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Home My WebLink AboutProduct Safety Date Sheet - Permits - 8/7/1985 PHILIP A. HUNT CHEMICAL. CORPORATION GARRET MOUNTAIN PLAZA WEST PATER ON, N.J.07424 PRODUCT SAFETY DATA SHEET S N I - _MAT' E_ RAAL DESCRIPTION Name: CP-10 DEVELOPER STARTER Chemical Name orSynonyms: N.A. Use: Photographic concentrates used to prepare a working solution for developing color prints . Description: An aqueous solution containing 'inorganic salts and organic cheating agents . SECTION II HAZARDOUS N RF I N` S Cocos it ion C.A.S. Number Percent Hazard Data Sodium bromide 7 7-15 - 1 3 LD- (oral- 'rat ) 3500 mg/kg Potassium carbonate 58 -08-7 12 - 1.6 D-5 oral-rat . 70 SECTION II - PHYSICAL DATA Boiling Point ° F : Approx. 1 ° Solubility in 'dater: Complete Specific Gravity: 1 * 16 Percent volatile by Vol . Vapor Density: H: 7e Vapor Pressure : Approx . 15 mm Evaporation Rate (water Appearance and Odor: very slightly yellowish, odorless , aqueous liquid , SECTION Iv - FIRE AND EXPLOSION HAZARD DATA Flash Point and Method Flammability Limits Lower Upper Not flammable N/A N/A P� I ................. Extinguishing Media: Water spray, dry chemical , foam or carbon dioxide . Special Fire Fighting Procedures : Water spray should be used to cool fire exposed containers and/or to RPM disperse vapors . Use I s MS A approved positive pressure self-contained breathing apparatus when any material is involved in a fire . SECTION v � HEALTH HAZARD DATA V: None established . Effects of over Exposure: 10 physiological effects encountered with the o d m y use of this product cont ' d Page 1 UQ) NAME * CP-1 1 DEVELOPER R SECTION v -HEALTH HAZARDS , nt d First Aid On • . Flush with watery If an irritation persistst call a physician. IFlush with clear warn - for UP to 15 minutes * irritation persi ts , call physician* Ingestion: Drink large quantities water. Induce vomiting * Call a � physician* SECTION vl REACTIVITY DATA Stability* Product is stale. } i void Strong acids will cause evolution Icopata �ty � ater�a � t of carbondioxide . Hazardous polymerization: Will not occur . ISECTION VII - SPILL, LEAKr AND DISPOSAL- PROCEDURES k Clean u and place in an approved DOT s t Aid day -s co n"t"6 i h dt a'nd a @ a 1 toproduct , empty containers and materials Disposal : Dispose of contaminated used in cleaning up Spills or lea} in a manner approved for this material . ` Federal , State and Local regulatory agencies t Consult appropriate fed , ascertain proper disposal procedures . ACTION vlll SPECIAL PROTECTION INFORMATION Respiratory r Protect ion: Normally not needed Local Exhaust : Recommended Mechanical : RecoMmended Eye Protection:ion: Safety glasses or goggles Protective Gloves: Dry rubber gloves SECTION IX - SPECIAL PRECAUTIONS AND COMMENTS + tainers closed and plainly marked . Store in Handling Storin : Keep cool , dry area. • skin or clothin . o not take internally, upon Avoid contact with eyes , contact with skin or eyes , wash off with water . Pa g Approved by fir. H. T. Viehmeer/nc August 7t 19 PHILIPA. HUNT CHEMICAL CORPORATION GARRET MOUNTAIN PLAZA WEST PATERSON, N.J. 07424 PRODUCT SAFETY DATA SHEET TELEPHONE: 201-585-7100 SECTION I MATERIAL USCRIPTION Name: COLOR PRINT o ER DEVELOPER Chemical Name Synonyms : REP N I S s i parts) Not applicable (NoA4, ) Use: Photographic concentrate used to prepare a working solution for developing color prints, Description: Part Aqueous solution containing hydrox r a ine sulfate SECTION II - HAZARDOUS INGREDIENTS Compos it ion: C.A.S Number Percent Hazard Data ydroxylaine sulfate 1089- -- 1 - .-mouse) 102 mq/kg Lithium chloride 7 7- 1 - 1 D- (oral-rat ) 2 mg/kg Material is classified as a D.O.T. Corrosive SECTION III - PHYSICAL DATA Boiling Point ( OF) : Approx. 212 Solubility in water: Complete Specif is Gravity: 1618 Percent Volatile -by Vol .. ( Approx. 7 'vapor Density; Evaporation Rate Vapor Pressure: Aprox. 15 mm Hg Water = 1 p 2 °C Appearance and odor: Clear, water white liquid; no odor SECTION I - FIRE AND EXPLOSION HAZARD ATA Flash point and Method Flammability Limits Lower � [upper None N.A. N.As xtinguishing Hied i a: Water spray, dry chemical , foam or carbon dioxide Special Fire Fighting Procedures : Solution is not a hazard but crystals from dried liquicl could.--be under disaster conditions . Explosion 'hazard for such crystals exists when exposed to heat 28 ° This danger is increased in the presence of excess alkalies which would liberate free hydroxyla ine . Use NIOS / 'SS A approved positive pressure self-contained breathing apparatus when any material is involved in a fire . Water spray should be used to cool ire exposed containers and/or to disperse unignited vapors , SECTION V HEALTH HAZARD DATA T None established , toxicity is moderate. Liquid is corrosive to skin , eyes and mucous membranes . It can cause irritation and burns wherever it comes in contact with the body. Avoid contact with eyes , skin or clothing , Do not take internally, Upon contact with skin or eyes , wash off with water. cont ' d Page PHILIP