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r: anm TEST REPORT 2022 COMPLIANCE TEST PROGRAM FOR r Prepared For: WHEELABRATOR NORTH ANDOVER, INC 285 Holt Road North Andover, MA 01845 t YWr mr U Prepared By: LMontrose Air Quality Services, LLC Y 2 New Pasture Road, Unit 5 Newburyport, MA 01950 Y� Document Number: NE01 3AS-021420-RT-1 303 Test Dates: October 17-18, 2022 & October 25-28, 2022 RE .Y Cc%, _ ,„r-,ti'� r Wt1f STFR Lt ffi::iL% �M 3 TEST REPOR 2022 COOMPLIAINICEMu a r Prepared For: r WHEELABRATOR NORTHVE , INC r r 285 Holt Road North Andover, MA 01845 r i r s i Prepared By: Montrose Air Quality Services, LLC r 2 New Pasture Road, Unit 5 Newburyport, MA 01950 r Document Number: NE013AS-021420-RT-1303 Test Dates: October 17-18, 2022 & October 25-28, 2022 STAC� !ACCREl9!!-kpI' ,:eX { 'a9 tLTNl?1:kg WAY f taK 4r _. u Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18, 2022&October 25-28,2022 TABLE OF CONTENTS SECTION PAGE 1.0 INTRODUCTION AND SUMMARY..................................................................................... 9 1.1 PROGRAM BACKGROUND........................................................................................ 9 1.2 OUTLINE OF TEST PROGRAM.................................................................................. 9 1.3 TEST PARTICIPANTS ............................................................................. .................. 9 2.0 SUMMARY OF RESULTS ..................................................................................................13 2.1 OVERVIEW................................................................................................................13 2.1.1 Reporting of Non-Detected (ND) Values ............................................................13 2.2 ABORTED AND/OR INVALIDATED RUNS ................................................................13 2.3 PARTICULATE AND METALS BLANK ANALYTICAL RESULTS...............................13 2.4 PCDD/PCDF ANALYTICAL RESULTS.......................................................................14 2.5 CONDENSABLE PARTICULATE BLANK ANALYTICAL RESULTS...........................14 3.0 PROCESS DESCRIPTION AND OPERATION ...................................................................32 3.1 GENERAL..................................................................................................................32 3.2 SOURCE AIR FLOW.................. ...............................................................................32 3.3 OPERATION DURING TESTING...............................................................................32 4.0 SAMPLING AND ANALYTICAL PROCEDURES.................................................................35 4.1 EPA METHOD 1, TRAVERSE POINTS......................................................................35 4.2 EPA METHOD 3, FLUE GAS COMPOSITION ...........................................................39 4.3 EPA METHOD 5/29, PARTICULATE MATTER AND METALS...................................39 4.4 EPA METHOD 202, CONDENSABLE PARTICULATE MATTER ...............................40 4.5 EPA METHOD 26A (MODIFIED), HYDROGEN CHLORIDE AND AMMONIA EMISSIONS........................................................................................................................42 4.6 EPA METHOD 23, POLYCHLORINATED DIBENZO-P-DIOXINS AND POLYCHLORINATED DIBENZOFURANS (4-8 PCDD/PCDF) EMISSIONS .......................43 4.7 EPA METHOD 9 AND 22, VISIBLE AND FUGITIVE EMISSIONS..............................44 4.8 ASH COLLECTION ....................................................................................................44 4.9 EQUIPMENT CALIBRATION......................................................................................44 5.0 QUALITY ASSURANCE AND REPORTING .......................................................................45 5.1 SAMPLING AND ANALYTICAL QA/QC .....................................................................45 5.2 SAMPLING EQUIPMENT MAINTENANCE AND CALIBRATION ...............................46 5.2.1 Equipment Inspection and Maintenance ............................................................46 5.2.2 Equipment Calibrations......................................................................................46 5.3 ANALYTICAL QA/QC RESULTS................................................................................47 NE01 3AS-021420-RT-1 303 Page 2 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18, 2022&October 25-28, 2022 LIST OF TABLES TABLE1-1 TEST LOG..............................................................................................................10 TABLE 1-1 TEST LOG (continued)...........................................................................................11 TABLE1-2 TEST PARTICIPANTS............................................................................................12 TABLE 2-1(A) OVERALL SUMMARY OF TEST RESULTS UNIT NUMBERS 1 AND 2............15 TABLE 2-1(B) AERMOD PREDICTED CONCENTRATIONS COMPARED TO MASSACHUSETTS GUIDELINES' OCTOBER 2022 STACK TEST RESULTS ...16 TABLE 2-1(C) STACK PARAMETERS FOR THE NORTH ANDOVER FACILITY JANUARY 2016 VERSUS OCTOBER 2022 ...................................................................................17 TABLE 2-1(D) QUARTERLY ROLLING AVERAGE MERCURY EMISSIONS SUMMARY UNIT NUMBERS1 AND 2 .............................................................................................18 TABLE 2-1(E) FACILITY AIR FLOW DATA...............................................................................18 TABLE 2-2 SUMMARY OF TEST RESULTS UNIT NO. 1.........................................................19 TABLE 2-3 SUMMARY OF TEST RESULTS UNIT NO. 2.........................................................20 TABLE 2-4 PERFORMANCE TEST BASED OPERATING REQUIREMENTS..........................21 TABLE 2-5 HYDROGEN CHLORIDE AND AMMONIA EMISSIONS UNIT NO. 1 .....................22 TABLE 2-6 PARTICULATE, METALS AND MERCURY EMISSIONS UNIT NO. 1 ....................23 TABLE2-6 CONTINUED ..........................................................................................................24 TABLE 2-6(B) CONDENSABLE PARTICULATE EMISSIONS UNIT NO. 1...............................25 TABLE 2-7 PCDD/PCDF EMISSIONS UNIT NO. 1...................................................................26 TABLE 2-8 HYDROGEN CHLORIDE AND AMMONIA EMISSIONS UNIT NO. 2 .....................27 TABLE 2-9 PARTICULATE, METALS AND MERCURY EMISSIONS UNIT NO. 2....................28 TABLE2-9 CONTINUED ..........................................................................................................29 TABLE 2-10 PCDD/PCDF EMISSIONS UNIT NO. 2...................... ..........................................30 TABLE 2-11 UNIT NO. 1 & 2 ASH PCDD/PCDF CONCENTRATIONS.....................................31 TABLE 3-1 UNIT NO. 1 & NO. 2 OPERATING PARAMETERS SUMMARY, TEST INTERVAL AVERAGES..........................................................................................................34 TABLE 5-1 SUMMARY OF ANALYTICAL QA/QC RESULTS ...................................................48 TABLE 5-2 SUMMARY OF DUPLICATE ANALYSIS FOR MERCURY — UNIT NO. 1 ...............49 TABLE 5-3 SUMMARY OF DUPLICATE ANALYSIS FOR MERCURY - UNIT NO. 2................50 TABLE 5-4 METALS BLANKS AND DUPLICATE ANALYSES RESULTS ................................51 TABLE 5-5 METALS REAGENT BLANKS CORRECTION RESULTS ......................................51 TABLE 5-6 EPA METHOD 5 BLANK CORRECTION RESULTS ..............................................52 TABLE 5-7 PCDD/PCDF BLANKS ANALYSES RESULTS........................... ...........................53 TABLE 5-8 PCDD/PCDF FLUE GAS SURROGATE STANDARDS PERCENT RECOVERIES 54 NE013AS-021420-RT-1 303 Page 3 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 5-9 PCDD/PCDF FLUE GAS EXTRACTION STANDARDS PERCENT RECOVERIES54 TABLE 5-10 PCDD/PCDF ASH EXTRACTION STANDARDS PERCENT RECOVERIES........54 TABLE 5-11 PCDD/PCDF ASH CLEAN UP STANDARDS PERCENT RECOVERIES .............55 LIST OF FIGURES FIGURE 3-1 UNIT NOS. 1 & 2 AIR FLOW SCHEMATIC ..........................................................33 FIGURE 4-1 UNIT NOS. 1 AND 2 SDA INLET TEST LOCATIONS ..........................................37 FIGURE 4-2 UNIT NOS. 1 AND 2 FF OUTLET TEST LOCATION............................................38 NE01 3AS-021420-RT-1 303 Page 4 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28,2022 APPENDICES A - Test Results (Volume 1) Al — Unit No.1 Inlet Hydrogen Chloride A2 — Unit No.1 Inlet Mercury A3— Unit No.1 Outlet Hydrogen Chloride and Ammonia A4— Unit No.1 Outlet Particulate, Metals and Mercury A5— Unit No.1 Outlet PCDD/PCDFs A6— Unit No.1 Outlet Condensable Particulate A7 — Unit No.2 Inlet Hydrogen Chloride A8 — Unit No.2 Inlet Mercury A9— Unit No.2 Outlet Hydrogen Chloride and Ammonia A10— Unit No.2 Outlet Particulate, Metals and Mercury Al 1 — Unit No.2 PCDD/PCDFs B - Field Data (Volume 2) 131 — Unit No.1 Inlet Hydrogen Chloride B2 — Unit No.1 Inlet Mercury B3— Unit No.1 Outlet Hydrogen Chloride and Ammonia B4 — Unit No.1 Outlet Particulate, Metals and Mercury B5 — Unit No.1 Outlet PCDD/PCDFs B6— Unit No.1 Outlet Condensable Particulate B7 — Unit No.2 Inlet Hydrogen Chloride B8— Unit No.2 Inlet Mercury B9 — Unit No. 2 Outlet Hydrogen Chloride and Ammonia B10— Unit No.2 Outlet Particulate, Metals and Mercury 1311 — Unit No.2 PCDD/PCDF 1312 —Ash Sampling B13 — Fugitive Emissions C - Analytical Data (Volume 2) C1 — Hydrogen Chloride, Ammonia, and Condensable Particulate C2 — Particulate, Metals and Mercury C3 — Flue Gas PCDD/PCDFs C4—Ash PCDD/PCDFs D - Calibration Data (Volume 2) D1 —Calibration Documentation D2 —AETB Documentation E - Process Data (Volume 1) El — Process Parameters' Test Interval Averages E2 —Continuous Opacity Monitoring System (COMS) data NE01 3AS-021420-RT-1 303 Page 5 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 STATEMENT OF CERTIFICATION REPORT: 2022 COMPLIANCE TEST PROGRAM FOR UNIT NOS. 1 & 2 All work, calculations, and other activities and tasks performed and presented in this document were carried out by me or under my direction and supervision. I hereby certify that, to the best of my knowledge, Montrose operated in conformance with the requirements of the Montrose Quality Management System and ASTM D7036-04 during this test project. Signature: Date: 12/28/22 Name: Michael Bruni Title: Client Project Manager NE01 3AS-021420-RT-1 303 Page 6 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TEST REPORT DISTRIBUTION LIST TITLE: 2022 COMPLIANCE TEST PROGRAM FOR UNIT NOS. 1 & 2 Date Number of Paper Delivered To Company/Agency Copies 1/3/23 1 David Cribbie Wheelabrator Date Number of Delivered To Company/Agency Electronic Copies 1/3/23 6 David Cribbie Wheelabrator NE01 3AS-021420-RT-1 303 Page 7 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 REVISION DESCRIPTION TITLE: 2022 COMPLIANCE TEST UNIT NOS. 1 & 2 Revision Revision Date Revision Description Number NE01 3AS-021420-RT-1 303 Page 8 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 1.0 INTRODUCTION AND SUMMARY 1.1 PROGRAM BACKGROUND Wheelabrator North Andover, Inc. contracted Montrose Air Quality Services, LLC (Montrose) of Newburyport, Massachusetts to conduct performance tests to demonstrate compliance with 310 CMR 7.08, the facility's Emission Control Plan MBR-98-ECP-005 and the Title V Operating Permit MBR-95-OPP-012. North Andover operates two (2) 750-ton per day mass-fired municipal refuse combustion furnaces. Each combustor is equipped with a spray dryer absorber(SDA) and fabric filter(FF), a Selective Non-Catalytic Reduction (SNCR) NO), control system and powdered activated carbon injection system (PACTS). Combustion gases exit the boiler economizer into the SDA and FF. Flue gases exit the FF to an induced draft fan prior to entering separate flues in a common stack. This report presents the test results for particulate, cadmium, lead, mercury, dioxin/furans, hydrochloric acid, ammonia, and visual/fugitive emissions. Upon request by the Massachusetts Department of Environmental Protection, testing for condensable particulate matter was conducted. These tests were performed concurrently with Method 5 particulate matter testing on Unit No. 1 for informational purposes only. Process ash samples were taken concurrently with the dioxin/furans sampling and analyzed for dioxin/furans. Those results are also presented. In accordance with 40 CFR 60.58b(c)(6) and 60.11(e)(5), Wheelabrator North Andover elects to submit continuous opacity monitoring system (COMS) results in lieu of EPA Method 9 observations to establish compliance with the opacity standard. Only COMS data recorded concurrently with particulate matter sampling are provided in Appendix E in reference to 40 CFR 60.11(e)(6) and the facility operating permit. 1.2 OUTLINE OF TEST PROGRAM Stationary source sampling was performed for Wheelabrator North Andover at their facility in North Andover, Massachusetts on October 17-18 2022 & October 25-28, 2022. A test log summarizing sampling locations, sampling objectives, sampling methods, test dates, and test run numbers for the test program is in Table 1-1. 1.3 TEST PARTICIPANTS A list of personnel involved in this test program is provided in Table 1-2. NE01 3AS-021420-RT-1 303 Page 9 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 1-1 TEST LOG Sampling Location Sampling Parameter Test Method Test Date Test Time Test Run Number Facility Ash Handling/ 10/18/2022 09:40-10:50 Ash Handler-M22-R1 Metals Loading System Fugitive Emissions EPA Method 22 10/27/2022 12:05-13:25 Ash Handler-M22-R2 10/28/2022 10:00-11:10 Ash Handler-M22-R3 Oxygen and Carbon Dioxide EPA Method 3 10/27/2022 09:25-10:25 Unit1-In-M26A-R1 Gas Stream Moisture EPA Method 4 10/27/2022 12:50-13:50 Unit1-In-M26A-R2 HCL EPA Method 26A 10/27/2022 15:50-16:50 Unit1-In-M26A-R3 Unit No.1 SDA Inlet' Volumetric Flow Rate EPA Methods 1 and 2 10/27/2022 09:25-11:35 Unit1-In-M29-R1 Oxygen and Carbon Dioxide EPA Method 3 10/27/2022 12:50-15:13 Unit1-In-M29-R2 Gas Stream Moisture EPA Method 4 10/27/2022 15:50-18:02 Unit1-In-M29-R3 Mercury EPA Method 29 10/28/2022 08:15-10:20 Unit1-In-M29-R4 Volumetric Flow Rate EPA Methods 1 and 2 10/25/2022 07:50-11:55 Unit1-Out-M23-R1 Oxygen and Carbon Dioxide EPA Method 3 10/25/2022 12:15-16:50 Unit1-Out-M23-R2 Gas Stream Moisture EPA Method 4 10/26/2022 07:35-11:40 Unit1-Out-M23-R3 PCDD/PCDFs EPA Method 23 Oxygen and Carbon Dioxide EPA Method 3 10/27/2022 09:25-10:25 Unit1-Out-M26A-R1 Gas Stream Moisture EPA Method 4 10/27/2022 12:50-13:50 Unit1-Out-M26A-R2 HCL and NH3 EPA Method 26A 10/27/2022 15:50-16:50 Unit1-Out-M26A-R3 Unit No.1 FF Outlet' Volumetric Flow Rate EPA Methods 1 and 2 10/27/2022 09:25-11:35 Unit1-Out-M5/29-R1 Oxygen and Carbon Dioxide EPA Method 3 10/27/2022 12:50-15:13 Unit1-Out-M5/29-R2 Gas Stream Moisture EPA Method 4 10/27/2022 15:50-18:02 Unit1-Out-M5/29-R3 Particulate,Cd,Pb,and Hg EPA Method 5/29 10/28/2022 08:15-10:20 Unit1-Out-M5/29-R4 Volumetric Flow Rate EPA Methods 1 and 2 10/27/2022 09:25-11:35 Unit1-Out-M202-R1 Oxygen and Carbon Dioxide EPA Method 3 10/27/2022 12:50-15:13 Unit1-Out-M202-R2 Gas Stream Moisture EPA Method 4 10/27/2022 15:50-18:02 Unit1-Out-M202-R3 Condensable Particulate EPA Method 202 'Unit 1 experienced a superheater tube leak during the week of October 17th and was taken off line for repair. Unit 1 Compliance testing was rescheduled for the week of October 24th,based on vendor availability. N E01 3AS-021420-RT-1 303 Page 10 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 1-1 TEST LOG (CONTINUED) Sampling Location Sampling Parameter Test Method Test Date Test Time Test Run Number Oxygen and Carbon Dioxide EPA Method 3 10/18/2022 09:40-10:40 Unit2-In-M26A-R1 Gas Stream Moisture EPA Method 4 10/18/2022 12:38-13:38 Unit2-In-M26A-R2 HCL EPA Method 26A 10/19/2022 07:50-08:50 Unit2-In-M26A-R3 Unit No.2 SDA Inlet Volumetric Flow Rate EPA Methods 1 and 2 10/18/2022 09:40-11:53 Unit2-In-M29-R1 Oxygen and Carbon Dioxide EPA Method 3 10/18/2022 12:38-15:50 Unit2-In-M29-R2 Gas Stream Moisture EPA Method 4 10/19/2022 07:50-10:00 Unit2-In-M29-R3 Mercury EPA Method 29 10/19/2022 10:22-12:27 Unit2-In-M29-R4 Volumetric Flow Rate EPA Methods 1 and 2 10/18/2022 09:40-13:43 Unit2-Out-M23-R1 Oxygen and Carbon Dioxide EPA Method 3 10/19/2022 07:50-11:54 Unit2-Out-M23-R2 Gas Stream Moisture EPA Method 4 10/19/2022 12:38-16:42 Unit2-Out-M23-R3 PCDD/PCDFs EPA Method 23 Oxygen and Carbon Dioxide EPA Method 3 10/18/2022 09:40-10:40 Unit2-Out-M26A-R1 Unit No.2 FF Outlet Gas Stream Moisture EPA Method 4 10/18/2022 12:38-13:38 Unit2-Out-M26A-R2 HCL and NH3 EPA Method 26A 10/19/2022 07:50-08:50 Unit2-Out-M26A-R3 Volumetric Flow Rate EPA Methods 1 and 2 10/18/2022 09:40-11:53 Unit2-Out-M5/29-RI Oxygen and Carbon Dioxide EPA Method 3 10/18/2022 12:38-15:50 Unit2-Out-M5/29-R2 Gas Stream Moisture EPA Method 4 10/19/2022 07:50-10:00 Unit2-Out-M5/29-R3 Particulate,Cd,Pb,and Hg EPA Method 5/29 10/19/2022 10:22-12:27 Unit2-Out-M5/29-R4 NE01 3AS-021420-RT-1 303 Page 11 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28,2022 TABLE 1-2 TEST PARTICIPANTS Facility Information Source Location: Wheelabrator Technologies Inc. Wheelabrator N. Andover, Inc. 285 Holt Road N. Andover, MA 01845 Project Contact: Mr. David Cribbie Mr. Kevin Beauregard Role: Source/Corporate Contact Source Contact Telephone: 603.393.4973 978.688.9011, ext. 223 Company: Wheelabrator Technologies Inc. Testing Company Information Testing Firm: Montrose Air Quality Services, LLC (Montrose) 2 New Pasture Rd. Unit 5 Newburyport, MA 01950 Contact: Michael Bruni, QSTI Title: Client Project Manager Phone: 978.499.9300 x11306 Email: mbruni@montrose-env.com Dioxin/Furan Laboratory Information Laboratory: SGS North America Wilmington, NC 28403 Contact: Amy Boehm Phone: 910.784.1613 Particulate & Metals Laboratory Information Laboratory: Element One Contact: Ken Smith City, State: Wilmington, NC 28403 Phone: 910.793.0128 Hydrochloric Acid and Ammonia Laboratory Information Laboratory: Enthalpy Analytical, LLC Contact: Ashley Miller City, State: Durham, NC 27713 Phone: 919.850.4392 NE013AS-021420-RT-1303 Page 12 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 2.0 SUMMARY OF RESULTS 2.1 OVERVIEW Tables 2-1(a), 2-1(d), and 2-2 through 2-4 present the emissions results for compounds having specific emissions stated in the applicable permit limits and/or required process parameters. Testing for condensable particulate was conducted on Unit No. 1 for informational purposes only with the data presented without a limit, along with the conventional particulate emissions results. Tables 2-1(b), 2-1(c), and 2-1(e) present a summary of modeling and stack parameters data. Tables 2-5 through 2-10 present run-by-run and sample-by-sample summaries; refer to the "List of Tables" and the "List of Figures" of the "Table of Contents" for a cross reference. Table 2-11 presents process ash dioxin/furans results. Detailed test results are presented in Volume 1, Appendix A; field and analytical data can be found in Volume 2,Appendices B and C, respectively; pertinent calibration data can be found in Volume 2, Appendix D; and detailed process data can be found in Volume 1, Appendix E. 2.1.1 Reporting of Non-Detected (ND)Values For all ND results for all emissions in all test report summary tables, the following guidelines have been followed: • ND values are reported as "ND (detection Limit)"with the detection limit in parentheses in the reported unit (unless otherwise noted on each summary table). • ND values for single test runs results are equal to zero (0) when calculating test averages (unless otherwise noted on each summary table). • ND values for single fractions (i.e. front-half or back half) are equal to zero (0) when calculating collection totals (unless otherwise noted on each summary table). • When all individual test results are ND, the average is reported as"ND (average detection limit)" (unless otherwise noted on each summary table). • When all individual fractions of a single test run (i.e. front-half and back-half) are ND, the total collection is reported as "ND (sum of detection limits)" (unless otherwise noted on each summary table). 2.2 ABORTED AND/OR INVALIDATED RUNS No test runs were aborted or invalidated during this test program. 2.3 PARTICULATE AND METALS BLANK ANALYTICAL RESULTS Particulate matter and metals were measured as part of a combined EPA Method 5/29 sampling train. The acetone reagent blank analytical result was < 0.1 mg residual particulate matter in a 100ml sample. The reagent blank analytical results for the combined front/back half fractions of lead was 0.517 tag. The reagent blank analytical results for the combined front/back half fractions of cadmium was determined to be < 0.2 pg. The reagent blank analytical results for mercury was below analytical detection limits. In accordance with Section 12.8 of EPA Method 5 and Section 12.6 and 12.7 of EPA Method 29, the runs' analytical results were adjusted to account for the reagent blank results for those blanks that were above analytical detection limits, the adjusted NE013AS-021420-RT-1303 Page 13 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 results were used in the concentration and emission rate calculations. Metals and particulate blank corrections are presented in Table 5-5(a) and 5-5(b), respectively. 2.4 PCDD/PCDF ANALYTICAL RESULTS A single symbol is used in the presentation of the analytical results. The symbol indicates results that have special significance and require different procedures in calculations and data interpretation. All symbols surrounded with "ND( )" and "{ }" carry this significance and are addressed as follows: The data reporting procedures outlined in EPA Method 23 are used in presenting all analytical results. For analytical results that were below detection limits, the values are surrounded by "NDQ", and are considered zero for calculating total catch weights per EPA Method 23, Section 9.9. Several results are reported as Estimated Maximum Potential Concentrations (EMPC). EMPC results do not meet all the identification criteria to be positively identified as a dioxin or furan since the integrated ion abundance ratios were not within 15% of the theoretical values specified in Method 23 Section 5.3.2.5, Table 4. For this reason, all EMPC results are enclosed in brackets {} and are considered zero when calculating total dioxin/furans. 2.5 CONDENSABLE PARTICULATE BLANK ANALYTICAL RESULTS The field train recovery blank analytical result was 3.6 mg. In reference to section 9.10 of Method 202, the maximum allowable correction is limited to 2.0 mg. 1.3 mg was used for correction of all analytical catch weights. Analytical results, along with field train recovery blank correction calculations, are provide in Appendix C, Section C1. NE01 3AS-021420-RT-1 303 Page 14 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 2-1(A) OVERALL SUMMARY OF TEST RESULTS UNIT NUMBERS 1 AND 2 310 CMR Test Series' Test Series' Operating 7.08(2) Average for Average for Permit Emission Emission Emission Test Parameter Unit 1 Unit 2 Limit Limits Process Parameters -- -- -- -- Steam Flow, Klb/hr' 165.4 165.9 N/A N/A Inlet Temperature, °F2 309 310 N/A N/A Carbon Feed Rate, Ib/hr3 12 12 N/A N/A Dioxins/Furans -- -- -- -- FF Outlet ng/dscm @ 7%02 5.96 6.62 30 30 Cadmium Emissions -- -- -- -- FF Outlet mg/DSCM @ 7% 02 0.0006 0.0005 0.02 0.02 Hydrogen Chloride Emissions -- -- -- -- SDA Inlet ppm d @ 7% 02 694.6 407.1 N/A N/A FF Outlet ppm,d @7% 02 19.2 6.6 294 or 294 or Removal Efficency (concentration basis) 9723.3% 9801.4% >_95%4 >_95%4 Lead Emissions -- -- -- -- FF Outlet mg/DSCM @ 7% 02 0.006 0.006 0.440 0.400 Mercury Emissions -- -- -- -- SDA Inlet mg/DSCM @ 7%02 0.013 0.022 N/A N/A FF Outlet mg/DSCM @ 7%02 0.001 0.002 0.080 5 0.050, Removal Efficency (concentration basis) 94.0% 92.7% N/A or>_85%5 Opacity -- -- -- -- % 0.6 0.8 10% 10% Particulate Matter Emissions -- -- -- -- FF Outlet mg/DSCM @ 7% 02 1.80 1.03 27 25 Ammonia Emissions -- -- -- -- FF Outlet ppm1d @7% 02 1.75 1.18 107 NIA Condensable Particulate Matter Emissions8 -- -- -- FF Outlet mg/DSCM @ 7% 02 7.58 N/A N/A NIA Fugitive Emissions, % -- -- -- -- (Common Sources for Units 1 and 2) 0% 5% 5% Average stem flow rate during dioxin/furans testing. 2Average FF Inlet Temperature during dioxin/furans testing. 3 Carbon feed rates during mercury or dioxin testing,whichever test series has the higher average. 4 Hydrogen Chloride permit limits are 29ppm„d @ 7%02 or z95%removal efficiency. 5 Single quarterly emission limit in accordance with 310CMR 7.08(2)(8)(2)is 0.080 mg/dscm @ 7%02 6 Mercury limit expressed as 0.050 mg/dscm @ 7%02 or z85%removal efficiency,whichever is less restrictive. Ammonia emission limit is 10 ppm„d @7%02,state only enforceable limit. 8 Condensable Particulate emissions are provided as additional information at the request of the agency. NE01 3AS-021420-RT-1 303 Page 15 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17'18.2022&October 25'28. 3022 TABLE 2-1(B) AERh8OD PREDICTED CONCENTRATIONS COMPARED TO MASSA[HUSETTS GUIDELINES' OCTOBER 2022 STACK TEST RESULTS AERIMOD October 2022 Total (Units 1&2) MA DEP Guidelines Emission RateS2 Modeled Concentrations 24-Hour Annual I Scaling analysis conducted utilizing normalized emissions(Q=lg/s)as determined by Epsilon Associates Inc.AcnxxOoxir Quality Modeling Analysis of the Wheelabrator North Andover Facility using the January 2016 Stack Test Data,March 9,2016. z,wasxemiaionn,tespnesemedfmmTab|eo2-sthmuQh2-z0(ammonia'mma|s,hydmgench|nnde,pCno/pCo|y). z00% boiler availability assumed in calculations(actual=94%>. From March 2016 Epsilon Associates Inc. Modeling Report,Table 2, Maximum Modeled Unit Concentrations (PA/m,per B/s) AERMOD(15181)with Lawrence/Gray Z0O9-2013 met data (AERW1ETl4l34) 24-hour 125718 Annual: 0.07503 NE013AG-021428'RT-1303 Page 1Snf55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 2-1(C) STACK PARAMETERS FOR THE NORTH ANDOVER FACILITY JANUARY 2016 VERSUS OCTOBER 2022 Unit 1 Unit 2 January October January October 2016* 2022** 2016* 2022** Air flow rate (ACFM) 173,400 183,554 180,200 180,748 Exit temp (OF) 288.9 293.5 297.9 288.8 Exit velocity (m/s), Baseline January 2016* 23.29 Exit velocity(m/s),October 2022** 24.04 Exit Velocity%Variation from Baseline -3.2 Average Exit temp (°K), Baseline January 2016* 418.4 Average Exit Temp (°K),October 2022** 417.1 Average Exit Temp(OK)%Variation from Baseline 0.3% *Unit 1 baseline parameters from the Method 23 testing performed on January 13-14,2o16. Unit 2 baseline parameters from the Method 23 testing performed on January 12-13,2o16. ** Unit 1 and Unit 2 October 2022 parameters reflect all isokinetic testing(Methods 23 and 5/29 testing)performed on October 17-18&25-26,2022. NE01 3AS-021420-RT-1 303 Page 17 of 55 Wheelabrator Environmental Systems, Inc.-Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2-Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 2-1(D) QUARTERLY ROLLING AVERAGE MERCURY EMISSIONS SUMMARY UNIT NUMBERS 1 AND 2 1st 2nd 3rd 4th Operating Quarter Quarter Quarter Quarter Four Permit Average Average Average Average Quarter (4 quarter) Emission Test Parameter (712020) (4/2021) (1/2022) (10/2022) Average Limit Unit No. 1 SDA Inlet mg/dscm @ 7% 02 0.040 0.039 0.045 0.013 0.034 N/A FF Outlet mg/dscm @ 7% 02 0.002 0.001 0.002 0.001 0.002 0.028 Removal Efficiency 96% 97% 96% 94% 96% N/A Carbon Feed Rate, Ib/hr 12 12 12 12 12 N/A Unit No. 2 SDA Inlet mg/dscm @ 7% 02 0.051 0.080 0.034 0.022 0,047 N/A FF Outlet mg/dscm @ 7% 02 0.002 0.002 0.002 0.002 0.002 0.028 Removal Efficiency 95% 96% 95% 93% 95% N/A Carbon Feed Rate, Ib/hr 12 12 12 12 12 N/A TABLE 2-1(E) FACILITY AIR FLOW DATA Steam Air Flow Run Time Flow Flue Gas Air Flow Air Flow dscfm Run Number Run Date Start Stop klbs/hr Temp F acfm OZ% cox% dscfm @7%02 Unit 1-M23-Run 1 10/25/2022 7:50 11:55 165.5 295.5 181,012 11.0 8.6 100,205 71,369 Unit 1-M23-Run 2 10/25/2022 12:15 16:18 164.7 295.0 184,450 10.9 8.7 101,454 72,989 Unit 1-M23-Run 3 10/26/2022 7:35 11:40 165.8 296.8 182,881 11.0 8.7 99,454 70,834 Unit 1-Out-M5/29-1 10/27/2022 9:25 11:35 165.3 293.1 185,427 11.5 8.1 100,432 67,918 Unit 1-Out-M5/29-2 10/27/2022 12:50 15:13 165 291.2 183,653 11.2 8.4 100,445 70,094 Unit 1-Out-M5/29-3 10/27/2022 15:50 18:02 166.0 293.0 183,865 10.9 8.6 100,274 72,140 Unit 1-Out-M5/29-4 10/28/2022 8:15 10:20 166.6 290.2 183,589 11.6 8 102,537 68,604 Unit 1 Average 165.6 293.5 183,554 11.2 8.4 100,686 70,564 Unit 2-M23-Run 1 10/18/2022 9:40 13:43 166.7 290.8 179,422 10.4 9.1 97,189 73,416 Unit 2-M23-Run 2 10/19/2022 7:50 11:54 165.5 290.2 181,485 10.9 8.6 101,994 73,377 Unit 2-M23-Run 3 10/19/2022 12:38 16:42 165.4 290.4 176,926 11.1 8.4 98,351 69,341 Unit 2-Out-M5/29-1 10/18/2022 9:40 11:53 166.4 289.1 181,411 10.4 9.1 98,749 74,595 Unit 2-Out-M5/29-2 10/18/2022 12:38 15:50 166.7 290.3 181,719 10.3 9.3 98,625 75,210 Unit2-Out-M5/29-3 10/19/2022 7:50 10:00 165.2 289.3 185,021 10.5 9.0 104,123 77,905 Unit 2-Out-M5/29-4 10/19/2022 10:22 12:27 165.9 281.3 179,255 10.9 8.6 102,599 73,812 Unit 2 Average 166.0 288.8 180,748 10.6 8.9 100,233 73,951 Facility Average 165.8 291.2 182,151 10.9 8.7 100,459 72,257 NE01 3AS-021420-RT-1 303 Page 18 of 55 Wheelabrator Environmental Systems, Inc.-Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2-Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 2-2 SUMMARY OF TEST RESULTS UNIT NO. 1 Operating 310 CMR Permit 7.08(2) Second Fourth Emission Emission Emission Test Parameter First Run Run Third Run Run Average Limit Limits Process Parameters -- -- -- - -- -- -- Steam Flow, Klb/hr' 165.6 164.7 165.8 Not Run 165.4 N/A N/A Inlet Temperature,°F2 309 309 310 Not Run 309 N/A N/A Carbon Feed Rate, Ib/hr' 12 12 12 Not Run 12 N/A N/A Dioxins/Furans -- -- -- - -- -- -- FF Outlet ng/dscm @ 7%02 6.80 5.49 5.58 Not Run 5.96 30 30 Cadmium Emissions -- -- -- -- -- -- FF Outlet mg/DSCM @ 7%OZ 0.0006 0.0006 0.0007 Not Run 0.0006 0.02 0.02 Hydrogen Chloride Emissions -- -- -- - -- -- -- SDA Inlet ppm d @ 7%02 629.1 726.9 727.6 Not Run 694.6 N/A N/A FF Outlet ppm d @7%02 12.9 19.5 25.2 Not Run 19.2 294 or 294 or Removal Efficency(conc. basis) 97.9 97.3 96.5 Not Run 97.2 >_95%° >_95%4 Lead Emissions -- -- -- -- -- -- FF Outlet mg/DSCM @ 7%02 0.007 0.005 0.006 Not Run 0.006 0.440 0.400 Mercury Emissions -- -- -- -- -- -- SDA Inlet mg/DSCM @ 7%02 0.009 0.015 0.011 0.016 0.013 N/A N/A FF Outlet mg/DSCM @ 7%02 0.001 0.001 0.001 0.001 0.001 0.080 5 or 0.050 5 or Removal Efficency(concentration basis) 92.1% 95.3% 93.3% 95.4% 94.0% N/A >_85%5 Opacity -- -- -- -- -- - % 0.6 0.6 0.6 0.7 0.6 10% 10% Particulate Matter Emissions -- -- -- -- -- -- -- FF Outlet mg/dscm @ 7%02 2.64 1.95 0.80 Not Run 1.80 27 25 Ammonia Emissions -- -- -- - -- -- -- FF Outlet ppm d @7%OZ 1.97 1.45 1.81 Not Run 1.75 107 N/A Condensable Particulate Matter Emissions8 -- -- -- - -- -- FF Outlet mg/DSCM @ 7%02 10.23 6.87 5.64 Not Run 7.58 N/A N/A 'Average stem flow rate during dioxin/furans testing. 2Average FF Inlet Temperature during dioxin/furans testing. 3 Carbon feed rate during mercury or dioxin testing,whichever test series has the higher average. °Hydrogen Chloride permit limits are 29ppm„d @ 7%02or>_95%removal efficiency. 5 Single quarterly emission limit in accordance with 310CMR 7.08(2)(8)(2)is 0.080 mg/dscm @ 7%02 5 Mercury limit expressed as 0.050 mg/dscm @ 7%02 or z85%removal efficiency,whichever is less restrictive. 'Ammonia emission limit is 10 ppm„d @7%02,state only enforceable limit. NE01 3AS-021420-RT-1 303 Page 19 of 55 Wheelabrator Environmental Systems, Inc.-Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2-Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 2-3 SUMMARY OF TEST RESULTS UNIT NO. 2 Operating 310 CMR Permit 7.08(2) First Second Third Fourth Emission Emission Emission Test Parameter Run Run Run Run Average Limit Limits Process Parameters -- -- -- -- -- -- -- Steam Flow, Klb/hr' 166.7 165.5 165.4 Not Run 165.9 N/A NIA Inlet Temperature, °FZ 310 310 310 Not Run 310 N/A NIA Carbon Feed Rate, Ib/hr3 12 12 12 Not Run 12 N/A NIA Dioxins/Furans -- -- -- -- -- -- -- FF Outlet mg/DSCM @ 7%O2 4.85 6.77 8.24 Not Run 6.62 30 30 Cadmium Emissions -- -- -- -- -- -- -- FF Outlet mg/DSCM @ 7%O2 0.0004 0.0008 0.0004 Not Run 0.0005 0.02 0.02 Hydrogen Chloride Emissions -- -- -- -- -- -- -- SDA Inlet ppm d @ 7%02 201.6 548.9 470.7 Not Run 407.1 NIA N/A FF Outlet ppm,d @7%02 6.5 3.1 10.1 Not Run 6.6 294 or 295 or Removal Efficency(conc. basis) 96.8 99.4 97.9 Not Run 98.0 >_95%° >_95%4 Lead Emissions -- -- -- -- -- -- -- FF Outlet mg/DSCM @ 7%O2 0.005 0.006 0.006 Not Run 0.006 0.440 0.400 Mercury Emissions -- -- -- -- -- -- -- SDA Inlet mg/DSCM @ 7%O2 0.022 0.031 0.025 0.012 0.022 N/A N/A FF Outlet mg/DSCM @ 7%O2 0.003 0.002 0.001 0.001 0.002 0.028 5 or 0.050 5 or Removal Efficency(concentration basis) 85.9% 94.6% 96.8% 93.6% 92.7% >_85%5 >85%5 Opacity -- -- -- -- -- % 0.7 0.8 0.8 0.8 0.8 10% 10% Particulate Matter Emissions -- -- -- -- -- -- -- FF Outlet mg/dscm @ 7%O2 1.56 0.57 0.97 Not Run 1.03 27 25 Ammonia Emissions -- -- -- -- -- -- -- FF Outlet ppm d @7%02 1.43 1.30 0.82 Not Run 1.18 107 N/A 'Average stem flow rate during dioxin/furans testing. 2Average FF Inlet Temperature during dioxin/furans testing. 9 Carbon feed rate during mercury or dioxin testing,whichever test series has the higher average. °Hydrogen Chloride permit limits are 29ppm„d @ 7%02or>_95%removal efficiency. 5 Single quarterly emission limit in accordance with 310CMR 7.08(2)(8)(2)is 0.080 mg/dscm @ 7%02 6 Mercury limit expressed as 0.050 mg/dscm @ 7%02 or>_85%removal efficiency,whichever is less restrictive. Ammonia emission limit is 10 ppm„d @7%02,state only enforceable limit. e Condensable Particulate emissions are provided as additional information at the request of the agency. NE01 3AS-021420-RT-1 303 Page 20 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 2-4 PERFORMANCE TEST BASED OPERATING REQUIREMENTS Maximum Demonstrated Maximum Demonstrated Average Carbon Mass C Unit No. MWC Unit Load, Klb/hr' PMCD Temperature, °FZ Feed Rate, Ib/hr3 1 165.8 310 12 2 166.7 310 12 'The highest 4-hour arithmetic average load(steam flow)achieved during four consecutive hours during the dioxin/furan emission tests. See 310 CMR 7.08(2)(c). 2 The highest 4-hour arithmetic average temperature achieved at the particulate matter control device(fabric filter) inlet during four consecutive hours during the dioxin/furan emission tests. See 310 CMR 7.08(2)(c). 3 The estimated hourly average carbon mass feed rate during the mercury and dioxin/furan,whichever is greater,emission tests. See 310 CMR 7.08(h)(4)(a)and/or 40 CFR 60.58b(m)(1). NE01 3AS-021420-RT-1 303 Page 21 of 55 Wheelabrator Environmental Systems, Inc.-Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2-Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 2-5 HYDROGEN CHLORIDE AND AMMONIA EMISSIONS UNIT NO. 1 Unit 1 Spray Dryer Absorber Inlet Stack Temp F 521.0 530.2 532.2 527.8 Stack Moist. % 15.6 15.7 15.5 15.6 Stack 02 % 9.9 9.8 10.0 9.9 Stack CO2 % 9.5 9.6 9.3 9.5 Meter Volume dscf 44.908 45.140 44.769 44.9 Meter Volume dscm 1.272 1.278 1.268 1.3 Hydrogen Chloride -- -- -- -- -- Catch Wt mg 959 1124 1095 -- Concentration mg/dscm 754.0 879.1 864.0 832.4 Concentration ppmvd@7%0Z 629.1 726.9 727.6 694.6 Unit 1 Fabric Filter Outlet Stack Temp F 293.1 291.2 293.0 292.4 Stack Moist. % 19.9 17.7 18.9 18.9 Stack 02 % 11.5 11.2 11.4 11.4 Stack CO2 % 8.1 8.4 8.1 8.2 Volumetric Flowrate acfm 185,139 182,732 183,572 183,814 Volumetric Flowrate dscfm 101,190 102,878 101,560 101,876 Meter Volume dscf 45.706 49.277 47.200 47.394 Meter Volume dscm 1.294 1.395 1.337 1.342 Hydrogen Chloride -- -- -- -- -- Catch Wt mg 17.16 28.76 34.91 -- Concentration mg/dscm 13.26 20.61 26.12 20.00 Concentration ppm d@7%02 12.9 19.5 25.2 19.2 Emission Rate Ib/hr 5.03 7.94 9.94 7.64 Ammonia -- -- -- -- -- Catch Wt, mg mg 1.220 1.000 1.172 -- Conc.,mg/dscm mg/dscm 0.94 0.72 0.88 0.85 Concentration ppm d@7%O2 1.97 1.45 1.81 1.75 Emission Rate Ib/hr 0.36 0.28 0.33 0.32 HCL Removal Efficiency % by conc. 97.9 97.3 96.5 97.2 NE01 3AS-021420-RT-1 303 Page 22 of 55 Wheelabrator Environmental Systems, Inc.-Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2-Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 2-6 PARTICULATE, METALS AND MERCURY EMISSIONS UNIT NO. 1 -Summary of Compliance Parameters- Parameter Units Run 1 Run 2 Run 3 Run 4 Average Test Date MM/DD/YY 10/27/2022 10/27/2022 10/27/2022 10/28/2022 Start Time HH:MM 9:25 12:50 15:50 8:15 End Time HH:MM 11:35 15:13 18:02 10:20 Process Parameters -- -- - Steam Flow Klb/hr 165.3 165.0 166.0 166.6 165.7 Inlet Temperature F 310 309 309 309 309 Carbon Feed Rate Ib/hr 12 12 13 12 12 Unit 1 Spray Dryer Absorber Inlet Stack Temp F 528.4 531.0 536.2 531.7 531.8 Stack Moist. % 17.2 16.0 16.2 16.6 16.5 Stack 02 % 9.8 10.0 10.2 10.0 10.0 Stack COZ % 9.6 9.5 9.3 9.5 9.5 Volumetric Flowrate acfm 176924 178656 180994 181594 179542 Volumetric Flowrate dscfm 77788 79417 79871 81766 79711 Meter Volume dscf 80.571 86.543 84.664 85.169 84.237 Meter Volume dscm 2.282 2.451 2.397 2.412 2.385 Isokinetic Rate % 102.3 107.6 104.7 102.9 104.4 Mercury -- -- - Total Catch Wt ug 16 28 19.4 30.7 23.5 Concentration ug/dscm@7%0Z 8.56 14.72 10.51 16.33 12.53 Concentration mg/dscm@7%02 0.009 0.015 0.011 0.016 0.013 Emission Rate Ib/hr 1.99E-03 3.44E-03 2.42E-03 3.90E-03 2.94E-03 Emission Rate ib/MMbtu 8.09E-06 1.38E-05 9.89E-06 1.52E-05 1.18E-05 Unit 1 Fabric Filter Outlet Stack Temp F 293.1 291.2 293.0 290.2 291.9 Stack Moist. % 20.6 20.1 20.1 20.2 20.3 Stack 02 % 11.5 11.2 10.9 11.6 11.3 Stack CO2 % 8.1 8.4 8.6 &0 8.3 Volumetric Flowrate acfm 185427 183653 183865 183589 184133 Volumetric Flowrate dscfm 100432 100445 100274 102537 100922 Meter Volume dscf 101.165 101.419 100.828 103.906 101.829 Meter Volume dscm 2.865 2.872 2.855 2.942 2.883 Isokinetic Rate % 103.9 104.2 103.7 104.5 104.1 Filterable Particulate -- -- -- -- -- Total Catch Wt mg 5.1 3.9 1.6 Not Run -- Concentration mg/dscm@7%02 2.64 1.95 0.80 Not Run 1.80 Concentration gr/dscf@7%02 1.15E-03 8.51 E-04 3.48E-04 Not Run 7.84E-04 Emission Rate ib/hr 0.672 0.513 0.216 Not Run 0.467 Emission Rate Ib/MMBtu 2.51E-03 1.84E-03 7.60E-04 Not Run 1.70E-03 NE013AS-021420-RT-1303 Page 23 of 55 Wheelabrator Environmental Systems, Inc.-Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2-Test Report Test Dates: October 17-18,2022&October 25-28,2022 TABLE 2-6 CONTINUED Parameter Units Run 1 Run 2 Run 3 Run 4 Average Cadmium -- Total Catch Wt ug 1.250 1.170 1.400 Not Run -- Concentration ug/dscm@7%02 0.65 0.58 0.68 Not Run 0.64 Concentration mg/dscm@7%02 0.0006 0.0006 0.0007 Not Run 0.0006 Emission Rate Ib/hr 1.64E-04 1.53E-04 1.84E-04 Not Run 1.67E-04 Emission Rate Ib/MMbtu 6.12E-07 5.72E-07 6.88E-07 Not Run 6.24E-07 Lead -- Total Catch Wt ug 13.1 10.9 12.4 Not Run Concentration ug/dscm@7%0z 6.75 5.43 6.03 Not Run 6.07 Concentration mg/dscm@7%02 0.007 0.005 0.006 Not Run 0.006 Emission Rate Ib/hr 1.72E-03 1.43E-03 1.63E-03 Not Run 1.59E-03 Emission Rate Ib/MMbtu 6.41E-06 5.32E-06 6.08E-06 Not Run 5.94E-06 Mercury -- Total Catch Wt ug 1.31 1.39 1.45 1.4 -- Concentration ug/dscm@7%02 0.68 0.69 0.71 0.74 0.70 Concentration mg/dscm@7%02 0.001 0.001 0.001 0.001 0.001 Emission Rate Ib/hr 1.72E-04 1.82E-04 1.91E-04 1.85E-04 1.83E-04 Emission Rate Ib/MMbtu 6.42E-07 6.55E-07 6.71 E-07 6.86E-07 6.63E-07 Mercury Removal Efficiency %by conc. 92.1% 95.3% 93.3% 95.4% 94.0% NE01 3AS-021420-RT-1 303 Page 24 of 55 Wheelabrator Environmental Systems, Inc.-Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2-Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 2-6(B) CONDENSABLE PARTICULATE EMISSIONS UNIT NO. 1 -Summary of Compliance Parameters- Parameter Units Run 1 Run 2 Run 3 Average Test Date MM/DD/YY 10/27/2022 10/27/2022 10/27/2022 -- Start Time HH:MM 9:25 12:50 15:50 -- End Time HH:MM 11:35 15:13 18:02 -- Process Parameters -- -- -- -- -- Steam Flow Klb/hr 165.3 165.0 166.0 165.4 Inlet Temperature `F 310 309 309 309 Carbon Feed Rate Ib/hr 12 12 13 12 Unit 1 Fabric Filter Outlet Stack Temp F 293.1 291.2 293.0 292.4 Stack Moist. % 20.6 20.0 20.4 20.3 Stack 02 % 11.6 11.1 11.1 11.3 Stack CO2 % 8.0 8.6 8.6 8.4 Volumetric Flowrate acfm 187043 185123 185527 185898 Volumetric Flowrate dscfm 101310 101323 100824 101152 Meter Volume dscf 91.72 92.14 89.86 91.2 Meter Volume dscm 2.60 2.61 2.54 2.6 Condensable Particulate -- -- -- -- -- Total Catch Wt. mg 19.8 14.6 12.1 -- Blank Wt.correction mg2 2.0 2.0 2.0 -- Total Net Catch Wt. mg 17.8 12.6 10.1 -- Concentration mg/dscm@7%02 10.23 6.87 5.64 7.58 Concentration gr/dscf@7%02 0.0045 0.0030 0.0025 0.0033 Emission Rate Ib/hr 2.60 1.84 1.50 2.0 Emission Rate Ib/MMBtu 0.0097 0.0064 0.0053 0.0071 Flue gas Flowrate for runs 1,2and 3 originates from pitot tube measurements from isokinetic filterable particulate sampling train. 2 The field train recovery blank weight was 2.0 mg. NE01 3AS-021420-RT-1 303 Page 25 of 55 Wheelabrator Environmental Systems, Inc.-Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2-Test Report Test Dates: October 17-18,2022&October 25-28,2022 TABLE 2-7 PCDD/PCDF EMISSIONS UNIT NO. 1 -Summary of Compliance Parameters- Parameter Units U1-M23-Run 1 U1-M23-Run 2 U1-M23-Run 3 Average Test Date MM/DD/YY 10/25/2022 10/25/2022 10/26/2022 Start Time HH:MM 7:50 12:15 7:35 End Time HH:MM 11:55 16:18 11:40 -- Steam Flow Klb/hr 165.6 164.7 165.8 165.4 Inlet Temperature °F 309 309 310 309 Carbon Feed Rate Ib/hr 12 12 12 12 Stack Temp °F 295.5 295.0 296.8 295.7 Stack Moist. % 19.5 20.1 20.1 19.9 Stack 02 % 11.0 10.9 11.0 10.97 Stack CO2 % 8.6 8.7 8.7 8.67 Stack Flow acfm 181,012 184,450 182,881 182,781 Stack Flow dscfm 100,205 101,454 99,454 100,371 Meter Volume dscf 197.576 197.676 191.787 195.679 Meter Volume dscm 5.595 5.598 5.431 5.541 Isokinetic Rate % 102.6 101.4 100.3 101.4 Dioxins/Furans-2,3,7,8 PCDDs and PCDDs 2005 WHO/EPA Toxic Equivalent(Tetra-Octa) Total pg (Including NDs&EMPCs) 260 215 198 -- ng/dscm @ 7%O: (Including NDs&EMPCs) 0,065 0.053 0.051 0.057 Total pg (Not Including NDs&EMPCs) 231.0 166 152 -- ng/dscm @ 7%OZ (Not Including NDs&EMPCs) 0.058 0.041 0.039 0.046 Ibs/hour (Not Including NDs&EMPCs) 1.55.E-08 1.13.E-08 1.04.E-08 1.24.E-08 1991 MA Toxic Equivalent(Tetra-Octa)' Total pg (Including NDs&EMPCs) 942 804 747 -- ng/dscm @ 7%02 (Including NDs&EMPCs) 0.236 0.200 0.193 0.210 Total pg (Not Including NDs&EMPCs) 899 739 697 -- ng/dscm @ 7%OZ (Not Including NDs&EMPCs) 0.226 0.183 0.180 0.196 Ibs/hour (Not Including NDs&EMPCs) 6.03.E-08 5.02.E-08 4.78.E-08 5.28.E-08 Dioxins/Furans-Total PCDDs and PCDFs Tetra-Octa PCDD/PCDDs Total pg (Including NDs&EMPCs) 27900 23500 22400 -- ng/dscm @ 7%% (Including NDs&EMPCs) 7.00 5.83 5.79 6.21 Total pg (Not Including NDs&EMPCs) 27,100 22,100 21,600 -- ng/dscm @ 7%02 (Not Including NDs&EMPCs) 6.80 5.49 5.58 5.96 Ibs/hour (Not Including NDs&EMPCs) 1.82E-06 1.50.E-06 1.48.E-06 1.60.E-06 MA Toxic Equivalents include a factor for tri-CDD and tri-CDFs,but results are not included.310 CMR 7.08(2)(c)defines dioxin/furans as tetra-octa NE01 3AS-021420-RT-1 303 Page 26 of 55 Wheelabrator Environmental Systems, Inc.-Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2-Test Report Test Dates: October 17-18,2022&October 25-28,2022 TABLE 2-8 HYDROGEN CHLORIDE AND AMMONIA EMISSIONS UNIT NO. 2 -Summary of Compliance Parameters- Parameter Units Run 1 Run 2 Run 3 Average Test Date MM/DD/YY 10/18/2022 10/18/2022 10/19/2022 -- Start Time HH:MM 9:40 12:38 7:50 -- End Time HH:MM 10:40 13:38 8:50 -- Process Parameters __ __ -- __ Steam Flow Klb/hr 166.4 167.5 165.6 166.5 Inlet Temperature 'F 310 310 310 310 Carbon Feed Rate Ib/hr 13 12 11 12 Unit 2 Spray Dryer Absorber Inlet Stack Temp F 452.7 454.8 451.8 453.1 Stack Moist. % 9.0 19.1 16.1 14.7 Stack Oz % 9.8 9.7 9.8 9.8 Stack CO2 % 9.6 9.7 9.6 9.6 Meter Volume dscf 46.538 43.709 46.735 45.661 Meter Volume dscm 1.318 1.238 1.323 1.29 Hydrogen Chloride -- -- -- -- -- Catch Wt mg 321 829 753 -- Concentration mg/dscm 243.8 669.7 569.3 494.3 Concentration ppmvd@7%O2 201.6 548.9 470.7 407.1 Unit 2 Fabric Filter Outlet Stack Temp F 289.1 290.3 289.3 289.5 Stack Moist. % 20.5 21.0 18.2 19.9 Stack 02 % 10.4 10.4 10.6 10.5 Stack CO2 % 9.1 9.1 8.9 9.0 Volumetric Flowrate acfm 181,462 181,999 185,121 182,861 Volumetric Flowrate dscfm 98,615 98,126 103,965 100,235 Meter Volume dscf 46.504 46.755 47.999 47.086 Meter Volume dscm 1.317 1.324 1.359 1.333 Hydrogen Chloride -- -- -- -- -- Catch Wt mg 9.83 4.75 15.42 -- Concentration mg/dscm 7.46 3.59 11.35 7.47 Concentration ppm d@7%02 6.5 3.1 10.1 6.6 Emission Rate Ib/hr 2.76 1.32 4.42 2.83 Ammonia -- -- -- -- -- Catch Wt, mg mg 1.007 0.919 0.586 -- Conc.,mg/dscm mg/dscm 0.76 0.69 0.43 0.63 Concentration ppm d@7%O2 1.43 1.30 0.82 1.18 Emission Rate Ib/hr 0.28 0.26 0.17 0.24 HCL Removal Efficiency % by conc. 96.8 99.4 97.9 98.0 NE013AS-021420-RT-1303 Page 27 of 55 Wheelabrator Environmental Systems, Inc.-Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2-Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 2-9 PARTICULATE, METALS AND MERCURY EMISSIONS UNIT NO. 2 -Summary of Compliance Parameters- Parameter Units Run 1 Run 2 Run 3 Run 4 Average Test Date MM/DD/YY 10/18/2022 10/18/2022 10/19/2022 10/19/2022 Start Time HH:MM 9:40 12:38 7:50 10:22 End Time HH:MM 11:53 15:50 10:00 12:27 Process Parameters -- -- -- -- -- Steam Flow Klb/hr 166.4 166.7 165.2 165.9 166.1 Inlet Temperature F 310 310 310 310 310 Carbon Feed Rate Ib/hr 13 12 13 11 12 Unit 2 Spray Dryer Absorber Inlet Stack Temp F 465.0 473.5 458.8 460.4 464.4 Stack Moist. % 18.6 18.5 17.0 15.3 17.3 Stack OZ % 9.2 8.8 9.6 10.0 9.4 Stack CO2 % 10.1 10.5 9.8 9.3 9.9 Volumetric Flowrate acfm 172679 173134 166257 172492 171140 Volumetric Flowrate dscfm 78942 78528 78374 82774 79655 Meter Volume dscf 81.818 81.980 84.583 82.958 82.835 Meter Volume dscm 2.317 2.321 2.395 2.349 2.346 Isokinetic Rate % 102.4 103.1 106.6 98.98 102.8 Mercury -- -- Total Catch Wt ug 42.6 63.0 48.1 22.7 44.1 Concentration ug/dscm@7%02 21.8 31.2 24.7 12.1 22.4 Concentration mg/dscm@7%02 0.022 0.031 0.025 0.012 0.022 Emission Rate Ib/hr 5.44E-03 7.98E-03 5.90E-03 3.00E-03 5.58E-03 Emission Rate Ib/MMbtu 2.07E-05 2.94E-05 2.33E-05 1.18E-05 2.13E-05 Unit 2 Fabric Filter Outlet Stack Temp F 289.1 290.3 289.3 281.3 287.5 Stack Moist. % 20.4 20.5 18.0 17.5 19.1 Stack 02 % 10.4 10.3 10.5 10.9 10.5 Stack COZ % 9.1 9.3 9.0 8.6 9.0 Volumetric Flowrate acfm 181411 181719 185021 179255 181852 Volumetric Flowrate dscfm 98749 98625 104123 102599 101024 Meter Volume dscf 97.052 98.391 108.475 101.023 101.235 Meter Volume dscm 2.748 2.786 3.072 2.861 2.867 Isokinetic Rate % 101.4 102.9 107.5 101.58 103.3 Filterable Particulate -- -- -- -- -- Total Catch Wt mg 3.2 1.2 2.2 Not Run -- Concentration mg/dscm@7%02 1.56 0.57 0.97 Not Run 1.03 Concentration gr/dscf@7%02 6.80E-04 2.48E-04 4.23E-04 Not Run 4.51 E-04 Emission Rate Ib/hr 0.436 0.160 0.283 Not Run 0.293 Emission Rate Ib/MMBtu 1.47E-03 5.29E-04 9.17E-04 Not Run 9.73E-04 NE01 3AS-021420-RT-1 303 Page 28 of 55 Wheelabrator Environmental Systems, Inc.-Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2-Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 2-9 CONTINUED Parameter Units Run 1 Run 2 Run 3 Run 4 Average Cadmium -- - Total Catch Wt ug 0.791 1.610 0.959 Not Run -- Concentration ug/dscm@7%02 0.381 0.758 0.417 Not Run 0.519 Concentration mg/dscm@7%02 0.0004 0.0008 0.0004 Not Run 0.0005 Emission Rate Ib/hr 1.06E-04 2.14E-04 1.22E-04 Not Run 1.47E-04 Emission Rate Ib/MMbtu 3.59E-07 7.22E-07 3.90E-07 Not Run 4.90E-07 Lead -- - Total Catch Wt ug 9.683 12.083 14.883 Not Run -- Concentration ugldscm@7%02 4.664 5.686 6.475 Not Run 5.608 Concentration mg/dscm@7%0Z 0.005 0.006 0.006 Not Run 0.006 Emission Rate Ib/hr 1.30E-03 1.60E-03 1.89E-03 Not Run 1.60E-03 Emission Rate Ib/MMbtu 4.40E-06 5.42E-06 6.05E-06 Not Run 5.29E-06 Mercury -- - Total Catch Wt ug 6.390 3.580 1.800 1.590 -- Concentration ug/dscm@7%02 3.078 1.685 0.783 0.772 1.580 Concentration mg/dscm@7%02 0.003 0.002 0.001 0.001 0.002 Emission Rate Ib/hr 8.60E-04 4.75E-04 2.29E-04 2.14E-04 4.44E-04 Emission Rate Ib/MMbtu 2.90E-06 1.57E-06 7.40E-07 7.34E-07 1.49E-06 Mercury Removal Efficiency %by conc. 85.9% 94.6% 96.8% 93.6% 92.7% NE01 3AS-021420-RT-1 303 Page 29 of 55 Wheelabrator Environmental Systems, Inc.-Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2-Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 2-10 PCDD/PCDF EMISSIONS UNIT NO. 2 -Summary of Compliance Parameters- Parameter Units U2-M23-Run 1 U2-M23-Run 2 U2-M23-Run 3 Average Test Date MM/DD/YY 10/18/2022 10/19/2022 10/19/2022 -- Start Time HH:MM 9:40 7:50 12:38 - End Time HH:MM 13:43 11:54 16:42 -- Steam Flow Klb/hr 166.7 165.5 165.4 165.9 Inlet Temperature °F 310 310 310 310 Carbon Feed Rate Ib/hr 12 12 12 12 Stack Temp °F 290.8 290.2 290.4 290.5 Stack Moist. % 20.6 18.0 18.9 19.2 Stack OZ % 10.4 10.9 11.1 10.8 Stack CO2 % 9.1 8.6 8.4 8.7 Stack Flow acfm 179,422 181,485 176,926 179,277 Stack Flow dscfm 97,189 101,994 98,351 99,178 Meter Volume dscf 196.568 205.844 201.774 201.395 Meter Volume dscm 5.566 5.829 5.714 5.703 Isokinetic Rate % 103.9 103.7 105.4 104.3 Dioxin/Furans-2,3,7,8 PCDDs and PCDFs 2005 WHO/EPA Toxic Equivalent(Tetra-Octa) Total pg (Including NDs&EMPCs) 190 315 424 -- ng/dscm @ 7%Oz (Including NDs&EMPCs) 0.045 0.075 0.105 0.075 Total pg (Not Including NDs&EMPCs) 141 292 232 -- ng/dscm @ 7%O: (Not Including NDs&EMPCs) 0.034 0.070 0.058 0.054 Ibs/hour (Not Including NDs&EMPCs) 9.22.E-09 1.91.E-08 1.50.E-08 1.44.E-08 1991 MA Toxic Equivalent(Tetra-Octa)' Total pg (Including NDs&EMPCs) 713 1020 1220 -- ng/dscm @ 7%O: (Including NDs&EMPCs) 0.170 0.243 0.303 0.239 Total pg (Not Including NDs&EMPCs) 659 944 1,110 -- ng/dscm @ 7%% (Not Including NDs&EMPCs) 0.157 0.225 0.276 0.219 lbs/hour (Not Including NDs&EMPCs) 4.31.E-08 6.19.E-08 7.16.E-08 5.88.E-08 Dioxins/Furans-Total PCDDs and PCDFs Tetra-Octa PCDD/PCDFs Total pg (Including NDs&EMPCs) 21300 30000 33800 -- ng/dscm @ 7%02 (Including NDs&EMPCs) 5.07 7.15 8.39 6.87 Total pg (Not Including NDs&EMPCs) 20,400 28,400 33,200 -- ng/dscm @ 7%02 (Not Including NDs&EMPCs) 4.85 6.77 8.24 6.62 Ibs/hour (Not Including NDs&EMPCs) 1.33E-06 1.86.E-06 2.14.E-06 1.78.E-06 MA Toxic Equivalents include a factor for tri-CDD and tri-CDFs,but results are not included.310 CMR 7.08(2)(c)defines dioxin/furans as tetra-octa NE01 3AS-021420-RT-1 303 Page 30 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18, 2022&October 25-28, 2022 TABLE 2-11 UNIT NO. 1 & 2 ASH PCDD/PCDF CONCENTRATIONS parts-per-trillion, (pg/g, dry) Combined Ash Target Anal Composite Fly Ash Composite 2,3,7,8-TCDD 7.56 33.2 1,2,3,7,8-PeCDD 19.9 85.7 1,2,3,4,7,8-HxCDD 19.5 82.1 1,2,3,6,7,8-HxCDD 33.9 154 1,2,3,7,8,9-HxCDD 24.6 118 1,2,3,4,6,7,8-HpCDD 240 1170 OCDD 514 2260 Totals -- -- TCDDs 200 803 PeCDDs 303 1300 Hx,CDDs 460 2180 HpCDDs 487 2340 OCDD 514 2260 Total PCDDs 1964 8883 Target Anal -- -- 2,3,7,8-TCDF 36.9 165 1,2,3,7,8-PeCDF 43.6 200 2,3,4,7,8-PeCDF 56.1 250 1,2,3,4,7,8-HxCDF 48 216 1,2,3,6,7,8-HxCDF 49 237 2,3,4,6,7,8-HxCDF 53.8 251 1,2,3,7,8,9-HxCDF (0.837)' (2.84)' 1,2,3,4,6,7,8-HpCDF 153 602 1,2,3,4,7,8,9-HpCDF 18.8 82.8 OCDF 74.3 255 Totals -- -- TCDFs 1070 4700 PeCDFs 708 3260 HxCDFs 458 2190 HpCDFs 232 944 OCDF 74.3 255 Total PCDFs 2542 11349 Total PCDDs/PCDFs 45002 202002 1 Not Detected or EMPC.Refer to Section 2.4 for more information 2 As reported in the SGS North Andover report provided in Appendix C. NE013AS-021420-RT-1303 Page 31 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 3.0 PROCESS DESCRIPTION AND OPERATION 3.1 GENERAL Wheelabrator North Andover operates a facility consisting of two identical 750 ton/day mass-fired municipal waste combustion units which produce steam for generation of electricity which is sold to the local utility company. Each combustor is equipped with a spray dryer absorber (SDA) and fabric filter (FF), a Selective Non Catalytic Reduction (SNCR) NOx control system and powdered activated carbon injection system (PACTS). Combustion gases exit the boiler economizer into the SDA and FF. Flue gases exit the FF to an induced draft fan prior to entering separate flues. The locations tested were Unit Nos. 1 and 2 SDA Inlets and FF Outlets. Unit Nos. 1 and 2 are identical. 