 12 to 48 hours depending on use pattern. See label. Paraquat binds readily to clay and soil which contains clay to become biologically inactive. In this bond form, leaching of paraquat does not occur. For emergency information on spills, leaks and fires involving GRAMOXONE(R) Extra, call (800) 424-9300 Chemical Transportation Emergency Center (CHEMTREC) . --------------------------------------------------------------------------- SECTION 10 REGULATORY INFORMATION --------------------------------------------------------------------------- TSCA (Toxic Substances Control Act) Regulations, 40 CFR 710: This product is a FIFRA-regulated pesticide and is exempt from TSCA regulations. CERCLA and SARA Regulations (40 CFR 355, 370, and 372) : Section 313 Supplier Notification. This product contains the following toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372: Paraquat dichloride (CAS 1910-42-5) . The Threshold Planning Quantity (TPQ) under EPCRA SARA (Section 302) for Paraquat dichloride is 10 lbs. EPA Registration No. : 10182-00280 Other Information: We assigned NFPA and HMIS ratings to this product based on the hazards of its ingredient(s) . Because the customer is most aware of the application of the product, he must ensure that the proper personal protective equipment (PPE) is provided consistent with information contained in the product MSDS.* NFPA HMIS 3 Health 3 Health 0 Flammability 0 Flammability 1 Reactivity 1 Reactivity Special Hazards PPE^l *This information is intended solely for the use of individuals trained in the particular hazard rating system. ^lSee appropriate MSDS section. The information herein is given in good faith but no warranty, expressed or http://www.autorain.com/MSDS_Sheets/570.txt 12/30/' Page 5 of implied, is made. ***This line or section contains revisions or new statements since the last issue date. http://www.autorain.com/N4SDS_Sheets/570.txt 12/30/' V O' GONA.van, MATERIAL SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTIFICATION Formulator: Gowan Company Emergency Phone: (928)783-3803 P.O. Box 5569 For 24-Hour Emergency Yuma, Arizona 85366-5569 Assistance(Spill, Leak, Fire,or (928) 783-8844 Exposure), Call CHEMTREC®: Inside the U.S.: (800)424-9300 Outside the U.S.: (703) 527-3887 For MEDICAL Emergency: (888)478-0798 Product: flmidan 70-W -)' EPA Signal Word: Warning EPA Registration.No.: 10163-169 Active Ingredient: Phosmet(70.0%) CAS No.: 732-11-6 Chemical Name: N-(Mercaptomethyl)phthalimide, S-(O,0-dimethyl phosphorodithioate) Chemical Class: Organophosphorous Pesticide 2. HAZARDS IDENTIFICATION Physical Properties Appearance: Tan powder Odor: Mercaptan odor Symptoms of Acute Exposure The active ingredient is an organophosphate, which, produces cholinesterase inhibition in experimental animals. Symptoms of cholinesterase inhibition include salivation, sweating, headache, nausea, muscle twitching, tremors, incoordination, blurred vision, tears, abdominal cramps, diarrhea, and chest discomfort. Exposure to high concentrations of dust may result in symptoms related to cholinesterase inhibition. Medical Conditions Likely to be Aggravated by Exposure No specific medical conditions are known which may be aggravated by exposure to the active ingredient in this product; however, any disease, medication, or prior exposure which reduces normal cholinesterase activity may increase susceptibility to the toxic effects of the active ingredient. Primary Routes of Exposure Harmful if ingested, inhaled, absorbed into skin or if it comes into contact with the eyes. Hazardous Decomposition Products Combustion products; toxic materials Unusual Fire, Explosion, and Reactivity Hazards Not defined as flammable or combustible. However, under fire conditions, the product may support combustion and decompose to give off toxic materials. 3. COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT NAME OSHA—PEL ACGIH—TLV OTHER NTP/IARC/OSHA CARCINOGEN Phosmet(70.0%) None None Not established No Only the identities of the active ingredient(s)and any hazardous inert ingredients are listed. Specific information on all of this product's ingredients can be obtained by the treating medical professional or spill emergency responder for the management of exposures, spills, or safety assessments. Product Name: Imidan 70-W Page 1 of 5 Revision Date: 2/22/2007 " 4. FIRST AID MEASURES If poisoning is suspected, immediately contact a physician, the nearest hospital, or the nearest Poison Control Center. Tell the person contacted the complete product name, and the type and amount of exposure. Describe any symptoms and follow the advice given. Ingestion: Immediately give several glasses of water and induce vomiting by gagging the victim with a finger placed on the back of the victim's tongue. Give fluids until vomit is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth. Inhalation: Remove to fresh air. If not breathing, clear victim's airway and start mouth-to-mouth artificial respiration. If breathing is difficult, give oxygen, preferably with a physician's assistance. Eye Contact: Immediately flush eyes with plenty of water. Get medical attention if irritation persists. Skin Contact: Flush all affected areas with plenty of water for several minutes. Seek medical attention if skin irritation occurs. Note to Physician May cause cholinesterase depression. Atropine sulfate is antidotal. 2-PAM is also antidotal and may be administered in conjunction with atropine. Administer atropine sulfate in large therapeutic doses. Repeat as necessary to the point of tolerance. Compound inhibits cholinesterase, resulting in stimulation of the central nervous system, the parasympathetic nervous system and the somatic motor nerves. Do not give morphine. Watch for pulmonary edema, which may develop in serious cases of poisoning even after 24-48 hours. At first sign of pulmonary edema, the patient should be placed in an oxygen tent and treated symptomatically. FOR MEDICAL EMERGENCIES INVOLVING THIS PRODUCT,CALL TOLL FREE: (888)478-0798 5. FIRE FIGHTING MEASURES Flashpoint(test method): Not applicable Flammable Limits(% in air): Not applicable Autoignition Temperature: Not available Appropriate Extinguishing Media Use water spray, CO2, and dry chemical. Fire Fighting Guidance The active ingredient in this formulation is a cholinesterase inhibitor. Refer to Section 4 — First Aid Measures for additional information regarding overexposure. Products of combustion are irritating to the respiratory tract and may cause breathing difficulty and pulmonary edema. Symptoms may be delayed several hours or longer depending upon the extent of exposure. As in any fire, prevent human exposure to fire, smoke, fumes, or products of combustion. Evacuate nonessential personnel from the fire area. Fire fighters should wear full face self-contained breathing apparatus and impervious protective clothing. Use standard fire fighting techniques to extinguish fires involving this material - use water spray, dry chemicals, or carbon dioxide. Use of high pressure water hose may spread product from broken containers increasing contamination hazard. Contaminated buildings, areas, and equipment must not be used until they are properly decontaminated. Unusual Fire, Explosion, and Reactivity Hazards Not defined as flammable or combustible. However, under fire conditions, the product may support combustion and decompose to give off toxic materials. 6. ACCIDENTAL RELEASE MEASURES In Case of Spills or Leaks Small spills can be handled routinely. Any person entering either a significant spill area, an area with inadequate ventilation, or an area with an unknown concentration of a gas, vapor, or dust should use an air-supplied respirator to prevent inhalation exposure. Wear protective clothing and eye protection to prevent skin and eye contact. Sweep up spilled material, being careful not to create dust. Place sweepings in an open drum. Generously cover the contaminated area with a common, powdered household detergent. Using a stiff brush and small amounts of water, work the detergent into the spill material forming a slurry. Do not splatter on one's self or bystanders, and completely avoid skin or eye contact with this material. Brush the slurry into cracks and crevices and allow to stand for 2-3 minutes. Spread a suitable absorbent such as clay, sawdust, or kitty litter on the slurried liquid. Shovel absorbed material into an open drum. Repeat if necessary. Flush area with water while observing proper environmental considerations. Seal drum and dispose of contaminated material in an approved pesticide landfill. Large spills must be handled according to a predetermined plan. For assistance in developing a plan, contact Gowan Company. Product Name: Imidan 70-W Page 2 of 5 Revision Date: 2/22/2007 7. HANDLING AND STORAGE May be harmful if swallowed, inhaled or absorbed through the skin. Avoid breathing spray mist. Avoid contact with skin, eyes, or clothing. Do not contaminate water, food or feed by storage or disposal. Store in the original container and keep closed. Store containers in a cool, dry place. Precautions in Storing DO NOT contaminate water, food or feed by storage or disposal. Storage Store in a cool, dry place and in such a manner as to prevent cross contamination with other pesticides, fertilizers, food and feed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Control This product is intended for use outdoors where engineering controls are not necessary. If use conditions are different(e.g. product reformulation or repackaging), employee exposure should be minimized using traditional techniques such as enclosed system design and/or local exhaust ventilation. Eye/Face Protective eyewear is not required; however to avoid eye contact with the material choose protective eyewear appropriate to exposure potential. Skin Protection Applicators and other handlers must wear long-sleeved shirt and long pants, waterproof gloves, shoes plus socks, and chemical-resistant headgear for overhead exposure. Respiratory Protection Use a dust/mist filtering respirator. Additional Protection Information Have eyewash and safety shower easily accessible to the work area. Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product's concentrate. Do not reuse them. Follow manufacturer's instructions for cleaning/maintaining personal protective equipment (PPE). If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry. Applicators/Handlers Applicators and other handlers must wear long-sleeved shirt and long pants, waterproof gloves, shoes plus socks, and chemical-resistant headgear for overhead exposure. User Safety Recommendations: Users should wash hands before eating, drinking, chewing gum, using tobacco, or using the toilet. Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Tan powder Odor: Odorless Melting Point: Not applicable Boiling Point: Not applicable Specific Gravity/ Density: 15 lbs./ft' Solubility in H2O Phosmet Not applicable Vapor Pressure Phosmet Not applicable Product Name: Imidan 70-W Page 3 of 5 Revision Date: 2/22/2007 10. STABILITY AND REACTIVITY Stability: Stable under normal storage conditions Hazardous Polymerization: Will not occur Decomposition Products: Combustion products; toxic materials. Hazardous Mixtures: Relatively non-reactive. Non-corrosive to materials commonly used in the construction of process equipment, storage, and shipping containers Conditions To Avoid: Excessive heat. 11. TOXICOLOGICAL INFORMATION Acute Toxicity/Irritation Studies Ingestion: Acute Oral LD50(rat): 275 mg/kg (male), 258 mg/kg (female) body weight Dermal: Acute Dermal LD50(rabbit): >2000 mg/kg (sexes combined) Inhalation: Acute Inhalation LC50(rat): >1.6 mg/L(sexes combined)4 hours Skin Sensitizer: Not a skin sensitizer Carcinogenic Potential None 12. ECOLOGICAL INFORMATION Summary of Effects Phosmet This pesticide is toxic to fish and wildlife. For terrestrial uses, do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water by cleaning of equipment or disposal of wastes. Drift and runoff from treated areas may be hazardous to aquatic organisms in adjacent aquatic sites. This product is toxic to bees exposed to direct treatment. Do not apply this product while bees are actively visiting the treatment area. 13. DISPOSAL CONSIDERATION Pesticide Disposal Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. Container Disposal Completely empty bag into application equipment. Then dispose of empty bag in a sanitary landfill, or by incineration, or if allowed by State and local authorities, by burning. If burned, stay out of smoke. 14. TRANSPORT INFORMATION DOT Classification UN 3077, Environmentally Hazardous Substance, Solid, N.O.S., (Phosmet), 9, PG III International Maritime Organization UN 3077, Environmentally Hazardous Substance, Solid, N.O.S., (Phosmet), 9, PG III, Marine Pollutant International Civil Aviation Organization UN 3077, Environmentally Hazardous Substance, Solid, N.O.S., (Phosmet), 9, PG III Product Name: Imidan 70-W Page 4 of 5 Revision Date: 2/22/2007 15. REGULATORY INFORMATION SARA Title III Classification Section 302/304: Not applicable Section 311/312: Immediate (acute) health hazard Section 313 chemical(s): Not applicable Extremely Hazardous Substance (EHS) Not applicable Proposition 65 Not applicable RCRA Classification If discarded in its purchased form, this product would not be a hazardous waste either by listing or by characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste. 16. OTHER INFORMATION NFPA Hazard Ratings Health: 2 0 Least Flammability: 0 1 Slight Reactivity: 0 2 Moderate 3 High 4 Severe Notice:The information and recommendations contained herein are provided in good faith and are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information herein. Prepared By: Gowan Company (928) 783-8844 Imidan is a registered trademark of Gowan Company,L.L.C. Product Name: Imidan 70-W Page 5 of 5 Revision Date: 2/22/2007 MATERIAL SAFETY DATA SHEET Emergency Phone: 800-992-5994 ���MDow AgroSciences LLC Dow AgroSciences Indianapolis, IN 46268 Effective Date: 10/16/03 EINDAR* 75WSP FUNGICIDE Product Code: 88797 MSDS: 007717 1. PRODUCT AND COMPANY IDENTIFICATION: INHALATION: Dust may cause irritation of the upper respiratory tract(nose and throat) and lungs. The aerosol PRODUCT: Indar*75WSP Fungicide LC50 for rats is>4.40 mg/L for 4 hours. COMPANY IDENTIFICATION: SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: For Dow AgroSciences fenbuconazole, in animals, effects have been reported on 9330 Zionsville Road the following organs: liver and blood. Indianapolis, IN 46268-1189 2. COMPOSITION/INFORMATION ON INGREDIENTS: CANCER INFORMATION: For fenbuconazole, available data are inadequate to evaluate carcinogenicity. Crystalline Fenbuconazole: CAS# 114369-43-6 75% silica has been shown to cause cancer in laboratory alpha-[2-(4-chlorophenyl) animals and humans. This mixture contains crystalline ethyl]-alpha-phenyl-1 H- silica,which is listed as a carcinogen for hazard 1,2,4-triazole-1-propanenitrile communication purposes under OSHA Standard 29 CFR Other Ingredients, Total, Including 25% Part 1910.1200. Crystalline silica is listed by IARC and Clay (Contains CAS#001332-58-7 NTP. Crystalline silica CAS#014808-60-7) TERATOLOGY (BIRTH DEFECTS): Fenbuconazole did This document is prepared pursuant to the OSHA Hazard not cause birth defects in laboratory animals. Has been Communication Standard (29 CFR 1910.1200). In addition, toxic to the fetus in laboratory animals only at doses toxic other substances not'Hazardous' per this OSHA Standard to the mother. may be listed. Where proprietary ingredient shows, the identity may be made available as provided in this REPRODUCTIVE EFFECTS: For fenbuconazole, in animal standard. studies, has been shown to interfere with reproduction in 3. HAZARDOUS IDENTIFICATIONS: females. 4. FIRST AID: EMERGENCY OVERVIEW Hazardous chemical. Off-white powdered solid with a EYE: Flush eyes thoroughly with water for several minutes. musty odor. Dust may irritate eyes. LD50 for skin Remove contact lenses after initial 1-2 minutes and continue flushing for several additional minutes. If effects absorption is >2000 mg/kg. Oral LD50 is 4000 mg/kg. Aerosol LC50 is >4.40 mg/L for 4 hours. occur, consult a physician, preferably an ophthalmologist. EMERGENCY PHONE NUMBER: 800-992-5994 POTENTIAL HEALTH EFFECTS: This section includes SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a possible adverse effects, which could occur if this material poison control center or doctor for treatment advice. is not handled in the recommended manner. INGESTION: Call a poison control center or doctor EYE: Essentially non-irritating to eyes. Dust may irritate immediately for treatment advice. Have person sip a glass eyes. of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. Never SKIN: Brief contact may cause slight skin irritation with give anything by mouth to an unconscious person. local redness. Did not cause allergic skin reactions when tested in guinea pigs. Prolonged skin contact is unlikely to INHALATION: Move person to fresh air; if effects occur, result in absorption of harmful amounts. The LD50 for skin consult a physician. absorption in rats is>2000 mg/kg. NOTE TO PHYSICIAN: No specific antidote. Treatment of INGESTION: Low toxicity if swallowed. Small amounts exposure should be directed at the control of symptoms swallowed incidental to normal handling operations are not and the clinical condition of the patient. likely to cause injury; however, swallowing larger amounts may cause injury. The oral LD50 for rats is 4000 mg/kg. . 'Trademark of Dow AgroSciences 1 F_ MATERIAL SAFETY DATA SHEET Emergency Phone: 800-992-5994 f§0. � Dow AgroSciences LLC Dow AgroSciences Indianapolis, IN 46268 Effective Date: 10/16/03 INDAR* 75WSP FUNGICIDE Product Code: 88797 MSDS: 007717 5. FIRE FIGHTING MEASURES: 7. HANDLING AND STORAGE: FLASH POINT: Not applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND METHOD USED: Not applicable STORAGE: FLAMMABILITY LIMITS HANDLING: Do not handle material near food, feed or UFL: Not applicable drinking water. Avoid high concentrations of dust in air and LFL: Not applicable accumulation of dust on equipment. An airborne dust of this material can create a dust explosion. When handling and EXTINGUISHING MEDIA: When product is involved in a processing this material local exhaust ventilation may be fire use carbon dioxide, dry chemical, water spray or foam. required to control dust and reduce exposure to vapors. To prevent-dust explosions employ bonding and grounding for FIRE & EXPLOSION HAZARDS: Pesticide particulates operations capable of generating static electricity. Protect can become airborne. Dusts at sufficient concentrations all equipment from explosions by following the guidelines in can form explosive mixtures with air. Combustion NFPA-68 and NFPA-69. For electrical equipment follow generates toxic fumes of the following: nitrogen oxides, local codes and electrical classification NFPA-70 (The sulfur oxides and hydrogen chloride. National Electrical Code), class II, division 2, group G. FIRE-FIGHTING EQUIPMENT: Remain upwind. Avoid STORAGE: Store in well-ventilated area. Store in a dry breathing smoke. Use water spray to cool containers area. Store out of direct sunlight in a cool place. Do not exposed to fire. Contain run-off. Wear self-contained store this material near food, feed or drinking water. The breathing apparatus(pressure-demand MSHA/NIOSH maximum recommended storage