A. HUNT CHEMICAL F" R TI N NAME , COORPRNT 101 ER DEVELOPER REPLENIHER ""' PARS` SECTION V HEALTH HAZARDS, cony First Aid: Skin: Flush with water for 15 minutes , call a physician. Eyes: Flush with water for 15 minutes , call a physician, Ingestion,: Drink la r ye quantities of water. Do not induce Call a physician. rSECTION VI - EACTI 'IT ' DATA Unstable: Avoid heat and excess of alkalies . Crystals 0dried up liquid s ill can explode at 2 Hazardous Polymerization: Will not occur. WN SECTION 'III ---SPILL , EAR AND DISPOSAL PROCEDURES Add dry absorbent , Clean up and place in an approved IT container peal . is e o c �ntaa.n and contaminated product , empty containers and materials used in cleaning up spills or leaks in a manner Consult � red for this material . aprori ate Federal , State and Local Regulatory agencies t ascertain proper disposal procedures , SECTION VII - SPECIAL PROTECTION INFORMATION Respiratory Protection: None should be needed Local Exhaust , Recommended mechanical : Recommended Protective Gloves : Dry rubber gloves Eye Protection: Safety glasses , goggles or face shield Other; SECTION IX - SPECIAL PRECAUTIONS AND COMMENTS Handling Staring: Store in coal , dr well entilated � place, Other Precautions : Personnel should be cautionedregarding a rd�n a nd 1i c and required to use protective clothing . Page 2 ' Approved by Mr. H. T. iehmeyer/ jc August 7 1985 ILPC-CP-266 S PHILIPA. HUNT CHEMICAL CORPORATION 5 GARRET MOUNTAIN PLAZA WEST PATERSON, N.J. 07424 PRODUCT SAFETY D SHEET TELEPHONE. 201-585-7100 y� �ECTION I MATERIAL D ffSCRIPTION DEVELOPER Chemical Name or Synonyms: Name: COLoP 1Not applicable .A. PLLNIS ons sts of 3 parts) used rear a k�. soluio for Photographic concentrate develo i color prints. ` mixture containing color Description: Par B - A aqueous ro r�.e � develop. agent • sIENTLION I HAZARDS 8S Hazard Data C C.A.S . Noe Percent Composition: 0 - 1- 3 - 44 LD-5 (oral-rat ) = Benzyl alcohol 1230 mg/kg agent 2 1 3 0 � Causes de ra i is Developingara� eg� ere diamine derivative D-5 (oral-rat) Sulfur acid 2140 mg/kg Material is considered a D &O*Te Corrosive SECTION III � PHYs COAL DATA Solubility in Water: Complete Gravity: le12 Percent Volatile y Vol . 74 Vapor Density:` Approxe 2e5 EvaporationRate* Vapor Pressure: -Approx. 1 7 mm Hg fat e � 1 �~ 5°C : Approx . 1 .5 pH• Amber color; sulfur dioxide odor . Appearance and odor* ADD I N HAZARD DATA sCCN -D �'la �na �.1 �. it S Loeser Upper Flash Point and Method 230° ' C.C . �.A. � ,A. rfoam, dry chemical , caro dioxide ExtinguishingMedia: �a � . fat sera should e used coole Special ire '�. t�. � Procedures . � sBA 4 to'disperse u i i t ed vapors . Ilse No S exposed rages ar�d�orrat erg and approved positive pressure self-contained bre � in material is involved in a fire * SECTION V REAL HAZ P, D DATA TLV � Maximum allowable oner�ty ra ion • Braes sulfur dioxide has � in air per -hour working da r e Sulfur dioxide gas causes it i a ion . can cause sensitization de Ana i i s . Skin Mucous hem rane: Irritant , Accidental .�ngestjon: Can cause headache , nausea, vomiting or i.area* coat ' d Page PHILIP A. HUNT CHEMICAL CORPORATION NAME: COLRPRIT 101 ER DEVELOPER RPLISR - PART B SECTION V - HEALTH HAZARDS co n-t d First Ai Skin: Immediately flush with water Eor 15 minutes , Call a physician. Eyes: Immediately flush with water for 15 minutes . Call a physician . Accidental Ingestionoo Drink large quantities of water, Do not idce vomiting. Call a physician, SECTION VI - REACTIVITY DATA Stablity: Material is stable , Hazardous Pol ymer i zat i.on: Will not occur, ncorrpatabiity: Avoid oxidant such as chromic acid f liquid chlorine S CT o 1 VII SPILL p LBAK F AND DISPOSAL PROCEDURES Spill. {or Leak: Neutralize with sodium bicarbonate . Add dry absorbent . Clean up and place in an approved DOT container and seal , Disposal : Dispose of contaminated product , empty containers and materials used in cleaning up spills or leaks in a manner approved for this Material Consult appropriate Federal , State and Local regulatory agencies to ascertain proper d.ispos l procedures . ' SECTION VI II - SPECIAL PROTECTION N "o iAT O Respiratory Protection: Do not breathe vapors directly: use an approved organic acid respirator Local Exhaust, Recommended Mechanical , Recommended Protective Gloves: ]dry rubber gloves Eye Protection: Safety glasses , goggles or face shield Other. As necessary to prevent skin contact SECTION IX - SPECIAL PRECAUTIONS AND COMMENTS Handling & Stor Store in cool area away from oxidants - liberates sulfur dioxide Avoiding contact with eyes , skin or clothing . Do not take internally, Upon contact with skin or eyes , wash off with water. Page Approved by Mr. H. T. Viehemyer/njc August , 1985 I LP -C P- 6 PHILIPA. HUNT CHEMICAL CORPORATION GARRET MOUNTAIN PLAZA WEST PATERSON,N.J.07424 PRODUCT SAFETY A A SHEET TELEPHONE: 201.5 85.710 0 SECTION I MATERIAL DESCRIPTION Name:e: COLORPRINT 101 ER DEVELOPER Chemical Name or Synonyms: R PL NISHS consists of 3 parts Not applicable (N . . Use: Photographs concentrate used to prepare a working solution for developing color prints. Description: Part C An aqueous , proprietary alkaline solution containing inorganic salts. SECTION II - HAZARDOUS INGREDIENTS oposit .on: C.A.S. Number Percent Hazard Data Potassium Hydroxide 1310-58-3 3 LD-50 (oral-rat ) 36 5mg/kg Potassium Carbonate 584-08-- 35 - 40 LD-50 (oral-rat ) .80 mg/kg Potassium Sulfite 1 117-38-1 1 - 3 LD-50 (IV-mice) 17 5mg/kg Material - 'is classified as a D.O.T. Corrosive. SECTION III - PHYSICAL DATA Boiling Point > 2120F , olu ility in Water:: Complete Specific Gravity: 1s50 Percent volatile by von. . ( % ) ; Approx . 