3.2 SOURCE AIR FLOW Figure 3-1 is an air flow schematic which shows the passage of flue gases exhausted from Unit Nos. 1 and 2 boilers. 3.3 OPERATION DURING TESTING Table 3-1 provides run averages for operational data for all Unit No. 1 and No. 2 emissions sampling intervals. Detailed data supplied by Wheelabrator North Andover is presented in Appendix E. NE01 3AS-021420-RT-1 303 Page 32 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 FIGURE 3-1 UNIT NOS. 1 & 2 AIR FLOW SCHEMATIC Atmosphere Stack ID Fan Test Location Fabric Filter Carbon Spray Dryer Injection Absorber ® t 4 est location F— Economizer F— Boiler Unit Nos. 1 and 2 are Identical NE01 3AS-021420-RT-1 303 Page 33 of 55 m -1 CD 0 D a 3 cD sv s 1p M m � cn m v N W Off ° j � com N NF 1p CCr DAS Data Averaged Over Test Intervals Z (D o 0 Wheelabrator North Andover ®) J L. W : FROM DAS FROM DISTRIBUTIVE CONTROL(PLC)SYSTEM Z a) (D WSteam Carbon FF Feed SDA SDA Slurry Diluton Percent Fabric Fabric Urea ® 0 O Flow Flow Inlet Water Inlet Total Flow H2O Slurry Filter Filter Flow N.) = Unit Run Time Temp Flow Temp Flow Flow Delta-P Outlet N C.� Test No. No. Date Start I Stop klbs/hr Ibs/hr deg F Klb/hr deg F gpm gpm gpm % In.H2O INWC GPH 90 N O N 1 1 10/27/2022 09:25 11:35 165.3 12 310 163.0 513 43.7 7.4 36.3 16.9 7.6 -10.5 5.4 Z 9 CD z CD TSP/Metals 1 2 10/27/2022 12:50 15:13 165.0 12 309 132.4 518 43.9 8.8 35.1 20.1 7.5 -10.3 5.5 ® 0 N to (M29;MS/M29) 1 3 10/27/2022 15:50 18:02 166.0 12 309 163.5 522 45.0 8.1 36.9 17.8 7.6 -10.4 7.2 N O Inlet/Outlet 1 4 10/28/2022 08:15 10:20 166.6 12 309 164.4 518 44.3 7.8 36.5 17.5 7.5 -10.3 4.7 EY n ® (CD go . Average 165.7 12 309 155.8 518 44.2 8.0 36.2 18.1 7.6 -10.4 5.7 -0 N N I Condensable PM 1 1 10/27/2022 9:25 11:35 165.3 12 310 163.0 513 43.7 7.4 36.3 16.9 7.6 -10.5 5.4 M Ut I (M202) 1 2 10/27/2022 12:50 15:13 165.0 12 309 132.4 518 43.9 8.8 35.1 20.1 7.5 -10.3 5.5 X N) -- CD CD Outlet 1 3 10/27/2022 15:50 18:02 166.0 12 309 163.5 522 45.0 8.1 36.9 17.8 7.6 -10.4 7.2 y® D N CCD Average 165.4 12 309 153.0 518 44.2 8.1 36.1 18.3 7.6 -10.4 6.0 s� N HCL/NH3 1 1 10/27/2022 9:25 10:25 165.9 12 310 162.9 511 43.3 7.5 35.8 17.4 7.6 -10.5 5.6 pzpy O CD C O W (M26A) 1 2 10/27/2022 12:50 13:50 165.5 12 309 162.9 519 44.2 8.6 35.7 19.3 7.6 -10.4 5.1 YI O O Inlet/Outlet 1 3 10/27/2022 15:50 16:50 165.5 12 310 162.8 520 44.4 8.3 36.2 18.6 7.5 -10.3 7.8 D "0 z O- Average 165.6 12 310 162.9 517 44.0 8.1 35.9 18.4 7.6 -10.4 6.2 D PCDD/PCDF 1 1 10/25/2022 7:50 11:55 165.6 12 309 163.2 501 39.6 7.9 31.7 20.0 6.9 -9.7 6.5 M > (M23) 1 2 10/25/2022 12:15 16:50 164.7 12 309 162.6 508 41.8 7.9 33.4 18.8 7.1 -9.9 5.5 (1) D Q- Outlet 1 3 10/26/2022 1 7:35 11:40 165.8 12 310 163.7 508 41.4 7.0 34.3 17.0 7.2 -10.0 5.0 ic (CD Average 165.4 12 309 163.2 506 40.9 7.6 33.1 18.6 7.1 -9.8 5.7 M CD TSP/Metals 2 1 10/18/2022 9:40 11:53 166.4 13 310 164.6 471 27.1 8.7 18.4 31.7 6.1 -8.5 7.9 m (M29;MS/M29) 2 2 10/18/2022 12:38 15:50 166.7 12 310 163.9 478 27.6 6.8 20.8 24.5 6.1 -8.5 8.6 Inlet/Outlet 2 3 10/19/2022 7:50 10:00 165.2 13 310 162.8 476 27.2 8.0 19.2 29.1 6.2 -8.7 6.8 (/) 2 4 10/19/2022 10:22 12:27 165.9 11 310 163.4 476 27.4 9.5 17.9 34.5 6.1 -8.5 6.2 (q Average 166.1 12 310 163.7 475 27.3 8.3 19.1 30.0 6.1 -8.6 7.4 C HCL/NH3 2 1 10/18/2022 9:40 10:40 166.4 13 310 164.1 471 27.9 10.1 17.8 35.9 6.2 -8.7 7.3 9 (M26A) 2 2 10/18/2022 12:38 13:38 167.5 12 310 164.3 476 27.4 6.6 20.8 24.0 6.1 8.6 9.0 9 Inlet/Outlet 2 3 10/19/2022 7:50 8:50 165.6 11 310 163.6 475 26.5 6.6 19.9 25.0 6.2 -8.7 6.4 D Average 166.5 12 310 164.0 474 27.3 7.8 19.5 28.3 6.2 -2.9 7.6 X PCDD/PCDF 2 1 10/18/2022 9:40 13:43 166.7 12 310 164.5 473 27.2 7.9 19.2 29.0 6.1 -8.5 8.2 (M23) 2 2 10/19/2022 7:50 11:14 165.5 12 310 163.0 476 27.1 8.5 18.7 31.0 6.1 -8.6 6.2 Outlet 2 3 SO/19/2022 12:38 16:42 165.4 12 310 162.8 481 28.0 8.6 19.4 30.5 6.1 -8.6 8.1 m Average 165.9 12 310 163.4 477 27.4 8.3 19.1 30.2 6.1 -8.6 7.5 Z Cn X C D r Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 .0 SAMPLING AND ANALYTICAL PROCEDURES All sampling and analytical procedures were those recommended by the United States Environmental Protection Agency (EPA), and the approved sampling protocol submitted to the Massachusetts Department of Environmental Protection (MassDEP). This section provides brief descriptions of the sampling and analytical procedures used for this test program. TABLE 4-1 TEST PROCEDURES Parameter Measurement Principle Reference Method Volumetric flow rate Pitot/temperature traverse EPA 1, 2 Molecular Weight Orsat EPA 3 Moisture Impinger weight gain EPA 4 Particulate Matter Gravimetric analysis EPA 5 Metals(Cd, Pb & Hg) ICP and CVAA EPA 29 HCI Ion chromatography EPA 26A, modified Ammonia Ion chromatography EPA 26A, modified Condensable Particulate Gravimetric analysis EPA 202, modified PCDD/PCDF high resolution gas chromatography/ EPA 23 (ALT-052) mass spectroscopy (HRGC/HRMS) Opacity COMS n/a Fugitive Emissions Visible reading EPA 22 4.1 EPA METHOD 1, TRAVERSE POINTS Units 1 and 2 are identical. The measurement site for the SDA inlet is located in a vertically- oriented circular duct at the economizer exit. The SDA inlet duct inside diameter is 105 inches. The nearest upstream disturbance is a breaching for a change in duct shape at about 294 inches (2.8 diameters) and the nearest downstream disturbance is a bend at 100 inches (0.95 diameters) from the sampling ports. This sampling location meets the minimum requirements specified by EPA Method 1. Two (2) 4-inch test ports are located at 900 offset on the side of each duct. A schematic of the SDA inlet sampling location is shown in Figure 4-1. The measurement site for the FF outlet is located in the rectangular vertical duct above the induced draft fan. Six (6) 4-inch sampling ports are provided in the 124 inch wide and 76 inch NE01 3AS-021420-RT-1 303 Page 35 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 deep duct. The duct equivalent diameter is 94.2 inches. The nearest upstream disturbance is a bend at about 204 inches (2.17 equivalent diameters) and the nearest downstream disturbance is the ID Fan at 48 inches (0.51 equivalent diameters form the sampling ports. This sampling traverse points were used to conduct the emission measurements at this location. A schematic of the FF outlet sampling locations is shown in Figure 4-2. Access to the test platform is provided via an outside stairway. For all isokinetic sampling, a 24-point velocity and/or particulate traverse in a total of six parallel directions (4 points per port) was made at the sampling location using a type-S pitot tube and sampling nozzle in accordance with EPA Methods 2 and 5 procedures. Gas temperatures were measured using a calibrated Type K thermocouples and digital readout devices. NE01 3AS-021420-RT-1 303 Page 36 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28,2022 FIGURE 4-1 UNIT NOS. I AND 2 SDA INLET TEST LOCATIONS -- Stack Configuration Description Distance Equivalent Diameters A Upstream (A) 1001, 0.95 C Downstream (B) 294" 2.8 Diameter(C) 105" NA 0 Number of Ports 2 NA Port Diameter 4" NA B Port Length 101, NA Isokinetic Sampling Traverse Points(per diameter)— not including port sleeve Flow Traverse Points %of diameter Distance(inches) 1 2.1 2.2 2 6.7 7.0 3 11.8 12.4 4 17.7 18.6 5 25.0 26.3 6 35.6 37.4 7 64.4 67.6 8 75.0 78.8 9 82.3 86.4 10 88.2 92.6 11 93.3 98.0 12 97.9 102.8 1 —All measurements were verified onsite. A cyclonic flow check performed to determine the absence of cyclonic prior to testing. NE01 3AS-021420-RT-1 303 Page 37 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 FIGURE 4-2 UNIT NOS. 1 AND 2 FF OUTLET TEST LOCATION From Baghouse Stack Configuration Description Distance Equivalent Diameters Flow Upstream (A) 204 inches 2.17 Downstream (B) 48 inches 0.51 A Duct Width (C) 124 inches NA Duct Depth (D) 76 inches NA Number of Ports 4 NA Port Diameter 4 inches NA Port Length 8.5 inches NA O O O O O O Traverse Points Distance Probe Marking (inches) (inches) B 1 9.5 18.0 2 28.5 37.5 3 47.5 56.0 To ID Fan 4 66.5 75.0 �— C • • • • • • i Traverse Points ® ® ® ® ® ® 6 ports D _______________________________ 4 points/port • ' • • ' ' • 24 point total i i F E D C B A NE01 3AS-021420-RT-1 303 Page 38 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 4.2 EPA METHOD 3, FLUE GAS COMPOSITION Dry gas molecular weight was determined concurrently with all sampling trains using the oxygen and carbon dioxide measurements following EPA Method 3 (Orsat Analyzers). Samples were collected according to procedures specified in EPA Method 3 (incorporated by ASTM D 7459-08, by reference). Stack gas moisture was measured in accordance with EPA Method 4 procedures for the condensation option contained with EPA Method 23, EPA Method 29, EPA Method 26A, and EPA Method 5. 4.3 EPA METHOD 5/29, PARTICULATE MATTER AND METALS A combined EPA Method 5/29 was used to collect particulate matter and Metals (Hg, Cd, and Pb) stack gas samples at the FF outlet sampling locations. A concurrent Method 29 sampling train collected mercury only at the SDA inlet sampling locations. A minimum of four 120-minute runs were conducted. A reagent blank was recovered for blank correction and a field blank was taken for contamination and/or recovery problems. The field blank consisted of a complete sampling train which was assembled as though to collect a sample, but flue gas was not pulled through the sampling train. The field blank was leak checked the same number of times as a sampling train used during a run. The train was placed at the sampling location for the duration of one run. The Train was returned to the laboratory and disassembled for recovery using the same procedure used to recover actual samples. The field blank was obtained using a train that was previously used to collect at least one sample. The sampling probe and filter exit were maintained at 248°F (±25°F) throughout testing, while the sample exit temperature was maintained at less than 680F throughout testing. The sampling train consisted of a basic EPA Method 5 train with a glass nozzle, Teflon-coated stainless-steel union, glass probe liner, glass filter holder, tared quartz glass fiber filter, Teflon filter support, and seven impingers. The first impinger (a knockout) was empty while the second and third impingers each contained 100 ml of 5% HNO3/ 10% H2O2 absorbing solution. The fourth impinger was left empty. The fifth and sixth impingers each contained 100 ml of 4% KMn04/ 10% H2SO4, while the seventh impinger contained a pre-weighed amount of silica gel, approximately 200 grams. Prior to mobilization, all glassware was washed in hot water and detergent, thoroughly rinsed with tap water, soaked for at least 8 hours in a 10% HNO3 bath, rinsed clean with HPLC-grade H2O, rinsed with HPLC-grade acetone, allowed to dry, sealed and labeled. Prior to sampling, a "K-factor" was established for setting the isokinetic sampling rate. The train was assembled and leak checked. After the probe and filter box reached the desired operating temperature, the probe was placed in the stack, and isokinetic sampling commenced at a rate of 0.5 to 1.0 cfm. Sampling consisted of collecting a sample isokinetically for 5 minutes at each of the 24 sample points previously identified in Figures 4-1 and 4-2 for a total of 120 minutes per run. Following each test run, the probe was recovered at the stack test platform level, while the remainder of the sample was recovered in the field laboratory. Each train yielded the seven sample fractions detailed below: • Fraction A: The nozzle, probe, and filter holder front half were first rinsed and brushed (with a Teflon probe brush)with a 100 ml of acetone into a prepared 250ml amber glass bottle. NE01 3AS-021420-RT-1 303 Page 39 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28,2022 • Fraction B: The nozzle, probe, and filter holder front half were subsequently be rinsed with a 100 ml of 0.1 N HNO3 into a prepared 250ml amber glass bottle. • Fraction C: The filter was carefully removed and placed in a labeled petri dish. • Fraction D: The first, second and third impingers were first measured for net condensate gain. These impingers, filter support, filter holder back half and connecting glassware were subsequently rinsed three times each with a total of 100 ml of 0.1 N HNO3 into a prepared 1000ml amber glass bottle. • Fraction E: The fourth impinger was first measured for net condensate gain, before subsequently being rinsed three times with a total of 100 ml of 0.1 N HNO3 into a prepared 250ml amber glass bottle. • Fraction F: The fifth and sixth impingers were first measured for net condensate gain, before subsequently being rinsed three times with a total of 100 ml of 4% KMn04/ 10% H2SO4, followed by being rinsed three times with a total of 100 ml of DI H2O. • Fraction G: The fifth and sixth impingers were then rinsed with another 100ml of DI H2O, then 25 ml of 8N HCl, followed by a last 100ml rinse of HPLC grade DI H2O all into a separate 250ml glass amber bottle. Particulate samples were analyzed gravimetrically in accordance with EPA Method 5. The acetone rinses were evaporated to dryness in tared beakers. All beakers and filters are subsequently stored in a desiccator for 24 hours then weighed at 6-hour intervals until a constant weight is obtained. The results are reported to the nearest 0.1 mg. Once gravimetric sampling is complete, the particulate from the acetone rinse residue is reconstituted with nitric acid. Then this solution and the filter are analyzed with the remaining sample fractions for cadmium, lead, mercury in accordance with EPA Method 29 via ICP (cadmium, lead)or CVAA(mercury). All analyses were performed by Element One of Wilmington, N.C. 4.4 EPA METHOD 202, CONDENSABLE PARTICULATE MATTER Condensable particulate matter (CPM) was measured using EPA Method 202 (dry impinger method), this sampling train was operated as part of the EPA Method 5 PM sampling. Essentially, the back half of the PM Method 5 train was modified to include the specific requirements of Method 202 (CPM). Sampling was conducted non-isokinetically for a period of 120 minutes per run. The Method 202 components of the sampling train include a vertical water-jacketed coil condenser, a dry hybrid impinger (initially containing no water), a dry modified Greenburg-Smith impinger(initially containing no water), a glass filter holder with an untared Teflon filter and Teflon filter support, a thermocouple mounted at the outlet of the filter holder, a modified Greenburg- Smith impinger containing 100 ml water, and a modified Greenburg-Smith containing approximately 200 grams of silica gel., The dry impingers are isolated from the wet/sigel impingers in a divided impinger bucket. The wet/sigel impingers are always kept well iced to maintain the sigel outlet temperature below 68°F. The dry impingers are immersed in the other half of the impinger bucket which contains water for the water-jacketed coil condenser. Ice is NE01 3AS-021420-RT-1 303 Page 40 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 slowly added to the water as required to maintain the dry Teflon filter outlet temperature between 65-85°F. Prior to mobilization, all Method 202 glassware was washed with soapy water, rinsed with tap water, DI H2O, acetone and finally hexane. All glassware was capped with Teflon tape. The Method 202 portion of the sampling sequence is as follows: the sample exits the Method 5 filter at 2480F ±25°F. The sample is routed through a glass coil condenser which is designed to reduce the sample temperature to 850F or less through the use of a pump which circulates water through the condenser coil jacket. Upon exiting the condenser coil, the sample is routed in series through an empty knockout (short stem) impinger and modified Greenburg-Smith impinger prior to being routed through an unheated condensable PM filter housing containing an untared Teflon filter and Teflon filter support (also equipped with a thermocouple to monitor the filter outlet gas temperature). The outlet of this dry filter is to be regulated between 65-85°F. The remainder of the sampling train consists of a third impinger initially loaded with 100ml of DiH2O and a fourth impinger initially loaded with a known amount of silica gel. The train field blank was collected from a sampling train after the first or second sampling run by assembling the EPA Method 202 train, purging it at 14 liters/minute for 60 minutes, and recovering it in the manner of a test run per Method 202 instructions. These samples were analyzed along with the reagent blank and the emissions test runs. Prior to sampling, the train was carefully assembled and successfully leak checked. After the probe and filter box reach the desired operating temperature of 2480F±25°F and verification of the proper process conditions, the probe was placed in the stack, and non-isokinetic sampling was initiated. During sampling the temperature of the dry Teflon filter outlet was maintained at 65-85OF by heated or cooling the impinger ice bath as required (in almost all cases, ice is slowly added to the impinger bucket to maintain this temperature). All impingers were weighed before sampling to obtain the initial weight. The first two impingers (hybrid and standard) are initially empty. Following each test run, the sampling train was first leak checked at the highest vacuum observed during the test run prior to being disassembled. Once disassembled, the Method 5 front half portion of the sampling train is recovered following Method 5 procedures. For EPA Method 202, the first two "dry" impingers (prior to the dry Teflon filter) are weighed for moisture net gain. The contents of the last two "wet/sigel" impingers are weighed for condensate gain and discarded. The sampling train components from the water-jacketed coil condenser through the dry filter holder were purged with nitrogen for 60 minutes at a rate of at least 14 liters per minute while maintaining the dry filter outlet temperature at 65-85°F. A "purge stem" was added to the hybrid impinger to facilitate bubbling. Following the purge, impinger contents are poured into a sample recovery bottle (Method 202 Fraction A). The dry Teflon filter is transferred to a separate sample jar (Method 202 Fraction C). Subsequently, each of the components in the dry impinger section (condenser coil through front half of the condensable PM filter housing) are rinsed twice with DI water into the water sample jar(Fraction A). Lastly, each of these components is rinsed first with acetone (once) and then hexane (twice) into a separate sample recovery bottle (Method 202 Fraction B). NE01 3AS-021420-RT-1 303 Page 41 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 4.5 EPA METHOD 26A (MODIFIED), HYDROGEN CHLORIDE AND AMMONIA EMISSIONS Hydrogen chloride emissions (SDA inlet and FF outlet) and Ammonia emissions (FF outlet only) were measured utilizing EPA Method 26A (modified). A minimum of three 60-minute runs were conducted simultaneously at the SDA inlet and the FF Outlet of each unit. A reagent blank was recovered for blank correction. This method utilizes a Method 26A sampling train, with the exceptions that no nozzle was used and it was constant rate sampling, making it "modified". The train consisted of a quartz glass probe liner, a glass filter holder, heated quartz fiber filter with Teflon support frit and five impingers. The first impinger contained 50 ml of 0.1 N sulfuric acid while the second and third impingers were each loaded with 100ml of 0.1 N sulfuric acid (H2SO4). The fifth impinger contained approximately 200 grams of silica gel. The optional cyclone was not be used at either location, since neither gas stream is saturated with moisture. This was confirmed at the end of, and during, sampling by visual inspection. A modified Method 26A has been approved by the EPA and the facility's air permit and used for HCI compliance testing at other MWC facilities. Modified EPA Method 26A is preferable over the Method 26 (midget impinger) train, because it is easier to maintain probe sample temperatures. The probe and filter housing were heated to or above stack temperature up to 320OF at the FF outlets and up to 350°F at the SDA inlet. This can eliminate the potential for moisture condensation which can scrub HCI, and result in low-biased HCI emissions measurements. Prior to mobilization, all glass and Teflon train components were thoroughly cleaned in hot soapy water, thoroughly rinsed with DI water, allowed to dry, and sealed with parafilm. The trains were operated at a constant sampling rate of about 0.75 cubic feet per minute (cfm). Pretest preparations, preliminary determinations and leak check procedures were those outlined in EPA Method 5. The sample was collected through a heated glass probe and a heated filter, followed by a series of chilled impingers where the stack gas HCI, and NH3 where applicable, were absorbed. After completion of sampling, the train was leak checked and transferred to the sample recovery trailer. In accordance with the method, all impingers were weighed before and after sampling and the data recorded. The first, second and third impinger solutions (sulfuric acid impingers) were quantitatively recovered from the train using deionized water, and transferred to separate sample bottles with Teflon-lined lids. These impingers and their connecting glassware (starting at the filter back half) were rinsed three times with deionized water into its designated sample jar. The fourth, fifth and sixth impinger solutions (sodium hydroxide impingers) were weighed and then discarded. The contents of the silica gel impinger were weighed and discarded. HCI and Ammonia samples were analyzed via ion chromatography (IC) by Enthalpy Analytical of Durham, N.C. NE01 3AS-021420-RT-1 303 Page 42 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 4.6 EPA METHOD 23, POLYCHLORINATED DIBENZO-P-DIOXINS AND POLYCHLORINATED DIBENZOFURANS (4-8 PCDD/PCDF) EMISSIONS Emissions of 4-8 PCDD/PCDFs were measured using an EPA Method 23 sampling train at the Unit No. 1 and Unit No. 2 FF Outlet. The sampling train consisted of a glass nozzle, stainless steel Teflon coated union, glass probe liner, quartz filter, Teflon frit, glass coil condenser, sorbent resin trap placed vertically in-line after the filter and before the first impinger, and a hybrid first impinger. The usual EPA Method 5 condenser impingers followed these components. The sorbent resin trap contained pre-cleaned XAD-2 resin. Prior to mobilization, all sorbent traps, XAD-2 resin, and glass fiber filters were pre-cleaned in accordance with the method. Traps were then packed with the XAD-2 resin and shipped on ice along with the filters just prior to mobilization. Prior to mobilization, all glassware and Teflon train components prior to the XAD trap were soaked in hot soapy water, rinsed three times with tap water, rinsed three times with deionized water, rinsed three times with HPLC-grade acetone, HPLC-grade toluene, and allowed to dry. After drying, all glassware (minus the probe liner) was baked at 450OF for 2 hours. All prepared components were then sealed with hexane-rinsed aluminum foil. All recovery tools, including Teflon-coated spatulas and forceps, Teflon dispenser bottles and Teflon recovery mat were also hexane-rinsed. Cotton gloves were worn during all preparation and recovery procedures. The sampling train was set up in accordance with Method 23 procedures while wearing cotton gloves. The first impinger was empty in order to collect any condensate that may have come through the sorbent trap. The second and third impingers each contained 100 ml of deionized distilled water. The fourth impinger was left empty. The fifth impinger contained a pre-weighed amount of indicating silica gel. The sorbent trap and condenser coil were both jacketed in a recirculating ice water bath designed to maintain the temperature at the trap exit of less than 20°C for maximum organic compound adsorption. The train was operated in the same manner as an EPA Method 5 train during each test run and operated isokinetically for a period of 240-minutes per run. Following sampling, the train was disassembled while wearing cotton gloves, and sealed with hexane-rinsed foil or Teflon. In the field lab, the impingers and XAD-2 trap were weighed for moisture determination. Acetone was used to rinse, in triplicate, all components of the sampling train prior to the XAD-2 trap. This includes the nozzle, probe liner, filter holder, coil condenser and connecting glassware. After these rinses, the coil condenser was filled with acetone and allowed to soak for three separate 5-minute periods. All acetone rinses/soakings were combined into one single sample jar. All rinses/soakings were then repeated using toluene and placed in a separate jar as requested by the laboratory. The acetone and toluene rinses were combined later at the laboratory after the concentrating step to avoid "bumping" the samples due to the different boiling points. The train components were recovered in four separate fractions: 1)filter; 2) XAD- 2 trap; 3) front half through coil condenser acetone rinse; and 4) front half through coil condenser toluene rinse. All rinses were conducted in triplicate. EPA Method 23 also specifies that methylene chloride be used as a rinse, in the same manner as acetone and toluene. EPA has issued an Approved Alternative Method 052 (ALT-052, Approved Method 23 Modifications for Incinerators and Waste Combustors) eliminating the methylene chloride portion of the Method 23 sample recovery. All Method 23 sorbent traps and NE013AS-021420-RT-1303 Page 43 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 particulate filters were refrigerated or kept on ice until they were delivered to the laboratory for analysis. All samples were extracted, combined, and aliquots analyzed for Polychlorinated Dibenzo-p- Dioxins and Dibenzofurans (PCDD/DF) by high resolution gas chromatography coupled with high resolution mass spectrometry (HRGC/HRMS). All EPA Method 23 analysis was conducted by SGS North America in Wilmington, NC. 4.7 EPA METHOD 9 AND 22, VISIBLE AND FUGITIVE EMISSIONS Wheelabrator North Andover operates and maintains a continuous opacity monitoring system (COMS) on the FF Outlet of all units. In accordance with 40 CFR 60.58b(c)(6) as provided under 40 CFR 60.11(e)(5), opacity data results from the COMS was used in lieu of EPA Method 9 observations to establish compliance with the opacity standard. COMS data recorded concurrently with particulate matter sampling are provided in Appendix E in reference to 40 CFR 60.11(e)(6) and the facility operating permit. EPA Method 22 fugitive emissions were determined by a qualified EPA Method 9 (opacity) observer (although this is not required by Method 22). The observer was in a position where the light source (of suitable intensity) was not directly behind the unit/process being observed. Observations were taken in 20-minute intervals with breaks of at least 5 minutes (but no more than ten minutes) between each interval. After the observer found a suitable observation site (as defined by the Method), a stopwatch was started at time zero. If at any point during the sampling interval, fugitive emissions were observed (water vapor is not considered a fugitive emission), a second stopwatch was run until fugitives were no longer visible. The second stopwatch was started with each subsequent fugitive emission and stopped when fugitives were no longer visible. At the end of each 20-minute interval, the total time (from the second stopwatch) that fugitives were visible during the interval were recorded. Three 1-hour observation periods (consisting of three 20-minute intervals each) were performed at the facility ash handling and storage points. 