temperature for this approved or equivalent) and full protective gear. material is 131°F (550C). Keep container tightly closed when not in use. 6. ACCIDENTAL RELEASE MEASURES: ACTION TO TAKE FOR SPILLS/LEAKS: Keep spectators OTHER: Completely empty bag into application equipment. away. Avoid breathing dust. Sweep up small spills and Dispose empty bag in a sanitary landfill as allowed by state transfer material to suitable container for recovery or and local authorities. disposal. Keep dust to a minimum. Keep spills and cleaning 18. EXPOSURE CONTROLS/PERSONAL PROTECTION: run-off out of municipal sewers and open bodies of water. Report large spills to Dow AgroSciences at 800-992-5994. These precautions are.suggested for conditions where the If exposed to material during clean-up operations, remove potential for exposure exists. Emergency conditions may all contaminated clothing promptly. Wash all exposed skin require additional precautions. areas with soap and water immediately after exposure. Thoroughly launder clothing before reuse. Do not take EXPOSURE GUIDELINE: clothing home to be laundered. Fenbuconazole: Dow AgroSciences Industrial Hygiene Guide is 1 mg/M3 TWA and 3 mg/M3 STEL. Clay: The ACGIH TLV is 2 mg/M3 respirable, A4; The OSHA PEL is 15 mg/M3 total dust and 5 mg/M3 respirable fraction. Silica, crystalline: ACGIH TLV is 0.1 mg/M3(respirable)for tripoli and fused silica, 0.05 mg/M3 (respirable)for cristobalite, tridymite, and quartz. Quartz has an A2 designation. OSHA PEL is(30 mg/M3)/(%SiO2+2)total dust, (250 mppcf)/(%SiO2+5) or(10 mg/M3)/(%SiO2+2) respirable for quartz, tripoli, and fused silica; the value for cristobalite and tridymite is 1/2 the value calculated from the respirable dust formula for quartz. 'Trademark of Dow AgroSciences MATERIAL SAFETY DATA SHEET Emergency Phone: 800-992-5994 f&'T,,DowAgroSciences Dow AgroSciences LLC Indianapolis, IN 46268 Effective Date: 10/16/03 INDAR* 75WSP FUNGICIDE Product Code: 88797 MSDS: 007717 ENGINEERING CONTROLS: Provide general and/or local HAZARDOUS DECOMPOSITION PRODUCTS: Thermal exhaust ventilation to control airborne levels below the decomposition may yield the following: hydrogen chloride. exposure guidelines. HAZARDOUS POLYMERIZATION: Not known to occur. RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING,AND PACKAGING 11. TOXICOLOGICAL INFORMATION: WORKERS: MUTAGENICITY: For fenbuconazole, in-vitro and animal genetic toxicity studies were negative. EYE/FACE PROTECTION: Use safety glasses. If there is a potential for exposure to particles, which could cause eye 12. ECOLOGICAL INFORMATION: discomfort, wear chemical goggles. ENVIRONMENTAL FATE: SKIN PROTECTION: Use gloves chemically resistant to this material. MOVEMENT& PARTITIONING: No relevant information found. RESPIRATORY: Atmospheric levels should be maintained below the exposure guideline. If respiratory irritation is DEGRADATION &PERSISTENCE: experienced, use a NIOSH approved air-purifying No relevant information found. respirator. For dusty atmospheres, use a NIOSH approved particulate respirator. ECOTOXICOLOGY: Based on information for fenbuconazole. APPLICATORS AND ALL OTHER HANDLERS: Refer to Acute oral LC50 in honeybee (Apis mellifera) is >292 pg/L. the product label for personal protective clothing and Acute oral LD50 in bobwhite quail (Colinus virginianus)and equipment. is>2150 mg/kg. Acute LC50 in rainbow trout(Salmo gairdnen) is 1.5 mg/L. 9. PHYSICAL AND CHEMICAL PROPERTIES: Acute immobilization EC50 in water flea (Daphnia magna) is COLOR: Off-white >2.2 mg/L. STATE: Powdered Solid Dietary LC50 in bobwhite quail (Colinus virginianus) is >4050 ppm. ODOR: Musty Dietary LC50 in mallard duck(Anas platyrhvnchos) is>2110 VISCOSITY: Not applicable ppm SPECIFIC GRAVITY(WATER= 1): 0.24 g/cc Bulk density Growth inhibition EC50 in algae (Selenastrum subsaicatus) VAPOR DENSITY(AIR= 1): Not applicable is 0.29 mg/L. VAPOR PRESSURE: Not applicable Acute LC50 in blue gill (Lepomis macrochirus) is 0.68 mg/L. MELTING POINT: Not determined Growth inhibition EC50 in green alga(Selenastrum BOILING POINT: Not applicable capricornutum) is 0.47 mg/L. SOLUBILITY IN WATER: Dispersible PERCENT VOLATILITY: 0% 13. DISPOSAL CONSIDERATIONS: EVAPORATION RATE (BAc= 1): Not applicable DISPOSAL METHOD: Do not contaminate food, feed, or pH: 7.6 Aqueous suspension water by storage or disposal. Wastes are toxic. Improper 10. STABILITY AND REACTIVITY: disposal of excess waste, spray mixture, or rinsate is a violation of federal law. Spray mixture or rinse water that STABILITY: (CONDITIONS TO AVOID) Stable under cannot be used according to label instructions must be normal storage conditions. Avoid contact with ignition disposed of in accordance with applicable local, state or sources (e.g. sparks, open flame, or heated surfaces). federal requirements. Contact your state pesticide or environmental control agency, or the hazardous waste INCOMPATIBILITY: (SPECIFIC MATERIALS TO AVOID) representative at the nearest EPA regional office for Avoid contact with the following: oxidizing agents and guidance. acids. *Trademark of Dow AgroSciences MATERIAL SAFETY DATA SHEET Emergency Phone: 800-992-5994 Dow AgroSciences LLC �TMDow AgroSciences Indianapolis, IN 46268 Effective Date: 10/16/03 INDAR* 75WSP FUNGICIDE Product Code: 88797 MSDS: 007717 14. TRANSPORT INFORMATION: STATE RIGHT-TO-KNOW: The following product components are cited on certain state lists as mentioned. U.S. DEPARTMENT OF TRANSPORTATION (DOT) Non-listed components may be shown in the composition INFORMATION: section of the MSDS. This material is not regulated for transportation. CHEMICAL NAME CAS NUMBER LIST 15. REGULATORY INFORMATION: Crystalline Silica 014808-60-7 NJ3 PA1 NOTICE: The information herein is presented in good faith NJ3=New Jersey Workplace Hazardous Substance and believed to be accurate as of the effective date shown (present at greater than or equal to 1.0%). above. However, no warranty, express or implied, is given. PAI=Pennsylvania Hazardous Substance(present at Regulatory requirements are subject to change and may greater than or equal to 1.0%). differ from one location to another; it is the buyer's responsibility to ensure that its activities comply with OSHA HAZARD COMMUNICATION STANDARD: This federal, state or provincial, and local laws. The following product is a"Hazardous Chemical" as defined by the OSHA specific information is made for the purpose of complying Hazard Communication Standard, 29 CFR 1910.1200. with numerous federal, state or provincial, and local laws and regulations. NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) RATINGS: U.S. REGULATIONS Health 1 Flammability 1 SARA 313 INFORMATION: To the best of our knowledge, Reactivity 0 this product contains no chemical subject to SARA Title III Section 313 supplier notification requirements. COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND LIABILITY ACT (CERCLA, or SARA HAZARD CATEGORY: This product has been SUPERFUND): To the best of our knowledge, this product reviewed according to the EPA"Hazard Categories" contains no chemical subject to reporting under CERCLA. promulgated under Sections 311 and 312 of the Superfund 16. OTHER INFORMATION: Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet MSDS STATUS: Moved to DAS Format the following categories: Reference: DR-0378-7222 Replaces MSDS Dated: 6/1/01 A delayed health hazard Document Code: D03-845-002 CALIFORNIA PROPOSITION 65: The following statement Replaces Document Code: D03-845-001 is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of 1986: This product contains a chemical(s) known to the State of California to cause cancer. The chemical is crystalline silica (CAS#014808-60-7). TOXIC SUBSTANCES CONTROL ACT(TSCA): All ingredients are on the TSCA inventory or are not required to be listed on the TSCA inventory. The Information Herein Is Given In Good Faith, But No Warranty, Express or Implied, Is Made. Consult Dow AgroSciences for Further Information. *Trademark of Dow AgroSciences 4 V f MATERIAL SAFETY DATA SHEET LI 700® FOR CHEMICAL EMERGENCY,SPILL,LEAK,FIRE,EXPOSURE OR ACCIDENT, CALL CHEMTREC-DAY OR NIGHT 1-800-424-9300 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION FORMULATED FOR: LOVELAND PRODUCTS,INC. 24-Hour Emergency Phone: 1-800-424-9300 P.O.Box 1286•Greeley,CO 80632-1286 Medical Emergencies: 1-800-301-7976 U.S.Coast Guard National Response Center:1-800-424-8802 PRODUCT NAME: C LI 7000 CHEMICAL NAME: Blend of Methylacetic Acid,processed Lecithin and surfactant CHEMICAL FAMILY: Surfactant CALIF.REG.NO.: 34704-50035 WASH.REG.NO.: 34704-04007 MSDS Number:L17-06b-LPI MSDS Revisions: Section 4 Date Of Issue: 12/14/06 Supersedes: 06/05/06 2. HAZARDS IDENTIFICATION SUMMARY KEEP OUT OF REACH OF CHILDREN-DANGER.LIQUID CAUSES SKIN AND EYE INJURY.Wear eye protection and chemical resistant gloves. This product is a dark brown liquid with pungent odor.Primary routes of entry are Inhalation,eye contact and skin contact. 3. COMPOSITION,INFORMATION ON-INGREDIENTS Chemical Ingredients: Percentage by Weight: CAS No. TLV(Units) Methylacetic Acid,and 34.70 79-09-4 30 mg/m' Phosphatidycholine,Alkyl Polyoxyethylene Ether 45.30 Inert Ingredients 20.00 This product is hazardous according to the OSHA Hazard Communication Standard(29 CFR 1910.1200) 4. FIRST AID MEASURES If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes.Remove contact lenses,if present,after the first 5 minutes,then continue rinsing eye.Call a poison control center or doctor for treatment advice. If on skin or clothing: Take off contaminated clothing.Rinse skin immediately with plenty of water for 15 to 20 minutes.Call a poison control center or doctor for further treatment advice. If swallowed: Call a poison control center or doctor immediately for treatment advice.Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor.Do not give anything by mouth to an unconscious person. If inhaled: Move person to fresh air.If person is not breathing,call 911 or an ambulance,then give artificial respiration.Call a poison control center or doctor for treatment advice. 5. FIRE FIGHTING MEASURES FLASH POINT(°F/Test Method): >212°F(100°C)/TCC FLAMMABLE LIMITS(LFL&UFL): Not established EXTINGUISHING MEDIA: Considered non-combustible;dry chemical,carbon dioxide,alcohol foam,foam,water spray or fog. HAZARDOUS COMBUSTION PRODUCTS: May produce hazardous by-products. SPECIAL FIRE FIGHTING PROCEDURES: Use water spray to cool containers exposed to fire.Remain upwind.Avoid breathing smoke.Wear self- contained breathing apparatus and full protective gear.Avoid using heavy streams of water. UNUSUAL FIRE AND EXPLOSION HAZARDS: None known. 6. ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Release or Spill:Wear chemical safety glasses with side shields or chemical goggles,rubber gloves, rubber boots,long-sleeved shirt,long pants, head covering,and a NIOSH-approved pesticide respirator or air-supplied respirator. For spills:Spills may be collected with absorbent material and placed in a container for proper disposal in accordance with Federal,State and Local Regulations.Prevent runoff from entering sewer drains and waterways. 7. HANDLING AND STORAGE HANDLING: Avoid eye and skin contact.Use with ventilation and avoid breathing vapors. STORAGE: Store above 40°F/4.40C.Store in a cool,dry place.Store in original container.Keep container tightly closed.Do not contaminate water,food or feed by storage or disposal. PAGE 1 OF 3 ,r MATERIAL SAFETY DATA SHEET LI 700® 8. EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Local ventilation recommended.Work in well-ventilated area or outdoors. RESPIRATORY PROTECTION: Wear a NIOSH approved respirator if necessary or if vapors exceed TLV(threshold limit value). EYE PROTECTION: Chemical goggles or shielded safety glasses. SKIN PROTECTION: Wear protective clothing:long-sleeved shirts and pants,hat,rubber boots with socks. Wear rubber or chemical- resistant gloves. OSHA PEL 8 hr TWA ACGIH TLV-TWA Propionic Acid not listed 30 mg/m' 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE AND ODOR: Dark brown liquid with pungent odor. SOLUBILITY: Miscible SPECIFIC GRAVITY(Water=1): 1.035 g/ml BULK DENSITY: 8.64 lbs/gallon pH:3.6(1%solution) VAPOR PRESSURE: not established BOILING POINT: not established PERCENT VOLATILE(by volume): not established EVAPORATION RATE: not established Note: These physical data are typical values based on material tested but may vary from sample to sample. Typical values should not be construed as a guaranteed analysis of any specific lot or as specification items. 1U. STABILITY AND REACTIVITY STABILITY: Stable CONDITIONS TO AVOID: High alkaline conditions. INCOMPATIBILITY: Strong oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS: None known. HAZARDOUS POLYMERIZATION:Will not occur. 11. TOXICOLOGICAL INFORMATION Acute Oral LD50(male rat): >5.0 g/kg Acute Dermal LD60(rat): >5.0 g/kg Eye Irritation(rabbit): Severe irritant Skin Irritation(rabbit): Severely irritating Inhalation LCSo(rat): >6.04 mg/L(4 hr) Skin Sensitization(guinea pig):Not a sensitizer. Carcinogenic Potential: Nothing listed in IARC,ACGIH,NTP or OSHA. 12. ECOLOGICAL INFORMATION Aquatic Acute Toxicity 24 HR LCw 48 HR LCso 96 HR LC, 96 HR No Effect Rainbow Trout 140 mg/L 130 mg/L 130 mg/L <100 mg/L Bluegill Sunfish 220 mg/L 210 mg/L 210 mg/L 100 mg/L 48 HR No Effect Daphnia Magna 450 mg/L 170 mg/L 100 mg/L 13. DISPOSAL CONSIDERATIONS Do not reuse product containers. Triple rinse (or equivalent), adding rinse water to spray tank, then offer for recycling at an ACRC site (go to httv:1/www.acrecyde.ora for locations) or by reconditioning, or puncture and dispose of in a sanitary landfill or by other procedures approved by state and local authorities. Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. Do not contaminate water,food or feed by storage or disposal. 14. TRANSPORT INFORMATION DOT Shipping Description:NOT REGULATED BY USDOT U.S.Surface Freight Classification:ADHESIVES,ADJUVANTS,SPREADERS OR STICKERS(NMFC 4610;CLASS:60) Consult appropriate ICAO/IATA and IMDG regulations for shipment requirements in the Air and Maritime shipping modes. Page 2 of 3 MATERIAL SAFETY DATA SHEET 1-1 700@ 15. REGULATORY INFORMATION NFPA&HMIS Hazard Ratings: NFPA HMIS 2 Health 0 Least 2 Health 1 Flammability 1 Slight 1 Flammability 0 Instability 2 Moderate 0 Reactivity 3 High G PPE 4 Severe SARA Hazard Notification/Reporting SARA Title III Hazard Category: Immediate Y Fire N Sudden Release of Pressure N Delayed N Reactive N Reportable Quantity(RQ)under U.S.CERCLA: Propionic Acid(CAS:79-09-4)5000 pounds SARA,Title III,Section 313: Not listed RCRA Waste Code: Not listed CA Proposition 65:Not listed 16. OTHER MSDS STATUS: Section 4 revised PREPARED BY: Registrations and Regulatory Affairs REVIEWED BY: Environmental/Regulatory Services OL/700 is a registered trademark of Loveland Products, Inc. Disclaimer and Limitation of Liability: This data sheet was developed from information on the constituent materials identified herein and does not relate to the use of such materials in combination with any other material or process. No warranty is expressed or implied with respect to the completeness or ongoing accuracy of the information contained in this data sheet,and LOVELAND PRODUCTS,Inc.disclaims all liability for reliance on such information. This data sheet is not a guarantee of safety. Users are responsible for ensuring that they have all current information necessary to safely use the product described by this data sheet for their specific purpose. Page 3 of 3 L/' BASF CORPORATION BASF HELPING MAKE PRODUCTS BETTER TM Safety data sheet T,ROWL H2O Revision date :2005/03/07 Page: 1/8 Version: 1.0 (30222408/MDS CPA US/EN) 1. Substance/preparation and company identification Company 24 Hour Emergency Response Information BASF CORPORATION CHEMTREC: (800)424-9300 100 Campus Drive BASF HOTLINE: (800)832-HELP Florham Park, NJ 07932 Molecular formula: C13 H19 N3 04 Molecular weight: 281.3 g/mol Chemical family: aniline derivative Synonyms: pendimethalin(active ingredient) 2. Composition/information on ingredients CAS Number Content(W/W) Chemical name 40487-42-1 38.7% pendimethalin 61.3% Proprietary ingredients 3. Hazard identification Emergency overview CAUTION:KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. CAUSES EYE IRRITATION. HARMFUL IF ABSORBED THROUGH SKIN. Avoid contact with the skin,eyes and clothing. Potential health effects See Product Label for additional precautionary statements. Primary routes of exposure Routes of entry for solids and liquids include eye and skin contact,ingestion and inhalation. Routes of entry for gases include inhalation and eye contact.Skin contact may be a route of entry for liquified gases. Acute toxicity: Relatively nontoxic after single ingestion.Relatively nontoxic after short-term inhalation. Relatively nontoxic after short-term skin contact. Irritation: May cause slight but temporary irritation to the eyes. May cause slight irritation to the skin. Sensitization: Skin sensitizing effects were not observed in animal studies. Medical conditions aggravated by overexposure: No data available. Potential environmental effects Aquatic toxicity: Very toxic(acute effect)to aquatic organisms. BASF CORPORATION BASF HELPING MAKE PRODUCTS BETTER TM Safety data sheet PROWL H2O Revision date :2005/03/07 Page: 2/8 Version: 1.0 (30222408/MDS CPA US/EN) Terrestrial toxicity: Acutely harmful to terrestrial organisms. 4. First-aid measures General advice: First aid providers should wear personal protective equipment to prevent exposure.Remove contaminated clothing.Move person to fresh air. If person is not breathing,call 911 or ambulance,then give artificial respiration,preferably mouth-to-mouth if possible.Call a poison control center or physician for treatment advice. Have the product container or label with you when calling a poison control center or doctor or going for treatment. If inhaled: Remove the affected individual into fresh air and keep the person calm. If on skin: Rinse skin immediately with plenty of water for 15-20 minutes. If in eyes: Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses,if present;after first 5 minutes,then continue rinsing. If swallowed: Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Do not induce vomiting. Have person sip a glass of water if able to swallow. Note to physician Symptoms: orange-red coloured urine caused by dye(not associated with methemoglobinemia) Antidote: No known specific antidote. Treatment: Treat symptomatically. 5. Fire-fighting measures Flash point: >230°F Suitable extinguishing media: foam,dry extinguishing media,carbon dioxide,water spray Hazards during fire-fighting: carbon monoxide,Carbon dioxide,nitrogen oxides If product is heated above decomposition temperature,toxic vapours will be released.The substances/groups of substances mentioned can be released if the product is involved in a fire. Protective equipment for fire-fighting: Wear self-contained breathing apparatus and chemical-protective clothing. Further information: In case of fire and/or explosion do not breathe fumes.Keep containers cool by spraying with water if exposed to fire. Collect contaminated extinguishing water separately,do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. NFPA Hazard codes: Health : 1 Fire: 1 Reactivity: 1 Special: BASF CORPORATION BASF HELPING MAKE PRODUCTS BETTER TM Safety data sheet PROWL H2O Revision date :2005/03/07 Page: 3/8 Version: 1.0 (30222408/MDS CPA MEN) 6. Accidental release measures Personal precautions: Take appropriate protective measures.Clear area.Shut off source of leak only under safe conditions. Extinguish sources of ignition nearby and downwind. Ensure adequate ventilation.Wear suitable personal protective clothing and equipment. Environmental precautions: Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.Contain contaminated water/firefighting water. Cleanup: Dike spillage. Pick up with suitable absorbent material. Place into suitable containers for reuse or disposal in a licensed facility.Spilled substance/product should be recovered and applied according to label rates whenever possible. If application of spilled substance/product is not possible,then spills should be contained,solidified,and placed in suitable containers for disposal.After decontamination,spill area can be washed with water.Collect wash water for approved disposal. 