50 Vapor Density: Evaporation Rate: Vapor Pressure: Approx. 17 Tnm Water 1 100 p 5° o Approx. 14 Appearance and odor; Clear, aqueous solution SECTION Iv - FIRE AND EXPLOSION HAZARD DATA Flash Point and Method la ►r a il i y Limits Lower Capper None N.A. N.A. xtingu1shing Media: Water spray, dry chemical , foam or carbon dioxide Special Fire Fight in s Procedures : pater spray should be used to cool fire exposed containers and/or to disperse un ignited vapors . Use NI SH S A approved positive -pressure self-contained breathing apparatus when any material is involved in a fire . SECTION v HEALTH HAZARD DATA Lv: None established - hazard considered slight Skin: Prolon ed contact may cause irritation and/or burrs Eyes : Contact with the liquid causes burns { cont ' d Page 1 PHILIP A. HUNT CHEMICAL CORPORATION I NAME : COLORPRINT 101 ER DSVELOPER RSPLENISHER - PART C SECTION V - HEATTH HEATH HAZARDS, coat' d First Aid: Skin: Flush with plenty of water for a minimum of 1 -minutes Call physician. Eyes: Flush eyes immediately with large volumes of water for a Minimum of 15 minutes , Get medical attention immediately, Accidental. Ingestion : Do not induce vomitin . -Gig at large quantities water an least 1 o . o vinegar in equal amount of water* Call si. i SECTION V REACTIVITY DATA an. Stab,ity: Material, is stable . Hazardous Polymerization: Will not occur. Inco patibility: Strong acids will cause evolution of carbon dioxide . SECTION VII - SPILL,, LEAK, AND DISPOSAL PROCEDURES Spill or Leak: Neutralize with sodium bisulfate . Add dry absorbent , Clean up and place in an approved DOT container and seal Disposal : Dispose of contaminated product , empty container and materials used in cleaning up spills or leaks in a manner approved for material , aeral . Consult appropriate 'Federal , State and Local regulatory agencies g � g ee t ascertain proper disposal Procedures , SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection: N.A. Local Exhaust : Recommended Mechanical : Recommended Protective Gloves : Plastic or rubber Eye Protection , Safety glasses , goggles or face shield Other: Rubber or plastic aprons SECTION I - SPECIAL PRECAUTIONS AND COMMENTS Handling & Stor it Store in cool area , Kee containers p closed , Avoid contact with eyes , skin or clothing , o not take internally. n ernall . Upon contact with skin or eyes , wash off with water. Page Approved by Mr, S. T. i rer/n j c August 7 , 1985 IL C-CP- 6 FRILL' A. HipiT CHEMICAL CORPORATION 40D TELEpmONE.- Cusumm amet Moxftn f4m PRODUCT SAFETY DATA SHEET 1 . Paters, N.J. 07424 eWbom 14=4M1 } CATALOG NO. NAME of PRODUCT P INS-P BLEACH-FIX LEN SHE (cons ME-3 6Party PURPOS9OFPRODUCT Photographic concentrate. used o prepare a Working solution for Bleaching and Fixing Color Prints oESCRIPTI0N 0 IN I ATERIAL +PART A - A proprietary, aqueous solution o inorganic salts CERTIFIED BY: H. . Viehmeyer, Director of Research EME RG ENCY T LEPHON . 0 -7100 STI ON I CHEMICAL NAME AND SYN NYM& TRADE INANE ANO SYNONYMS N.A. (Not Applica N.A* CHEMICAL FAMILY FORMULA SECTION I1- HAZAROOUS INGREDIENTS TLV PAINTS,,PRE.SKRVATIVRS AND SOLVCNTS (Una s) ALLOVS AND M TALLIC COATIM12S (Units) PIGMENTS BASE META. CATALYST ALLOYS VEHICLIE METALLIC COATINGS :. SOLVENTS FILLERMETAL, PLUS COATING OR CORE FLUX ADDITIVES OTHERS OTHERS HAZARDOUS MIXTURES RES OV OTHIER LI UIDSo SOLIDS,OR CASES TLV (Units) N.A. SECTION III • PHYSICAL DATA BOILING POINT(°F.) Approx. 212IF46 SPECIFIC GRAVITY (H om 1) 1 ,32 VAPOR P , Approx. 1 Mm e e L ME(%)VOLATILE so VAP OE ISITY(AIR*1) jaMEON RATE SOLUBILITY IN WATER Completq PH As Is 596 APPEARANCE ANO OOOR Clear, colorless, aqueous liquid, with very mild ammonia odor. S.ECTION I • FIRE ANO EXPLOSION HAZAAO DATA FLASH POINT (Method lased) Not Flammable FLAMMABLE LIMITS N.A. Lei U41 EXTINGUISHING MM OIA N.A* SPECIAL FIRE FIGHTING TIN PROCEO ES 14US AL FIDE ANO EXPLOSION HA AADS N.A* A t.W IN V F �r.ti TPA-�'wcr. %NW gkmr�---a'*.