4.8 ASH COLLECTION Ash sampling was conducted concurrently with EPA Method 23 sampling on April 13th-14th, following Wheelabrator North Andover's Ash Sampling and Analysis Plan. Sampling was conducted by SAK Environmental and final composite samples of combined ash and fly ash were transferred to Montrose in order to deliver to the contract laboratory. Samples were analyzed for tetra- through octa- (4-8) PCDDs/PCDFs, according to EPA Method 8290. Table 2-11 presents the PCDD/PCDF concentrations of the Combined and Fly Ash composite samples. .9 EQUIPMENT CALIBRATION Pertinent equipment calibration documentation is reproduced in Appendix D. NE01 3AS-021420-RT-1 303 Page 44 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28,2022 5.0 QUALITY ASSURANCE AND REPORTING 5.1 SAMPLING AND ANALYTICAL QA/QC Montrose Air Quality Services (MAQS), its management, and employees are committed to consistently providing the highest quality services to our clients that is delivered with honesty and integrity. These services result in data that are accurate, precise, timely, and legally defensible in support of our clients' environmental compliance, engineering evaluation, and other needs. A corporate culture of quality and continuous improvement is maintained as a positive and desirable aspect of business operations. Both qualitative and quantitative factors contribute to field measurement uncertainty and should be taken into consideration when interpreting test program results. Whenever possible, Montrose personnel reduce the impact of these uncertainty factors through the use of approved and validated test methods. In addition, Montrose personnel perform routine instrument and equipment calibrations and ensure that the calibration standards, instruments, and equipment used during test events meet, at a minimum, test method specifications as well as the specifications of our Quality Manual and ASTM D 7036-04. Limitations of the various methods, instruments, equipment, and materials to be utilized during this test have been reasonably considered, but the ultimate impact of the cumulative uncertainty to the final data may not be quantifiable. All calculations were conducted in strict accordance with the equations found in the individual Methods. Strict QA/QC protocols were followed during all phases of this project. These protocols included: • QA objectives for measurement data; • Data reduction; • Internal QC; • Calibration of equipment; • Corrective action, if necessary; and • Use of standardized field data sheets. These specific procedures in addition to Montrose's usual high standard of quality control aid to validate the results obtained during this test program. As the majority of our emissions testing work are done for compliance purposes, strict QC procedures are incorporated into our everyday work performance. The remainder of this section summarizes specific quality assurance aspects of the test program. NE01 3AS-021420-RT-1 303 Page 45 of 55 Wheelabrator Environmental Systems, Inc. —Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 5.2 SAMPLING EQUIPMENT MAINTENANCE AND CALIBRATION Our Quality Assurance Program is in place to ensure consistent standards for our equipment maintenance, calibration schedule, quality control acceptance limits, and any necessary corrective action. Below are specific examples of our control system. 5.2.1 Equipment Inspection and Maintenance • Each critical piece of field equipment is assigned a unique identification number to allow tracking of its calibration history • All field equipment is visually inspected prior to testing and includes pre-test calibration checks • Glassware is visually inspected prior to testing • Preliminary stack flow and temperature measurements will be taken to assure correct isokinetic sampling • Reagents are made fresh daily, when required. A new reagent blank is retained for every new stock of reagent. 5.2.2 Equipment Calibrations Montrose's meter boxes, pitot tubes, thermocouples and barometers are maintained in accordance with specifications set forth in EPA "Quality Assurance Handbook for Air Pollution Measurement Systems - Volume III Stationary Source Specific Methods" Section 3.3.5 dated January 15, 1980 and with manufactures suggested procedures. A summary is presented below: • Dry Gas Meter and Orifice Meter/EPA Method 5-All dry gas meters are calibrated using calibrated critical orifices, according to 40 CFR 60, Appendix A, Method 5, Section 16.2. The orifice meters in the meter control boxes are calibrated against the calibrated critical orifices and checked against the dry gas meters to which they are attached. All isokinetic sampling dry gas meters are post calibrated using Alternative Test Method-009. • Balance -All analytical balances are calibrated in the field against ANSI Class 3 weights. • Thermocouples - All type K thermocouples are calibrated against NIST traceable thermometers at three points. The first point is in an ice bath (0°C), the second point is in boiling water (100°C) and the third point is in heated oil (-2200C). Isokinetic sampling probes thermocouples are post calibrated using Alternate Test Method-011. • S-type or Standard Pitot Tubes - All standard and Type "S" stainless steel pitot tubes are designed to meet the dimensional criteria set forth in Method 2, therefore a coefficient of 0.99 (standard) or 0.84 (Type "S") is used. NE01 3AS-021420-RT-1 303 Page 46 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18, 2022&October 25-28, 2022 5.3 ANALYTICAL QA/QC RESULTS Analytical measurements of precision and accuracy were made on stack gas samples, and are detailed in each analytical report. In Table 5-1, a summary of the relevant analytical QA/QC results is provided. In Tables 5-2 & 5-3, the results for the duplicate analysis of each mercury sample fraction is provided. In Table 5-4 presents results for metals blanks and duplicate analyses. Table 5-5 presents metals reagent blanks correction results. Table 5-6 presents Method 5 particulate reagent blank correction results. Table 5-7 presents PCDD/PCDFs blanks analytical results. Table 5-8 presents results for flue gas PCDD/PCDFs surrogate standard percent recoveries. Table 5-9 presents results for flue gas PCDD/PCDFs extraction standards percent recoveries. Tables 5-10 and 5-11 presents results for ash PCDD/PCDFs standards percent recoveries. NE01 3AS-021420-RT-1 303 Page 47 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 5-1 SUMMARY OF ANALYTICAL QA/QC RESULTS Test Method Parameter QA/QC Criteria QA/QC Status 0.5 mg or 1%of the total Constant Weight weight less the tare <0.5 mg EPA Method 5 Paticulate weight;whichever is matter greater Acetone Blank <_0.001% by weight <0.1 mg/1 00 ml <0.0001%by weight EPA Method 26A Matrix Spike Recovery N/A 97.3- 111% Hydrogen Chloride Duplicate Analysis <_ 10% <_5.0% Reagent Blank N/A 7.46 ug ND Matrix Spike Recovery 80- 120% 94.0-97.6% EPA Method 26A Ammonia Duplicate Analysis <_ 10% <_5.0% Reagent Blank N/A 2.78 ug ND Matrix Spike Recovery 75- 125% 79 -86% (Cd) 107- 123%(Pb) EPA Method 29 Metals Duplicate Analysis <_20%from average <7.9(Cd) p y g <_ 1.1% (Pb) Reagent Blank(front/back- <0.2ug (Cd) half combined) N/A .517ug (Pb) Matrix Spike Recovery 75- 125% 89- 101% EPA Method 29 Mercury Duplicate Analysis <_ 10% <_7.1% Reagent Blank N/A <_0.5 ug Tetra-hexa extraction 40- 130% 63.3- 159/o° standards recovery Hepta-octa extraction 25- 130% 56.2- 159% EPA Method 23 standards recovery (PCDD/PCDFs)' Surrogate standards 70- 130% 46- 111% recovery Field Blank N/A 38 pg Total Tetra-hexa extraction 40- 130% 78.1 - 130% standards recovery ADL S007 Ash Sample Hepta-octa extraction o 0 25- 130/0 65.1 - 130/o PCDD/PCDFs' standards recovery Clean-Up standards 70- 130% 98-131 % recovery Refer to SGS Laboratory Raport QC Annotations page NE01 3AS-021420-RT-1 303 Page 48 of 55 Wheelabrator Environmental Systems, Inc.-Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2-Test Report Test Dates: October 17-18,2022&October 25-28,2022 TABLE 5-2 SUMMARY OF DUPLICATE ANALYSIS FOR MERCURY- UNIT NO. 1 Fraction Empty Front half H2O2/HNO3 Impinger K N04 HCI Sample Analysis (1A) (213) (3A) (313) (3C) #1, Pg 0.140 13.8 0.304 0.649 0.676 U1 Inlet R1 #2, pg 0.142 13.8 0.306 0.656 0.682 RPD 1.4% 0.3% 0.4% N/A 0.8% #1, Pg 0.249 26.5 ND 0.2 ND 0.5 0.629 U1 Inlet R2 #2, pg 0.250 26.7 ND 0.2 ND 0.5 0.624 RPD 0.5% 0.5% N/A N/A 0.8% #1, Pg 0.246 28.1 ND 0.2 ND 0.5 0.643 U1 Inlet R2 Dup #2, pg 0.243 28.4 ND 0.2 ND 0.5 0.653 RPD 1.1% 1.0% N/A N/A 1.5% #1, Pg 0.168 18.4 0.215 ND 0.5 0.561 U1 Inlet R3 #2, pg 0.170 18.5 0.218 ND 0.5 0.562 RPD 1.0% 0.2% 1.4% N/A 0.3% #1, Pg 0.333 28.8 0.656 ND 0.5 0.973 U1 Inlet R4 #2, pg 1 0.327 28.6 0.662 ND 0.5 0.964 RPD 1.8% 0.7% 0.9% N/A 90.0% #1, Pg ND 0.1 1.30 ND 0.2 ND 0.5 ND 0.4 U1 Outlet R1 #2, pg ND 0.1 1.31 ND 0.2 ND 0.5 ND 0.4 RPD N/A 0.8% N/A N/A N/A #1, Pg ND 0.1 1.38 ND 0.2 ND 0.5 ND 0.4 U1 Outlet R2 2 ND 0.1 1.39 ND0.2 ND 0.5 ND 0. 4 N/A 1.0% N/A N/A N/A ND 0.1 1.39 ND 0.2 ND 0.5 ND 0.4 0U1 Outlet R2 Dup ND 0.1 1.37 N ND 0.5 ND 0.4 RPD N/A 1.3% N/A N/A N/A ND 0.1 1.45 ND 0.5 ND 0.4 U1 Outlet R3 #2, pg ND 0.1 1.46 ND 0.2 ND 0.5 ND 0.4 RPD N/A 0.9% N/A N/A N/A #1, Pg ND 0.1 1.42 ND 0.2 ND 0.5 ND 0.4 U1 Outlet R4 #2, pg ND 0.1 1.41 ND 0.2 ND 0.5 ND 0.4 RPD N/A 1.0% N/A N/A N/A 'N/A-At least one of the analyses were below 5x analytical detection limits. RPD is not applicable in this Circumstance NE013AS-021420-RT-1303 Page 49 of 55 Wheelabrator Environmental Systems, Inc.-Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2-Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 5-3 SUMMARY OF DUPLICATE ANALYSIS FOR MERCURY - UNIT NO. 2 Fraction Empty Front half H2O2/HN Impinger KMN04 HCI Sample Analysis (1A) 03 (213) (3A) (313) (3C) #1, Pg 0.648 31.0 3.29 2.22 5.25 U2 Inlet R1 #2, pg 0.654 31.3 3.33 2.23 5.28 RPD 1.0% 1.0% 1.4% 0.3% 0.5% #1, Pg 0.172 59.7 0.434 0.610 2.29 U2 Inlet R2 #2, pg 0.172 59.5 0.440 0.586 2.29 RPD 40.0% 0.4% 1.4% 4.0% 0.0% #1, Pg 0.169 58.7 0.401 0.629 2.31 U2 Inlet R2 Dup #2, pg 0.172 60.1 0.412 0.615 2.29 RPD 1.4% 2.40/6 2.7% 2.2% 0.9% #1, Pg 0.397 45.6 0.785 ND 0.5 1.31 U2 Inlet R3 #2, pg 0.397 45.6 0.782 ND 0.5 1.320 RPD 0.1% 0.0% 0.4% N/A 0.7% #1, Pg 0.181 20.1 0.319 ND 0.5 2.12 U2 Inlet R4 #2, pg 0.178 20.0 0.312 ND 0.5 2.13 RPD 1.6% 0.4% 2.5% N/A 50.0% #1, Pg 0.116 5.83 ND 0.2 ND 0.5 0.481 U2 Outlet R1 #2, pg 0.117 5.75 ND 0.2 ND 0.5 0.485 RPD 0.8% 1.4% N/A N/A 0.8% #1, Pg ND 0.1 3.56 ND 0.2 ND 0.5 ND 0.4 U2 Outlet R2 #2, pg ND 0.1 3.60 ND 0.2 ND 0.5 ND 0.4 RPD N/A 1.3% N/A N/A N/A #1, Pq ND 0.1 3.56 ND 0.2 ND 0.5 ND 0.4 U2 Outlet R2 Dup #2, pg ND 0.1 3.59 ND 0.2 ND 0.5 ND 0.4 RPD N/A 0.8% N/A N/A N/A #1, Pg ND 0.1 1.79 ND 0.2 ND 0.5 ND 0.4 U2 Outlet R3 #2, pg ND 0.1 1.80 ND 0.2 ND 0.5 ND 0.4 RPD N/A 0.3% N/A N/A N/A #1, Pg ND 0.1 1.59 ND 0.2 ND 0.5 ND 0.4 U2 Outlet R4 #2, pg ND 0.1 1.59 ND 0.2 ND 0.5 ND 0.4 RPD N/A 0.2% N/A N/A N/A #1, Pg ND 0.1 ND 0.3 ND 0.2 ND 0.5 ND 0.4 Field Blank #2, pg ND 0.1 ND 0.3 ND 0.2 ND 0.5 ND 0.4 RPD N/A N/A N/A N/A N/A #1, ND(0.1) ND(0.2) ND(0.2) ND(0.5) ND(0.4) Reagent Blank 1 #2, pg ND(0.1) ND(0.2) ND(0.2) ND(0.5) ND(0.4) RPD 'N/A-At least one of the analyses were below 5x analytical detection limits. RPD is not applicable in this Circumstance NE013AS-021420-RT-1303 Page 50 of 55 Wheelabrator Environmental Systems, Inc.-Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2-Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 5-4 METALS BLANKS AND DUPLICATE ANALYSES RESULTS Analyte Matrix and Spike Rec, Unit1-Out-M29-R2 Unit2-Out-M29-R2 Analytical % Catch,ug Catch,ug Method Reagent Field Unit Unit First Second Relative% First Second Relative% (FH/BH) Fraction Blank,ug Blank,ug 1 2 Analysis Analysis Difference Analysis Analysis Difference Cadmium Front/ <0.2 <0.2 79/° 86/° 1.18 1.15 2.5/° 1.54 1.67 8.4% (ICP-MS) Back' ° ° Lead Front/ (ICP-MS) Back 0.52 0.319 123% 107%d 11.3 11.4 0.9%dF12.6 12.5 0.8%d ' I - The Front and back half fractions were analyzed together. TABLE 5-5 METALS REAGENT BLANKS CORRECTION RESULTS FH/BH Catch Filter Corrected Run#and Weight,ug Blank Catch,ug Diam., 1.4*Area 50%of Calculated Calculated Result to use Target Analyte (mphlBh(Actual)) (mfhb-bhb(actual)) inches and 1 ug 1/2Xntfh/bh(actua1) mfb(assumed) mBb(assumed) U91 Unit1-Out-M29-1 1.25 0 3.22835 11.46+ 1 0.0313 0.63 0.63 1.250 Cadmium Unitl-Out-M29-2 1.17 0 3.22835 11.46+ 1 0.0293 0.59 0.59 1.170 Cadmium Unitl-Out-M29-3 1.4 0 3.22835 11.46+1 0.0350 0.70 0.70 1.400 Cadmium Unit2-Out-M29-1 0.791 0 3.22835 11.46+1 0.0198 0.40 0.40 0.791 Cadmium Unit2-Out-M29-2 1.610 0 3.22835 11.46+ 1 0.0403 0.81 0.81 1.610 Cadmium Unit2-Out-M29-3 0.959 0 3.22835 11.46+ 1 0.0240 0.48 0.48 0.959 Cadmium Unitl-Out-M29-1 13.6 0.517 3.22835 11.46+1 0.3400 6.54 6.54 13.08 Lead Unitl-Out-M29-2 11.4 0.517 3.22835 11.46+ 1 0.2850 5.44 5.44 10.88 Lead Unitl-Out-M29-3 12.9 0.517 3.22835 11.46+ 1 0.3225 6.19 6.19 12.38 Lead Unit2-Out-M29-1 10.2 0.517 3.22835 11.46+1 0.2550 4.84 4.84 9.68 Lead Unit2-Out-M29-2 12.6 0.517 3.22835 11.46+1 0.3150 6.04 6.04 12.08 Lead Unit2-Out-M29-3 15.4 0.517 3.22835 11.46+ 1 0.3850 7.44 7.44 14.88 Lead ' For the combined Front-half/Back half blank correction we deduct mfhb-bhb(c°mbined), Which is equal to:mfhb(assumed)+mbhb(assumed) To Calculate mfhb(assumed)we use the following guidelines: If 0<_('/2 X mfWbhb(actuap)<11.46,then mfhb(assumed)_ (t/2 X mfhb-bhb(actual)),otherwise use the greater of the I or II: Where:I=11.46pg(derived by multiplying the filter area by 1.4) II=the lesser of(a)(%x mfhb-bhb(actuap),or(b)5%of('/2 X mfhb-bhb(actua1)) To Calculate mbhb(assumed)we use the following guidelines: If 0 5(1/2 X mfht bhb(actuaq)<11.46,then mfb(ass°med)= (t/2 X mfhb-bhb(actuap),otherwise use the greater of the I or II: Where: I= 1 pg(derived by multiplying the filter area by 1.4) II=the lesser of(a)('/2 x mf,abhb,or(b)5%of('/2 x Mfhb-bhb) NE01 3AS-021420-RT-1 303 Page 51 of 55 Wheelabrator Environmental Systems, Inc.-Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2-Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 5-6 EPA METHOD 5 BLANK CORRECTION RESULTS RB RB M5 Reagent Fraction Fraction Catch Vol. Blank Conc. Blank Corrected Run#and Target Catch Wt. Volume Wt(mob) (Vrb) (Ca X pa) Correction Result to Analyte Fraction (W1,2) mg (V2,3) ml mg ml mg/ml (Wa) mg' use mg2 Unit1-Out M5/29-1 FHAce 5.2 86 0.1 102 -- 0.084 5.1 Filter ND(0.1) -- ND(0.0) -- -- -- ND(0.1) Unit1-Out-M5/29-2 FHAce 4 90 0.1 1 102 -- 0.084 3.9 Filter ND(0.1) -- ND(0.1) -- -- -- 0.1 Unit1-Out-M5/29-3 FHAce 1.7 60 0.1 102 -- 0.084 1.6 Filter ND(0.1) -- ND(0.1) -- -- -- ND(0.1) Unit2-Out-M5/29-1 FHAce 3.3 62 0.1 102 -- 0.084 3.2 Filter ND(0.1) -- ND(0.1) -- -- -- ND(0.1) Unit2-Out-M5/29-2 FHAce 1.3 95 0A 102 -- 0.084 1.216 Filter ND(0.1) -- ND(0.1) -- -- -- ND(0.1) Unit2-Out-M5/29-3 FHAce 2.3 70 0.1 102 -- 0.084 2.2 Filter I ND(0.1) -- ND(0.1) -- -- -- ND(0.1) For Method 5 Fractions,Wa=Ca x pa x Vaw not to exceed 0.001%of the weight of acetone used during recovery 2 For Method 5 fractions,W,+W2-Wa=Catch weight,mg 3 Analyte in sample is less that analytical detection limits. N E01 3AS-021420-RT-1 303 Page 52 of 55 Wheelabrator Environmental Systems, Inc.-Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2-Test Report Test Dates: October 17-18,2022&October 25-28,2022 TABLE 5-7 PCDD/PCDF BLANKS ANALYSES RESULTS Compound Method Blank, pg Field Blank, pg 2,3,7,8-TCDD ND' (7.89) ND' (7.41) 1,2,3,7,8-PeCDD ND ND (6.73 1.2,3,4,7,8-HxCDD ........_._....._. N ._._._..... .__�9.33).m. .m.N _ _. (7 41) 1,2,3,6,7,8-HxCDD_ ND (8.83 ND (8.6 1,2,3,7,8,9-HxCDD ND 9 ND 8.78 1,2,3,4,6,7,8-H CDD ND 8.38 ND (7.62 OCDD ND 1 T6 J 38 2,3,7,8-TCDF ND 3.66 ND 3.69 1,2,3,7,8-PeCDF ND 2.96 ND (2.77 2,3,4,7,8-PeCDF ND 3.62 ND (3.5 1,2,3,4,7,8-HxCDF ND 4.14 ND (3.8 1,2,3,6,7,8-HxCDF ND 3.71 ND (3.44 2,3,4,6,7,8-HxCDF ND0(6.37) 1 ND 5.071,2,3,7,8,9-HxCDF ND ND 5.181,2,3,4,6,7,8-H CDF ND ND 2.44I1,2,3,4,7,8,9-H CDF NDND (5.61 OCDF ND . ND (14.8 Total TCDD ND 7.89 [ ND (7.41 Total PeCDD ND 8.26 ND 6.73 Total HxCDD ND 9.02 ND (8.24 Total H CDD ND 8.38 ND 7.62 Total TCDF ND _._... ..13.66_... - ._(3.69�- iTotal PeCDF_.____...._.......-.._. __._..ND _(3.26) ... N ._..._-_._(3:09� Total HxCDF ND 4.96 ND (4.23 Total H CDF ND 4.47 ' ND (3.51 ._.....-.-............. Total PCDDs ND 0 ND 38 Total PCDF_s_ ND 0 ND 0.0 Total PCDD/PCDFs ._. N®_. . _®Z _._.38Z__ ' Not Detected or EMPC.Refer to Section 2.4 for more information. 2 As reported in the SGS Laboratory Report provided in Appendix C. NE01 3AS-021420-RT-1 303 Page 53 of 55 Wheelabrator Environmental Systems, Inc.-Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2-Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 5-8 PCDD/PCDF FLUE GAS SURROGATE STANDARDS PERCENT RECOVERIES '3c 13C- 13C- 13c- t3C_ 13c- 13c- 13c_ 13c_ 13C_ 13c_ 19c_ 13C_ 13C_ t3C- 13c- 13c. SampleDescription TCDD PeCDD HxCDD HxCDD HxCDD HpCDD OCDD TCDF PeCDF PeCDF HxCDF HxCDF HxCDF HxCDF HpCDF HpCDF OCDF Method Blank 87268_19628 85 85.7 80.3 83.1 80.4 84.2 78.5 68 88.5 74.5 91.7 106 81.5 67.1 142 68.2 58.9 M23-U1-R1 75.4 76.7 84.3 83.6 78.7 88.5 88.5 66 88.1 69.2 87.7 104 77.6 66.1 138 67.8 63.8 M23-U1-R2 89.7 93.3 90 94.2 82.6 92.7 102 73.8 95.2 75.2 98.8 114 89.6 73.7 154 78 72.9 M23-U1-R3 85.2 89.3 91.3 89.5 82.1 96.1 102 69 92.8 74.6 102 113 90.9 73.3 159 76.8 77 M23-U2-FB 86.4 86.6 91 86.7 80.9 92.7 80.5 75.3 94.1 75.2 96.1 111 86 74.8 138 79.8 66.5 M23-U2-R7 81.6 90.7 85.9 87.7 75.8 87.4 74.5 70.3 91.7 72.6 87 103 81.6 63.3 142 fib 56.2 M23-U2-R2 92.1 93 88.3 87.4 80.1 91.3 94.8 711 96.5 79.3 93.5 106 1 82 1 71.3 137 79.9 74.5 M23-U2-R3 84.9 1 87.9 1 90.1 1 93.7 1 83.4 96.3 83.7 72.8 95.7 78.4 93.1 108 1 86.3 1 74.8 136 81.8 69.9 TABLE 5-9 PCDD/PCDF FLUE GAS EXTRACTION STANDARDS PERCENT RECOVERIES Surrogate Sample Description 37C1- 13C- 13C- I 13C- 13c- TCDD PeCDD PeCDF [ HxCDF HpCDF Method Blank B7268_19628 98.8 111 87.3 78.3 51 M23-U1-R1 88.8 103 80.4 71.4 52 M23-U1-R2 89.9 95.9 78.2 72.8 47.8 M23-U1-R3 93.5 109 84 79.2 52.8 M23-U2-FB 89.3 98.6 79.6 80.1 58.5 M23-U2-R1 85.5 97.7 80.2 75.9 45.5 M23-U2-R2 90.3 100 84.9 80.7 57.7 M23-U2-R3 91 2T 105 82.5 77 60 TABLE 5-10 PCDD/PCDF ASH EXTRACTION STANDARDS PERCENT RECOVERIES 13C- 13C- 13C_ 13C- 13C- 13C_ 13C 13C 13C 13C 13c 13, 13c 13C 13C- 13C 13C_ Sample Description TCDD PeCDD HxCDD HxCDD HxCDD HpCDD OCDD TCDF PeCDF PeCDF HxCDF HxCDF HxCDF HxCDF HpCDF HpCDF OCDF Method Blank B7250_19622 92.1 1 98.2 =85.6 102 77.4 82.6 95.8 88.1 86.6 88.8 89.8 87.3 120 101 68.3 Combined Ash Sample 94.4 104 112 93.9 89 101 94.7 98.2 98.3 98.3 102 130 115 87.6 Fly Ash Sample 89.1 94.2 95.8 73.2 83.8 92.3 85 86.4 87.2 86.2 85.5 116 93.3 65.1 NE013AS-021420-RT-1303 Page 54 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2—Test Report Test Dates: October 17-18,2022&October 25-28, 2022 TABLE 5-11 PCDD/PCDF ASH CLEAN UP STANDARDS PERCENT RECOVERIES CS/SS Percent Recoveries, % 37CI- 13C- 13C- 13C- 13C- Sample Number TCDD PeCDD PeCDF HxCDF HpCDF Method Blank B7250 19622 98.2 116 101 101 118 Combined Ash Sample 102 118 106 108 131 Fly Ash Sample 98.6 109 102 99.9 118 NE01 3AS-021420-RT-1 303 Page 55 of 55 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2 Test Dates: October 18-19,2022&October 25-28, 2022 Field Data 1 - Unit No. 1 Inlet Hydrogen Chloride - Unit No. 1 Inlet Mercury - Unit No. 1 Outlet Hydrogen Chloride and Ammonia - Unit No. 1 Outlet Particulate, Metals and Mercury 5 - Unit No. 1 Outlet PCDD/P Fs 6 - Unit No. 1 Outlet Condensable Particulate B7 - Unit No. 2 Inlet Hydrogen Chloride - Unit No. 2 Inlet Mercury 9 - Unit No. 2 Outlet Hydrogen Chloride and Ammonia 1 - Unit No. 2 Outlet Particulate, Metals and Mercury 11 - Unit No. 2 Outlet PCDD/PCDFs 12 - Ash Sampling 13 - Fugitive Emissions M0N^t k()Sf :u. 0P.111.111 _r.twit:G,X NE01 3AS-021420-RT-1 303 Appendix B-Page 1 of 98 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2 Test Dates: October 18-19,2022&October 25-28,2022 131 i HydrogenChloride NE01 3AS-021420-RT-1 303 Appendix B-Page 2 of 98 MO NTRO S E � `I r r Method L_Fleld Datasheet(Isokinetic) Page x of/ Project Information Sampling Conditions ALT 011 TC ID: Ambient°F Ref.°F Date -y Project# 2:`& ;to Static Pressure,in.H2O (, Ambient Temp,°F Stack Customer/Facility 124Vkharometric Pressure,in.Hg Ref.Barometer ID Probe a Unit ID/Sample Location , Wind Speed/Direction 40 r� Precipitation,Y/N,type Filter Boxt Run# t Operator Probe/Filter Temp Range,°F Filter Exit Sampling Equipment IDS Calibration / `, Equipment Checks Pre Mid Post Meter outlet. Meterbox ID ��� Meterbox Y ` -v Pilot(+),pass @ in.H2O @ @ @ Impinger Exit �� Z Umbilical ID 106 - Meterbox AH@,in.H2O Pitot(-),pass @ in.H2O @ ❑ @ Other Nozzle,ID Nozzle diameter,Dn,in. Pilot visual inspection pass ❑ ss pass Ref.Thermometer ID e Pilot/Probe ID Pilot coefficient,Cp w � � Nozzle visual inspection pass ❑ pas pass . Continuity Check Continui w/Proper Polarity Manometer ID Lam!t` V Manometer zerq and level 61./yes Meter,cm@ in.Hg (�`(��@ @ # Notes: Sensitivity 0, 000 0v K-Factor N1 Intermediate leak check volume,ft3 Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Stack Temp, Probe Temp, Filter Temp,°F Impinger Exit a AP in H Differential,AH -. Temperature,°F �" Vacuum, Pbint# Time 24hr Vm,ft2O Target Actual °F °F Box Exit Temp,°F Inlet Outlet in.Hg �5 d rco e dD 5 r o S Oq a d® L 0 It 0f� Q 7AD D m 0I oP 9- U 1✓ rV �/ �✓ V �- 5 Q v yIfs .S �(� 449 5 G " 1 y D d qDa 10 l M O co H , O N N O U) I _M [� O W Z Averages QA/QC C ompleteness_Legibility_Accuracy_Specifications Checked By t Team Leader 001A FM-225 MONTROSE Methods ) Field Dateshaat(Isoldnatic) Page of .1.. AIR QUALITY SERVICES Project Information Sampling Conditions / ALT 011 TC ID: Amblent'F Ref.'F Date °( ^) :22project# 0 `�--� Static Pressure,In.H2O "C Ambient Tamp,'F Stack lei Customer/Facllity r-AJ, Barometric Pressure,In.Hg a Ref.Barometer ID V AJS Probe Unit ID/Somple Location V n , v- Wind Speed/Direction E Precipitation,Y/N,type Filter Box l Run# Operator ^ cCJ Probe/Filter Temp Range,'F hP 6 Flter Exit Sampling Equipment 113s Calibration Equipment Checks Pre Mid Post Meter outlet Materbox ID 16 L4 Meterbox Y . Pilot(+),10s @ in.H2O Arb _ @ @ Impinger Exit Umbilical ID Meterbox AH@,in.H20 ,T Pitot(-),pass @ In.H2O -@ ❑ Other Nozzle ID Nozzle diameter,Dn,In, Pilot visual inspection pass ❑ ss pass Ref.Thermometer ID Pilot Probe ID Pilot coefficient,Cp o Nozzle visual Inspection -"pass ❑ pas pass ContinuityCheck ❑Continul w/Pro r Polarl Manometer ID t Manometer zero nd level ryes Meter,cfm @ In.Hg ,dC @ @ (x1Z @. Notes: Sensitivity ,v IK-Factor Intermediate leak check volume,e Traverse Elapsed Clock Time DGM Reeding, Velocity Head, Orifice Pressure Dry Gas Meter Pump Stack Temp, Probe Temp, Filter Temp,'F Impinger Exit - Point# Time 24hr Vm,if AP in H2O Differential,AH .F °F Tamp,-F Temperature,°F ,(1 Vacuum, Target Actual Box Exit Inlet Outlet i" in.Hg 0% pt) �' ®CZ 5-3 a)0 3 Qq =o i M O M i I— N 1 i N O M 0 LLJ Z Averages QA/QC Check:Completeness_Legibility_Accuracy_Specifications�scked By Team Leader 001AS-QMS-FM-225 .MO N TRO S E Method Field Datashest(Isokinetic) Page of AIR CtUAI.ITY SERVICES Project Information Sampling Conditions ALT 011 TC ID: Ambient°F Ref.°F Date t. Project# Ir Static Pressure,in.H2O J,G Ambient Temp,°F Stack Customer/Facillty �� r arometric Pressure,In..Hg Ref.Barometer ID Probe Unit ID/Sample Location Wind Speed/Direction /v Precipitation,Y/N,type Filter Box Run# Operator Probe/Filter Temp Range,°F Filter Exit Sampling Equipment IDs Calibration Equipment Checks Pre Mid Post Meter outlet Meterbox ID Meterbox Y ` ' Pitot{+),pass @ in.H2O @ @ Impinger Exit Umbilical ID -fbQ Meterbox AH@,In.H2O , Pitot(-),pass @ in.H2O @ @ [ @ Other Nozzle ID Nozzle diameter,Din,in. Pitot visual inspection (pass LXPass pass Ref.Thermometer ID pilot/Probe ID Pitot coefficient,Cp I Nozzle visual Inspection pass ❑ p s pass Continuity Check ❑Continuityw/Proper Polarity Manometer ID Manometer zero and loyal yes Meter,cfm @ in.Hg @ @ I�b�@ Notes: Sensitivity6• d D K-Factor � Intermediate leak check volume,ft' Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Differential,AH Stack Temp, Probe Temp, Filter Temp,°F Impinger Exit Tempereture,°F Vacuum, Point# Time 24hr Vm,i? AP In H2O Target Actual 'F °F Box Exit Temp,°F' inlet Outlet in.Hg ?