7. Handling and storage Handling General advice: RECOMMENDATIONS ARE FOR MANUFACTURING,COMMERCIAL BLENDING,AND PACKAGING WORKERS.PESTICIDE APPLICATORS&WORKERS must refer to the Product Label and Directions for Use attached to the product for Agricultural Use Requirements in accordance with the EPA Worker Protection Standard 40 CFR part 170. Ensure adequate ventilation. Provide good ventilation of working area (local exhaust ventilation if necessary). Keep away from sources of ignition-No smoking. Keep container tightly sealed. Protect contents from the effects of light. Protect against heat. Protect from air.Handle and open container with care. Do not open until ready to use.Once container is opened,content should be usedup as soon as possible.Avoid aerosol formation.Avoid dust formation. Provide means for controlling leaks and spills.Do not return residues to the storage containers. Follow label warnings even after container is emptied.The substance/product may be handled only by appropriately trained personnel.Avoid all direct contact with the substance/product.Avoid contact with the skin,eyes and clothing.Avoid inhalation of dusts/mists/vapours.Wear suitable personal protective clothing and equipment. Protection against fire and explosion: The relevant fire protection measures should be noted. Fire extinguishers should be kept handy.Avoid all sources of ignition:heat,sparks,open flame.Sources of ignition should be kept well clear.Avoid extreme heat.Keep away from oxidizable substances.Electrical equipment should conform to national electric code. Ground all transfer equipment properly to prevent electrostatic discharge.Electrostatic discharge may cause ignition. Storage General advice: Keep only in the original container in a cool,dry,well-ventilated place away from ignition sources, heat or flame. Protect containers from physical damage. Protect against contamination.The authority permits and storage regulations must be observed. Storage incompatibility: General:Segregate from incompatible substances.Segregate from foods and animal feeds.Segregate from textiles and similar materials. BASF CORPORATION BASF HELPING MAKE PRODUCTS BETTER TM Safety data sheet PROWL H2O Revision date :2005/03/07 Page:4/8 Version: 1.0 (30222408/MDS CPA MEN) 8. Exposure controls and personal protection Users of a pesticidal product should refer to the product label for personal protective equipment requirements. Advice on system design: Whenever possible,engineering controls should be used to minimize the need for personal protective equipment. Personal protective equipment RECOMMENDATIONS FOR MANUFACTURING,COMMERCIAL BLENDING,AND PACKAGING WORKERS: Respiratory protection: Wear respiratory protection if ventilation is inadequate.Wear a NIOSH-certified(or equivalent)TC23C Chemical/Mechanical type filter system to remove a combination of particles,gas and vapours.For situations where the airborne concentrations may exceed the level for which an air purifying respirator is effective,or where the levels are unknown or Immediately Dangerous to Life or Health(IDLH),use NIOSH- certified full facepiece pressure demand self-contained breathing apparatus(SOBA)or a full facepiece pressure demand supplied-air respirator(SAR)with escape provisions. Hand protection: Chemical resistant protective gloves,Protective glove selection must be based on the user's assessment of the workplace hazards. Eye protection: Safety glasses with side-shields.Tightly fitting safety goggles(chemical goggles).Wear face shield if splashing hazard exists. Body protection: Body protection must be chosen depending on activity and possible exposure,e.g. head protection,apron, protective boots,chemical-protection suit. General safety and hygiene measures: The statements on personal protective equipment in the instructions for use apply when handling crop- protection agents in final-consumer packing.Avoid contact with the skin,eyes and clothing.Wearing of closed work clothing is recommended.Wear long sleeved work shirt and long work pants in addition to other stated personal protective equipment.Work place should be equipped with a shower and an eye wash. Handle in accordance with good industrial hygiene and safety practice.Personal protective equipment should be decontaminated prior to reuse.Gloves must be inspected regularly and prior to each use. Replace if necessary(e.g. pinhole leaks).Take off immediately all contaminated clothing.Store work clothing separately. Hands and/or face should be washed before breaks and at the end of the shift. No eating,drinking,smoking or tobacco use at the place of work.Keep away from food,drink and animal feeding stuffs. 9. Physical and chemical properties Form: microencapsulated,suspension Odour: faint odour,nutty Colour: dark orange pH value: 7-8 Density: 9.76 lb/USg approx. 1.165- (20°C) 1.185 g/cm3 BASF CORPORATION BASF i HELPING MAKE PRODUCTS BETTERTm Safety data sheet PROWL H2O Revision date :2005/03/07 Page: 5/8 Version: 1.0 (30222408/MDS CPA MEN) 10. Stability and reactivity Conditions to avoid: Avoid all sources of ignition:heat,sparks,open flame.Avoid extreme temperatures.Avoid prolonged exposure to extreme heat.Avoid contamination.Avoid electro-static discharge.Avoid prolonged storage. Hazardous reactions: The product is chemically stable. Hazardous polymerization will not occur. No hazardous reactions if stored and handled as prescribed/indicated. Decomposition products: Hazardous decomposition products:No hazardous decomposition products if stored and handled as prescribed/indicated.,Prolonged thermal loading can result in products of degradation being given off. Thermal decomposition: Possible thermal decomposition products: carbon monoxide,Carbon dioxide,Nitrogen oxide Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. If product is heated above decomposition temperature hazardous fumes may be released. Corrosion to metals: Corrosive effect on:brass mild steel 11. Toxicological information Acute toxicity Oral: LD50/rat/male/female: >5,000 mg/kg Inhalation: LC50/rat/male/female: >5.23 mg/1 14 h Dermal: LD50/rat/male/female: >5,000 mg/kg Skin irritation: rabbit: Mildly irritating.(Primary skin irritation test) Eye irritation: rabbit:Mildly irritating. Sensitization: Buehler test/guinea pig:Non-sensitizing. Chronic toxicity Genetic toxicity: Information on:pendimethalin No mutagenic effect was found in various tests with microorganisms and mammals. BASF CORPORATION BASF HELPING MAKE PRODUCTS BETTERTM Safety data sheet PROWL H2O Revision date :2005/03/07 Page:6/8 Version: 1.0 (30222408/MDS CPA US/EN) Carcinogenicity: Information on:pendimethalin In long-term studies in mice in which the substance was given by feed,a carcinogenic effect was not observed. In long-term studies in rats the substance induced thyroid tumors. A marked decrease in body weight gain and an increase in benign thyroid proliferative lesions were observed in the lifetime rat study at the highest dose tested. The substance is not considered to pose a carcinogenic risk at low human exposure levels. Reproductive toxicity: Information on:pendimethalin The results of animal studies gave no indication of a fertility impairing effect. Developmental toxicity/teratogenicity: Information on:pendimethalin No indications of a developmental toxic/teratogenic effect were seen in animal studies. Experiences in humans: Pendimethalin is a strongly orange-red compound-virtually an aniline dye.Cases have been described of of orange-yellow colouration of urine following heavy exposure of workers to the dust of pendimethalin.Despite its structure as both a nitro-compound and aromatic amine,exposure to pendimethalin is NOT associated with methemoglobinemia. 12. Ecological information Information on:pendimethalin Acute and prolonged toxicity to fish: Rainbow trout/LC50(96 h): 0.89 mg/1 Information on:pendimethalin Acute toxicity to aquatic invertebrates: Daphnia magna/EC50(48 h):0.977 mgA ---------------------------- Information on:pendimethalin Toxicity to aquatic plants: green algae/EC50(72 h):0.0081 mgA algae/EC50:0.055 ppm Information on:pendimethalin Other terrestrial non-mammals: mallard duck/LD50: 1,421 mg/kg Acutely harmful to terrestrial organisms. Honey bee/LD50: 49.8 ug/bee Acutely harmful to terrestrial organisms. 