�', on r4& �s _.. ^�ii i ak . ...7y .r,r�Fis" •�#V#4041- PART PHILIP A. HUNT CHEMICAL RPOR 1T1 SECTION 1 , HEALTH HAZARD TA- THRESHOLD Ey.II4AiT VALUE Noe established. EFFECTS OF OV IE R EXPOSU RF. on a va ors may 2roduce mild irritation to eyes and mucous membranes of nose. Spills on Skin.! Wash affected areas wit h water until irritation is re I ieved. EMERGENCY ANo F1R T Ai PROCEDUR ES In Eyes: Immediately flush eyes with water for 15 minutes. Get Medical attention immediately, Accidental Ingestion: Induce vomiting. Get medical attention immediately, SECTION 1 - REACTIVITY DATA STABILITY CONDITIONS To AVOID UNSTABLE STABLE x INCO PATA81LITY fMaterials to avoid) None HAZARDOUS DECOMPOSITION PRODUCTS None CONDITIONS To AVOID HAZARDOUS MAY OCCUR - POLYMERIZATION WILL NOT OCCUR x r i SECTION V1 •SPILL OR LEAK PROC O STEPS TO SE TAKEN iN CASE MATERIAL 1 RELEASED OR SPILLED Flush to dra in with water Ammonia fumes are evolved mace strongly al a ire. Do not contact with strong alkalies , STE DISPOSAL METHODDilution it water.* flush to drain. SECTION Vill •SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION tSpecih, rope) Not nor alrequired; avoid breathing of ammonia vapors 4. VENTILATION LOCAL EXHAUST Recommended SPECIAL MECHANICAL(General) OTHER Recommended PROTECTIVE GLOVES EYE PROTECTION Plastic or rubber ,glove Safe s glasses or qoqcjles OTHER PROTECTIVE EQUIPMENT Plastic or rubber aprons SECTION IBC -SPECIAL PRECAUTIONS PR ECAUTI ONS To 8 E TA EN i N HA14OLI NG AN STOR#NG Keep containers closed. Store in cool area. OTHER PRECAUTIONS None PAGE 2 of 2 Nov. 17, / D:bb Dorm O A• 0 Rev.May 72 PHILIP A. CHEMICAL CORPORATION � � Pima USAFETY DATA SHEET 11. Paterson, N.J. 07424 (20) TELSorM caw 140)4M-0661 CATALOG NO, NAMIM OF PRODUCT o oR N - o BLEACH— TX R ' I E ones Party PU RP105 IE 0 F P RO DUCT' Photographic concentrate used to prepare a Working Solution for Bleaching and FixingColor Prints 0F.SCRIWnON of MATFERIA PART B - A proprietary aqueous, almost neutral solution containing .inorganic salts and organic chelating agents CERTIFIED BY, H. T. Viehmeyer, Director of Research EMERGENCY TELEPHONE: 01)585-7100 SECTION I CHEMICAL NAMS AND SYNONYM&�. � 1 TRAMNAM OSYNONYMS pplicab .e .A. CHEMICAL.FAMILY FORMULA N*A. .A SECTION 11 • HAZAROOUS INGREDIENTS TLV TLVF^II TS,PRMAVATIVIES ANO SOLVENTS ALLOYS AND METALLIC COATINGS (Emits) (Units) PIGMENTS BASE METAL CATALYST ALLOYS VEHICLE METALLIC COATINGS SOLVENTS FILLER METAL PLUS COATING OR CORE FLUX ADDITIVES OTHERS OTHIERS HAZARDOUS MIXTURIES OF OTHER UQUIDS,SOLIDS. OR GASES % TLV (Units) N.A* SECTION III - PHYSICAL 6ATA 0 SOILING POINT( F.) A22rox, 212 0 SPECIFIC GRAViTY (m ove) 1 , 3 VAPOR PRESSURE(mm Hg,) PERCENT,VOLATILE C. 1.5 rm. BY VOLUME E( ) so VAPOR DENSITY (AIRmll EVA Tloi+4 RATE SOLUBILITY IN WATER jcomple.t pH 0 As Is 810 APPEARANCE AND ODOR R ddis �brown; aqueous liquid: with mild ammonia odor, SECTION IV • FIRE ANO EXPLOSION HAZARD DATA FLASH Poli+,i"T(Iahat:I sec3) Not Flammable FLAMMABLE I.IMIT LEI LiGl XTI r.UIS I NG M E01A N.A* SPECIAL~FIRIM FIGHTING PROCEDURES N.A. UNUSUAL FI R E A O Em XPLOS ION MA Z FAROS N* . PAE 11 of 2 Nov. �. / �T Pam�� •�� PHIL.M A. HUNT CHEMICAL of q ATI R13 10. SECTION V• HEALTH HAZARD DATA THRESHOLD LIMIT VALUE None established. EFFECT'S of OVEREXPOSURE, A on a vapors ME 2roduce mild irritation to eyes and mucous membranes. Ills on Sk nd wash affected areas with water until irritation is relieved. EM IE Rr.rzNCY AN 0 Jul RST Al PROC EOURES In Eyes: Immediately flush eyes with water for 15 minutes. Get medical attention imp d ately. Accidental Ingestion: Induce vomiting. Get medical attention immediately. S-ECTION VI - REACTIVITY DATA STABILITY CONDITIONS TO AVOID UNSTABLE STABLE 114COM PAT ADILITY (Materfah tO 4vai l done HAZARDOUS DECOMPOSITION PROOUCTS None CONDITIONS TO AVOID HAZAA00US MAY OCC U R POLYMERIZATION WILL NOT OCCUR x SECTION VII.-SPILL OR LEAK PR EOU S STEPS To BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEf Flush to drain with water, WASTE DISPOSAL I ET oo Dilution with water; flush to drain, SECTION VIII -SPECIAL PROTECT!---O IN.FOR ATION RESPIRATORY PR 'TECT'ION r eCi rvp ) Not normal r ui d s avoid breathing of ammonia vapors . VENTILATION LOCAL EXHAUST SPECIALReoomended MECHANICAL(General) OTHER Recommended PROTECTIVE GLOVES EYE P F OT rzr'TI O Plastic or rubber g-love s Safety glasses or goggles OTHER PROTECTIVE EQUIPMENT Plastic or rubber aprons . SECTION IX - SPECIAL PRECAUTIONS. PRECAUTI,KeepONS To 93 TAKEN I ► NDLI AND STORING con tamers o o �. Store in cool area., OTHER PRECAUTIONS Moue PAGE 2 of 2 Nov. 17, 1. 76/ D :b Farm OSHA* o PHILIP AsCHEMICAL CORPORATION 5 GARRET MOUNTAIN PLAZA WEST PAT RSON, V.J. 07424 PRODUCT SAFETY DATA SHEET TELEPHONE. 201-585-7100 # A . 4 LIUUT SECTION I MATERIAL DESCRIPTION Name. N AC oR-2DEVELOPER STARTER Chemical Name or Synonyms : N.A. Not applicable ) Use: Are additive to convert Negacolor-2 Developer Rep .enisb r to Developer. Description : A proprietary aqueous solution containing inorganic salts and organic c elat i g agents , SECTION II - HAZARDOUS INGREDIENTS HAZARD DATA L Composition: !rllWi VIi�Y�T� Sodium bromide Approx . 1 of a s ium carbonate 1 -- 2 Sodium sulfite 1 - SECTION III - PHYSICAL DATA Boiling Point( Approx. 2121 solubility in water : Complete Specific Gravity: 1 * 24 Percent Volatile by Vol. Approx . Vapor Density* -�- Evaporation Rate (water l ) : 1 y Vapor Pressure : Approx. 