- i� D 0) d z �l� 3 [� ° b 10 ,.D C j { t , 6 tM D 1 1, ,O 0 � 3 / 0 r r t O t-(� ✓ CL Q Fill 1 I M O O N V 6 N Pyt O U) A a M i o Lu z Averages QA/QC Check:Completeness Legibility_Accuracy_Specifications V Checked By Team Leader 001AS-QMS-FM-225 MONTROSE Sample Recovery&Calibration Check Datasheet Page l of �.. AIR QUALITY SERVICES Project Information i Equipment Identification Date G -Z Z Protect# Ref.Thermometer' Customer/Facility N d�L✓ Hygrometer _UJOUnit ID/Sample location `()DA- � - S pd� �11� Field Balance Run# _ operator, Check Weights Calipers Balance Audit(Field balance must be within 0.5g of check weight mass) Ambient Conditions(Mobile Lab) Date + 7Z Relative humidity,% Standard mass,g OC-0"Q Temperature,°F Field balance mass,g — Mobile lab# N Moisture Determination Runi Run 2 Run 3 Contents Initial Final Net Initial Final Net Initial Final Net Knockout Impinger 1 Tk)N 6 Z. �, 0 4 1 ,0 Impinger 2 H 1��( �`�,, O; �C� H. Impinger 3 (�zStJ Z CJ7�; (o. 2- Impinger (5 ,� 4 S, (U Z, 7, o G Impinger 5 Impinger 6 Impinger 7 Impinger 8 Silica Gel Z L r v Line Rinse Train Net Gain(Vic) Nozzle Measurements(Difference between any two measurements must not be more than 0.004 in(0.1 mm)) Nozzle 1 diameters D1 — D2 D3 Average Nozzle 2 diameters D1 D2 D3 Average Nozzle 3 diameters D1 D2 D3 Average N atarial ❑ gyprtz ❑glass ❑ steel ❑ titanium ❑ inconel ❑ other Probe Type heated ❑ un led ❑ air-cooled El water-cooled ❑ other Probe Liner ® quartz glass ❑ steel El Teflon ❑ other Filter Inform;�qLa, Front Half fiber ❑ glass fiber ❑ Teflon ❑ Teflon/quartz ❑ other Filter Number. Run 1: Run 2: Run 3: Run Back Hall ❑ quartz fiber ❑ glass fiber ❑ Teflon ❑ Teflon/quartz ❑ other Reagent Information Sample Observations Type Lot Number QA/QC Check:Completeness_Legibility_Accuracy_Specifications Checked by. Team Leader: 001AS-QMS-FM-226 NE01 3AS-021420-RT-1 303 Appendix B-Page 6 of 98 L EPA Met hod 3'Data Sheet Project#: Test Date: ClIentfs Ite: Operator. Pre-Test Leak Check: 0 Pipette Fluid Level In Capillaries: CO2(&/N) 02&/N) ORSAT Analysis Audit: Date: CO2 02 Audit Gas Time of Reading Reading %02 *NOTE:Audit results must agree within Concentration Anal sis A) (B) (B-A) :t 0.5%of the audit gas concentration %02: value. %CO2: Analyzer I.D.-A-ORS- lAudit Gas Cylinder I.D.: Run No. Orsat Bag ID. Time: Sam le 1 Sample 2 Sample 3 Average CO, 0,+CO, .0,Net (Al- pip-& Run No. Orsat Bag ID. Time: Sample I Sample 2 Sample 3 Average CO, O;j+COZ q A Net C ` U Run No. Orsat Bag ID. Time: :Sample I Sample 2 Sample 3 Average CO, Z71:3 7 I.S 02+COZ -4� /5. 3 Ci�-� 02 Net (0-0 M& 4E Run No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average CO, 02+COZ .02 Net -- Dry Gas Molecular Weight *281100) Md=(COS*44/100)+(O2*32/100)+(N, Montrose Air Quality Services,LLC 2 New Pasture Road,Unit 6-Newburyport,MA 01950,T.(978)499-9300,F:(978)499-9303 www.montrose-env.com N E01 3AS-021420-RT-1303 Appendix B-Page 7 of 98 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc_ Compliance Test Program on Unit Nos. 1 &2 Test Dates:October 18-19,2022&October 25-28,2022 Unit No. 1 Inlet ()i,J i K0 E NE01 3AS-021420-RT-1 303 Appendix B-Page 8 of 98 M.,JII M®NTR®S E Method Field Datashest(isoldnetic) Page of _ AIR CLUAI.ITY SERVICES Project Information ` Sampling Conditions ALT Q11 TC ID: Ambient°F Ref."F Date 1 0- �� Project# !� of o Static Pressure,In.H2O Ambient Temp,°F Stack Barometric Pressure,In.Hg ��-Z?U _Ref.Barometer ID ProbeJ Customer/Facility Vv 2`' Y� y ` Unit ID/S pie L cation U` \ Wind Speed/Direction G Y r — I`recipitation,Y/Qtype Filter Box Run# ' � Operator Probe/Filter Temp Range,'F Filter Exit G)3 Sampling Equipment ID. Calibration Equipment Checks Pre Mid Post Meter outlet \�30 _,..,..._ Meterbox ID Meterbox Y \ V b Pltot(+),pass @ in.H2O L�@ ❑ @ @ 3 Impinger Umbfllcal ID .e. Meterbox eH@,in.H2O .C(� r Pitot(-),pass @ In.H2O @' \ ❑ @ @' ?j t Other Nozzle ID ® C�.J Noale diameter,Dn,in.® ®J Pitot visual inspection s ❑ ss Lg pass Ref,Thermometer ID Pilot/Probe ID — Pttot coefficient,Cp Nozzle visual inspection pass pass pass Continuity Check ❑Contnuiy w/Pro er Polarity Manometer ID Manometer zero and level yes Meter,cfm @ in.Hg @ -k-3@ Notes: — Q�:1 Sensitivity ®-O� K-Factor - Intermediate leak check volume,fO Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Stack Temp, Probe Temp, Filter Temp,°F Impinger Exit Temperature,'F Vacuum, oP in H2O Differential,9H -F 'F Temp,"F Point# Time 24hr Vm,fts Target Acival Box ft Inlet Outlet in.Hg 6 qA5 k 6,A a 1 5a ZSC q L �;Z- 5 a`A 1�v S 25 2S -+ 5 5 �5 5 .� S S � as o 5' 2v 2`6 C9 � d - a3 SS �25 0 2 .0 2.o S),5S- ��� r a. a5 a s X ro 145 Soto _ 0 r n-,Gk, suI� \b - . 0 5 5© \� 35"4-4 0- 3 , . 5- 2 55 15 S 6 6 5 6 .3 �. \. 55 5& 9 S \ o. 1 (. 6 S 5 56 Cl) fig o C c 32 �56 a5 'z A 5 t o S I B 0 4`b e6 0 100 5,A to r, 153S 150 9 ff J6 `d � (V 10 ,5 I 5 c9_ 1. 5 k D-5 D- �- 5'0 9 5 CD N ,\ 0 1 r 2 25 a 5 1 t� 5 t6a5 .� r. �- �3� `a.S �- 52 Cl) LU z Averages CWQC Check:Completeness_Legibility_Accuracy_Specifications_Checked By Team Leader 001AS-QMS-FM-225 M .,rl®N T RO S E Y�Method ._Field Datashest(Isokinetic) Page ..r ` AIR QUALITY SERVICES Project Information Sampling Conditions ( ALT 011 TC ID: Ambient°F Ref.°F Date I Prcjact# �O Static Pressure,In.H2O I o Ambient Temp,°F Stack 1Q� Customer/Faclllty ��t� v�. Baromeblc Pressure,In.H/gg u1 Ref.Barometer ID Probe Unit ID/Sample Location U -,t Wind Speed/Direction �J Precipitation,Y ttype Filter Box Run# Operator 5 Probe!Filter Temp Range,°F Filter Exft D Sampling Equipment IDs Calibration ( ( Equipment Checks Pre Mid Post Meter outlet l Ci b Meterbox ID 170D Meterbox Y © \ 'o Pitot(+),pass @ in.H2O Le@ _" t ❑ @ @ '3 " Impinger E)(d Umbilical ID — (Z) Meterbox AH@,In.H2O `-q3 Pilot(-),pass @ in.H2O Iff@ Zj `1 ❑ @ @ 3 Other Nozzle ID Nozzle diameter,Dn,in. \/ J Pilot visual inspection W- ass ❑ ass 3/pass Ref.Thermometer ID Pilot/Probe ID —°,_Z Pilot coefficient,Cp Nozzle visual Inspection ass pass pass Continui Check ❑Continui w/Proper Polla£ari Manometer ID �7� I-Factor anometer zero and level. yes Meter,cfm @ in.Hg (�_Oc0@ l @ g @ 1 Notes:Sensitivity C� Intermediate leak check volume,ft3 1 / S,10 tl$p Orifice Pressure Dry Gas Meter _..Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Stack Temp, Probe Temp, Filter Temp,°F Impinger Exit Point# Time 24hr Vm,fi2 8P in H2O Differential,AH °F °F Temp,°F Temperature,°F Vacuum, Target Actual Box it Intel Outlet In.Hg 1Z5�, C9- 3 1. S'3 265 ZS S 12 co 10 13cso e - 0 _ l . C. 53 Z -5 6 2- l t3n5 1 . 6, -3 25 -a S 6 4S S 3°5. 0 5 l k® i �6 N-4 53.5 5 5 2 5 °i 5 9-5 13115 1 Vq -72a - 9 2. O :1 , 0 5'*�325 ,5 �1 0 5 �' 47 t3�-5 Ar a _ (5. 46 D , 0 . - S 3 2 2 5 ;z 7'� x 11� __Z , 53 �S ^� ° , ` � S �: cv 255 aS t S 3 l, C r '"z Z 5 5 ash .o �, 60 (3CL 50 Z 65 ' A\5 - ., ' ��3 2 S 5 1 a. a �- t, �. 2 2- 9 1-5 1, 5 1 -3 �r � o , t.� J 2S 2 �3 M � 35 � O . ® - .� a. _ 5a5s �� �,5 '4 kiG' , )- ® _ , t. � � aS '5 5 z 5 5 5a 2g 55 5 46J, G N 1©0 1 . 5 0. t_ 5� a 55 a 55 it 10c)1o0,, L9 .� 1. �, a a�. � o° 5 i. 1. 5� �5 49 B a 6 5 S Averages CA/QC Check:Completene _Legibility_Accuracy_Specifications_Checked By Team Leader 101AS-QMS-FM- rA6^1 MONTRO S E Method� Field Datashest(isokinetle) Page of - AIR Cj UALITY SERYLCES Project Information Sampling Conditions i ff ALT 019 TC ID: Ambient°F Ref.°F Date 0-a -�a Project# �- Static Pressure,in.H2O \> V Ambient Temp,°F 7- Stack M 13_tq3 C) Customer/Facility VU f (( �- vVe� klarometric Pressure,In.Hg Z t�, Abe Ref.Barometer ID k W Probe 1-1-It-�. Unit ID/Sample Location \- Y\ Q T Wind Speed/Direction �V"�(!V"�(!��V��.J Precipitation,Y/pe Filter Box H t3- Run# Operator f2 Probe/Filter Temp Range,°F Filter Exit Sampling Equipment IDs 2, Calibration 1 / Equipment Checks Pre Mid Post Meter outlet P`t t j (�l Meterbox ID " , + Meterbox Y t V v Pilot(+),pass @ in.H2O K" @ 3 ❑ @ �@ >� Impinger Exit Umbilical ID Meterbox AH@,in.H2O - �2f A Pilot(-),pass @ in.H2O ❑ @ 3,. ❑ @ Er @ Other Nozzle ID i;!J Nozzle diameter,Dn,in. 05 Pilot visual inspection ['pass ❑ pa ❑ pass Ref.Thermometer ID Pilot/Probe ID 19- --- Pftot coefficient Cp !� - Nozzle visual Inspection Ef pass �pass ❑ pass ContinuityCheck ❑Contlnul w/Pro er Polarity Manometer ID V l Manometer z ro and level Imes Meter,cfm @ in.Hg C9»e;Z@ O oad@ i � Not., �,cP' Sensitivity - t K-Factor �- Intermediate leak check volume,fta 1 / 3.2�-6o-d- 5 e Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Stack Temp, Probe Temp, Filter Temp,°F Impinger Exit Temper,ture,°F Vacuum, 'AP in H O ,} Differential,aH °F °F Temp,°F Point# Time 24hr Vm,ftgjj 2 Target Actual Box t Inlet Outlet in.Hg _ �3 2' 256 00 >o t o Ilk _ t t S o 25 t6v5 a L > �, 1. `6 2- ; �5(0 _ `�-� I q ,e �_� '�-4 + a55 �- - S �3 m 0 5 t i5 \4b - �? - . !. 6 3 S � � t� SG 1 �a� o \, s s 2s1 +9 �z 5 s`Z�, o _ 53 a5 255 i t�5o -x .6o 5 1. t, 35 � 55� 35 -5 \, t. 9� 5 � 5 4 6 3 3. 5 0 co 0 . ,q a -0 3 � 3 C6 5, 5 �55 5 5 \ � - 5 53� 1 • -5 55 N l� 42 15 r2 ; 2 b- `\-e4 5 Q 5 2 .y S 7 s 5 1 _S 2 55 ;Z5 5 1S . D , �5 q t, �. aZ55 r�' 56 1 10co o Q i it5 t b LU Averages 110 0 5 QA�r 4- Z QA/QC Check:Completeness_Legibility_Accuracy_Specifications_Checked By Team Leader 001AS-QMS-FM-225 A A M11 1 N T RO S E EPA Method Fit i Sheet(Isokinetic) Page \ of 1. A ALITY SERVICES Project Infom►a on Sampling Conditions ALT 011 TC ID: Ambient°F Ref.°F Date: 'l�- - �� Projttect#: 6 ' �(� Static Pressure(in H20): "1 Ambient Temp(IF: Stack: }�(�7 -``30 Customer/Facility: Z1 i chi c7� r (J Barometric Pressure(in Hg):�C�_-¢2j Ref.Barometer ID: Probe: \ ^`j' ( Otyp ) o Unit ID/Semple Location: U _T Precipitation Y/ e: Filter Box: Run#: Operator: Wind Speed/Direction: V- 1� <. Filter Exit: C`3 d tn Sampling Equipment IDs y Calibration Equipment Checks Pre Mid Post Meter outlet MB ID 19?7 Meterbox ID: {� '�� 1� Meterbox Y: ©� Meter,chn @ in Hg: Q ei )5 @ %tv la Impinger Exit: �� `� 47 Umbilical ID: CJ - Meterbox AH@(in H20): Leak Check,ft2: Other: Nozzle ID: © - 750 tJ Nozzle diameter,Dn(in): © 270 5 Pilot(+),pass @ in H2O: t�'@� ❑ @ @ .3tt Reef.Thermometer ID: �tkq Pitot/Probe ID: i �[- Pilot coefficient,Cp: ,- Pilot(-),pass @ in H2O: (���'` ❑ @ t 1 Continuity Check: ontinul w/Pro er Polarity Manometer ID: - 1 Manometer zero and level: yes Pilot visual inspection: Vpass passpass Notes: \�G ` 0 `cJ `�'0 cf a C� Sensitivity:�-O K Factor: 3. Nozzle visual Inspection: pass pass pass �5 i t<D, 5 _�- Orifice Pressure Impinger Dry Gas Meter Pump Traverse Time per Clock Time DGM Reading Velocity Head Stack be Filter Temp°F Sample a Differential AH Exit Temp Tem erature°F Vacuum Point No. Point 24 hr (Vm,ft) (AP in H2O) Target Actual Temp°F Temp°F gox it °F net Outlet (in.Hg) ate '� S a5 �;5 55 5 a 5 aS3 53 3 16 0—'6 S 5 t 4 ( . 5 255 _D1 5 3q 0 CU o 0 © 0 t (. 532- a57 - 55 S 1 r7 5 0 0 �- t - l y 5 5 5 6 .S m 533 ,5 25 5 5 CL � o .�. � p� t• l� 33 � � �6 I Q t -5 c� i 5 o g 5 �. 1 t� [= G� �. - 65 5 40 0 L 3,6 n: q i, 5 -S5 `�,5 a `4� 65� 5 0`t �•'R 0 2-cam - .0 'D, 0 � 6 S 3 90 bn 0 b AA,v D, 5 0 C) a 5 o1qc55 L4 is 1. -). 9,5 ')_ o I AN 1_0 Cl) 100 1 WOO I)L, 1)-55 �;L 5 0 i D5 Aao5 t 9: a iio 1'k i5 �5 0 a , s S �cli \.10 e2J 1 �- v� ' M Averages: O W QA/QC Check:Completeness:_Legibility:_Accuracy:_Specifications:_Checked By: Team Leader. 0 1AS-OPS-FM123 Z MONTROSE Sample Recovery&Calibration Check Datasheet Page of AIR 0,VAt[TY SERVICES Project Information Equipment Identification Date Project# Ref.Thermometer Customer/�ailfly' (A)Kee J-b.4,, —A-� Hygrometer Unit ID/Sample Location — S nA 1/1 W Field Balance .5A-7 i 14- Run# Operator ZV6 Check Weights Calipers-- Balance Audit(Field balance must be within 0.6g of check weight mass) Ambient Conditions(Mobile Lab) Date 22 Relative humidity,% Standard mass,g TO-O&D Temperature,*F Field balance mass.g 61 Mobile lab# (2k 1, Moisture Determination . Runt Run 2 Run 3 Contents Initial Final Net Initial Final Net Initial Final Net Knockout ;Z- -10.57 Impinger 1 IrA. 3,T IQ G �?77511�' Impinger 2 S-(Io I Tfs W 11'3 , 6111 6`(3"-f— Impinger 3 Qco' 6Z& Impinger 4 60'x t5 0 impinger 5 1;ut-s 6, (12g, 5 Impinger 6 Impinger 7 Impinger 8 7K Silica Gel IV)310, Line Rinse I Train Not Gain(Mc) Nozzle Measurements(Difference between any two measurements must not be more than 0.004 In(0.1 mm)) Nozzle 1 diameters jc?)7 DI D2 _.O,$D_C_D3 836S Average Nozzle 2 diameters D1 D2 D3 Average Nozzle 3 diameters D2 D3 Average Nozzle Material 0 quartz glass El steel El titanium L1 inconel F1 other Probe ❑Type heated ZLI�un�lied El air-cooled 1:1 water-cooled -1 other Probe LinerLl quartz glass ass.. El steel El Teflon LJ other Filter Information Front Half quartz fiber L1 glass fiber El Teflon El Teflon/quartz ❑ other Filter Number. Run I- r Run 2: Run 3: Run quartz fiber glass fiber Teflon El Teflon/4uartz other Reagent Information Sample Observations Type Lot Number OAIQC Check:Completeness Legibility_Accuracy-�'—/Specfficatlons V Checked by. Y L/I ..Tearn Lead.,: 00IAS-QMS-FM-226 NE013AS-021420-RT-1303 Appendix B-Page 13 of 98 ...M1® ri J E Sample Recovery&Calibration Check Datasheet Page G. of AIR QUALITY SERVICES Project Informat n Equipment Identification Data I Z� tit' Project# Ref.Thermometer Customer/Facility ee a�jt2 (,� /V� y�(.v�/ Hygrometer Unit ID I Sample Location n f h(4 Field Balance 1 (T Run# t Operator Check Weights Calipers Balance Audit(Field balance must be within 0.5g of check weight mass) Ambient Conditions(Mobile Lab) Date L Relative humidity,% Standard mass,g ( uo 0 Temperature,"F Field balance mass,g `/f�_ Mobile lab# , In�� Moisture Determination Run Run 2 Run 3 Contents Initial Final Net initial Final Net Initial Final Net Knockout �.- 50,9 - Impinger 1 o 017—R ILI,� - 6 Impinger 2 S(O q Impinger 3 3 Imp1nger4 W001 tv, Impinger 5 P 2 Z Impinger 6 Impinger 7 Impinger 8 Silica Gel S1 e 4 Line Rinse Train Net Gain(Vic) Nozzle Measurements(Difference between any two measurements must not be more than 0.004 in(0.1 mm)) Nozzle 1 diameters 0;Zo C D1 �,3 y D2 3D r D3 d.3D 5 Average Nozzle 2 diameters D1 D2 D3 Average Nozzle 3 diameters `D1 D2 D3 Average Nozzle Material ® quartz glass ❑ steel ❑ titanium ❑ inconel ❑ other Probe Type heated �L] .n led ❑ air-cooled ❑ water-cooled El other Probe Liner ❑ quartz glass ❑ steel ❑ Teflon ❑ other Filter hrformatio Front Half quartz fiber ❑ glass fiber ❑ Teflon ❑ Teflon/quartz ❑ other Filter Number. Run 1: �r Run 2: — Run 3: Run B c alf ❑ quartz fiber ❑ glass fiber ElTeflon ❑ Teflon/quartz ❑ other Reagent Information Sample Observations Type Lot Number QA/QC Check:Completeness_Legibility racy Specification , Checked by: /M1_Team Leader: 001AS-QMS-FM-226 NE01 3AS-021420-RT-1 303 Appendix B- Page 14 of 98 EPA Method 3 Data Sheet Project# — Test Date Client/Site: 0, Operator. A- Pre-Test Leak Check: L/-br Pipette Fluid Level in Capillaries: CO2(P N) 02(6t%/N) ORSAT AnalysisAudit: Date: CO2 02 Audit Gas Time of Reading Reading %02 *NOTE:Audit results must agree within Concentration Analysis (A) (B) (B-A) 0.5%of the audit gas concentration %02. value. %CO2: Analyzer I.D.-A-ORS- ]Audit Gas Cylinder I.D.: W-- Run No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average CO2 ci-(0 Ci A. 02+CO2 kqA 1� 02 Net u i Run No. Orsat Bag ID. Time: Sample I Sample 2 Sample 3 Average CO2 q,.5— -- 1'(0 q.S' o.+CO2 's 1 9.ko 0,� -- 02 Net 0, Run No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average CO2 9"s 02+CO2 0;!Net SCE. 0. 2. Run (Z 11— S P 0-14 LO No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average CO, 02+CO2 (0 02 Net 10-0 (3 10.0 Dry Gas Molecular Weight: Md=(CO2*44/1 00)+(Oz*32/1 00)+(N2*28/1 00) Montrose Air Quality Services,ILLC 2 Now Pasture Road,Unit 5-Newburyport,MA 01950*T(978)499-9300•F:(978)409-9303 www.montmse-env.com N EO 1 3AS-021420-RT-1303 Appendix B-Page 15 of 98 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2 Test Dates: October 18-19,2022&October 25-28,2022 Outletall iAmmonia N M 0 N T i:oSE NE013AS-021420-RT-1303 Appendix B-Page 16 of 98 MONTROSE Method zcn Field Datasheet(Isoklnetie) Page AIR QUALITY SERVICES Project Information Sampling Conditions ALT 011 TC ID: Ambient°F Ref.°F Date 0 A ' �iect# Static Pressure,In.H2O `0:5 Ambient Temp,°F Stack Customer/Facility �" , ' Barometric Pressure,In.Hg Z� Ref.Barometer ID Probe Unit ID/Sample Location Wind Speed/Direction D�+ct Precipitation,Y/N,type Filter Box Run# !!!Operator G Probe/Filter Temp Range,°F Q Filter Exit ' Sampling Equipment IDs Calibration )) Equipment Checks Pre Mid Post Meter outlet Meterbox ID Meterbox Y 3a t Pilot(+),pass @ in.H2O ❑ @ eP ge Exit (/ Umbilical ID aC'J —75 Maferbox eH@,In.H2O Pilot(-),pass @ in.H2O @ 1] @ Other Nozzle ID Nozzle diameter,Din,in. /1 Pilot visual inspection 2— pass-- Q Pas Ref.Thermometer ID Pitot/Probe ID Pltot coefficient,Cp /1 y Nozzle visual inspection `'-El—pa .W.:._.Q-=pass— Continuity Check ❑Continuity w/Proper Polad Manometer ID Manometer zero and level yes Meter,cfm @ in.Hg C)Occ @' O,.oO 3 @1 S Notes: Sensitivity K-Factor 7 V Intermediate leak check volume,fe ! / Traverse Elapsed Clock Time DGM Reading, Velocity Head, Orifice Pressure Stack Temp, Probe Temp, Filter Temp,"F impinger Exit Dry Gas Meter Pump Point# Time 24hr Vm,ft AP in H2O Differential,aH ,F "F Temp,'F Temperature,°F Vacuum, Target Actual Box Exit Inlet Outlet in.Hg J �C) 00 ?cam 7+ o 7 c p 2 IS 2��1 81.1 � .a Zss� 1 212 '2qO 2 �95 Lt b 2 g� H (o "�-l m '�S 3 • " �D 2�"} W Z Q IK CV2 2 � 3 2 H Q 5Y 1-1 .3 2K5 IS 9 co O H 1Y O N d' N O W Q _M O W Z Averages QA/QC Check:Completeness_Legibility_Accuracy_Specifications_Checked By Team Leader 001AS-QMS-FM-225 MI �VLO NTRO S E EY•=l Method Field Datashest(Isokinetic) Page of / „L. AIR QUALITY SERVICES Project Information Sampling Conditions ALT 011 TC ID: Ambient'F Ref.°F Date ZI ZZ rProoject# Static Pressure,in.H2O - 0, S Ambient Temp,°F A I Stack to 5-3 Customer/Facility '�J1L�1G�1 A/ Barometric Pressure,In.Hg ���. Ref.Barometer ID V`+ Probe l�-S Unit ID/Sample Locatlon / t i J Wind Speed/Dlrection Precipitation,Y N e Filter Box 1U Run# Operator Probe/Filter Temp Range,°F Filter Exit Sampling Equipment IDs Calibration Equipment Checks Pre Mid Post Meter outlet Meterbox ID !5 Meterbox Y /.0301 Pitot(+),pass @ in.H2O .B—@' @ *3g Impinger Exit 3 0 Umbilical ID j 1 Meterbox AH@,In.H2O ,aL j(� Pitot{-),pass @ in.H2O '@� Other �'- Nozzle ID Nozzle diameter,Dn,in. Pitot visual inspection —8--ryaes- s Ref,Thermometer ID Pitot/Probe ID Pitot coefficient,Cp o Nozzle visual inspection .-B-P— s Continuity Check ❑Continuity w/Proper Polarity Manometer ID 1 Manometer zero and level , yes Meter,ctrn @ in.Hg 0�0a�{ @ ( r @ Notes: Sens&A IK-Factor Intermediate leak check volume,If ! / M Traverse Elapsed Clock Time DGM Reading, Velocity Head, Orifice Pressure Dry Gas eter Pump Stack Temp, Probe Temp, Filter Temp,°F Impinger Exit Tem ereture,°F Vacuum, - Point# Time 24hr Vm,fe AP in H2O Differential,AH °F °F Temp,°F p Target Actual Box Exit inlet Outlet in.Hg b AN 2A0 I0 2 5f0 & a& & s I Z.0 0( Z� Z a 9 y co i q1 Z 3 2$5 5Ll 00 0q C1 3 , 3-1 2�� 2iv 0 u -9 2-0 0 (0 2,q 5 21 x ILD 2�1-1' 2�l Z ��- 1 2. Z 2 q 26-5 �3 9 (�"�- CL O M i O N d' ' N O U) Q co r O W Z Averages QA/QC Check:Completeness_Legibility_Accuracy_Specifications_Checked By Team Leader 001AS-OMS-FM-225 MO NTRO S E 2-LA—Method Field Datasheet(Isoklnetic) Page of Alit QUALITY SERVICES Project�T; Sampling Conditions ALT 011 n TC ID: Ambient°F Ref.'F Date Project# �� Static Pressure,in.H2O "�•5 Ambient Temp,°F Stack Customer/Facllity �fJ U(' a Barometric Pressure,in.Hg Ref.Barometer ID Probe -�✓ Z Unit ID/Sample Location Wind Speed/Direction Precipitation,Y e Fllter Box Run# A v, Operator Probe/Filter Temp Range,°F M CYIFilter Exit Sampling Equipment IDs Calibration Equipment Checks Pre Mid Post Meter outlet ' Si 2 Z- Meterbox ID Meterbox Y Pitot(+),pass @ in.H2O �'�-o-- @ 0 @�'- Impinger Exit 700Z Z Umbilical ID Meterbox aH@,in.H2O Pitot(-),pass @ in.H2O ❑@ 1 ❑ �'�� Other Nozzle ID Nozzle diameter,Dn,in. Pitot visual inspection 8-pass. ❑ ss s$"P Ref.Thermometer ID Pttot/Probe ID Pilot coefficient,Cp Nozzle visual InspectionS ant ; = Des pass Continui Check ontlnulty w/Proper Polarity Manometer ID Manometer zero and level ❑yes Meter,cfm @ in.Hg 0.0(@ 15 --g` 0•LZ3 @ lo' Notes: Sensltiv' K Factor Intermediate leak check volume,fe ! ! Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Differential,tsH Stack Temp, Probe Temp, Filter Tamp,°F Impinger Exit Temperature,°F Vacuum, Point# Time 24hr Vm,if AP In H2O Target Actual °F °F Box Exit Temp,°F Inlet Outlet in.Hg 00 3 0, 2-Q s 2" 5 S '�2 `f i; y Zo of Sss y o ZS y 2 (0 296, 5� � 65 9L 5.`� 1110 S 2�5 2 `6 � '(] 6 a� S . 2, W & l�'Z G 1 6 1, 2- 0 S-P Z 2fS� 3 �I �� Q (oLI.� 2.t7 ZSL( 23r'(o e Z LX 1 o `l 2, 'Z/Y (o M O M ' O N et' N O U) Q M_ O W Z Averages CWQC Check:Completeness_Legibility_Accuracy_Specifications_Checked By Team Leader 001AS-QMS-FM-225 ITT 1 V 1 S E Sample Recovery&Calibration Check Datasheet Page \of .�. AIR QUALITY SERVICES Project Information Equipment Identification Data T®/771.7 Project# Ref.Thermometer Customer/Facility 11 Hygrometer Unit ID/Sample Location 1 i•l t k — F"F O 0 OkQ - Field Balance `7A 3 1 t 2 rr Run# ',�i Operator Check Weights V) i lRW ki Calipers Balance Audit(Field balance m st be within 0.5g of check weight mass) Ambient Conditions(Mobile Lab) Date Relative humidity,% Standard mass,g (000,0 Temperature,°F Field balance mass,g Mobile lab# Moisture Determination Runt Run 2 Run 3 Contents Initial Final Net Initial Final Net Initial Final Net Knockout Impinger 1 �t OM (O t�i �, `� Impinger 2 0 �• 776- �b•� �� y ' j Impinger 3 H1104 \3` Impinger4 -- Ipt`I- lit, ,uSM LS G ok1 Impinger 5 Impinger 6 Impinger 7 Impinger 8 -7- Silica Gal 2Q.3 •'Z Z• Z. Line Rinse Train Net Gain(Vic) Nozzle Measurements(Difference between any two measurements must not be more than 0.004 in(0.1 mm)) _. Nozzle 1 diameters _ 1 �D2 3 Average Nozzle 2 diameters D1 D2 D3 Average Nozzle 3 diameters D1 D2 D3 Average Nozzle rill ❑ quartz ❑glass ❑ steel ❑ titanium ❑ inconel ❑ other Probe Type heated El unheated ❑ air-cooled ❑ water-cooled ❑ other Probe Liner ❑ quartz glass ❑ steel ❑ Teflon ❑ other Filter Information �-- Front Half: �;V quartz fiber ❑ glass fiber ❑ Teflon ❑ Teflonlquartz ❑ other Filter Number. Run 1: Run 2: —'^ Run 3: Run Bac If: ❑ quartz fiber ❑ glass fiber ❑ Teflon ❑ Teflon/quartz ❑ other Reagent Information Sample Observations Type Lot Number QA/QC Check:Completeness_.Legibility_Accuracy_Specifications Checked by. Team Leader- 001AS-QMS-FM-226 I N E01 3AS-021420-RT-1 303 Appendix B-Page 20 of 98 9 IN, EPA Method 3 Data Sheet Test Date Project#: Client/Site: Operator. Pre-Test Leak Check: Pipette Fluid Level in Capillaries: CO,(VN) 02(t,/N) ORSAT AnalysisAudit: Date: co, 0, Audit Gas Time of Reading Reading %02 *NOTE:Audit results must agree within Concentration Analysis A B)_ (B-A) 1 —.1 of the audit gas concentration %02: value. %CO2: Analyzer I.D.-A-ORS- Audi�Gas Cylinder I.D.: W-ND 40 R Run No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3— Avera CO2 4A-. L - , 02+CO2 TLI- 'Q 1.7 0- .02 Net Run No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average Coi— (6 97 02+COZ 11�1 .02 Net LA j zA Run No. U— Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average cc, 02+CO2 fts" 02 Net i Ct t LLi Run No. Orsat Bag ID. Time: Sample I Sample 2 Sample 3 Average CO3 02+CO2 .02 Net Dry Gas Molecular Weight: Md=(CO2*44/100)+(02*32/1 00)+(N2*2811 00) Montrose Air Quality Services,LLC 2 Now Pasture Road,Unit 5,Newburyport,MA 01950,T:(978)499-9300-F:(978)499-9303 www.montrose-env.com NE01 3AS-021420-RT-1 303 Appendix B- Page 21 of 98 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2 Test Dates: October 18-19,2022&October 25-28,2022 Particulate,unit No. 1 Outlet NE013AS-021420-RT-1303 Appendix B-Page 22 of 98 //�s MO NTRO S E Method Field Datashest(Isoldnetic) Page of AIR QUALITY SERVICES Project Inf a on Sampling Conditions ALT 011 TC ID: Ambient°F Ref.°F Date �/�Z ZZ Project# 021�ZU Static Pressure,in.H2O � U- Ambient Temp,°F Stack customer/Facility • I Barometric Pressure,in.HgF Raf.Barometer ID Probe Unit IDlSemp Location y(a17 Wind Speed/Direction Precipitation,Y/N,type Filter Box — Run M Operator Probe/Filter Temp Range,°F Z�6 2 5 Fliter Exit 3 z Sampling Equipment los Calibration Equipment Cheeks Pre Mid Post Meter outlet i Meterbox ID t` Meterbox Y 7/ Pitot(+),pass @ in.H2O @ j ❑ @ @ `f 3 Impinger Exit 3c�2 Umbilical ID j Meterbox OH@,in.H2O �'j t� Pilot(-),pass @ In.H2O @ 7j ❑ @ @ 2J Other Nozzle ID Nozzle diameter,Dn,in. (9 1 3 L Pilot visual Inspection pass ❑ ass pass Ref.Thermometer ID Pilot/Probe ID Pilot coefficient,Cp (f If Nozzle visual inspection pass pass pass Continuity Check ontinuity w/Pro er Polari Manometer ID Manometer d level yes Meter,cfm @ in.Hg �,zv@ f' @ �f )�) oe U Notes: Senst0v' `U IK-Factor 7 Intermediate leak check volume,fe — / / Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Differential,OH Stack Temp, Probe Temp, Filter Temp,'F Impinger Exit Temperature,'F Vacuum, Point# Time 24hr Vm,ft, AP In H2O Target Actual of eF Box Exit Temp,°F Inlet Outlet in.Hg Z 10 Z,lp r (0 2 q Z °° rn r 0 O L N CU L 2. 0 3 b U 2 "�2- 2.q 25 2 2 Z -Cep a) vo 3 Z Z 4 Z o c iZ 3 Z 'U M h O ZCF• Z � � i_ z-�Z o B' �- Z'w 9 M Z'_3 w z i Averages QA/QC Check:Completeness_Legibility_Accuracy_Specifications_Checked By Team Leader 001AS-QMS-FM-225 MO N TRO S E Method Field Datasheet(Isokinetic) Page_�of AIR. QUALITY SERVICES Project Inform n Sampling Conditions j( ALT 011 TC ID: Ambient°F Ref.°F Data Project# LU Static Pressure,in.H2O Ambient Temp,°F Informed Stack s 7 s Customer/FacilityR�G1f- Barometric Pressure,In.Hg (.C1.