13. Disposal considerations Waste disposal of substance: Pesticide wastes are regulated. BASF CORPORATION BASF HELPING MAKE PRODUCTS BETTER TM Safety data sheet PROWL H2O Revision date :2005/03/07 Page: 7/8 Version: 1.0 (30222408/MDS CPA MEN) Improper disposal of excess pesticide,spray mix or rinsate is a violation of federal law. If pesticide wastes cannot be disposed of according to label instructions,contact the State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Contaminated packaging: Rinse thoroughly at least three times(triple rinse)in accordance with EPA recommendations.Consult state or local disposal authorities for approved alternative procedures such as container recycling. Recommend crushing,puncturing or other means to prevent unauthorized use of used containers. RCRA: D028 14. Transport information Reference Bill of Ladino 15. Regulatory information Federal Regulations Registration status: TSCA,US released/exempt SARA hazard categories(EPCRA 311/312): Acute,Chronic SARA 313: CAS Number Chemical name 40487-42-1 pendimethalin 16. Other information Refer to product label for EPA registration number. Recommended use:crop protection product Local contact information Product Stewardship 919 547-2000 BASF CORPORATION RAQF HELPING MAKE PRODUCTS BETTERTm Safety data sheet PROWL H2O Revision date :2005/03/07 Page: 8/8 Version: 1.0 (30222408/MDS CPA MEN) IMPORTANT:WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE.NO WARRANTIES OF ANY KIND,EITHER EXPRESSED OR IMPLIED,INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE,ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS,DATA OR INFORMATION SET FORTH,OR THAT THE PRODUCTS, DESIGNS,DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS,INFORMATION,DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER,YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS,DESIGNS,DATA,AND INFORMATION FURNISHED BY BASF HEREUNDER ARE GIVEN GRATIS AND BASF ASSUMES NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED,ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATA SHEET MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREENBOOK.NET 1 ZEAL TM MITICIDE' POTENTIAL HEALTH EFFECTS Avoid breathing smoke and mists. Avoid personnel This Material Safety Data Sheet (MSDS) serves dif- Acute Toxicity(Primary Routes of Exposure) and equipment contact with fallout and runoff. Mini- ferent purposes than and DOES NOT REPLACE OR Signs and Symptoms of Systemic Effects: Signs of mize the amount of water used for fire fighting. Do MODIFY THE EPA-APPROVED PRODUCT LABEL- toxicity observed in test animals exposed to high doses not enter any enclosed area without full protective ING(attached to and accompanying the product con- of Etoxazole Technical included abnormal gait, de- equipment, including self-contained breathing equip- , tainer). This MSDS provides important health,safety, creased respiratory rate,lethargy,vomiting,decreased ment. Contain and isolate runoff and debris for proper body weight and reduced food consumption. disposal. and environmental information for employers,employ- posal. Decontaminate personal protective equip- ees,emergency responders and others handling large Acute Eye Contact: This product can cause brief ment and fire fighting equipment before reuse. Read quantities of the product in activities generally other and/or minor eye irritation. The expected adverse the entire document. than product use, while the labeling provides that in- health effects resulting from an exposure may include HAZARDOUS COMBUSTION PRODUCTS: Normal formation specifically for product use in the ordinary redness and possible swelling. combustion forms carbon dioxide, water vapor and course. Acute Skin Contact: This product can cause brief may produce: Oxides of nitrogen. Combustion may Use,storage and disposal of pesticide products is reg- and/or minor irritation. The expected adverse health produce toxic: Fluorine compounds. Incomplete com- ulated by the EPA under the authority of the Federal effects resulting from an exposure may include redness bustion can produce carbon monoxide. Insecticide, Fungicide, and Rodenticide Act (FIFRA) and possibly some minor swelling. This product is through the product labeling. All necessary and appro- minimally toxic when absorbed through the skin. This 6. ACCIDENTAL RELEASE MEASURES priate precautionary, use, and storage, and disposal Product is not expected to cause allergic skin reactions. information is set forth on that labeling. It is a violation Acute Ingestion:This product is minimally toxic when VALENT EMERGENCY PHONE NUMBER: (800) of federal law to use apesticide product in any manner ingested. 892-0099 not prescribed on the EPA-approved label. Acute Inhalation:This product is minimally toxic when CHEMTREC EMERGENCY PHONE NUMBER:(800) inhaled. 424-9300 1. CHEMICAL PRODUCT AND COMPANY IDENTI. Chronic Toxicity(including cancer): Repeated high OBSERVE PRECAUTIONS IN SECTION 8: PER- FICATION doses of Etoxazole Technical in laboratory animals SONAL PROTECTION PRODUCT NAME:ZEAL TM Miticide produced liver toxicity,but did not produce cancer. Stop the source of the spill if safe to do so.Contain the VC NUMBER(S): 1289 Developmental Toxicity(birth defects): Slight de- spill to prevent further contamination of the soil,surface ITEM:69766 velopmental effects were produced in animals exposed water,or ground water. For additional spill response to Etoxazole Technical at maternally toxic dose levels. information refer to the North American Emergency EPA REGISTRATION NUMBER:59639-123 Reproductive Toxicity: Based on the results of an information V-1283 72 WDG;Secure Miticide imal studies, Etoxazole Technical is not expected to Response Guidebook. MANUFACTURER cause adverse reproductive effects. FOR SPILLS ON LAND: VALENT USA CORPORATION Potentially Aggravated Medical Conditions: Indi- CONTAINMENT:Reduce airborne dust. Avoid runoff P.O.Box 8025 viduals with preexisting diseases of the liver may have into storm sewers or other bodies of water. 1600 Riviera Avenue,Suite 200 increased susceptibility to the toxicity of excessive ex- CLEANUP: Clean up spill immediately. Vacuum or Walnut Creek,CA 94596-8025 posures. sweep up material and place in a chemical waste con- EMERGENCY TELEPHONE NUMBERS For complete discussion of the toxicology data from tainer. Wash area with soap and water. Pick up wash HEALTH EMERGENCY OR SPILL (24 hr): 1-800- which this evaluation was made, refer to Section 11. liquid with additional absorbent and place in a chemical 892-0099 For Regulatory Information,refer to Section 15. waste container. TRANSPORTATION (24 hr.): CHEMTREC 1-800- FOR SPILLS IN WATER: 424-9300 or(202)483-7616 4. FIRST AID MEASURES CONTAINMENT: This material will disperse or dis- PRODUCT INFORMATION EMERGENCY NUMBER(800)892-0099 solve in water.Stop the source of the release. Contain AGRICULTURAL PRODUCTS:(800)682-5368 Have the product container or label with you when and isolate to prevent further release into soil,surface PROFESSIONAL PRODUCTS:(800)898-2536 calling a poison control center or doctor, or going for water and ground water. The current MSDS is available through our website treatment. You may also contact 1-800-892-0099 for CLEANUP: Clean up spill immediately. Absorb spill or by calling the product information numbers listed emergency medical treatment,information. with inert material. Remove contaminated water for above. (www.valent.com) EYE CONTACT:Hold eye open and rinse slowly and treatment or disposal. 2. COMPOSITION/INFORMATION ON IN I- gently with water for 15-20 minutes. Remove contact ENTS lenses, if present, after the first 5 minutes,then con- 7. HANDLING AND STORAGE tinue rinsing eye.Call a poison control center or doctor for treatment advice. END USER MUST READ AND OBSERVE ALL PRE- ACGIH OSHA SKIN CONTACT: Take off contaminated clothing. CAUTIONS ON PRODUCT LABEL. weight/ Exposure Exposure Rinse skin immediate) with len of water for 15- Chemical Name percent Limits Limits y plenty Keep pesticide in original container. Do not store or 20 minutes. Call a poison control center or doctor for transport near food or feed. Do not contaminate food Etoxazole(2-(2,6- 70-75 None None treatment advice. or feed. Do not put concentrate into food or drink difluorophenyl)- INGESTION: Call a poison control center or doctor containers. Do not dilute concentrate in food or drink dimetimmediately iiimethylethyl)-2- y f or treatment advice. Have a person sip containers. Store in a cool, dry place, out of direct ethoxyphenyll-4,5- a glass of water if able to swallow. Do not induce sunlight. dihydrooxazole)• vomiting unless told to do so by the poison control (153233-91-1) center or doctor. Do not give anything by mouth to an 8. EXPOSURE CONTROLS/PERSONAL PROTEC- Particulates 0-100 10 mg/m3 15 mg/m3 unconscious person. TION Not Otherwise TWA TWA(total INHALATION:Move person to fresh air. If person is Classified••(No (inhalable dust);5 CASO) particulate); mg/m3 TWA not breathing, call 911 or an ambulance, then give END USER MUST READ AND OBSERVE ALL PRE- 3 mg/m3 (respirable artificial respiration, preferably by mouth-to-mouth, if CAUTIONS ON PRODUCT LABEL. TWA fraction) possible. Call a poison control center or doctor for EYES: Do not et this material in our eyes. Eye (respirable further treatment advice. g y y y fraction) NOTES TO PHYSICIAN: None contact can be avoided by wearing protective eyewear. Others••(No 25-30 None None RESPIRATORY PROTECTION:Use this material only CASA) 5. FIRE FIGHTING MEASURES in well ventilated areas. Unless ventilation is adequate 'Active Ingredient FLASH POINT:Not applicable to keep airborne concentrations below recommended " Other ingredients, which are maintained as trade AUTOIGNITION:No data available exposure standards, approved respiratory protection secrets,are any substances other than an active in- EXTINGUISHING MEDIA:Water fog,carbon dioxide, should be worn. gredient contained in this product. Some of these may foam,dry chemical SKIN PROTECTION:Avoid contact with skin or cloth- be hazardous, but their identity is withheld because FLAMMABLE LIMITS IN AIR-LOWER(%): Not ap- ing. Skin contact should be minimized by wearing pro- they are considered trade secrets.The hazards asso- plicable tective clothing including gloves. ciated with the other ingredients