15 mm pH as is Appearance and odor : Clear, colorless , aqueous solution with little or no odor . SECTION IV - FIRE AND EXPLOSION HAZARD DATA `lash Point and method lammab lit imi is sower er Non-Flammable N .A ti guishing Media: N .A. PIIII�FIW�YWi1W�iWiIWiYY1Fi�YYM iiPPlWi�iiYYiliYiFiIXr9�f e sal Fire ting Procedures . N.A. Unusual Fire & Ex ,plosion. Hazardso N.A. SECTION v -- HEALTH HAZARD DATA TLV: None established - hazard considered slight . Effects of over Exposure No physiological effects encountered w-ith ordinary use of this roduct coat' d Page P ILIP A. HUNT CHEMICAL CORPORATION NAME : EG L -2 DEVELOPER START SE'CTION V - HEALTH EAR oln t ' d First Aid : Eyes : Flush with water; if irritation persists , get medical anent ion . Internal : induce vomiting ; if discomfort persists ; get medical attention . SECTION v - REACTIVITY DATA Incompatibi %,t�: None , Hazardous Decoy os .t ion Products : None , Hazardous Polymerization.: will not occur. St bi l i . r: F Product is stable . Avoid contact with strong acids . SECTION I SPILL, LEAK , AND DISPOSAL PROCEDURES ill or Leak : flush with water to drain . Di s osal Flush with water to drain . Biodegradable - no problem in sew r i nc . SECTION VIII - SPECIAL PROTECTION INFORMATION A` IO Respiratory rot tion: [ one requ i red . Mechanical :anical : None required , Local Exhaust : None required . Eye Protection: Safety goggles or glasses recommended , Protective Gloves : Rubber gloves recommended . SECTION IX -- SPECIAL. PRECAUTIONS AND COMMENTS Handling Stor i. g : Keep containers closed and plainly marked . Store in cool , dry area . other Precautions : None . Page 2 Approved by: . T. vie m ye r/ c Date : 1/31/85 { PHILIP A. HUNT CHEMICAL CORPORATION 42 WEST PATERSON,N.J.07424 PRODUCT TELEPHONE: fit+3 �}}�'W�O[N 20 1 .}�y5 L0,0 Lr 1�r�i F■V F w�+ M+�.#{ YV#��Y Y � r SECTION I MATERIAL DESCRIPTION Name;e. i A , LOR-2 DEVELOPER REP L sHER (Consists of three parts Chemical 1 Synonyms : N.A. Not Applicable ) Use: Photographic concentrates used to prepare a working solution and replenisher for developing color negatives * Description: PART A -- A proprietary aqueous alkaline solution of inorganic salts and organic c e ating agents $ SECTION II HAZARDOUS INGREDIENTS HAZARD DATA TV Composition : Nit i oacetic acid i Potassium carbonate Sodium sulfite: 3 - SECTION III PHYSICAL DATA Boiling Point Approx. 2120 Solubility in Water : Complete Specific Grar vit : 1 o45 Percent Volatile by Vol . 42 Vapor Density: p as is : 1 . Vapor Pressure : Approx. 15 mm Evaporation Rate (water Appearance and odor: Colorless aqueous solution with little or no odor . SECTION I - FIRE AND EXPLOSION HAZARD DATA Flash Point and Method Flammability Limits Lower upp.e.r Not Flammable Extinguishing € ed ia: N .A. S.2.ecial Fire Fighting Procedures: N- ,,Ab Unusual Fire an x sion Ha a d e N.A. SECTION V HEALTH HAZARD DATA TLV: N.A* material is alkaline , containing a small amount o free 0 potassium yd o ide , Effects of Over osue pH is approximately 11o4o Irritating to skin and tissue . cont ' d fag PHILIP A. HUNT CHEMICAL CORPORATION NAME : NEGATIVE-2 DEVELOPER REPLENISHERr PART A SECTION HEALTH HAZARDS , con t ' First Aid: Spills on Skin : Wash affected areas with soap and water , In Eyes , Flush with clear warm water for up to 15 minutes . Get medical attention. Accidental ingestion : Glare large quantities of water including one ounce of vinegar . If discomfort persists , get medical attention . SECTIONDTI REACTIVITY DATA tab i l i ty : Product is stable. nco ata i l i t (materials to avoid) , Contact with strong ace. . Hazardous Polymerization : Will not occur. SECTION V11 - SPILLr LEAKr AND DISPOSAL PROCEDURES S2ill or Leak : Flush with water to drain . Di. po al : Di lute ' i th water , Biodegradable - no problem in sewed.ng . SECTION V I I - SPECIALS PROTECTION INFORMAT O Respiratory Protect ion: None required , Local Exhaust * None required , mechanical , None required . Eye Protection : Safety glasses or goggles . Protective Gloves , Plastic or rubber gloves , oche • SECTION IX - SPECIAL PRECAUTIONS AND COMMENTS Handling & Stoning : Keep containers closed and plainly marked . Store in cool dry area . other Precautions: None . Page 2 Approved by Mr. H . T. p i e hmeye r/n j c 1/31/85 PHILIP A* CHEMICAL CORPORATION 1 5 GARRET MOUNTAIN PLAZA VEST P T RSON,N.J.07424 � �DUCT SAFETY TELEPHONE. 201-585-7100 V M -T C: _J!_ SECTION I MATERIAL DESCRIPTION Name : ] G A OL R-2 DEVELOPER REPLENISHER. Consists of three parts) Chemical Marne or Synonyms ; NeAs Not Applicable Useg concentrates used to prepare working solution an . Photographic . replenisher for developing color negatives * Description : PART Aqueous solution containing hydroxylamine sulfate * SECTION I HAZARDOUS INGREDIENTS A A D DATA TLV Composition ,* drox laine sulfate Approx . 30 No TLV establ fished . Toxicity is moderate . main hazards are exp los i b i l i ty at 2 See I below) and corrosiveness to the body ( See Section below). SECTION III PHYSICAL DATA Boiling Point ( * F) o, A . r x, 2 20 Solubility In Water: C omplete S Percent Volatile 1 . pec� � a ��.y . � . � y Vapor Density: pH at 20 of concentrate : 2 .2 Vapor Pressure : Approx . 