� Ref.Barometer ID UJ 3 Probe Unit ID/Sample .cation ` " L Wind Speed/Direction Precipitation,Y/N,type Filter Box Run# ML Operator Probe/Filter Temp Range,°F Z r Filter Exit Sampling Equipment IDS; Calibration Equipment Checks _ Pre Mid Post Meter outlet Meterbox ID ' Meterbox Y t (J Z �— Pitot{+),pass @ in.Hz0 -8— @ Impinger Exit Umbilical ID Meterbox et I@,in.H2O Z Pilot(-j,pass @ in.H2O i"@ ❑ @ @ �/ et Other Nozzle ID s Nozzle diameter,Dn,in. Pilot visual inspection wpass ❑ ass ass Ref.Thermometer ID Pilot/Probe ID Pilot coefficient,Cp IFY Nozzle visual inspection pass pas pass Continui Check Cantinui w!Pro er Polan Manometer ID �� Manometer zero and level �s Meter,cfm @ in.Hg @ �� - @ Notes: Sensitivity v° r K-Factor �l Z Intermediate leak check volume,i / I r Traverse Elapsed Clock Time DGM Reading, Velocity Head, Orifice Pressure Stack Temp, Probe Temp, Flter Temp,°F Impinger Exit Dry Gas Meter Pump Point# Time 241 Vm,fe AP in H2O Differential,nH 'F °F Temp,°F Temperature,°F Vacuum, Target Actual Box Exit Inlet Outlet In.Hg < 0)( Z z; 2_ 25Z s rn o 2, f z N 3 2„Z 2 X 0-1 U 4 Q Z49Z �v -43 Z 2� 2 z:1 co4-2 ry Z z Z zS�3 co � o Z 3 co r e Z z z Sv z S1� 5-1 Z 3 2 l 2 5 2,q5 z C .- U) U L M w z Averages QA/QC Check:Completeness,Legibility_Accuracy!Specifications_Checked By Team Leader 001AS-QMS-FM-225 M MONTROSE ) II Method Field Datasheet tsokinetie Page L Of ,L AIR QUALITY SERVICES Protect Info an Sampling Conditions `/ ALT 011 TC ID: Ambient°F Ref,°F Date Z Project# �6 W Static Pressure,in.H2O �lQ, Ambient Temp,°F — Stack Customer/Facility Barometric Pressure,In.Hg L�•� Ref.Barometer ID Probe Unit ID/Sampl Location t — Wind Speed/Direction /'Precipitation,Y>/N,type Filter Box , Run#M Operator Probe!Filter Temp Range,°F Z T Z Filter Exit ���/z— Sampling Equipment IDs Calibration y Equipment Checks Pre Mid Post Meter outlet Meterbox ID Meterbox Y a (/ Pilot(+),pass @ in.H2O - ❑ @ Impinger Exit Umbilical ID ?J " Meterbox AH@,in.H2O Pilot(-),pass @ in.H2O @ ❑ @ @ 3 Other Nozzle ID Nozzle diameter,Dn,in. Pilot visual inspection p s ❑ 9dSs pass Ref.Thermometer ID Pilot!Probe ID �Pltot coefficient,Cp Nozzle visual inspection pass pass pass Continuity Check ontinuity w/Proper Polarity Manometer ID Manometer zero and level Q.YeS Meter,cfm @ in.Hg '�@ Z(� @ 0,0Z co 20 Notes: Sensitivity K Factor v intermedlate leak check volume,ft3 / ✓ / Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Differential,6H Stack Temp, Probe Temp, alter p,7 Impinger Extf Tem erature,°F Vacuum, Point# Time 24hr Vm,ft9 AP in H2O Target Actual "F °F Temp,°F Inlet Outlet in.Hg 5 ��a 3Db SJ S'3 co LiZ5 rn 0 �.c zwllr) 2� 2 Z.S Z m 2 L Z m � C x 70 42 e 2 Z Z y, 3: z° Z Z- Q r 3©Ii. Q Z Z :' ZCe i ZiLe M Sa 2-b' 2 Z o N Z /0 t, b 3 D of M z Averages QA/QC Check:Completeness—Legibility_Accuracy_Specifications_Checked By Team Leader 001AS-QMS-FM-225 1�1 -.�O N T RO S E LILA Method 5/ Field Datasheet(Isokinetie) Page t t AIR QUALITY SERVICES Project information Sampling Conditions ALT 011 TC ID: Ambient'F Ref.'F Date 10-0`?-- Project# 20,0 '- Static Pressure,In.H20 l b;S AmbientTemp,'F Stack el-y Customer/Facliity I REIE to j LA`1$R- - No!K7�( A+W`vt2e�, t4 Barometric Pressure,In.Hg 3 0-53 Ref.Barometer ID At W5 Probe - Unit ID/Sample Location it - ou'i'LET Wind Speed/Direction Precipitation,Y Ntype Filter Box Run# y Operator C Probe/Filter Temp Range,'F 2�t of �?-5 Filter Fait Sampling Equipment IDs Calibration Equipment Checks re Mid- Post Meter outlet Meterbox ID ICE--4 Meterbox Y Pilot(+),pass @ in.Hz0 >; u ❑ @ Er @ .,`3 Impinger EYft 3466 y Umbilical ID d--3 Meterbox AH@,in.H,.O �02 Pilot(-),pass @ in.H2O @ �." ❑ @ �% V Other Nozzle ID Nozzle diameter,Dn,in. 0�3 iV Pilot visual inspection [pass ❑ p s 1 pass Ref.Thermometer ID Pilot/Probe ID {���^ Pilot coefficient,Cp o.9�v Nozzle visual Inspection C9/pass ❑ ssl% pass Continuity Check ❑Continultyw/Proper Polarity Manometer ID - Manometer zero and level yes Meter,cfm @ in.Hg 10,W1 @ 13" O.00Z @ U.Uc)�@ /3 Notes: Sensitivity 0.0 f K-Fac o S,) Intermediate leak check volume,fe f j / t / Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Stack Temp, Probe Temp, Filter Temp,'F Impinger Exit Point# Time 24hr Vm,ft AP in H2O Differenfial,AH 'F 'F Temp,'F Temperature,'F v1A Vacuum, Target Actual Box Exit Intel Outlet in.Hg t (9 d Sl gsl, 159 d,`/5 2, ;-3 xf� o �Sv �23 yS �� .� a 5 755,0 0•36 /, l48 %; .�M .7-s0 '�L 2- 5 q.3 co 3 ti SB,z 6,� 2.0 �.v �g3 aNSf 25"o • 36 d � y is '161, d • . y 1 '790 2-so �So 2-31 2/5 0 G )-v 966.,2 8,41.E 2_ Ll14 1 ycli a 15 d v,KS 2% 3Z -2 50 a5 -3'f 14 Y7 3 Co 3 �o �(0 via t.� t•y .X 2 2sv 2� G `(� ° 35 °l 7. D,�l a. L ?_ ), S a 2so �3x so s/ m e r pro z, z"�, 2-SS 2So 2- �5o 9S3 So 3 a 3 5a 9,3 61 qq a. q 1 3 Q y 5 1 3,0 q3 2-,i9 a.z 2,S1 2-5a 240 '23�- 5'c- 6� 3 l 6D o zv -4.116 a'D a S2- 1,250 22""L 53 .So 65 rDbt, 6,Ll �( 2-. 30� S!� ;-%5; o23 5 6d 3 7-0ioayr� c�.�JS ���� 3 29 .�SvS1 2�t K 60 3 -:� 5 1a05,6 0,15 6 2.55 2. 6 ;92, 5 ass /-1 �' 8D rnra_G d a, 5 ss ass trr K6 411 3 0 eg-5 D ,o U. s ?,66 ;.G `3t�. ;�.5� Zy5 �� 5 63 3co o,y zt 2, ��>," �s3 ASS L� �t 5 1lSaS,6 �,5v a•55 ��6 ;L5 0"51 3,CIL) 30 2-23 ASS aye �3 3 r65 163`l,6 0,60 3,66 3 -4- -s 155 2f q6 s� o 3 Ito 1039,E 065 303 L-1 �-55 q6 Oq Q r(s t o`t 3,) o 5 �v a<� 9 5 6 .-55 ?-c Ill?, 6 ra-o to;W o�1 35 z Averages t QA/QC Check:Completeness_Legibility_Accuracy_Specifications_Checked By Team Leader 001AS-QMS-FM-225 Op�ry�yy LA 1 I! S E Sample Recovery&Calibration Check Datasheet Page of^L ...�. AIR QUALITY SERVICES Project Infgrmati n Equipment Identification Data C'I Z L Project# ^ Ref.Thermometer Customer/Facility ��\Ce k r-�rl��f — Af o(� 114�c0 d�c l a O A• Hygrometer Unit ID/Sample Location Q fir (r E b V k�A. Field Balances) Run# �'' Operator MG Check Weights )�)06 Calipers Balance Audit(Field balance ust be within 0.5g of check weight mass) Ambient Conditions(Mobile Lab) Date C� 73 ZZ Relative humidity,% Standard mass,g (WO-® Temperature,"fF�_ Field balance mass,g Cl�rl. Mobile lab# Moisture Determination Runt Run 2 Run 3 Contents Initial Final Net Initial 1 Final Net Initial Final Net Knockout S(.Lt G gi t �'Sq•Z f'� �(olo,�" ( .9 Impinger 1 5 ND 51, Impinger 2 5 < <n• 2" U`QQ Impinger3 — l �. I (,Z2.� -5 Impinger 4 4' Z s S 1 7-3 3 Impinger5 KWO, I C �• Impinger 6 Impinger 7 Impinger 8 pQ Silica Gel S 3-e 1 S I Gu 6-91 Line Rinse Train Net Gain(Vic) Nozzle Measurements(Difference between any two measurements must not be more than 0.004 in(0.1 mm)) Nozzle 1 diameters O•.3)() D1 0-3 1p D2 0.Z i Q D3 G 3 0 Average Nozzle 2 diameters D1 D2 D3 Average Nozzle 3 diameters , / D1 D2 D3 Average Nozzle Material ❑ quartz glass ❑ steel El titanium ❑ inconel ❑ other Probe Type heated ❑ unh 4ad ❑ air-cooled ❑ water-cooled ❑ other Probe Liner ❑ quartz glass ❑ steel ❑ Teflon ❑ other Filter Information Front Half: ; quartz fiber ❑ glass fiber ❑ Teflon ❑ Teflon/quartz ❑ other Filter Number. Run 1: `I()�1'('l. Run 2:"e 3-I C)�-)3 Run 3:G l`ko Ol-i� Run Back Hatt. ❑ quartzfiber ❑ glass fiber ® Teflon ❑ Teflon/quartz ❑ other Reagent Information Sample Observations Type Lot Number QA/QCCheck:Completeness—Leglbllittj✓ Accuracy_,•,S eciflcatio Checked by O Team Leader, *. 001AS-OMS-FM-226 NE013AS-021420-RT-1303 Appendix B-Page 27 of 98 MONTROSE Sample Recovery&Calibration Check Datasheat Page of AIR QUALITY SERVICES Project Infortnation, Equipment Identification Date JOIL5- 1-11- Project# Ref.Thermometer Customer I Vacuity, ve(. 'A.- ab Aajaf t-- Hygrometer Unit ID/Sample Location Jr\ `�V 0\j�-VRA- Field Balance Run# Lk Operator Check Weights tj 00 q? 0 k"' ICalipers Balance Audit(Field balance njust op within 0.5g of check weight mass) Ambient Conditions(Mobile Lab) Date U Z.2. Relative humidity,% Standard mass,g (C7--0. Temperature,*F Field balance mass.g Mobile lab# Moisture Determination Run$ Run 2 Run 3 Contents Initial Final Net Initial Final Net Initial Final Net Knockout sw 01 'an,I Impinger I t Impinger 2 S t d 6Jl Z.0 Impinger 3 0-0 Impinger 4 ':h 1. 3 Impinger 5 k 5.0 251 13 Impinger 6 Impinger 7 Impinger 8 Silica Gel Line Rinse Train Net Gain(Vic) Nozzle Measurementsi(Difference between any two measurements must not be more than 0.004 In(0.1 mm)) Nozzle I diameters X Dl CJ,1�0 D2 Q,3\0 D3 0, \0 _Average Nozzle 2 diameters D1 D2 D3 Average Nozzle 3 diameters -D1 D2 Average Nozzle Material L1 quartz glass 1:1 steel 0 titanium 11 inconell El other Probe Type Whetd Ll ated 11 air-cooled El water-cooled L1 other Probe Liner ❑ quartz steel 0 Teflon Q other L— Filter Information Front Half Vql.rtz fiber L1 glass fiber LJ Teflon El Teflon/quartz LJ other Filter Number. Run 1:eg Run 2: Run 3: Run Back Half F-1 quartz fiber L1 glass fiber 11 Teflon 11 Teflon/quartz 1:J other I— Reagent information Sample Observations Type Lot Number QA/QC Check:Completeness A eglbllit y �� w , Accuracy Specificafl Checked Team Leader. 001AS-QMS-FM-226 NE013AS-021420-RT-1303 Appendix B-Page 28 of 98 EPA Method 3 Data Sheet Project# Test Date: Cllent/Slte: Operator: Pre-Test Leak Check: Pipette Fluid Level in Capillaries: CO,(&/N) 0,&N) ORSAT AnalysisAudit: Date: CO2 0, Audit Gas Time of Reading Reading % 2 *NOTE:Audit results must agree within Concentration Analysis (A) (B) B-A t 0.5%of the audit gas concentration %02: 9.LA 7,C).'L - (o,8 value. %CO2: . I I 0�9 I Analyzer I.D.-Ape-ORS- JAudit Gas Cylinder I.D.: (—C-WZCE U(— 12q— fe(—F-iT--0LI4(tJ-- Run No. Orsat Bag ID. Time: Sample I Sample 2 Sample.3 Average C, CO3 L.-A \ E, 02+CO2 0,Net Run No. Orsat Bag ID. Time: Sample I Sample 2 Sample 3 Average CO, 7a- Lt b.'5- 00.1-( 02+CO, 117. G k Cl, 0,Net net CA 0i Run No. Cirsat Bag ID. Time: Sample I Sample 2 Sample 3 Average CO, 02+COZ (,0 -0,Net 10, U(- rpnpq- DLA Time: Run No. Orsat Bag ID. Sample 1 Sample 2 Sample 3 Average CO, �5", 0 -- 02+CO2 Net Dry Gas Molecular Weight: Md=(CO2*44/100)+(02*32-/100)+(N2*281100) . Montrose Air Quality services,LLC 2 New Pasture Road,Unit 6-Newburyport,MA 01950-T-(978)499-9300-F:(978)499-9303 www.montrose-env.com N EO 1 3AS-021420-RT-1 303 Appendix B-Page 29 of 98 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2 Test Dates:October 18-19,2022&October 25-28,2022 Unit No. 1 Outlet PCDD/PCDFs ivtOWI AWSE NE01 3AS-021420-RT-1 303 Appendix B- Page 30 of 98 MONTROSE —EPA Method ; 3 Field Datashest(Isokinetic) Page of AIR QUALITY SERVICES Project Information Sampling Conditions ALT 011 TC ID: Ambient'F Ref.°F Date 10-)S--9X Projectt## , Static Pressure,In.H2O l Ambient Temp,°F Stack Customer/Facility —tJ0" W4AIO�rP' Barometric Pressure,in.Hg 30. 19 Ref.Barometer ID IV" Probe Unit ID/Sample Location V t — 0 uTt-GT Wind Speed/Direction Precipitation,Y I&type Filter Box 1-18-5 Run# i Operator 04 Probe/Filter Temp Range,°F )V:f-;-s Filter Exit Sampling Equipment IDs Calibration Equipment Checks Pre i Mid Post Meter outlet IT-6 Meterbox ID GG Meterbox Y �'2 GL Pitot(+),pass @ in.H2O @ 3 " @ ' _ Impinger Exit 306 L Umbilical ID UAAf;—5 f)—3 MeterboxAH@,in.H2O 1, Pltot(-),pass @ in.H2O @ > ..r L @ 7 Other 6916 Nozzle ID Nozzle diameter,Dn,In. 0,310 Pitot visual inspection [pass amass p''pass Ref.Thermometer ID Pitot/Probe ID 9 Pitot coefficient,Cp D Nozzle visual inspection ET'pass pass O'pass Continuity Check ❑Continuity w/Proper Polarity Manometer ID Manometer zero and level Ayes Meter,cfm @ in.Hg 0;w3 @ 15 4 aciol @ 15 ' t"003@ 15 w I Notes: X A P 4 6$°F Sensitivi 0�0 I IK-Factor ,9 Intermediate leak check volume,fe / / Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Stack Temp, Probe Temp, Filter Temp,°F Impinger Exit YCAD s Differential,off Temperature,°F Vacuum, Point# Time 24hr Vm,ft DP in H2O Target Actual °F °F Box Exit Temp,°F Inlet Outlet �UF) in.Hg t - 0 50 Zl' 1&jq� D' 2-6q 7�6 �—S Q 7`i`I 6 66 60 f IR i S ggb;L-2 0.5$ 2.6K 2-6 -3vi 50 2-5� 5 6`l 6' 5 10 q Y-6,6 0, 56 2-6 V .. 301 �-S o 2•t2 6 0 g o 53 co i 5 �iG q D_ 5� 2-69 �9- 1501 ;-50 250 6© '-70 60 .`3 M 0 o 1 >3 0,SI 2.k 2r 3�v c 5o Gt) 3 6 S M 7 �5 �tyyr� 0.5r Lf 30 50u,i 6<1'15 ),'30 .-3 0Lgo g50. -150 SAS E 6 55 `fCU 35 0'y 6 2,') 3 2 sv 2-50 s -q-!� 56 9 m 6Q � sz x < <t S t 3 v. 53 2-3 2-5 -�CQ�> 2-�;U 6z 65 60 9 2 0 5 a 1, 6 d s q ' �3 0 2- 3csa a s :ZSO1 619 �� b4 6 I a 2 s 5;?-51---� 6111 2.Jv 9.3 `3oaz� 2-50 �5o I `;q- g,2 6-;iL S 9 � 3 60 5`30. 1 D,q ),1(, 2..2 3ao � 2Y0 1 6 6y 3 b5 53 011 y n.q j LL 3cTv © :;L$G 1 61 %z dg s 513913 L9< 5L) y0 '�.q 21l2 �-5o 2S0 6to S13 CFil Si 9 S 5 Ll2 a 1 ®.5© ;Z.qo 2' 2 d 2`5 a :Uo 60 69 53 g t 60 5�16. D t"12 ItR 2 230 �Fo sc? ;'Y t gj SS (II`tD I.12 1.01 �T D—F 5 5S S( co 0 co 2 1110 55q;2 1,C1 cc 250 60 g n SS 2 125' O' 1, -3ct- :Z--5ca, a-5o 3 lc� 5C71.� 0��1.2 � (5i �•6 �5v 25L 67- g5 c� S.f o 6 62 o tL 5' -3. G,�l S ZLIG 1�2 21 950 y C x 3 58 Q 149 0150 .610 M Averages o W Z QA/QC Check:Completeness_Legibility_Accuracy_Specifications_Checked By Team Leader 001AS-QMS-FM-225 MI Z)NTR®SE Method ;laid Datashest(Isokinetic) Page ..1. ...n Q.VALIT4 SERVICES Project Information Sampling Conditions ALT 011 TC ID: Ambient°F Ref.°F Date Project# Static Pressure,in.H2O Ambient Temp,°F Stack 10 p—1 Customer/Facility 67!tMi.,/h�P, VP, — NDP(u A fJVO Xk Barometric Pressure,in.Hg 7i�c��1 Ref.Barometer ID Alln.fs Probe 1?-1'f Unit ID/Sample Location L/i` OaTLF—( Wind Speed/Direction Precipitation,Y&�type Filter Box Run# 1 OperatoOperato�ZXk Probe/Filter Temp Range,°F ate($ — Filter Exit Sampling Equipment IDs Calibration Equipment Checks Pre Mid Post Meter outlet . Meterbox ID Meterbox Y 1-O� (� Pilot(+),pass @ in.H2O ❑ @ @ @ It impinger Exit ��L1 Umbilical ID blIry— 5 0 "3 Meterbox OH@,in.H2O I.g-� Pi tot(-),pass @ in.H2O ❑ @ @- ❑ @ Other lj 1 Nozzle ID """ Nozzle diameter,Dn,in. d, Lo Pilot visual inspection ❑ pass ❑ pass ❑ pass Ref.Thermometer ID Pitot/Probe ID 9—tS-"4 Pilot coefficient,Cp D- Nozzle visual inspection ❑ pass ❑ pass ❑ pass Continuity Check ❑Continuity w/Proper Polari Manometer ID 6' Manometer zero and level JVyes Meter,elm @ in.Hg @ @ @ Notes: )(AP 4 6V aF Sensitivity ()r6 IK-Factor q-5$ Intermediate leak check volume,ft3 Traverse Elapsed Clock Time DGM Reading, Velocity Head, Orifice Pressure Stack Temp, Probe Temp, Filter Temp,°F impinger Exit Dry Gas Meter PumpxltD Point# Time 24hr Vm,ft AP in H2O Differential,aH °F °F Temp,°F Temperature,°F u Vacuum, Target Actual Box Exit Inlet Outlet f'� in.Hg Aso 62 341 -7-2, s1 �S 2.5'o �0 :?02 9-50 00 r 35 5'? 0¢L1 q 7 gs o `f 1.14 1-'1 :7-56 Oa 56 8 M 1.-13 °t 5 �o :7-5d t; If t5' fob d-- 3 1--97- 1-9 2-5,.5 s 6 5 62 I m l/ Lf�rrDG �/1,0 ry21 1�,/dal Ll �� �f J 21. ��[°1� 2/Y�' .2S© fig S c(/� (51 l t-t7/ 4 1 -s� �r-f L .f•�1( a2 lU t ! S�' CJ 6 l'� O C 0,((0 1.WZ 119 30-0 Mfrs 7-5�0 67- S ' *6 60 $ Q t 5 d�a�v o, qe) 1.�� � 2-99 � o 256 16 9 6 SS k 0,3 3 s 6 2 C1,"1 0,35 6 5� 2-f0 2 0 63 g9 Iq 3 3, 01"to �91 4 5 ZS0 ;Lf u o' 5q � CaS 436J5 19,g0 1�92 ('C1 2 5 2,50 �-51-3 Gl 6 SS & t bGl®,5-? or yS ;?./1 2-7- 2-47 ZOO 2fo 61 gJ I q 56, ( $ tqK, 0,� 2.16 2.�. 201 �Sb )I-fo 62 90 M a °),I,o 6i-16I 5 dt lid g 1<'4- 210 2S0 274o 62- qo 2,90 7-56 �Zfv 1 61 S;Z o f 55,16 0115, /T$ L 119 2 F(IX 250 2$0 S 1 C5 z�5 G S'7r 5 d 31 / t,9 2-so 50) 99 6&33 0,1;15 1.1& 2.- �Zs X50 ;7-50 5g q0 s3 `t 735 4661 OM 1,6 2,�L 2S 7-5o 750 1 59 Flo 777- MID 1155 611taq6 - 0 Averages UJ Z QA/QC Check:Completeness_Legibility_Accuracy_Specifications_Checked By Team Leader 001AS-QMS-FM-225 MONTROSE L,4 Method -1-3 Field Datasheet(Isokinstic) Page r of ..�. mR 4.UALITY SERVICES Project Information Sampling Conditions AST 011 TC ID: Ambient°F Ref.°F Date 10 ``� Project# Static Pressure,in.H2O '10 Ambient Temp,°F Stack 10-6-y _ Customer/Facility w�C t " AMfUN A,VO4V&'fl, PA Barometric Pressure,in.Hg Ref.Barometer ID Arlule, Probe 'g`K Unft IDISample Location U 2- �Vt-Z�7 Wind Speed/Direction Precipitation,Y/&Yiype Filter Box l(> Run# Operator Gvt Probe/Filter Temp Range,°F $ o2�i Filter Exit -� Sampling Equipment IDs Calibration Equipment Checks Pre Mid Post Meter outlet Meterbox ID Meterbox Y I•o Pilot(+),pass @ in.H2O @ -3 ` @ 3 @ 3 Impinger Exit y Umbilical ID 1PMfi }0-3 Meterbox OH@,in.H2O /. Pilot(-),pass @ in.H2O @ 5 3 t` t�@ 7 tom@ Other 3(IS Nozzle ID Nozzle diameter,Dn,in, 0,)1 0 Pitot visual inspection [pass ass [rpass Ref.Thermometer ID Pilot/Probe ID P,` Pilot coefficient,Cp 0_ l Nozzle visual inspection (pass [pass [pass Continuity Check ❑Continu w/Proper Polarity Manometer ID &—e`6 Manometer zero and level Oyes Meter,cfm @ in.Hg o XO' L@ 1 `' d,Lu^�@ 1 S` oCID3@ is Notes: �� Gg°r' Sensitiv' D 01 K-Factor q-9 Intermediate leak check volume,ft3 / / eFa Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Stack Temp, Probe Temp, Filter Temp,°F Impinger Exit Y Differential,aH Temperature,°F o 1 Vacuum, Point# Time 24hr Vm,fe AP in H2O Target Actual °F °F Box Exit Temp,°F Inlet Outlet F I in.Hg 4t o 1a15 r✓ 01 ,2.11 �. aCY5 2-5� a-St 4A GS 49 5500 ( b5,t D°K• fit( 2. a9 �S� �Sd1 8' b 0-35 116:� 62 M t5 6 IF 9- Is ®.35 r,Es I'� ��� �52 �c� 6 R 1zy 59 F Y) ?o ��s&-6 e.qa 1.91 119 Pa �So �-�0 �3 �.3 :�fl S 52 Sc� 65 �3 C of S �.t� �-2- � S" BSc BSc 6"� � 6 S Q de qc J�t �_� Xq L �50 G SAS � 6Z Q o -4 t t, L-1 � °it 2 O 9-9T �s� Asa G 9 � 5V �- 55 �t�i.6 t�61 d<� 5,y3 �-50 2-50 �� 5 01 fi 2 / �$o Z5a5� 63 59 . 0,�1t� 1.1z t.y 251 0 sc � 6 � , 6 o Gt 3- �, 6,c15 Z."7o a• 7-q ;tsue :zs� 6� 3 8 co �3+. v z��' 2,3G 30� r zs�; 66 I`0 � 66 X t 149.0 0<L[3� 2--25 o Ca Ch 0. t• 6v 4Q �g sus z t✓2C� 1�11 S 65J15% -- `—` Averages QA/QC"`4ck:Completeness_Legibility_Accuracy_Specifications_Checked By Team Leader 001AS-QMS-FM-225 MMO NTRO S E i PA Method Field Datasheet(Isokinetic) Page AtR QUALITY SERVICES Project Information Sampling Conditions ALT 011 TC ID: Ambient°F Ref.°F Date to--�-5--17- Project# Static Pressure,in.H2O ^1 v Ambient Tamp,°F Stack Customer/Facility tdofC jC jtt41 a r AAA Barometric Pressure,in.Hg 30<t`) Ref.Barometer ID N Probe Unit ID/Sample Location U1 Ot4l,6-f Wind Speed/Direction Precipitation,Y&+pe Filter Box 14e Run# Operator CM Probe/Filter Temp Range,°F 7-"V$ 9-1 Filter Exit Sampling Equipment IDs Calibration Equipment Checks Pro Mid Post Meter outlet 6V-6 Meterbox ID eE-L Meterbox Y 1.014t 0 Pilot(+),pass @ in.H2O ❑ @ El El@ r Impinger Exit Umbilical ID VMZ-SD'3 Meterbox BH@,in.H2O t.��� Pilot(-),pass @ in.H2O ❑ @ ❑ ❑ @ Other 3l Nozzle ID Nozzle diameter,Dn,in. 0.3 iu Pilot visual inspection ❑ pass ❑ pass ❑ pass Ref.Thermometer 1D Pitot/Probe ID -� Ll Pilot coefficientCp D:'64 Nozzle visual inspection ❑ pass ❑ pass ❑ pass Continuity Check [IContinuity w/Proper Polarl Manometer ID Manometer zero and level Pyes Meter,cfm @ in.Hg @ @ @ Notes: SensftN b-6 I JK-Factor b1-g Intermediate leak check volume,it' / / Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Ori Stack Temp, Probe Temp, Filter Temp,°F Impinger Exit Temperelure,°F X Vacuum, oP in H O Differential,GH °F °F Temp,'F Point# Time 24hr Vm,fts s Target Actual Box Exft Inlet Outlet AP in.Hg p t ea-v 7q, 165,5-7- O,q.Z 2_d( 9v 2°l a-53 �-So &r to � S $ c�5 61's' 0.Yz .Ct 2.0 301 �5� Sv �� q0 8 �i 00 ?� 1 L30 I'M qd 7? 1,0 0 21-11 ;7. '3 ko `31< 0-q 5 '2,t z �� �S� 5 6 5 Rv 6 s' �( f� Wi.o X35 9,-11 20 a-s-o Is 6s qt t�.K`1 a<35 2.41 � ,b 0,5y 2.5 .L ca BSc 2-fo 1 63 ci i q-9 60 2,10 2-- 36z- 2-50 2-56 1 61 RCS G3 to Q 0�50 30z 7,50 0 6,2 6 to IC n o p 6 g q `1 g ,g 01`t t ;L•9 a.z fir, -2 y0 2--so 90 0.50 2r410 a y )-CiS �Sv 5� 6s G� %3t< d<5 3 �_� 3(s d2Sv .2Sc` I S 3 2-S 306 s0 sc� 5 dS X 3gglo 015 3 Z_ 03 aso zs� �0 �" G it N �-V, 2_y • ;jz� St. �v a( 8 6( /0 0 1 ail S /d M z, Averages QA/QC Check:Completeness_Legibility_Accuracy_Specifications_Checked By Team Leader 001AS-QMS-FM-225 i MO N T RO S E Method Field Datasheet(Isokinstic) Page 1 of AIR QUALITY SERVICES Project information Sampling Conditions ALT 011 TC ID: Ambient°F Ref.°F Date 10 "ZQ-m Project# Static Pressure,In.H2O ®.(� Ambient Temp,°F (00 Stack ' CA Y Customer/Facllity h l�b -No c/ Barometric Pressure,In.Hg Ref.Barometer ID Jif V,7 57 Probe (10 00 Unit ID/Sample Location ` —r- ov}w Wind Speed/Direction Precipitatior&N,type Filter Box Run# Operator Probe/Filter Temp Range,°F Filter Exit Sampling Equipment IDs Calibration Equipment Checks Pre Mid Post Meter outlet / Meterbox ID FrL\e Meterbox Y t•024 0 Pilot(+),pass @ in.H2O @ Impinger Exit Umbilical ID !d Meterbox AH@,In.H2O 1, - Pilot(-),pass @ in.H2O @ E}--- ❑ @ Other 'I t Nozzle ID Nozzle diameter,Dn,in. G : Pilot visual inspection pass pass ass Ref.Thermometer ID Pilot/Probe ID Pitot coefficlent,Cp 0.b Nozzle visual inspection pass pass pass Continuity Check WContinuf w/Proper Polarity Manometer ID Manometer zero and level yes Meter,cfm @ in.Hg 0.01;Z @ �, ` @ ` Notes: Sansifiv' 0-©1 K-Factor °6 Intermediate leak check volume,fe Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Stack Temp, Probe Temp, Filter Temp,°F Impinger F Tam erature,°F Vacuum, Point# Time 24hr Vrn,ftg AP in H2O Differential,©H °F °F Temp,°F p Target Actual Box Exit Inlef Outlet in.Hg f b S S6b, 100 `t 2, �% 2 5z- gLj 6 1 ° S;_ Z [ a !J Ir.� 2, c 25 !o toy- o 1. 7- -LS1 244i o M CU 3� 3. 3 ' X 751 `'1 Z.IL Z°1 S- ZS 3 U-1 S'3" ` -4- Fi � CL Z.t q ?T 1 Z r o v q I N 0 Zc Zit vil 2 qA ® 0 ! zst '150 61 fit, 2., 0.513, s' ZTt z41 > b l T 6125i p 0.13 IAO Z vo ZS'L Z4ei Cj C� Z1510 Z.L1 Ito ?n I i 71 o z 170 36° t�.L4 S Z.7- 0 51 Zs� t it t q a.° 30 2S 251— 5- 61 0 fv� o co 1 t� 011 1 r -tcyd zI(Cl 75(1 Averages QA/QC Check:Completeness_Legibility_Accuracy—Specifications_Checked By Team Leader ODIAS-QMS-FM-225 MMONTROSE �P�(' -Method 2 Field Datasheet(Isokinetic) Page Z of AIR C.LUALITY SERVICES Project Info ation Sampling Conditions ALT 011 TC ID: Ambient IF Ref.IF Date 0 7i ZZ Project# Static Pressure,in.H2O —10.0 Ambient Temp,IF Stack Customer/Facility W�Q�lrb�r t .�,�9 G �Ar Barometric Pressure,In.Hg VBIZ Ref.Barometer ID w3 Probe Unit ID/Sample Location I k t F � Wind Speed/Direction Precipitation�N,type Yr, Filter Box Run# Operator AA Probe/Filter Temp Range,IF Filter Exit Sampling Equipment IDS; Calibration Equipment Checks Pre Mid Post Meter outlet Meterbox ID Meterbox Y •®ZK O Rot(+, s @ In.H2O ❑ @ ❑ @ ❑ @ Impinger Exit Umbilical ID Meterbox AH@,In.HZO j Pltot(-),pass @ in. , ❑ @ @ ❑ @ Other Nozzle ID Nozzle diameter,Dn,in. J(a PRot visual Inspection ❑ pass ❑ pass Ref.Thermo er ID Pilot/Probe ID - Pilot coefficient,Cp 0' Nozzle visual inspectio ❑ pass ❑ pass ❑ pass Continul heck ❑Continuitywi er Polarity Manometer ID Manometer zerfof,and level yes Meter,cim g @ @ Note . Sens" K-Factor 'D In ediate leak check volume, o Ortlice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Stack Temp, Probe Temp, Filter Temp,°F Impinger Exit Temperature,°F Vacuum, AP in H O Differential,AH °F °F Temp,°F Point# Time 24hr Vm,fts z Target Actual Box Exit Inlet I Outlet in.Hg 0, 'Z4Q VACI M 1 611 8Z, .� 6 Z.O Z'SQ 75D 1 6Z 1 :73 b 1 00 Z 13 ' -+7, ® fir C�.HC 7.Z. Z-(q Zs-L z b �-�{ �i a 4 su - ® Z 1"Z '700 zro 6-L 0 6 -4 q 6 11 ) re, 4 Z. Z. 3 0 -ZS1 z 1 b -4 -�- co 30s Q ti t 1 or5 2.1{) 3ot 70 750 Z 13S 160ILl, GD S .4 Zsl zS L �- 1 "Z5u I (a O. 7 . q e'�- j °t 2 2 `1 �S i In 1, 1 0.11. Z 715 'ISO �53 ss E I ZOO ��2fi,(� 0s5® 2. 7 Z""i Zi�i r3rd 5" Cl) 1 toy- ZIS Zy� S % -75- �clJ ?i v C2 4( T1 1100 Z ,2 Zr 1 .S-0 Z, -1KA 2a 0 53 95 ems' (. N 0 LA 730 0)•0 ©. 'S Z.Z 'Z 1b( Z�C' 7b ILI M 2 _ :� L S o 1 `:r (19 Averages CA/QC Check:Completeness_Legibility_Accuracy_Specifications_Checked By Team Leader 001AS-QMS-FM-225 M �T�+q� 1V 1 ll Sample Recovery&Caliibration Check Datasheet Page of ®_.�, AIR QUALITY SERVICES Project Info atlon Equipment Identification Date I-Project# �A r Ref.Thermometer Customer Facility W �(' 'fio✓� r — .A)OA)L4 NCtc t r Hygrometer Unit ID/Sample Location i1i k r r Uu�-�Q t' Field Balance j pr l Z Run# 3 Operator Check Weights 1 ofl(�An Calipers Balance Audit(Field balance m t be within 0.5g of check weight mass) Ambient Conditions(Mobile Lab) Date /C7 ZS 7-within 4i �� Relative humidity,% Standard mass,g /y6 0-O Temperature,°F Field balance mass,g Mobile lab# list.0 nk Moisture Determination Runt Run 2 Run 3 Contents Initial Final Net Initial Final Net ,� Initial Final Net Knockout ��. 71,5 � . 101 tV .�rjU•S 10 S:S: Impinger 1 W10 j(�, o ��. G G Impinger 2 41-0 • 1c (01 U rrJ G 33 1 Impinger 3 60 b. b,o, 10. `�- Impinger 4 Impinger 5 Impinger 6 Impinger 7 Impinger 8 Silica Gel Si �3. �o Z(D•v C1 4+6 Line-Rinse 3 (® !3�/� U3, .0 Traln Net Gain(Vic) Nozzle Measurements(Difference between any two measurements��must not be more than 0.004 in(0.1 mm)) Nozzle 1 diameters (9'3 '10 _D1 Q�M C7 D2 D3 Q.j 0 _Average Norde 2 diameters D1 D2 D3 Average Nozzle 3 diameters D1 D2 D3 Average Nozzle Material �❑ qu �glass ❑ steel ❑ titanium ❑ inconel ❑ other Probe Type 6 heated ❑�unnhh led El air-cooledEl water-cooled ❑ other Probe Liner ❑ quartz Lv'glass ❑ steel ❑ Teflon ❑ other Filter Information Front Half: quartz fiber ❑ glass fiber ❑ Teflon ❑ Teflon/quartz ❑ other Finer Number. Run 1: Run 2: '— Run 3: Run Back Half: ® quartz fiber ® glass fiber ❑ Teflon ❑ Teflon/quartz ❑ other Reagent Information Sample Observations Type Lot Number QA/QC Check:Completeness_Legibility✓Accuracy_ pecificabons_ Checked by: �q Team Leader. AlM ODIAS-QMS-FM-226 r—+ N E01 3AS-021420-RT-1 303 Appendix B-Page 37 of 98 EPA Method 3 Data Sheet Project Test Date: Client/Slte: Operator lwvr Pre-Test Leak Check: m�0 Pipette Fluid Level In Capillaries: co,0Y IN) 0"61N) ORSAT Anal sisAudit: Date: /0 6 co, 02 1-NOTE:Audit results must agree within Audit Gas Time of Reading Reading %0' Concentration Analvsis (A) (B) (B_A) 5%of the audit gas concentration %02;1().Cl'? i6lw/2I_ q.-5 U. I& value. %CO2: (0. Analyzer I.D.-A-ORS- Audit Gas Cylinder I.D.: CC_60'z1"'( Run No.0 11"13 Orsat Beg ID. Time: Sample 1 Sample 2 Sample 3 Average CO, E5, (o 02+CO2 6 47 02 Net Run No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average CO2 v. 02+COZ .5�_ d 02 Net ((),q \0. t 0-� Run No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average CO, 02+CO2 tt�0% �2 A Net \. — Run No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average CO2 02+CO2 .02 Net Dry Gas Molecular Weight: Md=(c02*44/100)+(02*32/100)+(N2*28/100) Montrose Air Quality Services,LLC 2 Now Pasture Road,unit 5,NewbuWart,MA 01950*P(978)4911-9300•F:(978)499-9303 www.montrose-env.com N EO 1 3AS-021420-RT-1303 Appendix B-Page 38 of 98 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2 Test Dates: October 18-19,2022&October 25-28,2022 Unit No. 1 Outlet CondensableParticulate NE01 3AS-021420-RT-1 303 Appendix B- Page 39 of 98 ALONTR®SE Method _Field Datasheet(Isokinetic) Page= AIR. QUALITY SERVICES Project Information Sampling Conditions ALT 011 TC ID: Ambient°F Ref.