are addressed in this FLAMMABLE LIMITS IN AIR-UPPER(%): Not ap- EXPOSURE LIMITS-See Section 2. document. Specific information on other ingredients plicable for the management of exposures,spills,or safety as- NFPA RATING: 9. PHYSICAL AND CHEMICAL PROPERTIES sessments can be obtained by a treating physician or Health: 1 PHYSICAL STATE:Granule nurse by calling 1-800-892-0099 at any time. Flammability: 1 Reactivity: 0 COLOR:Brown 3. HAZARDS IDENTIFICATIONSpecial: None ODOR:No data available EMERGENCY OVERVIEW (Least-0, Slight-1, Moderate-2, High-3, Extreme-4). BULK DENSITY:27.8 Ib./cu. ft. CAUTION These values are obtained using professional judge- VAPOR PRESSURE: 7.000_6 Pa @ 25°C (etoxa- • May cause skin,eye and respiratory irritation. ment. Values were not available in the guidelines or zole) ° •Avoid breathing dust or spray mist. published evaluations prepared by the National Fire pH:6.43 @ 21•C(1/suspension) Protection Association,NFPA. CORROSION CHARACTERISTICS: No data avail- • Do not get in eyes,on skin or on clothing. FIRE FIGHTING INSTRUCTIONS: Products of com- able • Keep out of reach of children. bustion from fires involving this material may be toxic. SOLUBILITY:Dispersible in water Database and format copyright©by VPC Acquisition Corporation. All rights reserved. MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREENBOOK.NET 2 (Ames Test),in vivo mouse micronucleus assay,Un- Section 2 for Exposure Limit information. For Louisiana 10. STABILITY AND REACTIVITY scheduled DNA Synthesis and the in vitro chromo- Right to Know refer to SARA information listed under CHEMICAL STABILITY: Stable at normal ambient some aberration test in Chinese hamster lung cells. U.S. Regulations above. temperatures. A positive response was observed in the mammalian California Proposition 65: Not listed INCOMPATIBILITY:None known mutation assay using L5178Y mouse lymphoma cells. CANADIAN REGULATIONS: OXIDATION/REDUCTION PROPERTIES: Not reac- For a summary of the potential for adverse health ef- WHMIS Hazard Class: Not determined five with water,monoammonium phosphate,zinc,and fects from exposure to this product,refer to Section 3. For information regarding potential adverse health ef- potassium permanganate. For information regarding regulations pertaining to this fects from exposure to this product, refer to Sections EXPLODABILITY:Not expected to be explosive. Product,refer to Section 15. 3 and 11. HAZARDOUS DECOMPOSITION PRODUCTS: No 12. ECOLOGICAL INFORMATION 16. OTHER INFORMATION data available AVIAN TOXICITY: Etoxazole Technical is considered REASON FOR ISSUE:Change the Manufacturer's ad- 11. TOXICOLOGICAL INFORMATION to be practically nontoxic to birds based on results of dress, input MSDS into the new system and update test in the following species: the Emergency Overview. Correct the product name. ACUTE(Product Specific Information): Mallard duck oral LD50: greater than 2000 mg/kg; MSDS NO.: 0096 Eye Irritation: This product produced brief and/or mi- Bobwhite quail dietary LC50: greater than 5200 ppm. REVISION NUMBER:2 nor eye irritation in the eyes of test animals. (Toxicity No reproductive effects were observed in bobwhite REVISION DATE:10-10-03 Category III) quail exposed to 1000 ppm of Etoxazole Technical, SUPERCEDES DATE:8-25-00 Skin Irritation: This product produced brief and/or the highest dose tested. THE INFORMATION IN THIS MSDS IS BASED ON minor irritation in animals. (Toxicity Category IV) AQUATIC ORGANISM TOXICITY:Etoxazole Techni- DATA AVAILABLE TO US AS OF THE REVISION Oral Toxicity:The oral LD50 in rats is>5000 mg/kg. cal is moderately to highly toxic to fish and very highly DATE GIVEN HEREIN,AND BELIEVED TO BE COR- (Toxicity Category IV) toxic to aquatic invertebrates: RECT.CONTACT VALENT USA CORPORATION TO Dermal Toxicity: The dermal LD50 in rats is>5000 96-Hour LC5o rainbow trout: 2.8 mg/i; CONFIRM IF YOU HAVE THE MOST CURRENT mg/kg(Toxicity Category IV). 96-Hour LC50 bluegill sunfish: 1.4 mgA; MSDS. Inhalation Toxicity:The 4-hour inhalation LC50 in rats 96-Hour LC50 Japanese carp: 0.89 mg/I; JUDGEMENTS AS TO THE SUITABILITY OF INFOR- is>2.28 mg/L.(Toxicity Category IV) 48-Hour EC50 Daphnia magna: 7.1 jig/I; MATION HEREIN FOR THE INDIVIDUAL'S OWN USE Skin Sensitization: This product was not a skin sen- Early life-stage rainbow trout MATC:0.022 mgA; OR PURPOSES ARE NECESSARILY THE INDIVID- sitizer in animals. Life-cycle Daphnia magna MATC:0.48µgA. UAL'S OWN RESPONSIBILITY. ALTHOUGH REA- TOXICITY OF ETOXAZOLE TECHNICAL (MATC - Maximum Acceptable Toxicant Concentra- SONABLE CARE HAS BEEN TAKEN IN THE PREPA- SUBCHRONIC: Compound-related effects observed tion) RATION OF SUCH INFORMATION, VALENT EX- in rodent studies,at high dietary dose levels of Etox- OTHER NON-TARGET ORGANISM TOXICITY:Etox- TENDS NO WARRANTIES,MAKES NO REPRESEW azole Technical, included increased liver weight, his- azole Technical is practically nontoxic to adult worker TATIONS,AND ASSUMES NO RESPONSIBILITY AS tological changes in the liver, and slight changes in honey bees.The 48-hour LD50 values were:Oral LD50 TO THE ACCURACY OR SUITABILITY OF SUCH IN- hematology and blood biochemistry parameters. The >200µg/bee&Contact LD50 >200µg/bee. FORMATION FOR APPLICATION TO THE INDIVID- NOELs in rats and mice were 100 and 400 ppm, re- UAL'S PURPOSES OR THE CONSEQUENCES OF spectively. In a 13-week feeding study in dogs with 13. DISPOSAL CONSIDERATIONS ITS USE. Etoxazole Technical,dose-related effects noted at the END USERS MUST DISPOSE OF ANY UNUSED Emergency Telephone: 1-800-892-0099 top two levels (10000 and 2000 ppm) included in- PRODUCT AS PER THE LABEL RECOMMENDA- MSDS NO.: 0096 creased liver weights, decreased prostate weights, TIONS. REVISION NUMBER:2 histological changes of the liver and prostate(acinar DISPOSAL METHODS: Check government regula- REVISION DATE: 10-10-03 VID 12.16.03 cell atrophy),and changes in blood biochemistry(high tions and local authorities for approved disposal of this dose only). The NOEL for this study was 200 ppm. material. Dispose in accordance with applicable laws In a 28-day dermal toxicity study,no adverse effects and regulations. were observed at doses of Etoxazole Technical up to 1000 mg/kg/day. 14. TRANSPORT INFORMATION CHRONIC/CARCINOGENICITY: Two rat DOT (ground) SHIPPING NAME: Pesticide, Solid, chronic/oncogenicity studies have been conducted Non-regulated with rats fed Etoxazole Technical in the diet. The first DOT TECHNICAL SHIPPING NAME: Etoxazole 72% study, conducted at dose levels of 0, 4, 16 and 64 granules mg/kg/day, indicated liver toxicity and tumors of the DOT REPORTABLE QUANTITY(RQ):None testis and pancreas, but a MTD was not achieved. HAZARD CLASS:Not applicable A second confirmatory study was conducted at dose UN/NA NUMBER:Not applicable levels of 0, 50, 5000 and'10000 ppm. The findings REMARKS:None of the second study confirm that Etoxazole Technical EXEMPTION REQUIREMENT:None is not carcinogenic. Two oncogenicity studies were 15. REGULATORY INFORMATION also conducted in mice using dietary levels ranging from 15 to 4500 ppm. Again, Etoxazole Technical REGULATIONS UNDER FIFRA: All pesticides are was found to be toxic to the liver at high doses, but governed under FIFRA (Federal Insecticide, Fungi- not carcinogenic. In a one year study in dogs with cide,and Rodenticide Act). Therefore,the regulations Etoxazole Technical, an increase in absolute and presented below are pertinent only when handled out- relative liver weights was observed with corresponding side of the normal use and applications of pesticides. histopathological changes in the liver at 1000 and This includes waste streams resulting from manufac- 5000 ppm. The NOEL for this study was 200 ppm. turing/formulation facilities, spills or misuse of pFod- DEVELOPMENTAL TOXICITY: No developmental ucts,and storage of large quantities of products con- toxicity was observed in rats even at maternally toxic taining hazardous or extremely hazardous substances. levels of Etoxazole Technical. Based on decreased OTHER U.S.FEDERAL REGULATIONS: food consumption at the 1000 mg/kg/day level, the CWA Section 311: No data maternal NOEL was 200 mg/kg/day and the devel- SARA 313 Chemicals: None opmental NOEL was 1000 mg/kg/day. In rabbits, CERCLA Reportable Quantity(RQ):None Etoxazole Technical produced a slight increase in SARA(311,312): skeletal variations, but only at the maternally toxic Immediate Health: Yes level of 1000 mg/kg/day (based on decreased body Chronic Health: Yes weight gain,reduced food consumption and enlarged Fire: No liver). The maternal and developmental NOELS were Sudden Pressure: No both 200 mg/kg/day. Reactivity: No REPRODUCTION: In a two-generation rat reproduc- STATE REGULATIONS:Each state may promulgate tive study with Etoxazole Technical, an increase in standards more stringent than the federal govern- relative liver weight was observed in the FO and F1 ment. This section cannot encompass an inclusive males in the 2000 ppm group. At the 2000 ppm level, list of all state regulations. Therefore,the user should the viability index on lactation day 4 was reduced in F1 consult state or local authorities. The state regula- pups. Body weights of this group were also reduced tions reviewed include: California Proposition 65,Mas- in Ft and F2 pups during the latter half of the lactation sachusetts Right to Know, Florida Substance List, period. The NOEL for both adults and offspring was Michigan Critical Materials List, New Jersey Right to 400 ppm. Know, Pennsylvania Right to Know, Rhode Island MUTAGENICITY: Etoxazole Technical was negative Right to Know and the Minnesota Hazardous Sub- in the Microbial/Microsome Reverse Mutation Assay stance list. For Washington State Right to Know,see Database and format copyright©by VPC Acquisition Corporation. All rights reserved. r Smolak Farms 315 South Bradford Street f North Andover, Massachusetts 01845 (978) 682-6332 - Stand (978) 687-4029 - Tours &Activities _ (978) 688-8058 - Office www.smolakfarms.com The North Andover Board of Health 27 Charles Street North Andover, MA 01845 June 9, 2003 Dear Brian: In accord with our telephone conversation concerning the report from the consultant, these are the items we will incorporate into the plan: 1)The hand wash sink will be at the front corner of the area to allow quicker access for employees. 