15 mM Evaporation Rate (water �- l Appearance and odor : Clear, water white , Obi le liquid* No odor . SECTION I -- FIRE AND EXPLOSION HAZARD DATA Flash Point and Method Flammability Limits Lower U e.-- r Not Flamm- able N A xtin is in Media: Solution is not a hazard , but crystals from dried liquid could be , especially under disaster conditions . Exp.losion Hazard for such crystals exists when exposed o heat - e .g . 2 ° e T 1 danager would ld be increased in the presence excess of alkalies which . could liberate e free yd rcxy 1.am i ne . SECTION V HEALTH HAZARD DATA TLV: NeAs Effects of Over Ex sure Liquid is corrosive to skin, eyes and mucous membranes * It can cause irritation and burns wherever it comes in contact with the body, cost ' d Page l PHILIP A.HUNT CHEMICAL CORPORATION NAME • NEGATIVE-2 DEVELOPER REPLENISHERr PART D SIN V "R HEALTH HAZARDS con t I d First Ai Affected body areas should be washed with copious quantities of soap and warm water , In Eyes : Immediately flush with clean warm water for 15 minutes and get medical attention . SECTION I REACTIVITY DATA. Sta il Product is unstable . Avoid heat and excess of alkalies . Crystals dried up liquid spill can explode at 2650F . Income ata it it materials to avoid) : A, alw.ies Hazardous Polymerization: Will not occur, SECTION VII - SPILL, LEAK ,, AND DISPOSAL PROCEDURES Spill or Leak : Flush to drain with copious amounts of water . Di oral : Flush -to drain with copious amounts of water . SECTION DTII - SPECIAL PROTECTION INFORMATION Respiratory Protection : Not normally needed. Local Exhaust : Recommended , Mechanical : Recommended . Eye Protection : Safety glasses or ogles . Protective Gloves : Dry rubber gloves , other ,• SECTION X - SPECIAL PRECAUTIONS AND COMMENTS Handling Storm : Keep containers closed . Store in a cool , ventilated pace . other Precautions : Personnel should be cautioned regarding its handling and required to use protective clothing , Page 2 Approved by Mrs H. T. Viehmeyer/njc 1/31/85 F PHILIPA. HUNT CHEMICAL CORPORATION 5 GARRET MOUNTAIN PLAZA VEST PATERSON,N.J.07424 PRODUCT TELEPHONE: 201-585-7100 a SECTION I -• MATERIAL DESCRIPTION ar e : -2 DEVELOPER REPLENISHERCorpsi is of 3 Parts Chemical Name or Synonyms : N .A. ( Not applicable ) Use: Photographic concentrates used to prepare a working so l u t ion and :. replenisher for developing color negatives , Description: PART C - A proprietary aqueous acidic solution of inorganic salts and an organic color developing agent . SECTION Il - HAZARDOUS INGREDIENTS HAZARD DATA T v composition: organic Developing Agent No TLV esta lis ed . Beta hydroxyethyl aniline sulfate Approx 35 oral toxicity to rats is moderate . DOT CORROSIVE. Contains small amounts of free Sulfuric acid * SECTION III - PHYSICAL DATA Boiling Point( Off,) : Approx . 2 l Solubility in Water , Complete Spec i is gravity: 14, 18 Percent Volatile by lol. . 55 vapor Density: Evaporation Rate , 1 Vapor Pressure : A pro . 15 mm pH as is : 2 . Appearance and odor : Amber aqueous solution with odor of sulfur dioxide SECTION ICI - FIRE AND EXPLOSION HAZARD DATA Flash Point and Method Flammabili.ty Limits Lower Upper Non-Flammable N.A. xtinguis ing edia: I .A. i •wrrr�� -wry-nr�snninrnii�n ecial Fire fi!2_h,ting Procedures : None Unusual Fire & EU10sion Hazards : None SECTION V HEALTH -HAZARD DATA TLC : None established . Effects of Over Exp sure Skin & Mucous Membranes irritant; can cause sensitization dermatitis con t Page 1 PHILIP A. HUNT CHEMICAL CORPORATION NAME NEGACOLOR-2 DEVELOPER R LE S `' R PAR ' d SEC 'ION V HEALTH HAZARDS , ont First id: ` water Do not use soap at first) Skin Contac t : Flush �,t Eyes : Flush with watery t medi,al attention immediately* internal : induce vomiting -, get medical attention , SC VI -� REACTIVITY DATA ibilit None . Hazardous Deco .for Products :: Sulfur dioxide in small amounts * Hazardous polymerization: �11 not occur * stab i i t prodLS3=ECCT ION VI.I uct 4 s stable * - tPILL EAK t ADD DISPOSAL PROCEDURES Leak :spili or Flush with water to drain . �.acre ad ► e -� r� problem �. i os a : Flush with water to drain . B s werin e SECTION II � CISPROTECTIONINFORMATION Respiratory Prot ion: Not required * mechanical : cared . Exhaust : coer�d . LocalSafety 90991es or glasses Eye Protections. Protective Gloves * Rubber os . _. SPECIAL PRECAUTIONS AND COMMENTS sFCTION IX Han dl ire Stor . Keep costa ner closed and plainly marked . Store 4. in coal , dry area . other Precautions * Noneo page 2 Approved bye ie ern date : li PHILIPA. HUNG" CHEMICAL CORPORATION �'* '� GARRETMOUNTAIN PLAZA WEST PATERSON, k .J,07424 PRODUCT SAFETY DATA SHEET TELEPHONE; 01- 8 -7100 SECTION I -- MATERIAL DESCRIPTION Name. ULTRA N GA oLOR 2 BLEACH Chemical Name or Synonyms CONCENTRATE RA' Not applicable (N .A. ) Use: Photographic concentrate used to prepare a goring solution for bleaching color negatives $ Descriptions A proprietary aqueous solution cor taininq inorganic salts and or2anic chelating agents SECTION II HAZARDOUS INGREDIENTS Composition C.A.S. Number Percent Hazard Data :. Ammonium bromide 12124- 7- 20 - 25 dnd-mars=iy 50 n o1 L Acetic acid 4-19-7 1 - 3 LD-50 (oral rat ) = 3310 g/ g Ethylene diamine tetraac ti 15709-41-5 20 25 None established acid ferric salt Potassium nitrate 77 7-79- . l 4 LD-50 (oral-rat) = 3015mg/kg SECTION II PHYSICAL DATA Boiling Point ( OF) : Approx. 