°F Date 10•-7q -�L7•. Project# Static Pressure,in.H2O �- Ambient Temp,°F Stack °-/-/-I Customer/Facility l�rH t'4kr'8�" �0 [IKOpVt%R Barometric Pressure,in.Hg Z'1 10 Ref.Barometer ID Probe " iy-/ Unit ID/Sample Location U't - a Wind Speed/Direction Precipitation,Y type Fllter Box Run# ( Operator Probe/Filter Temp Range,°F 5; Filter Exit Sampling Equipment IDs Calibration Equipment Checks Pre Mid Post Meter outlet Meterbox ID tE' 6 Meterbox Y t 6:�K O Pilot{+),pass @ in.H2O @ nger Exit Umbilical ID UP9 _100 _r Materbox AH@,in.H2O Pltot(-),pass @ in.H2O ��. ❑ Other �,073 Nozzle ID Nozzle diameter,On,in. Pilot visual inspection ass ss 0"Pass Ref.Thermometer ID Pilot/Probe ID 1PItot coefficient,Cp Q Nozzle visual inspection ss Continuity Check ❑Contlnuity w/Proper Polarity Manometer ID t '' Manometer zero and level ,V yes Meter,cfm @ in.Hg 16,6041 @ l$" 7 @ o,6o 3 @ Notes: CAM 465 T Sensitivity t}�t7 ( JK-Factor �-' Intermediate leak check volume,f0 / ! Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Stack Temp, Probe Temp, Filter Temp,°F impinger Exit Tem ereture, IQI Differential,6H °F Vacuum, Point# Time 24hr Vm,fe AP in H2O Target Actual °F °F. Box Exit Temp,°F Inlet Outlet °F in.Hg S 61, 5 -r6 �-Y7- Sz �Sz a �9 �� 251 5 Io 1-1 t.� ��6 S© �5b S � S °° rn 56 . 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Pilot(-),pass @ in.H2O ❑ ❑ A Other :0 31 Nozzle ID Nozzle diameter,Dn,in. Pilot visual inspection ass ❑ a P Ref,Thermometer ID Pilot/Probe ID ( Pltot coefficient Cp (� Nozzle visual inspection ass Continuity Check [IContinuity w/Proper Polarity Manometer ID �' Manometer zero and level }yes Meter,cfm @ in.Hg fj,00 t @ /3 @ �,OD 3 @ 3 �Notes: 6NyL �'G Sensitivity— .v f K-Factor intermediate leak check volume,fP / / I e. 05CP IYIG_ X(1? Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Stack Temp, Probe Temp, Filter Temp,°F impinger Exit Temperature,°F C M Vacuum, - Point# Time 24hr Vm,fe AP in H2O Differential,AH °F °F Tamp,°F Lr� in.Hg Target Actual Box Exit Inlet Outlet 0 l .2,�1uz t.S7Sf E;f6 b ' 30 �- C) 25'0 SS � t.� 1. 30 750 e155 S t S P77- 6 � ! 3 ZS' �5'� G g 1- 0� S �56 65 $ 2-5 1�! S' r>0 e LSD � 6 o 35 174,v l a-q� Z� 6 -4 m q0 q5 19619 1. `3� e) Sv 57 7, 0. 50 1�o�2 1. 65 � sv s z "4- -4 5* �! 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OOIAS-QMS-FM-225 M MO N TRO S E FP A Method 2't Field Datasheet(Isokin®flc) Page AIR QUALITY SERVICES Project Information Sampling Conditions ALT 011 TC ID: Ambient°F Ref.°F Date jQ-�� ��'� Project# ��f3 3 -C7�1 u,2D Static Pressure,in.H2O 1 IS Ambient Tamp,°F Stack Customer/Facility �'t - q Barometric Pressure,In.Hg Ref.Barometer ID ArW5 Probe 't P Unit ID/Sam le Location �}(� `fl riT Wind Speed/Direction Precipitation,Y(3 type Filter Box KB-tt Run# 3 Operator Probe/Filter Temp Range,°F Filter Exit -- Sampling Equipment IDS Calibration Equipment Checks Pre Mid Post Meter outlet Meterbox Y 63 e �- 1r '-!o Pilot(+),pass @ in.HZO @ � Impinger Exit Meterbox ID (7 �qQ(7 Umbilical ID U� - ©�'� � Meterbox�H@,in.Hz0 1.$'�-y Pilot(-),pass @ in.HZO _ ElOther �,.0,�.3 r-- s- Pilot visual inspection pass ❑ ss —�-P=sQ Ref.Thermometer ID Nozzle ID Nozzle diameter,Dn,in, Pilot/Probe ID `j P'dat coefficient,Cp U..'2, 4 Nozzle visuai inspection ❑ pa --Q--P3 Confinui Check ❑Continulty wt Proper Polarl Manometer ID �'b Manometer zero and level yes Meter,cfm @ in.Hg oxo y @ /3` @ ;(��' @ 1 Notes: rd 5 Sensitivity0,0( K-Factor -- intermediate leak check volume, Orifice Pressure Filter Temp,°F tmpinger Exit Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, DifferenBal,aH Stack Temp, Probe Temp, Temperature,°F nM Vacuum, Point# Time 24hr Vm,to oP in HZO Target Actual °F °F Box Exit Temp,°F Inlet Outlet (�—) in.Hg 1550 �13 1-mod 1 3iv �s� �S1� �3r 6 t-s' 00 tt, �-511 1-9 2-5;0 s� '73 69 5 ;-541�17 1z9 36� �S�- S k 6 ° Nr �� 6 8- 6 53 -IT 69 6` 4. a) -4 6 a 3y .a b g 30 61 6 g 6 :zg 3�G asz �sc� sl doe d 4S z G,G 1-S' 64- 550 c 51 4fb706� 6 6g 6` Q gt -1-6 '4-5t, G o t � �6 <a`l b _� 3vz� sd S 176 -3 36 �4Cg ass1 1 51 r 6 o Ct(t 1-$ 105 25,9 53 53 r3 G & ( 305 aS'> r2Scs s3 �ZO 3 1 30S o q 6 Ica �5 12, -30 5 50 S 0 8( 70 4( 6 0 i0c) 369 ) o 61 $z 7-0 3 6 Utl C) 8Z ( 6 o q$ sa &7, :7-S Q il5 tY� fSO:Z, 33 Sc1 w z Averages QA/QC Check:Completeness_Legibility_Accuracy_Specifications_Checked By Team Leader D01AS-QMS-FM-226 j i MONTROSE Sample Recovery&Calibration Check Datasheet Page of AIR QUALITY SERVICES Project Information Equipment(dentfflcatton Date walm';_7 Project# Ref.Thermometer Custom;PIF.cillty P Hygrometer Unit ID/Sample Location Field Balance 5-AV Check Weights 10(n- Run Operator Calipers Balance Audit(Field balance must be within 0.5g of check weight mass) Ambient Conditions(Mobile Lab) Date Lyf�11:7_ Relative humidity,% Standard mass,g WOO Temperature,'F -- Field balance mass,g _Lcil, 9 Mobile lab# ZSLrAe,� Moisture Determination . Runt Run 2 Run 3 Contents Initial Final Net Initial Final. Net Initial Final Net -;-,1 4 , ri 9 Knockout JTr _A21il"I - -' 77 5 6 '0 - '1 & 1g, I Impinger I M-r _6D (ko"" 16, Impinger 2 LN -46TE 76!ILL ZILt-It Impinger 3 Impinger 4 Impinger 5 Impinger 6 Impinger 7 Impinger 8 Silica Get Line Rinse Train Net Gain 0/10 Nozzle Measurements(Difference between any two measurements must not be more than 0.004 in(0.1 mm)) a 's�D1 D2 D3 Average Nozzle 1 diameters Nozzle 2 diameters �_Dl D2 D3_Average Nozzle 3 dia rs DI D2 _D3 Average NozrJe5ptfi'r1aI El quartz 11 glass El steel 0 titanium ❑ inconel L1 other Probe Type P"'heated 0 unheated' El air-cooled El water-cooled El other U" Probe Liner EI quartz 'glass 13 steel L1 Teflon LJ other Filter Information Front Half. IiYquartz fiber Ll glass fiber L1 Teflon F1 Teflon/quartz ❑ other Filter Number. Run 1: Run 2: —Run 3: Run Back Half L1 quartz fiber Ll glass fiber Tefion EJ Teflordquartz ❑ other Reagent Information Sample Observations Type Lot Number QA/QC Check:Completeness_,Z[egibility—LZAccura-Y_LZ913-cificall-ns Checked Team Leader: ODIAS-QMS-FM-226 NE01 3AS-021420-RT-1 303 Appendix B- Page 43 of 98 EPA Method 3 Data Sheet Project#: Test Date: Operator: Client/Site: Je ' S/ 10 Pre-Test Leak Check: Pipette Fluid Level in Capillaries: C%(bl N) 02((Y IN) ORSAT Analysis Audit: Date: CO2 02 Audit Gas Time of Reading Reading %0' *NOTE:Audit results must agree within Concentration Analysis (A) (B) _ (B-A) 0.5%of the audit gas concentration %02: �C).9q 'q-1 20-1z' value. %CO2: �ILI, 0 2().11 Analyzer I.D.-A-ORS- Audi Gas Cylinder I.D.: CC (cO'ZP U I — pop 3— Run No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average CO2 O 1 02+CO2 1�1 Co 0,Net RIC)- Run No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average CO, '5 02+CO2 0,Net 9 Run No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average CO, 02+CO2 0,Net Run No. Orsat Bag ID. Time: Sample I N-1Sample,1-"'- Sample 3 Average CO, X 02+CO2 A Net Dry Gas Molecular Weight: Md=(CO2*44/100)+(02*3211 00)+(N2*28/1 00) Montrose Air Quality Services,LLC 2 New Pasture Road,Unit 5-Newburyport,MA 01950-T:(978)499-9300•F:(978)499-9303 www.mantrose-env.com N EO 1 3AS-021420-RT-1303 Appendix B-Page 44 of 98 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2 Test Dates:October 18-19,2022&October 25-28,2022 Unit No. 2 Inlet Hydrogen Chloride � v MOtom!TKOSE NE013AS-021420-RT-1303 Appendix B-Page 45 of 98 Static Pressure,In.H20 /I Ambient Tamp,T (C7 r"!fall— Barometric Pressure,In.Hg .4 Ref.Barometer ID • _ I lr,. . Unit ID/Sample . ,. G • �� _ FilterProbe/ Tamp Range,Operator _ CalibrationNozzle diameter.Dn,In. -1AM DGM Reading, Velocityi CM MOM ■��r ME ���0 ME .„ at Information sampling Conditions - _ y _ -• •= r Precipitation,stomeriFeclifty ��J'Baromstrlc Pressure,In.Hg Ref.Barometer ID _Unit ID/Sample Location Wind Speed/DIredon Probe I Filter Tamp Range,T Rvb e-\14 A Calibration Meterbox Y:Noz7Je diameter,Dn,In. .. ._ ,_ i rc 4 ■ , IIIIIIIIIIIIIIIIIIIIIIIIINanom :_ zero and _* ��Olr _ - i • • � . yam 'Nozzle ID Nozzle diameter,D in. 61-Y ME Lim K-Fact HIM a . .. DGM Reading, Velocity Head, ® Vm,fe at,in r12V . MOTS f'r1 � F� li' � i' �� ��'� • p Moro«�r � MNIIEMM MIEMMAIMOM 2�,-R - �j)U - v O 1T S E Sample Recovery&Calibration Check Datasheet Page—L-of ...'.. AIR W)ALITY SERVICES Project hrformado Equipment Identification Date I(Ut Z 1 P_roje�c"t# Ref.Thermometer Customer/Facility Hygrometer Unit ID/Sample location V rll I — _— t�l-1 � Field Balance Run# ��3 Operator /^V n�ff Check Weights Calipers Balance Audit(Field balance must b within 0.5g of check weight mass) Ambient Conditions(Mobile Lab) Date c 2 Relative humidity,% Standard mass,g /�7J Temperature,°F Field balance mass,g �J�1�7 3 Mobile lab# Moisture Determination Runt Run 2 Run 3 Contents Initial Final Net Initial Final Net Initial Final Net Knockout Impinger 1Ll Impinger 2 Impinger3 Impinger4 Impinger 5 Impinger 6 Impinger 7 Impinger 8 Silica Gel Line Rinse Train Net Gain(Vic) Nozzle Measurements(Difference between any two measurements must not be more than 0.004 in(0.1 mm)) _y Nozzle 1 diameters D1 D2 D3 Average Nozzle 2 diameters D1 D2 D3 Average Nozzle 3 diameters D1 D2 D3 Average Nozzle Material ❑ quartz ❑glass ❑ steel ❑ titanium ❑ inconel ❑ other Probe Type ❑ heated ❑ unheated ❑ air-cooled ❑ water-cooled ❑ other Probe Liner ❑ quartz ❑glass ❑ steel ❑ Teflon ❑ other Filter Information Front Half: ❑ quartz fiber ❑ glass fiber ❑ Teflon ❑ Teflon/quartz ❑ other Filter Number. Run 1: Run 2: Run 3: Run Back Half: ❑ quartz fiber ❑ glass fiber ❑ Teflon ❑ Teflon/quartz ® other Reagent Information Sample Observations Type Lot Number QA/QC Check:Completeness_Legibility_Accuracy Specifications_ Checked by- Team Leader. 001AS-QMS-FM-226 NE013AS-021420-RT-1303 Appendix B- Page 49 of 98 A. EPA Method 3 Data Sheet Project# C� t 44Drb Test Date Client/Site: W �u`ct iVqjZw- JV_ Operator: Pre-Test Leak Check: 0!!�4-6 Ic' Pipette Fluid Level in Capillaries: CO,(0Y N) 02(6)/N ORSAT Analysis Audit: AfClr Date: CO2 02 Audit Gas Time of Reading Reading %02 NOTE*Audit results must agree within —Concentration Analysis (A) (B) (B-A) 0.5%of the audit gas concentration %0" value. %CO2: xl``J' 7.2-- 22. 16 Analyzeri.D.-A-ORS- r Audit Gas Cylinder I.D.: CC aRD"I P?D�614--(7't-5.P FQ No. Orsat Bag ID. Time: Sample 1 Sample 2. Sample 3 Average C>1 / CO, c1l, kp 02+CO2 02 Net _11TW Run No. Orsat Bag ID, Time: Sample 1 Sample 2 Sample 3 Average -7 CO, 1 17 Z 02+COI 11 9 — — 02 Net "7"'7 Run No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average CO, rQ 17i 01+CO2 7'Lr If'Y 02 Net C"'- Run No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average CO, 02+CO2 02 Net Dry Gas Molecular Weight: Md=(CO,*44/100)+(02*32/100)+(N2*281100) Montrose Air Quality Services,LLC 2 New Pasture Road,Unit 5-Newburyport,MA 01950-T:(978)499-9300-F:(978)499-9303 NE01 3AS-021420-RT-1 303 ApVVWTrmg T%896998 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2 Test Dates:October 18-19,2022&October 25-28,2022 Unit No. 2 Inlet Mercury NE01 3AS-021420-RT-1 303 Appendix B-Page 51 of 98 MO NTRO S E Method L� Field Datasheet(Isoktnetic) Page�_of AIR QLALSTY SERVICES Project Information Sampling Conditions ALT 011 TC ID: Ambient°F Ref.IF Date ,Project``# �5���'-OZ Static Pressure,in.H2O Ambient Temp,IF b, Stack — Customer/Facility W ' a b f\ (�! Barometric Pressure,In.Hg 2A S1 Ref.Barometer ID � Probe —t Unit ID/Sampie Location U n i f Z l nwA - Wind Speed J Direction ,7 Preclpiiallon,Y/N,type boo\ Filter Box Run# ` O orator 1.. Probe/Fitter Temp Range,IF 'L�1 Cam✓ Filter Exit t Sampling Equipment IDS �t Calibration Equipment Checks Pro Mid _ Post Meter outlet Meterbox ID ` 7 Meterbox Y .V t7 Pilot(+),pass @ in.H2O EA Qc @ 9 @ Impinger Exit fJ Umbilical ID U Meterbox dH@,in.H2O . q� Pilot(-),pass @ in.H2O @ ?� 3 Other r Nozzle ID b ~�1 Nozzle diameter,Dn,in. �175 Not visual inspection pass pass pass Ref.Thermometer ID /Probe ID ' \ Pilot cofficient,Cp Nozzle visual Inspection pass !tp--s- PW pass ConUnul Check ❑Continul w/Proper Polarl Manometer ID 1 \ Manometer zero and level yes Meter,cfm @ in.Hg p,cX�l @ g O,c @ ®. 3@ Z Notes: �,. �'{D" ®s Sensitivity K-Factor vl Z Intermediate leak check volume,ft Orifice Pressure Dry Gas Meier Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Stack Temp, Probe Temp, Filter Temp,°F Impinger Exit Point# Time 24hr Vm,if nP In H2O Dffferentlal,6H ,F °F Temp,°FoTempamW.MuF Vacuum, Ta et Actual B x Extt In.Hg AIG t evi Co o LO p I $° L4 L4 co It`tno q 45) 1 OO-Z.-3 Q ,L4 t a,`72 1 Ll 2 TZ-b 15,Z 1 - q —I I C Vo So g' S- �► e.� t 6 2�v 2S 2 1 ow on C\ �,°\ LA-�q 51 2 Z t o -7�'t 1 � toe t c� •3S .�''l t,H ��� t ��� � �1�7 1k1 l. 0,Ll+�t t � 1,s 2 2 Z � � ply ot N 0,L42 15Z S o tt4,j et �,� 1.sc� `, V1-111 1g� 25'Z Z 3 - q W tZ, \ b,a•�,bW® t7• b t.�1 t• 2�Z �°"L '� ®7 10 z Averages CIA/QC Check:Completeness_L _egibility_Accuracy Specifications J Checked By�_ Team Leader 001AB-OMS-FM-225 _ — i MO N TRO S E EEL Method 2� Field Datasheet(Isokinetie) Page- —of AIR gUALITY SERVICES Project InformGation Sampling Conditions ALT 011 TC ID: Ambient°F Ref.°F Data , t p'2� Project# Oz0,L/l Static Pressure,In.H2O .Q Ambient Temp,°F �� Stack Customer/Facility ti,Sk?.i\D�7(a\'Ul I I � _ Barometric Pressure,in.Hg p .) Ref.Barometer ID `^f�7 Probe . Z Unit ID/Sample Location (t i !1 Wind Speed/Direction p Precipitation,Y/N,type Filter Box Run# Operator t..� Probe/Filter Tamp Range,°F H Z Filter Exit Sampling Equipment IDs Calibration Equipment Checks Pre Mid Post Meter outlet A Q Meterbox ID J17 Meterbox Y Q Pilot(+),pass @ in.H2O @ @ �j Npass Impinger Exit`, Umbilical ID Up) `Q Meterbox aH@,in.H2O l•�3 C\ PhOt(-),pass @ In.H2O @ j @ 3 Other Nozzle ID (D Nozzle diameter,Dn,in. C), �5 Pilot visual inspection pass pass Ref,Thermometer ID W Pilot/Probe ID d b�- Pilot coefficient,Cp � Nozzle visual Inspection pass passss Continuity Check ElContinui w/Pro er Polari Manometer ID Manometer zero and level yes Meter,cfm @ in.Hg E,tom @ V,)b @ 4 3 Note, } (,'• "' \� Sensitivity ;1 rC7 K-Factor ,t Intermediate leak check volume,f? 0�b, �! Q h , / (�V S \t'1`1 b \��i AZ5 Traverse Elapsed Clock Time DGM Reading, Velocity Head, Orifice Pressure Dry Gas Meter Pump Differential,�H Stack Temp, Probe Temp, Filter Temp,°F Impinger Exit . Temperature,°F Vacuum, Point# Time 24hr Vm,fe DP In H2O Target Actual °F °F x Exft Temp,°F Inlet Outlet in.Hg O 123 IS 26 {3�I, 0 j-1 i. 1• " Cl) 51 LA LA in 5 - (3) tab 0 k• S 1 �6 S� 25U 2;t +mot a �i -lid x g 2,�1 251 k 1 1`�2i d a� �7•�i'1 1 S' Z 5 Z Z- IZ. (t b 2 5Z Z 0, 10A is w Illy �+ b q H6 t co ow 1A15 0 , HS t.� \• 25 t I x t fj•e.1 IT 1,� (A QL12 Lt t� 2 Z. �+6 q � "I It ` D \0 b.2 ` t` " 2-104 ZS-2 S Jl g co Q t� e. 5�14 0 ,mot ,�` .�'1. \ Z�st� s2 a W 9 �H ®,''Y) 5S \ SVM. IL TO st (n z Averages ��tt rv� I QA/QC Check:Completeness NJ Leglbllflp�Accuracy_Specifications Checked By Z_y Team Leader t 001AS-QMS-FM-225 tMMONTROSE Method Lw Field Datashest(Isokinetic) Page of I AIR QUALITY SERVICES Project Information Sampling Conditions ;1 ALT 011 TC ID: Ambient°F Ref.°F Data ,�-\ I I Project# + `�-A Steil.Pressurs,in.H2O •V vAmbientTemp,°F Stock Customer/Faclitiy ��t;li`P�3('Gi�� ��C1�tTV� Barometric Pressure,in.Hg 2R, Ref.Barometer iD Probe Unit iD/Sample Location i, L �n\�� Wind Speed/Direction 3 N Precipitation,Y/N,type Filter Box Run# �j Operator Probe/Filter Temp Range,°F IL i f. Fitter ExS + -t �. Sampling Equipment We Calibration 1 Equipment Checks Pro Mid _ Post Meter outlet a1 Meterbox iD Meterbox Y V C e 4 Plot(+),pass @ in.H2O @ A @ Impinger Exft, Umbilical ID jt 1 "'1 Metarbox AH@,In.H2O ` Pilot(-),pass @ In.H2O @ Other Nozzle ID 0+��^ Nozzle diameter,Dn,in. :I C?5 Pilot visual inspection ri pass pass pass Ref.Thermometer ID Pttot I Probe iD Pilot coefficient,Cp Nozzie visual Inspection a pass pass pass Continua Check ❑ConUnu w/Pro er Pola Manometer iD N Manometer zero and level yes Meter,cfm @ in.Hg O @ 6.� @ �� ,�@ 01 Notes; C✓: ".A Sensitivity K-Factor L4•Z intermediate leak check volume,fta i p i Z� / al- IA i Orifice Pressure Dry Gas Meter Pump Traverse lapsed C;24hr DGM Reading, Velocity Head, Stack Temp, Probe Temp, Filter Temp,°F impinger Exit Point# Time Vm,fts AP in H2O Dliferentlal,AH °F °F Tamp,°F Temperature,°F Vacuum, Target Actual ox Exit inlet Outlet in,Hg 0 0 : �C\ o Li 00'Z!A 0 LAS i o 1, tD S- \S-1: 0 ,3q 1. U 2u1 'LS'� vl�1 V 2 It 011� �5K 2�� 2'� �� s �q CU 30 0 "l0 1� `� �•"t5- 1,�� 1+ Sh 25Z m Zo1-IL-0 b, -1 \:ham i. S 53 2S LA \-i5,� t .-Ib t,� LA 5-7 Zvi Z'A� 0) .72 u5 b�3s �-� ,z o.y�. �L �.-, hs� �g 2�1 ti a Q 05�1+0 ��Z 6 �, h� '6s ►�6 St Sb Z Sc� bb ' � 0�� q: �q o• 3 i.si i,s' � 6 "� z. 3 �Z -�3 K ro RO� 2S\-I I 2�n - S1 _1.26-7 1Z \b W�,1 (�,i 1, IAZ Sty ILA ;.A -I �" q�,' C� 5 K t, b Lt 2 C� s LA " -1 91 L', Ll ID 0 z..ti Zos.>, 0,13 >,.'t\ i-% +IA63 -5- SZ Vie 2 5 M l-\1- Z !7 0. 2 t•-1(1 \.1 CN 21 Q),-i +.tie 1• 2- tW O,N� t:%q LA6o 17 L4 '-AIDN a-i 22 ,'S Q,L4 1 .-�2 2S' ILS1 tA'l 21 t l qso Zh 0"'AID k Vb LA 5C 2LA 0" 2 s'o LAI 1 -1 Z M (.9N55 O• _► �.SS �.5 0 ZSd 2� 1 �� 13 0 LU tt vim H iM z Averages QA/QC Check:Completeness—Legibility_Accuracy Specifications_Checked By Team Leader o01AS-QMS-FM-225 1 MO NT'RO S E >s P Method Field Datasheet(Isokinetic) Page l of AIR DUALITY SERVICES Project Information Sampling Conditions ALT 011 TC ID: Ambient°F Ref.°F Date `0—k0(-It ProJect# �`US- 07 I410 Static Pressure,in.H2O ,D Ambient Temp,°F Stack -- Customer/Facility Barometric Pressure,In.Hg Z.1. 6 Ref.Barometer ID NW Probe Unit ID/Sample Location V n t MA i!,k Wind Speed/Direction Precipitation,Y/N,type Filter Box �.—�- Run# Operator Probe/Filter Temp Range,°F Z."t - Z Filter Exft INSt Sampling Equipment IDs Calibration Equipment Checks Pre Mid I Post Meter outlet Meterbox ID Meterbox Y 1, Pitot(+),pass @ in.H2O @ @ 19,@ 3 Impinger Exit - Umbilical ID \ -1Q Meterbox AH@,in.H2O y D('Sq Pilot(-),pass @ in.H2O @ @ Other Nozzle ID >O"^ Nozzle diameter,Dn,in. 0 QS Pifot visual inspection pass pass pass Ref.Thermometer ID Pilot/Probe ID Phot coefficient,Cp OAH Nozzle visual Inspection pass pass pass Continuity Check 0 Contlnuity w/Proper Polarity Manometer ID `�� Manometer zero and level yes Meter,cfm @ in.Hg d,d. @ 1 a-poo o@ i 5 pOJ @ Vs I Notes: QQC 21—. 2--1 Sensitivity ,l� K-Fedor �•(., Intermediate leak check volume,ft3 Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Differential,�H Stack Temp, Probe Temp, Filter Temp,°F Impinger Exit Temperature,°F Vacuum, Point# Time 24hr Vm,fe DP in H2O Target Actual °F °F Box Exit Temp,°F Inlet I Outlet In.H9 0 102,2 Z 1 ; b"► Z t O 10IY2 23-b� 5 t vl"1 (. � �- to�,'1 2 1 + 5�0 1• 'LTb 25 5\ -i Z- Z LO L A 2 W 4 �, �1 0 L. LA 6 2 1 `-� 3 5 2ti�• 0• 43 t. 1A `A L460 0 oS'Z rt.�2. 1 ,`l g3 1.CN s l0� v.L � 1� >•�°I b 2 2sZ SIZ .n o •BIZ �.� i,"� Q to S4 �\�Z 2 3 3 1•b�► 1 b �tsS 2s0 2 S`1 S5' lt'1 2bW t :3 t S5 i , �t�Z 2 SD �Z ( 0 at 1-13:0Z-1 \.SI t 5 LA � 2SZ a `�3 �► 1 S \\3Z 2"t6. 7 a. 35 t•H-i t H 'AS v+. 5O WLQ 2 0,0 o.3 S' 0A-1 \,y ) 0 � i S t;S +��,'S 2—o S3 �q l� ID. � 0. .t( 1.->2 \, 1 b`S 5� 253 �q Sa M V\o. t, 2Sx 2 " L 1 1 3 b a LA bo �S(7 �,0 2 S a `A5-1 25k �53 -t $Z v ti1o� 3011 c7 `'12 \•`t \ `1S-j ZL( 2S q ik0 \Zt 3U b 0, 40 6b t;l; Liss, St7 2sZ Ss � �L1 $ co < Q 2 0 0, o b t.b ubZ 2�b 2�2 51 Z —1`t W tZ IZ� \1VI 3>S,�Zb 0,31 5 1•T k-1, z Averages CA/QC Check Completeness—Legibility Accuracy peciftca5-1 Checked By L Team Leader Iv t 001AS-QMS-FM-225 N ®S E Sample Recovery$Calibration Check Datasheet Page of ,L. 1 AIR 0,VALITY SERVICES Project Inform tion Equipment Identification Date t0 t Project# Ref.Thermometer Customer/Facility Vl a Hygrometer Unit ID/Sample Location Field Balance Run# L Operator 7 Check Weights Calipers Balance Audit(Field balance mu s be within 0.5g of check weight mass) Ambient Conditions(Mobile Lab) Date D 4 2'1. Relative humidity,% Standard mass,g Temperature,"F Field balance mass,g `f 221 1- Mobile lab# Moisture Determination Runt Run 2 Run 3 Contents Initial Final Net Initial Final Net rI-n�itiial Final Net Knockout '' �� �o 5 `r.Z 1. Impinger 1 tO y G G Impinger 2 S 10 Y��2 7_ %o.5 Impinger3 3. ,� ,e (0.5 Z►• t 3`1,0 Impinger 4 �130 r� 3�. y b, Impinger5 &A1J() ® ��. 5r , Impinger 6 Impinger 7 Impinger 8 Silica Gel Line Rinse Train Net Gain(Vic) Nozzle Measurements(Difference between any two measurements must not be more than 0.004 in(0.1 mm)) _.. Nozzle 1 diameters 41,3 D1 _-0 10 S D2 t'7.,�f D3`�/��� Average Nozzle 2 diameters D1 132 D3 Average Nozzle 3 diameters 131 132 D3 Average Nozzle Material ❑ quartz ®glass ❑ steel ❑ titanium ❑ inconel ❑ other Probe Type ❑ heated ❑ unheated ❑ air-cooled ❑ water-cooled ❑ other Probe Liner ❑ quartz ❑glass ❑ steel ❑ Teflon ❑ other Filter Information Front Half ❑ quartz fiber ❑ glass fiber ❑ Teflon ❑ Teflon/quartz ❑ other Filter Number. Run 1: Run 2: Run 3: Run Back Half: ❑ quartz fiber ❑ glass fiber ❑ Teflon ❑ Teflon/quartz ❑ other Reagent Information Sample Observations Type Lot Number QAIQC Check:Completeness_Legibility_Accuracy_Specifications_ Checked by. Team Leader 001AS-QMS-FM-226 NE01 3AS-021420-RT-1 303 Appendix B-Page 56 of 98 1 J Sample Recovery&Calibration Check Datasheet Page of -."(64% L. AIR QUALITY SERVICES Project In_for/m�atl n Equipment Identification Data I p_(J_�� _L Project# - ' Ref.Thermometer Customers I Facicility �iJ H e e-(r^U xu« ir— N 6 Hygrometer Unit ID/Sample Location ��.;}- 2 .- SPA INLEI Field Balance Run# Operator Check Weights Callpers Balance Audit(Field balance must be within 0.5g of check weight mass) Ambient Conditions(Mobile Lab) Date '-=r:tq ft Z Relative humidity,% Standard mass,g 10 '-.l) Temperature,"F Field balance mass,g �l .` Mobile lab# Moisture Determination Run* � Run 2 Run 3 Contents Initial Final Net Initial Final Net Initial Final Net Knockout Z.�•� Impinger 1 10 Impinger 2 $el o Impinger 3 Impinger4 G�ANOi L3. ( �C7 Impinger5 Impinger 6 Impinger 7 Impinger 8 Silica Gel 5-1"C Line Rinse Train Net Gain(Vic) Nozzle Measurements(Difference between any two measurements must not be more than 0.004 in(0.1 mm)) J Nozzle 1 diameters D1 6.3 d$ D2 133 �,�,c�S Average Nozzle 2 diameters D1 D2 D3 Average Nozzle 3 diameters D1 D2 D3 Average Nozzle Material ❑ quartz ❑glass ❑ steel ❑ titanium ❑ inconel ❑ other Probe Type ® heated ❑unheated ❑ air-cooled ❑ water-cooled ❑ other Probe Liner ® quartz ®glass ❑ steel ❑ Teflon ❑ other Filter Information Front Half: ❑ quartz fiber ❑ glass fiber ❑ Teflon ❑ .Teflon/quartz ❑ other Filter Number. Run 1: Run 2: Run 3: Run Back Half: ❑ quartzfiber ❑ glass fiber ❑ Teflon ❑ Teflon/quartz ® other Reagent Information Sample Observations Type Lot Number QA/QC Check:Completeness_-Legibility_Accuracy`Specifications_ Checked by: Team Leader: 001AS-QMS-FM-226 NE01 3AS-021420-RT-1 303 Appendix B- Page 57 of 98 EPA Method 3'Data Sheet Project 0 (1 Test-- Test Date: ClienVSde: Operator. Pre-Test Leak Check: 0 Pipette Fluid Level in Capillaries: CO,6)N) 02((YJ N ORSAT Analysis Audit: Date: CO, 02 Audit Gas Time of Reading Reading %0' NOTE:Audit results must agree within Concentration Analysis (A) (B) (B-A) 0.5%of the audit gas concentration %02: )0.97 value. 5i H Analyzer I.D.-A-ORS- Audit Gas Cylinder I.D.: cc— Run No. Orsat Bag ID. Time: It Sample 1 Sample 2 Sample 3 Average CO, _T9.7- 02+CO2 02 Net C(,- D r,\- Run No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average CO, 01 02+CO2 A Net Run No. Orsat Bag ID. Time: Sample I Sample 2 Sample 3 Average CO, 9. 02+CO2 ,0,Net uf;)-- 0� Run No. Orsat Bag ID, Time: Sample I Sample 2 Sample 3 Average CO, C!-'3 02+C07 02 Net Dry Gas Molecular Weight: Md w(COz*44/100)+(02*321100)+(N2*28/100) Montrose Air Quality Services,ILLC 2 New Pasture Road,Unit 5,N=uryport,MA 01950-T:(978)499-9300-F:(978)499-9303 www.mo ntrose-env.com NE013AS-021420-RT-1303 Appendix B- Page 58 of 98 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2 Test Dates:October 1 B-1 9.2022&October 25-28,2022 B9 Unit No. 2 Outlet Hydrogen Chloride and Ammonia M 0 N T kc)S E NE013AS-021420-RT-1 303 Appendix B-Page 59 of 98 MO N T RO S E EPA Method �`'`t Field Datasheet(Isokinetic) Page ( of AIR QUALITY SERVICES Project Information Sampling Conditions ALT 011 TC ID: Ambient°F Ref.°F Date Project# (��., Static Pressure,in.HZO AmblentTemp,°F �j Stack _ Customer/Facility WJJF-EL W 9AMR nro/t17� AND�/Z Barometric Pressure,in.Hg 3. () Ref.Barometer ID V3 `j Probe ^J"3 Unit ID/Sample Location \J?— 8 Wind Speed/Direction Precipitation,Y/ Imo,ype Filter Box i Run# I Operator Probe/Filter Temp Range,°F Filter Exit _ Sampling Equipment IDs Calibration Equipment Checks Pre Mid Post Meter outlet ^ e5 Pltot +, ass in.H 0 ° Meterbox ID ��-=' A Meterbox Y �_ `�• O P @� 2 @ 113 @ @ Impinger Exft ql ts Umbilical ID 11-OQp c MeterboxeH@,in.H2O Pitot(-),pass @ in.H2O @ (° ❑ @ @ Other Nozzle ID ® Nozzle diameter,Dn,in. Pitot visual inspection ass ❑ ass Erpass Ref.Thermometer ID Pilot/Probe ID ' S Pitot coefficient,Cp 1b Nozzle visual inspection passy Continuity Check ❑Continuity w/Pro er Polarity Manometer ID Manometer zero and level yes Meter,cfm @ in.Hg t),06 1 @ @ A CD @ "d Notes: Sensitivity IK-Factor-6— Intermediate leak check volume,if J d— s Traverse Elapsed Clock Time DGM Reading, Velocity Head, Orifice Pressure Stec Temp, Probe Temp, Filter Temp,°F Impinger Exit Meter Pump Dry Ga AP in H O Differential,off F Temp,°F Temperature,°F Vacuum, Point# Time 24hr Vm,ft2 z Target Actual x It Inlet I Outlet in.Hg 15 . E a-9 1-4 o a 5 a C, 5 1 4 S A. a a r2- S G S U 4.5 x a 5 119 ANI C- a__ toI S -10 . S Q 5� n M O co H O N N O i Cb Q co O W Z Averages OA/QC Check:Completeness_Legibility`Accuracy,Specifications_Checked By Team Leader 001AS-QMS-FM-225 rA6�, MO NT RO S E Method Z�(5 Field Datasheet(isokinetic) Page of AIR QUALITY SERVICES Project Information Sampling Conditions ALT 011 TC ID: Ambient°F Ref.