2) Since we have a floor drain we do not need a mop sink. 3) There will be covered trash containers outside. 4) There will be screens at the service windows. 5) There will be shelving for storage of supplies and food items. 6)There will be insect control both inside and outside. 7) The menu will consist of ice cream and frozen yogurt, both cones and dishes, frappes, sundaes and possibly snow cones. If you have any other concerns, please let us know of them. Thank you for your consideration. Sincerely, 4, H. Michael Smolak Jr. TOWN OF NORTH ANDOVE BOARD OF HEALTH Location_ A".7�/�'�`� Permit Food Service Retail Food $ Limited Retail $ Seasonal $ Disposal Works Installers $ Disposal Works Construction $ Soil Testing $ Design Approval Permit $ Dumpster Permit $ Burial Permit $ Swimming Pool Permit $ Animal Permit $ Recreational Camp Permit $ Well Construction Permit $ Funeral Directors Permit $ Massage Establishment License $ Massage Practice License $ Suntanning Establishment $ Offal/Trash Hauler $ Other $ 6854 Health Agent Vd ite - Applicant Yellow - Dept. Pink - Treasurer TOWN OF NORTH ANDOVE BOARD OF HEALTH Location C/Wdl��Z< Permit # Food Service Retail Food $ Limited Retail $ Seasonal $ Disposal Works Installers $ Disposal Works Construction $ Soil Testing $ Design Approval Permit $ Dumpster Permit $ Burial Permit $ Swimming Pool Permit $ Animal Permit $ Recreational Camp Permit $ Well Construction Permit $ Funeral Directors Permit $ Massage Establishment License $ Massage Practice License $ Suntanning Establishment $ Offal/Trash Hauler $ Other $ . 17 GU- 51 Health Agent Vd ite - Applicant Yellow - Dept. Pink - Treasurer VM.G.L - Chapter 40, Section 3. 4/9/03 10:37 AM GENERAL LAWS OF:MASSA,CHUSETTS PART I. ADMINISTRATION OF THE GOVERNMENT. TITLE VII. CITIES,TOWNS AND DISTRICTS. CHAPTER 40A. ZONING: Chapter 40A: Section 3. Subjects which zoning may not regulate; exemptions; public hearings; temporary manufactured home residences. Section 3. No zoning ordinance or by-law shall regulate or restrict the use of materials,or methods of construction of structures regulated by-the state building code,nor shall any such ordinance or by-law prohibit,unreasonably regulate or require,a special permit for the use of land for the. primary purpose.:of.agriculture;horticulture;floriculture,or viticulture;nor prohibit,or unreasonably regulate,or require a special permit for the use, expansion,or reconstruction of existing structures thereon for the primary purpose of agriculture,horticulture,floriculture,or viticulture,including those facilities for the sale of produce,and wine and dairy products,provided that during the months of June,July,August;and September of every year or during the harvest season of the. primary crop raised on land of the owner or lessee,the majority of such products for sale, based on either gross sales dollars or volume,have been produced by the owner or lessee of the land on which the facility is located,except that all such activities may be limited to parcels of more than five acres in area not zoned for agriculture,horticulture,floriculture,.or viticulture. For such purposes, land divided by a public or private way.or a waterway;shall'beconstrued as one'parcel.No zoning ordinance or by-law shall exempt.land or structures from flood plain or wetlands regulations established pursuant to.general law.For the purpose of this section,the term horticultureshall include the growing and keeping of nursery stock and the sale thereof.Said nursery stock shall be considered to be produced by the owner or lessee of the land if it is nourished,maintained and managed while on the premises. No zoning ordinance or by-law shall regulate or restrict the interior.area of a single family residential building nor shall any such ordinance or by=law prohibit;regulateor restrict the use of land or structures for religious purposes or for educational purposes on land owned orleased by. the commonwealth or any of its agencies, subdivisions or bodies politic or by a religious sect or denomination,or by a nonprofit educational corporation;provided,however,that such land or structures may be subject to reasonable regulations concerning the bulk and height.of.structures and determining yard sizes,lot area,setbacks;open space,parking and building coverage requirements. Lands or structures used,or to be used by a public service corporation maybe . exempted in particular respects from the operation of a zoning ordinance or by-law if,upon petition of the corporation, the department of telecommunications and energy shall,after notice given pursuant to section eleven and public hearing in the town or city,determine the.exemptions required and find that the present or proposed use of.the land or.structure is reasonably necessaryy for the convenience or welfare of the public;provided however,thaf if lands:or structures used or to be. used by a public service corporation are located in more than one municipality such lands or structures may be exempted in particular respects from the operation of any zoning-ordinance or, by-law if,upon petition of the corporation,the department of telecommunications and energy shall after notice to all affected communities and public hearing in one of said municipalities,detemune the exemptions required and find that the present or proposed use of the land or structure is reasonably necessary for the convenience or welfare of the public. No zoning ordinance or bylaw in any city or town shallprohibit,.or require a special permit for,the use of land or structures,or the expansion of existing structures,for the primary,accessory or incidental purpose of operating a child care facility;provided,however,that such land or structures http://WWW.STATE.MA.US/LEGIS/LAWS/MGL/40A-3.HTM Page 1 of 2 M.G.L - Chapter 40, Section 3. 4/9/03 10:38 AM may be subject to reasonable regulations concerning the bulk and height of structures and determining yard sizes, lot area, setbacks, open space, parking and building coverage requirements. As used in this paragraph, the term ""child care facility" shall mean a day care center or a school age child care program, as those terms are defined in section nine of chapter twenty-eight A. Notwithstanding any general or special law to the contrary, local land use and health and safety laws, regulations, practices, ordinances, by-laws and decisions of a city or town shall not discriminate against a disabled person. Imposition of health and safety laws or land-use requirements on congregate living arrangements among non-related persons with disabilities that are not imposed on families and groups of similar size or other unrelated persons shall constitute discrimination. The provisions of this paragraph shall apply to every city or town, including, but not limited to the city of Boston and the city of Cambridge. Family day care home and large family day care home, as those terms are defined in section nine of chapter twenty-eight A, shall be an allowable use unless a city or town prohibits or specifically regulates such use in its zoning ordinances or by-laws. No provision of a zoning ordinance or by-law shall be valid which sets apart districts by any boundary line which may be changed without adoption of an amendment to the zoning ordinance or by-law. No zoning ordinance or by-law shall prohibit the owner and occupier of a residence which has been destroyed by fire or other natural holocaust from placing a manufactured home on the site of such residence and residing in such home for a period not to exceed twelve months while the residence is being rebuilt. Any such manufactured home shall be subject to the provisions of the state sanitary code. No dimensional lot requirement of a zoning ordinance or by-law, including but not limited to, set back, front yard, side yard,rear yard and open space shall apply to handicapped access ramps on private property used solely for the purpose of facilitating ingress or egress of a physically handicapped person, as defined in section thirteen A of chapter twenty-two. No zoning ordinance or by-law shall prohibit or unreasonably regulate the installation of solar energy systems or the building of structures that facilitate the collection of solar energy, except where necessary to protect the public health, safety or welfare. No zoning ordinance or by-law shall prohibit the construction or use of an antenna structure by a Federally licensed amateur radio operator. Zoning ordinances and by-laws may reasonably regulate the location and height of such antenna structures for the purposes of health, safety,or aesthetics; provided, however, that such ordinances and by-laws reasonably allow for sufficient height of such antenna structures so as to effectively accommodate amateur radio communications by federally licensed amateur radio operators and constitute the nunimum practicable regulation necessary to accomplish the legitimate purposes of the city or town enacting such ordinance or by-law. Return to: * Next Section ** Previous Section ** Chaoter 'ryblg of Contents ** Legislative home Page http://WWW.STATE.MA.US/LEGIS/LAWS/MGL/40A-3.HTM Page 2 of 2 _LQ:euva - 3-nros W41 AA •nn tt ��rn� �� a