212 Solubilityin Water: Complete Specific Gravity: 1934 Percent Volatile by vol . 50 Vapor Density: v aporat ion Rate: Vapor Pressure : Approx . 15 mm {Water 1 1 6.0 (when diluted 1: 1 with water Appearance and Odor: Reddish-brown, aqueous liquid; little or no odor . SECTION Iv - FIRE AND EXPLOSION HAZARD DATA Flash Point and Method Fla nmabilit Limits Lower Upper Not Flammable N•A# N.A. Extinguishing Media: Water spray, dry qhemical , foam or carbon dioxide , Special Fire Fighting Procedures: Water spray should be used to cool f ire exposed containers and/or to disperse vapors . Use NIOSH/MSHA approved positive pressure self-contained breathing apparatus when any material is involved in a fire. SECTION v � HEALTH HAZARD DATA LV. None established * Effects of Overexposure: Ammonia vapors may produce mild irritation to eyes and mucous membranes * 0 PHILIP A. HUNT CHEMICAL CORPORATION NAME: ULTRA NEGACOLOR 2 BLEACH CONCENTRATE S'ECTION V HEALTH A Ai S , cont First Aid: On skin: wash affected areas with water, if irritation persists , call a physician. In Eyes : Immediately flush eyes with water for 15 minutes . Get medical attention immediately. Accidental Ingestion : Induce vomiting, Get medical attention immediately. SECTION VI - REACTIVITY DATA Stabl ter: Material is stable . Conditions to Avoid: Strong alkalies will release ammonia vapor . Hazardous Polymerization; will not occur . SECTION VII SPILL a LEAK , AND DISPOSAL PROCEDURES Spill or Leak: Add dry absorbent . Clean yap and place in an approved DOT container and seal . Disposal : Dispose of contaminated product , empty containers and materials used in cleaning up spills leaks in a Danner approved for this material . Consult appropriate Federal , State and Local regulatory agencies to ascertain proper 1sposal procedures . SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection: Not normally required , avoid breathing of any ammonia vapors . Local Exhaust : Recommended Mechanical . Recommended Eye Protection : Safety glasses or qoaqles Protective Gloves. Rubber SECTION IX - SPECIAL PRECAUTIONS AND COMMENTS Handling & Storing : Deep containers closed and plainly marked . Store in cool , dry area , Avoid contact with eyes , skin or clothing . Do not take internally. Upon contact with skin or eves , wash off with water , Page 2 Approved by Mr. H. T. iemeye /njc August 71 1985 1 f PHILIP A. HUNT CHEMICAL CORPORATION f GARRET MOUNTAIN PLAZA SHEET WEST fi PAT F SON,N.J.0742 PRODUCT SAFETY TELEPHONE- 2 1.58 •7]00 SECTION MATERIAL DESCRIPTION Name:e: UNIVERSAL & ELECTROLYTIC COLOR FIXER Chemical Name or Synonyms: N.As lot applicable) Use: photographic oncentrate used to prepare a working solution for processing color film and aper* Description: A proprietary, aqueous solution of inorganic salts and organic chelating agents . SECTION II HAZARDOUS INGREDIENTS oion C.A.S. Number Percent Hazard Data Cow Ammonium u►m ' iosul fate 7783-l 8-8 43 - 47 Sodium sulfite -* - - 10 LD-50inv-rat) 115 mg/fig *Approx. 12 g can be taken daily by mouth with no ill effects except Catharsise SECTION III PHYSICAL DATA Bonin Point F : Approx. 2 1 ° Solubility in water: Complete Specific Gravity:: 1 . 38 Percent Volatile by Vol. Alpo . 43 Vapor Density: -��- Evaporation Rate Apox796 . l Va o e s re: Approx. 15 mm Hj ° : p Appearance and odor: Colorless liquid; slight odor of am oni . SECTION I - FIRE AND EXPLOSION HAZARD DATA Flash Point and Method Flammability Limits Lower Upper Non-Flammable 1.Ae Exting.u.ishingMedia: water spray, dry chemical , foam or carbon diox i e. SEecial Fine Fi tin Procedures: Water spray should e used to cool fire exposed containers and o todisperse vapors * Use N I S H/MS HA approved 4 - breathing apparatus when an material i positive pressure self-contained r g � involved in a fire. SECTION V � HEALTH HAZARD DATA TLV: None established . Effects of Over Fx ose Ammonia vapors may' produce mild irritation to eyes and mucous membranes . � ct ' Page QUO PHILIP A. HUNT CHEMICAL CORPORATION NAME: UNIVERSAL &k ELECTROLYTIC COLOR FIXER SECTION v HEALTH HAZARDS , coat First Aid, Skin Contact : Mash affected areas with water until irritation is relieved . Eyes : Immediately flush eyes with water for 15 minutes . Get medical attention i med i at ely. Ingestion: Induce vomiting . Get medical attention immediately, SECTION VI - REACTIVITY DATA Incom atibilit : None. Hazardous Decomposition Products: Sulfur dioxide in small amounts Hazardous Polymerization: Will not occur. Stability: Product is stable SECTION VII SPILL, LEAK, AND DISPOSAL R EDURE S2ill or Leak: Add dry absorbent . Clean up and place in an approved Do's { container and seal . Disposal : Dispose of contaminated product , empty containers and materials usedi cleaning up spills or leaks in a manner approved for this material. . Consult appropriate Federal. , State and Local regulatory agencies to ascertain proper disposal procedures , SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protect io : Not necessary; avoid breathing traces of sulfur di oide vapors . Local Exhaust : Recommended mechanical . Recommended Eye Protection: Safety goggles or glasses TrFotect,ive Gloves : Plastic or rubber gloves Other: Rubber apron SECTION IX - SPECIAL PRE AU I O S AND COMMENTS andl in.g....... __Storing . Keep containers closed and plainly marked . Store in cool , dry area. Avoid contact with eyes , skin or clothing . Do not take internally. gory contact with skin or eyes , wash off with water. Page Approved by i eh eye /nj c August 7 , 1985 PHILIPA. HUNT CHEMICAL CORPORATION GARRET ET MOUNTAIN L 1 VEST PATERSO ,N.J.07424 PRODUCT SAFETY DATA SHEET TELEPHONE: 01- 85.7100 SECTION I � MATERIAL DESCRIPTION Name: E AC LOR-2 STABILIZER & RE LE ISHER Chemical Dame or Synonyms: N.A. t d fading use: stabilize color negatives against � Description: A proprietary aqueous solution of Formal i n and an organic the at i ng a t SECTION II - HAZARDOUS INGREDIENTS Cop0Siion: C.A.S . Number Percent Hazard Data Note: Formaldehyde solution can contain 0 - 1 methanol 67-57-1 10 200 PPm Formaldehyde 50-00-0 37 3 p * :. 8 m acceptable continuous; 10 pp acceptable maximum 30 minutes. SECTION III - PHYSICAL DATA Boiling Point 2 0-218 ° specific Gravity: 1009 Vapor or Pressure 77°F *H HO) : 1 Mn Percent Volatile by Volume H 23 mm at 4 5*F: 1 0 Vapor Density: 1*03 Evaporation Rate water=i : Faster Com fete tea 1 ISolubility �n Water: Appearance and Odors. Colorless solutions strong r pungent , irritating odor * SECTION IV - FIRE AND EXPLOSION HAZARD DATA Fl as Point an method- amnia slit Limits Lower der FF OclosedcuQ er 2 °F` open cu 7 73 tn isineda: dater spray or canon dioxide cial Fire '� ` tl�'I Procedures: Use water spray to knock down irritating Spe vapor. Unusual �r� and ` Explosion Hazards : On heating , formaldehyde solution may r lea ---aFlammable met ano vapor. Use protect ire equipment ent OSHA Class 3 , Combustible Liquid* SECTION V HEALTH HAZARD DATA • for 8-hour working days 1 ppm max . , 3 minutes . L Formaldehyde : Effects of Over Exposure eyes , nose and throat , and may cause core unt - Vapor �. very irritating to � , t i r bronchitis rolonged exposure . Contact cases severe e rr t a t ion, hardening and irritation of skin, dermatitis in some individuals . Swallowing irritates and inflames the mouth , throat and stomach , causing abdominal pain, nausea, vomiting and general collapse . cont'd Page ]. PHILIP A, HUNT CHEMICAL CORPORATION I NAME: - N GACOLOR-2 STABILIZER & REP L NI SH R SECTION V vm HEALTH HAZARDS, co t' First Aid: Remove to fresh air, give artificial respiration or oxygen if not breathing. I nhal at� .• RemoveRemove Skin Contact: Wash skin immediately with plenty water; remove contaminated c , thing Flush immediately with plenty of water for at least 15 minutes and call physician. lion: Calla physician. Induce vomiting finger down throat or with warn salt 6 es water (tablespoon salt per glass) . Repeat till wit is clear, then give milk or white of beaten in water. SECTION VI - REACTIVITY DATA Inc at i.bilit : a►p Reacts with oxidants, phenols; arnines. Acid= & bates catalyze polymerizat'lone Sail Product is stable. OSHA Gass 3A Coubusti.hle Liquid. Keep away Fran sparks and n flames* Store at recommended temperature to avoid polym ri at ion. Conditions to Avoid: Exposure to cold may cause precipitation of polymers, which redissolve slowly on heat irx . hazardous siti n Products* Burning may produce irritating formaldehyde vapor or carbon monoxide Hazardous Rol riati,on: Will not occur, SECTION VI I - SPILL,, LEAKf AND DISPOSAL PROCEDURES Spill or Leak: Ventilate area. Cover with inert, absorbent rr teri.al and remove to disposal container. Flush area with water. Wash with dilute a wnia to remove any residual odor. Disposal: Dispose o r contaminated product, empty containers � materials used in u ills o leaks in a manner rowed for this material* Consult Federal, cleanin g p � is sal procedures. State, and Local regulato agencies to ascertain roper d SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protect ion: If concentration exceeds TLV, use air lane respirator, or Bureau of Mines approved cartride respirator for organic vapors* Local Exhaust: For confined area. Mechanical* Acceptable for small vol r-e transfer. e Protect ion: splash prom ogles or face shield Protective Gloves: Waterproof gloves t avoid skin contact. other: Wash contaminated clothing before re-use. Safety shower, eye wash fountain, protective hand cream. SECTION IX - SPECIAL PRECAUTIONS AND COMMENTS Handling Storing: Keep containers closed and plainly marked. Store in cool, dry place. Other Precautions: WkHNING: Strong irri t ant. Avoid breathing vapors. Avoid contact, with eyes, sin r clothinq. Do not take internally. age Approved by Mr. H. To Viehmeyer/roc August 7, 198