°F Project# Q�L Static Pressure,in.H O d Ambient Temp,°F b Stack Data c9� �� �. z customer/Facility WW16Z"b QiC Barometric Pressure,In.Hg c�.!ff,�e�C) Ref.Barometer ID Probe -T- Unit ID/Sample Location Wind Speed/Direction Precipitation,Y/49,type Filter Box Run# Operator Probe/Fitter Temp Range,°F Filter Exit ' Sampling Equipment IDs Calibration Equipment Checks Pre Mid Post Meter outlet" !'F i , 4 Meterbox Y Meterbox ID Pitot(+),pass @ in.H2O @ 7j '% ❑ @ ❑ @ Impinger Exit Umbilical ID �j Meterbox AH@,in.H2O _ Pitot(-),pass @ in.H2O @ 3` ❑ @ El@ Other Nozzle ID Nozzle diameter,Din,in. Pitot visual inspection pass pass ❑ pass Ref.Thermometer ID Pilot/Probe ID - Pilot coefficient,Cp Nozzle visual Inspection pass Continui Check ❑Contlnuhy w/Proper Polarity Manometer ID Manometer zero and level yes Meter,cfm @ In.Hg A�@ @ (�. Notes: Sensttiv ' �K-Factor ® Intermediate leak check volume,ft3 Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocityliead, Differential,aH Stack emp, Probe Temp, Filter Temp,° Impinger Exit Tem ereture,°F Vacuum, Point# Time 24hr Vm,fe DP i H2O Target Actual F °F Box Temp,°F Inlet Outlet r in.Hg "t L © 1 a �� �y� 55 � ,� 56 Po At 5 co � ® �i� � 6 5 0 z) a 6 9 -5 v 4-0 4.0 2 a S 5 `� � 5 � 5 CL ® �k a- 5 4-.,5' Q 55 cd 51 �! 5 M O M O i N d' N O Cn Q co O W Z Averages QA/QC Check:Completeness_Legibility_Accuracy _Specifications_Checked By Team Leader 0 AS-QMS-FM-225 MO NTR O S E Method Field Datashest(isok►netic) Page of AIR CLUALITY SERVICES 1��L Project Information Sampling Conditions ALT 011 TC ID: Ambient°F Ref.°F Date Q -- �.Prcoct# ® Static Pressure,in.H2O 1 Ambient Temp,°F Stack Customer/Facility Barometric Pressure,In.Hg t� Ref.Barometer ID NVJ Probe "J�- Unit ID/Semple Location - Wind Speed/Direction Precipitation,Y/&type Filter Box lU Run# Operator Probe/FliterTemp Range,°F Filter Exit '- Sampling Equipment IDs Calibration r Equipment Checks Pre Mid Post Meter outlet J Pilot(+),pass @ n. ZLEI'@ '� ❑ @ @ '� Im in Meterbox 1D � - ' Meterbox Y i HO I er Exft P 9 Umbilical ID Meterbox AH@,In.H2O / Pilot(-),pass @ in.H2O V01, ❑ @ @22 Other _ Nozzle ID ® Nozzle diameter,Dn,in. Pilot visual inspection V pass QrPBss Ref.Thermometer ID Pilot/Probe ID - Pitot coefficlent,Cp Nozzle visual inspection ,►G-P lConfinulty Check ❑Continuity w/Proper Polari Manometer ID -`� Manometer zero and level yes Meter,cfm @ in.Hg F0,8045)5- @ 0.00k @ Notes: Sensitivity ° K-Factor Intermediate leak check volume,fe Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Stack T mp, Probe Temp, Filter Temp, Impinger Exit Differential,AH ° Temperature,°F Vacuum, Point# Time 24hr Vm,fT" AP[n H2O Target Actual F ° ° Box Temp, F Inlet Outlet in.Hg "aq,R 0,750 45 1 • 5 o g6 0 a�b� 5Z 5 5 G s CL X 61 1 I-= a 6 - 53 Q 66 Jg - - - - �( <3 b7 5 co O co h LY O N N O CD Q M O W Z Averages QA/QC Check:Completeness_Legibility_Accuracy_Specifications^Checked By Team Leader 001AS-QMS-FM-225 26 MONTROSE Sample Recovery&Calibration Check Datasheet Page of L. AIR QUAL-ITY SERVICES Project Informatlo Equipment Identification Date Project# Pp —021/Z— Ref.Thermometer Customer aclity Hygrometer Unit ID J Sample Location /!A/ _IC� P$lA� � Field Balance Run# 3 Operator Check Weights Calipers Balance Audit(Field balance must be within 0.5g of check weight mass) Ambient Conditions(Mobile Lab) Date & Relative humidity,% Standard mass,g Temperature,°F Feld balance mass,g �df�•a Mobile lab# Moisture Determination Runt Run 2 Run 3 Contents Initial Final Net initial Final Net Initial Final Net Knockout Impinger 1 SO4,L-/><Sf� e Impinger 2 gONO ` o ,.s - 10 Impinger 3 dUMG SO Impinger4 Impinger 5 Impinger 6 Impinger 7 Impinger 8 q� Silica Gel Line Rinse Train Net Gain(Vic) Nozzle Measurements(Difference between any two measurements must not be more than 0.004 in(0.1 mm)) Nozzle 1 diameters D1 D2 D3 Average Nozzle 2 diameters D1 D2 D3 Average Nozzle 3 diameters D1 D2 D3 Average Nozzle Material ❑ quartz ❑glass ❑ steel ❑ titanium ❑ inconel ❑ other Probe Type ® heated ❑ unheated ❑ air-cooled ❑ water-cooled ® other Probe Liner ® quartz ❑glass ❑ steel ❑ Teflon ❑ other Filter Information Front Half: ❑ quartz fiber ❑ glass fiber ❑ Teflon ❑ Teflon/quartz ❑ other Filter Number. Run 1: Run 2: Run 3: Run Back Half ® quartz fiber ❑ glass fiber ❑ Teflon ❑ Teflon/quartz ❑ other Reagent Information Sample Observations Type Lot Number QA/QC Check:Completeness_.Legibility_Accuracy_Specifications— Checked by. Team Leader. 001AS-OMS-FM-226 NE013AS-021420-RT-1303 Appendix B- Page 63 of 98 4 EPA Method 3 Data Sheet n Project#: Test Date: - �/�_�. Client/Site: W f ` � ' /` Operator. Pre-Test Leak Check: Pipette Fluid Level in Capillaries: CO2 49 N) 02(66/N) ORSAT Analysis Audit: Date: ` CO2 02 Audit Gas Time of Reading Reading %02 *NOTE:Audit results must agree within Concentration Analysis A) B B-A 0.5%of the audit gas concentration %02: Q- T value. Analyzer I.D.-A-ORS- jAudit Gas Cylinder I.D.: Run No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average CO, 1a0 02+CO2 N . MIS'- 0,Net I � . Run No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average CO, , ` 02+CO2Ur ^� 02 Net p ®. 0 1 H f� S j No. 0 Bag W- Time: Sample 1 ¢Sample 2 Sample 3 Average CO, s f7{ 02+CO2 �+7. 02 Net V 0 q Run No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average CO, 02+CO2 02 Net Dry Gas Molecular Weight: Md=(COz*44/100)+(02*32/100)+(Nz*28/100) Montrose Air Quality Services,LLC 2 New Pasture Road,Unit 5^Newburyport,MA 01950•T:(978)499-9300•F:(978)499.9303 www.mo-trose-env.cam NE01 3AS-021420-RT-1 303 Appendix B- Page 64 of 98 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2 Test Dates: October 18-19,2022&October 25-28,2022 MetalsUnit No. 2 0"utlet Particulate, E NE013AS-021420-RT-1303 Appendix B- Page 65 of 98 _ M MO N TRO S E �Method�� Field Datasheet(Isokinetle) page� of� AIR QUALITY SERVICES / Project Information Sampling Conditions ALT 011 TC ID: Ambient°F Ref.°F 0 Date yZ r Pr/o}ject# j Static Pressure,in.HZO - Ambient Temp,°F -1 �� Customer/Feclliiy G�" icy Barometric Pressure,In.Hg A q i�D� Ref.Barometer ID cS Probe Unit ID/Sample Location i Wind Speed/Direction AIIA Precipitation,Y/N,type Filter Box H6� " Run# Operator ( Probe/Filter Temp Range,°F a 4- ® Filter Exit 'fie -I/✓? Sampling Equipment IDs Calibration Equipment Checks Pre Mid ost Meter outlet �7 Meterbox ID K-7 Meterbox Y �' /_®02-7 Plot(+),pass @ in.HZO ❑ @ Q Impinger Exit Umbilical ID $®�3 Me terb � n.H2O Pitot(-),pass @ in.H2O @ S ❑ @ @ Other Nozzle ID l Nozzle diameter,Dn,in. ,' �!® Pitot visual inspection ass ❑ ss VP ass Ref.Thermometer I,D_,/ Pitot/Probe ID NoPit coefficienk Cp Nozzle visual inspection pass pass pass Continuity Check l�J Continuity w/Pro er Polari Manometer ID -� Manometer zero and level eyes Meter,cfm @ in.Hg ,191 @ /5 @ `® 10,00t @ ( Notes: Sensitivity K-Factor 5-2- Intermediate leak check volume,ft' .'W 2f 77- / - Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Differential,�H Stack Tamp, Probe Temp, Filter Temp,°F Impinger Exit Temperature,°F Vacuum, Point# Time 24hr ey Vm,to AP in H2O Target Actual °F °F Box Exit Temp,°F Inlet Outlet 11 in.Hg 51 rrJ�©.ill✓ �. 5C� S �Ga 3c� 2X.ti . Y& z• `�3 / 5 5r Ss 613 m 3 aft-�' a 3 a 3 a ey -/a 22r6-7 2, 2. �� aso ay& b P Q 2 3 &L a< a�� A $ ''SD .20 7 3 �s 9Q r �2' �� a J/ -k 2 25 6 g 5 If Y � � � z 0 91711 Tys tea• - 2� 51 �S� 02� Go 70 cli 3®9.0 �^. 0 ;c , Q/ ilP J S 5� 7Q 3 �s 311.5 zeq a. a �.� o ,2�1 4C3 s c, 7 2.3 r ?7 • r/c ISO a 8 ! F M 7 2/P 250 A-2L5 0 A + 7 S ? 7 9 0 ;3!7 3 S i ys �.3 2B9 asp a2 s9 P 8 ,1/0 .2.® a-® ,ZSD d2 gyy �o 21, Q 3 ils y3 r s z. 3 L.� as° 1250 a y� �� 79 z /:Z o �y7, 73 J,9 ! �� �2Sa Averages 1 (aA/OC Check:Completeness G Legibility G'�Accuracy�pecificabons L�Checked By 2� Team Leader 001A5-4MS-FM-225 l6 MMONTROSE 4O� Method Field Datasheet(isokinetic) Page / of AIR QUAI.ITY SERVICES Project Information Sampling Conditions _ ALT 011 TC ID: _Ambient°F Ref.°F Date / /4/n, Project# D s Static Pressure,in.H20 Ambient Temp,°F 0 Stack Customeerr/F-ac�iiity� 2�� Barometric Pressure,in.Hg Ref.Barometer ID Probe Unit ID/Sample Location Us'li O�, Wind Speed/Direction Precipitation,Y/N,type IV Filter Box Run# Operator ] Probe/Filter Temp Range,°F t - ° Filter Exit 3i Sampling Equipment IDs Calibration li Equipment Checks Pre Mid Post Meter outlet 111 Meterbox ID 7 Meterbox Y rI7� Pilot(+},pass @ in.H2O @ y,1/ ❑ @ _ Impinger Exft Umbilical ID Meterbox AH@,In.H2O Pilot(-},pass @ in.H2O @ JY.16 ❑ @ Other Nozzle ID /® Nozzle diameter,Dn,in. �j/� Pilot visual inspection pass ❑ s pass Ref.Thermometer ID Pilot 1 Probe ID P- Pilot coefficient Cp e ,U� Nozzle visual Inspection pass pass pass Continuity Check ❑Continuity w/Pro er Polafi Manometer ID Manometer zero and level eyes Meter,cfm @ in.Hg @/��J @ ®(�@ .^Il Notes: Sensitiv �09 K-Factor Intermediate leak check volume,fIS Orifice Pressure Dry Gas Meter Pump r�, Elapsed Clock Time DGM Reading, Velocity Head, Stack Temp, Probe Temp, Filter Temp,°F Impinger E)dt Differential,�H Temperature,°F Vacuum, Point Time 24hr Vm,f AP in H2O Target Actual °F °F Box Exit Temp,°F Inlet Outlet in.Hg U /-7 3t ,.3,50. s7 A5 0 a5® v 3 ?3 rn . .o (1,5 �,a a .-/:2. 0 15'91 asJ a zC/ o zo �• 9 22.2 2. 2, a 0 �3 "S2 ��`� �fI ' G, ocu 2s 3171. 2< 2 2 , 2 '?O ;� 2V5 !v 303 7� d .�- ,�. l a ems/ �s� ^/9 G2 i m N ,so%S 3 -01:1 , /. �5 asp ay7 62 CL 009-- Y16 9,3 2 5 ' V If -10 ^a - -5-7 -1 2 -55 70 1105. e5 2, s 5-7 7 O® r ®,`l q �g �"7 "UI 2 5® )it 6 -5 D 'T6 5 C a o 2 a!Y 5 �8 �p Y3®✓J v a• G, 29V s 2 2,50 e/7 59 79 a o a5 35- a �5 3 2,1 a. 9d 50 W50 6Z�� GO YO 6n a<9 I � 'T a 21 at A3pe '901 aye 2 y5 dvf ?3! f Z Averages QA/QC Check:Completeness 4 egibility ✓Accuracy 2/Z—Specifications /0"Checked By elj2 Team Leader.V 0o1AS-QMS-FM-225 /S 5'� MO NTRO S E Method Field Datasheet(Isokinstic) Page of AIR QUALITY SERVICES 16��4 5 , Project Information Sampling Conditions ALT 011 TC ID: Amblent°F Ref.°F Date /a k/aI Pr oject //# 11 _ Static Pressure,In.H2O - $ Ambient Temp,°F 370 Stack �✓•- '�y 35 Customer/Facility aysP,r rr�(�,�R7GY _ Barometric Pressure,In.Hg �I�•7 5a Ref.Barometer ID A// ,5 Unit ID/Sample Location I`,/2 o w/ 1 Wind Speed/Direction 4114 Precipitation,Y/N,type Filter Box /1 —3 0 Probe 1 Filter Temp Range, F �/ .41 a�rj Filter Exit 31Z 8 3$ 33 Run# Operator /�/G 9 .° Sampling Equipment IDs Calibration Equipment Checks Pre Mid Post Meter outlet Ql-7 36 Meterbox ID / E-7 Meterbox Y A- ,Z Pftot(+),pass @ in.H2O El @ y ❑ @ d Impinger Exit 30&Y 3,Y ,33 Umbilical ID 56 3 Meterbox eH@,in.H2O "97Z Pitot(-),pass @ in.H2O @ ,2 ❑ @ `(_ Other Nome ID 3r0 Nozzle diameter,Dn,in. 3/0 Pilot visual inspection pass ❑ ss Pam Ref.Thermometer ID is a t' Pilot/Probe ID Pilot coefficient,Cp Nozzle visual inspection pass pass ass Continul Check ZContinui w/Proper Polarity Manometer ID Manometer zero and level Zyes Meter,cfm @ in.Hg ,pVo @ j j// @ Notes: Sensitivity r K-Factor S• ^cam Intermediate leak check volume,If Orifice Pressure ._.--- Dry Gas Meter Pump EA Elapsed Clock Time DGM Reading, Velocity Head, Stack Temp, Probe Temp, Filter Temp,°F Impinger Exit Point Time 24hr Vm,ft9 DP in H2O Differential,9H °F °F Temp,°F Temperature,°F Vacuum, Target Actual Box Exit Inlet Outlet in.Hg (" 5o Wry$20 --�r 5 3«�I ° 2. 2. 2.2 $ °2 S 2 a-S0 ays �� S 00 ! !� a ^ � 5� s elsX, Z. o r15 --!61 0 4 211 .I 2'd 251 a 5I 2VS eft vY -- -- 5" co iy 70 �S D -0 2, 0 2,0 02$8 53 X50 a 8 �y 5 25 `16 99 •G� ° � � 02�9 �5e7 yS y(o 5 � 3o yY7 a. r� r5J35 77, y 52 2 7 a 7 a �So a.51 ay5- Y9 y8 T- < yo b > - 5 0 c� 2. a ;Z V, a f o aye 6,0 c 1 y5 ' 57.E Co 2 �. 2 ago a s 2 zso s 53 51 Q 2 .50 �`�'/ S �0 3. r > a9< �51 ;s o a yy 61 Q 5 �s � 76•o S� a .q a �� � so a� a zo2 sg 9 �� (00 0!0 .51 :9 L4 2 p f i95 ao 5 5106 & Z• 3 �. 02�9 DSO X52 5 6( .G-- z 70 S o•� �`1 2.c� A51 0-si ��� 5-7 69S 3 Sty, 0 a q ail ayy 57 G 2 � 2 27 / 2 • aqd SO ,�-�a y3 58 co z go 51- 5 .' e15 �. 2 3 ;2g� 2!141 as1 -- a5 52 V /00 >5•A 5Q 1O5 -5 3 2F 2, a5v a ys s i o 3 0 5 �`8� r yS 3 a� S t a51 aye 52 6-7 o y 12-0 /090 sv.r53 Y3 2, ;2 '2.P- Qa as ao 1 '2YY 52- 6-7 — z Averages ' QA/QC Check:Completeness/Legibility i��Accuracy-ZSpecifications(-fir Checked By �� Team Leader 001AS-QMS-FM-225 1 - i'Lt MO NTRO S E N Method Field Datasheet(Isoldnetic) Page / of AIR gUAIJTY SERVICES Project Inf;mAtl n Sampling Conditions ALT 011 TC ID: Ambient OF Ref._OF Date /®J At 'rojj�ec��t## 4rov Static Pressure,In.HZO - Ambient Temp,°F Stack �j Customer/Facility C 1-11 ,7 Barometric Pressure,In.Hg o2 '`7 Ref.Barometer ID 5 Probe Unit ID/Sample Location y Wind Speed/Direction A1/ Precipltatlon,Y/N,type Filter Box Run# Operator G7`± Probe/Filter Temp Range,OF f/` SD Filter Exit Sampling Equipment IDS; Calibration Equipment Checks Pre Mid Post Meter outlet Meterbox ID 7 Meterbox Y /• 7- Pftot(+),pass @ in.H2O 2 ❑ @ � �iQ Impinger Exit Umbilical ID 50-3 Meterbox AH@,in.HZO / 7�i Pilot(-),pass @ in.Hz0 @ .7.7 ❑ @ ®'@ $t i Other Nozzle ID Nozzle diameter,Dn,In. /� Pilot visual Inspection pass ❑ ss pass Ref.Thermometer ID d '03 Pilot/Probe ID P Piitot coefficient,Cp Nozzle visual inspection pass pass pass Contlnui Check RT Contlnul w/Proper Polad Manometer ID �- Manometer zero and level 01 yes Meter,cfm @ in.Hg 6w4 @/�S'� @ LCQ @ Notes: Sensitivity 01 K-Factor 5.2 Intermediate leak check volume,i / / p DGM Reading, Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time 9, Velocity Head, Stack Temp, Probe Temp, Filter Temp,°F Impinger Exit Tempereture,°F Vacuum, DP in H O Differential,aH OF OF Temp,OF Point# Time 24hr Vm,ft3 z Target Actual Box Exit Inlet Outlet in.Hg /4z2 552. of 2• 290 1750 ay 56 Cor 00 2 !d 560,3 Z 2./ •� • � agta a s l a2S/9 aye/ 5C� cal % 0 . 5 2. 3 z,7 a a5o 251 ��cs ss C97 tt ® yam. .5-70. 9 . yi �./ �. r '0 � 50 ay � 57 y d• a a:0 a90 s� dSa ay ScP °� 0- 2 0 579r -5 2 a. �. l a--9 8 a5© ay 57 70 m gyP • 39 119 r a,9 aY7 aSl a y3 57 72 x IIIy'D i/c�2 587. Q zt� o a5o yj 5 7l aD c 1 S/-5 - yz/' 2. 2 2.-2 0 asD a5/ ys s7 �l s a 2 50 '5 ys �. '3 ado a g 5 �zi/y 5-7 7.2 5 Q 3 5s 597a5 3 <• 2,-z 0 a A o2_50 at1V 5-7 72 s ta2� <! &C, /22 G0/ • Y�' 2,2 z.z aN� a5� 5� 7a 5_. r 2� Pwy i� j 65 //37- <005.5/ . 50 2• CO 2•C,, 0 SO 250 y5 " 58 7-2 5 (I 2 70 �0�.8 . s2 a•7 a-7 a99 a 250 a 53 72 5 9 `7� �0/5,0 5 t9 a.9 a2 :g q Q :251 a '1 5 9 2 5 '( 00 /° Co 8•S S a Z0 a•� O �S t3 a 5o a y 59 -7q x' M ds a3 3 �/s a Y a- ' a�� aya aY a13 5g 7yCS a 90 fro z </� a, ,5 9 -5 O aSa ayy 59 75 47 3 9'5 5 t/5 2- � m2. 02%0 'oZ�O �Y9 ot� 3 �D C0 S V F I ros �32). G � �- 2, -4 990 a 5 0� l94 a�!/ i a� 5 0 2 ro � a 2, S a 2 z. 2 90 a5i a aye r 77 5 M 5 rrs �yam.' yz ;Z .r a. r , 90 a5l dt �i ay3 ! 77 0 LU /a27 65/• 2'L ! 2., aV -?s-0 .20? a2 v 2 77 S z Averages QA/QC Check:Completeness IQ<Legibility 1-4 Accuracy-Kf-Specificatfons 14 Checked By -Team Leader �� 001AS-QMS-FM-226 R S E Sample Recovery&Cal 2-9 II 1 Mbration Check Datasheet Page of L. AIR RUALITY SERVICES Project In7771on Equipment Identification Date Q /� Project# p�T- �Z1 T� Ref.Thermometer Customer;F cilityn ,®/�>'/2l�' _ '/� - AI �� Hygrometer Unit ID/Sample Location 77 Field Balance Run# �_ Operator Check Weights Calipers Balance Audit(Field balance must be within 0.5g of checkht mass) Ambient Conditions(Mobile Lab) Date G� Q eig Relative humidity,% Standard mass,g Temperature,"F Feld balance mass,g -4� Mobile lab# Moisture Determination ✓�/ Runt Run 2 Run 3 Contents Initial Final Net Initial Final Net Initial Final Net Knockout ITT ' d 15 0 r' 491&- Impinger 1 Ohl ' '`- Impinger2 t :7 O Impinger 3 Impinger 4 d t ,: e Impinger5 0 �` �� q •d Impinger 6 Impinger 7 Impinger 8 q Silica Gel �U'(.iq S e / Line Rinse Train Net Gain(Vic) Nozzle Measurements(Difference between any two measurements must not be more thanfi0.00?4 In(0.1 mm)) -' Nozzle 1diameters 5 !� D1 /� .�14 �D2 �D3 (/ ,)/q Average Nozzle 2 diameters D1 D2 D3 Average Nozzle 3 diameters D1 D2 D3 Average Nozzle Material ❑ quartz glass El steel ❑ titanium ❑ inconel ❑ other Probe Type heated ❑ unheated ❑ air-cooled ❑ water-cooled ❑ other Probe Liner ❑ quartz r glass ❑ steel ❑ Teflon ❑ other Filter Information Front Half: ❑ quartz fiber ❑ glass fiber ❑ Teflon ❑ Teflon/quartz ❑ other Filter Number. Run 1: Run 2: Run 3: Run Back Half: ❑ quartz fiber ❑ glass fiber ❑ Teflon ❑ Teflonlquartz ❑ other Reagent information Sample Observations Type Lot Number QA/QC Check:Completeness_.Legibility_Accuracy_Specifications Checked by. Team Leader: 001AS-QMS-FM-226 NE013AS-021420-RT-1303 Appendix B- Page 70 of 98 gA^, MONTROSE Sample Recovery&Calibration Check Datasheet Page of • AIR QUALITY SERVICES p 'act Informati n Equipment Identification Pro) a]ro Date /7 Project# Ref.Thermometer Customer I F ity -4 AA AM HygrometerE-k— — Unit ID/Sarnple Location 2611 2- EL Qim'er— Field Balance Run# Operator Check Weights ICallpers A Balance Audit(Field balance must be within 0.5g of check weight mass) Amblent Conditions(Mobile Lab) Date Relative humidity,% Relative Standard mass,g Temperature,'F Field balance mass,g Mobile lab# Moisture Determination . Runt Run 3 Contents Initial Final Net Initial Final Net Initial Final Net Knockout q r 5-sm.� Impinger 1 V/0 '?v 11-3 aq,� OE. � . (As-.� Impinger 2 70 Impinger 3 72 Impinger 4 -i- �Z-7 1 Impinger 6 M" Impinger 6 Impinger 7 Impinger 8 Silica Gal 5 WILL- q6z-.6 Line Rinse Train Net Gain(Vic) Nozzle Measurements(Difference between any two measurements must not be more than 0.004 in(0.1 mm)) DI D2 D3 Average Nozzle 1 diameters Nozzle 2 diameters D1 —D2 - —D3 Average Nozzle 3 diameters 131 D2 D3 Average Nozzle Material El quartz LJ glass LJ steel Ll titanium El inconel 0 other Probe Type 1:1 heated LJ unheated El air-cooled El water-cooled Ll other Probe Liner L1 quartz Ej glass El steel Ll Teflon LJ other Filter Information Front Halt 0 quartz fiber Ll glass fiber L1 Teflon El Teflon/quartz LJ other Filter Number. Run 1: Run 2:- Run 3: Run Back Half. Ll quartz fiber D glass fiber El Teflon Ll Tefloniquartz Ll other Reagent Information Sample Observations Type Lot Number QAJCC Check:Completeness_.Legibility_Accuracy_Specifications Checked by Team Leader_ 00IAS-QMS-FM-226 N E01 3AS-021420-RT-1 303 Appendix B- Page 71 of 98 V 1 C EPA Method 3 Data Sheet Project M4 L( Test Date: Client/Site: kLPIL— All(R- Operator Pre-Test Leak Check: Pipette Fluid Level in Capillaries: CO,(bl N) 02 KY N ORSAT AnalysisAudit: Date: CO, 0, Audit Gas Time of Reading Reading %0' *NOTE:Audit results must agree within Concentration Analysis (A) (B) (B-A). t 0.5%of the audit gas concentration -iAO.: value. %CO2: IC> C Analyzer I.D.-A-ORS- Audit Gas Cylinder I.D.: CC ko 2 ?z Run No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average lc�' I lenk .0 CO, 02+CO, 19,&— 11 5--- 1 17,!L — 02 Net 0 1 Lf I Y -Fk � Run No. Orsat Bag ID. 41- Time: Sample 1— Sample 2 Sample 3 Average CO, d - S 9 02+CO2 Z. 4 -1,'? 02 Net Run No. Orsat Bag D. y Time: Sample I Sample 2 Sample 3 Average CO, er 02+CO2 0,Net 0 Run No. Orsat Bag ID. Time. Sample 1 Sample 2 Sample 3 Average CO, 9-7(P 02+CO2 p IT 15 y-!� 1215-- 1 �' 02 Net (9-t 0� y I u 7 Dry Gas Molecular Weight: Md=(CO2*44/100)+(02*32/100)+(N2*28/100) Montrose Air Quality Services,LILC 2 Now Pasture Road,Unit 5-Newburyport,MA 01950-T.-(978)499-9300-F:(978)4W9303 www.montrose-env.com NE013AS-021420-RT-1303 Appendix B-Page 72 of 98 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2 Test Dates: October 18-19,2022&October 25-28,2022 B11 M 0 N T R0 S E NE01 3AS-021420-RT-1 303 Appendix B-Page 73 of 98 ®N T R®S 6-Ra Method _Field Datasheet(Isokinetic) Page_ - .. R QUAI.,ITY SERVICES Project Information Sampling Conditions ALT 011 TC ID: Ambient°F Ref.°F Date it)+19,-;L)-Project# Static Pressure,in.H2O Ambient Temp,°F Stack to--f•3 Customer/Facllity 1JeV.4gAMf\^ MORflh ��MtR Barometric Pressure,in.Hg ;�°l.b� Ref.Barometer ID Nki Probe '-7"7 Unit ID/Sample Location U�,- OUJIl 1 Wind Speed/Direction Precipitation,Y/&Fype Filter Box 1-/Q"®f Run# I Operator CK Probe/Filter Temp Range,°F 5 Filter Exit Sampling Equipment IDS; Calibration Equipment Checks Pre Mid ost Meter outlet 5T 5 Meterbox ID &F-5 Meterbox Y f e D Pitot(+),pass @ in.H2O @ > @ ?,3 @-,3 Impinger Exit Umbilical ID UAG- j--t Meterbox AH@,in.H2O j(y Pitot(-),pass @ in.H2O @ --, F (�@ 73`r @>3 Other '31 �S Nozzle ID — Nozzle diameter,Dn,in. Pitot visual inspection 2"pass Z pass M"'Pass Ref.Thermometer ID Pitot/Probe ID _ 1 Pilot coefficient,Cp 0- Nozzle visual inspection &pass pass (pass Continuity Check ❑Continuity w/Proper Polarity Manometer ID '5 Manometer zero and level yes Meter,ofm @ in.Hg 0,i301 @ 1S` �/I�J @ l$` 0-��@ lS' Notes: < Sensitiv' Or AK-Factor 5'3 Intermediate leak check volume,ft/ / Orifice Pressure Dry Gas Meter Pump TtPoint# Elapsed Clock Time DGM Reading, Velocity Head, Stack Temp, Probe Temp, Filter Temp,°F lmpinger Exit X Time 24hr Vm,fe AP in H2O Differential,off 'F °F Temp,°F Tem erature,°F Vacuum, Target Actual Box Exit inlet Outlet in.Hg o��(0 ),)a.q� Os3 �� 010 6 9-s 2-�� 6 I 6`5 G�S .-3Kr 0 - `0 l_�6 5 5 L 6 Y� 7 4r� 23ss,� d` � 52 5 6 6V 4(7 oo ? ak5. 0��11 �.[� �. ��10 S 5 2� 63 ti Z5 2-`2 ,� O.�l a,) .� 0- 25( s 3 63 Sc� 8 tf 30 2-5311 0 .� 0 2-10 :s2 9-s� 56 6S �9 � 0- 35 5I-e) 0:3 r a %Q 5--52 �5�- 51s �g 65 Q � I>; t �a 6J.� 0.3 -'1 L �.c `SS 251 2-52 5 G�, Y 0,3 �_Ct ��t� S� 2-5 S� ( G8 Q 9qo �50 �S 5 �z 6q St fl 3 c� � 9•� 0.5v 2.43 2--- �19 0 �-5� 52. S� S S s'�- Ga 2� 0 s0 X4-5 Z-90 �5� �s �� S b K 0.50 2.6 5 2„� a8 2 2- 253 �o S 5S W i ' 3iQ 6-q Xn 13 $9 �L5 1 )-51 G S !a 2`� 3 `f -3 a ® 7- 7- 215 I 1 L--c) 5sS '+3 5 t d M 2 1115 30,<,6( 0.ctl MIA. 61 S- -3 55 Ir i c�v 3ILo.c a� 1� L ,z-v $3 ,Zs N Ito 31 .11 6t V- 5 57 Ch 3�-115 0,Ll 2 D r� D 35��60 �-- W Averages Z QA/QC Check:Completeness_Legibility_Accuracy_Specifications_Checked By Team Leader 001AS-QMS-FM-225 rA6^ MONTROSE O-A Method Field Datashest(Isoklnetic) Page of L AIR gUALITY SERVICES ProJect Information Sampling Conditions ALT Di 1 TC ID: Ambient°F Ref.°F Date I C)-16-�-x Project# Static Pressure,In.H2O - Ambient Temp,°F Stack Customer/Facility U fIE_ELA13f:ATTM �P "+R Barometric Pressure,in.Hg )M b O Ref.Barometer ID t/ws Probe (�- Unit ID/Sample Locatlon V)- ' L Wind Speed/Direction Precipitation,Y1 type Filter Box Run# 1 Operator Probe/Filter Temp Range,°F 4 2-5 Filter Exit a Sampling Equipment IDs Calibration 2 Equipment Checks Pre Mid Post Meter outlet S Meterbox ID 5 Meterbox Y (. 7 Pact(+),pass @ in.H2O ❑ @ ❑ @ ® @ Impinger Exit Umbilical ID U Mkt !� - Meterbox DH@,In.H2O O a, Pilot(-),pass @ in.H2O ❑ @ ❑ @ @ Other Nozzle ID Nozzle diameter,Dn,in. p-`3 i� Pitot visual inspection ❑ s a ❑ Ref.Thermometer ID Pilot/Probe ID �NE:l Pilot coefficient,Cp iq' S Nozzle visual Inspection ❑ pass ❑ pass ❑ pass Continuity Check ❑Continuity w/Proper Polarity Manometer ID i Manometer zero and level [ yes Meter,cfm @ in.Hg @ @ @ Notes: Sensitiv' a-d 1 K-Factor S� Intermediate leak check volume,fe I / Orifice Pressure Dry Gas Meter }t,,I/•�J Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Differential,OH Stack Temp, Probe Temp, Filter Temp,°F Impinger Exit*Inlet ature,°F Vacuum, Point# Time 24hr Vm,ft3 AP In H2O Target Actual °F °F Box O Temp,°FOutlet CIF) in.Hg oic t �S ©, o,�i �� 5 t� b �t �5� lS rn 33 !1_� 2,6! o 2S i 5 6 � 3 0 0-3 5 2�0t 2.� a s� 25 8�1 q� 5 tqo 342- o- w Z„3 2.3 2R6 2S S t 5 LID ° alb SS S o 3 Say" � � � 2-3 r7 2 S3co v m 15 35�i�6 O.w� �, 3 a� o �52 2s t 6� �i 5G L� d a6, LJ 9z 5 Gd Q n�'�,K 3 LTD a.q 5 st 2-5a 57 tv .1 s a 55 d t !.o t `30;-e ®-50 26 `t2 2S2 2-52 6 Ss2 6 !oco ( �( c� 0�So a `t Zs� ZS� b6 Z 1! a :✓ �o l�� o.s S 2 X.q 3 z 5 Z1-- �3 , CS CS 2-5 66 83 60 /Z .z-5 s t R's 8-5 S /A !z3 to 2 � 2 M0.30 767— 6 ( 6 1 a t �3 G� rz o W Averages Team Leader 001AS-QMS-FM-225 CWQC Check:Completeness_Legibility_Accuracy_Specifications_Checked By MONTR®SE EPA Method ; Field Datashest(Isokinetic) Page � of AIR QUALITY SERVICES Project Information Sampling Conditions ALT 011 TC ID: Ambient°F Ref.°F Date 140—0 —;�Z Project# Static Pressure,In.H2O Ambient Temp,°F Stack p-7-3 Customer/Facllity VWLA'AMI K — Ag;M A LL" Barometric Pressure,In.Hg 2'�t Tj Ref.Barometer ID Probe /9'-'-: -� Unit ID/Sample Location U�L- ` CLIZZf Wind Speed/Direction Precipitation,Y I-ype Filter Box Run# a; Operator CIIA Probe/Filter Temp Range,°F Filter Exit Sampling Equipment IDs Calibration Equipment Checks Pre Mid Post Meter outlet 6-21r—j Meterbox ID 61�-5 Meterbox Y v Pilot(+),pass @ in.H2O 91@ >3" lff @ ;;1 3 ` _ 3 impinger Exit 3"q Umbilical ID UM2 7$_ 1 Meterbox AH@,in.H2O 10g6 Pilot(-),pass @ in.H2O @ 7 5" @ —3 @ >3 4 Other 3 j Nozzle ID Nozzle diameter,Dn,in. C7.�1R Pitot visual inspection ai,pass a pass M"pass Ref.Thermometer ID Pitot/Probe ID 10—1'3 Pilot coefficient,Cp Nozzle visual inspection [pass pass M"pass Continuity Check ❑Continuity w/Proper Polari Manometer ID "j Manometer zero and level Oyes Meter,cfm @ in.Hg 0-CID3 @ @ l 5` Notes: XAD C 6VF Sensitivity O-Q 1 K-Factor 5.3 Intermediate ies k check volume,fe Traverse Elapsed Clock Time DGM Reading, Velocity Head, Orifice Pressure Stack Temp, Probe Temp, Filter Temp,°F impinger ExitDry Gas Meter Pump Point# Time 24hr Vm,fe AP In H2O Differential,dH °F °F Temp,°F Temperature,°F ro Vacuum, Target Actual Box Exit Inlet Outlet G F In.Hg l a n5o ° 55 2,11 2-9 2 9S 2.5;Z- '15el AIA tl5 u5 `13 q Cl I ( 5 -T 0.55 1. 2c1 29 2-435 52- � Liy � 413 52 16 00 �, � 0)! cq36.$ 5� 2, 2-52- 53 15 52 10 � 5.2- 1`3y4 T 55 �5 5• 1-0 a -3 25 5 0, a-sl �.�o 9.1" `O 5% q( S,+ to a 0,y$ 2.5� 2.5 �-912 52 252 5 b0 'ico s5 tv y -35 y,(so.0 b,Y 2.s`t r5 2`�2 �52 "*;1L 53 5:4 to X 0 64 tl�;r S' to r- �cS $= 0 5n 2.G5 2-- ��0 z5� 5 50 GY td� SG 10 0. 2 s q-+3,0 ny 2 5 z l 2 ;41 53 66 51 60 to Q r3q L .3 0'qI � � � � 2 5,2 2- .Z 5 6 S,Z 62 (�60 Li`o1,5 v.'15 1. ASS 2 �hz �52 a-52 5� VI 53 04q S� 0��-15 a.3S5 a. aJ, ?5� 52 2- 4 Y 6®LJ-J 0,5t> 2 &5 2,—+ ,-5`� �5� 2-5`l 5-4 �U SH 60 1 q. 3 o"So 2.�5 �� �53 �s3 5�6 '�l 55 55 r08� �1�8.5 �� a.06 �.( 253 �53 s3 I S6 5J o9-5 so3-0 0.3'1 9r0& ;I_1 ��� � 2s sue► 2 57 sr9a 5�' .1 0,4JJ 2.t� a,� ��Z 25 �53 53 3 55 241 N-113 53 ;L53 l 52S Sa 19 N 3 � 515 ,3 3 t�s 5 ,1i6 D,yt-I 3"3 3.3 5 l `�51 5� �G �© 55 �' o„4 6M 2,` 'i a_s �52 )-53 53 �G d 5'+ 9 MS)L� 'o 0-Lt ;Liy �.5 2-5LJ a-52 S5 -4 - !l 66 0 (2o 050 p S -- — z Averages QA/QC Check:Completeness_Legibility_Accuracy_Specifications_Checked By Team Leader 001AS-QMS-FM-225 MO NTRO S E ER/� Method �� Field Datasheet(isokinetic) Page 2— of Z AIR QUALITY SERVICES Project Information Sampling Conditions ALT 011 TO ID: Ambient*F Ref.'F Date t O— 1 k-?;L Project# Static Pressure,In.H2O — Ambient Temp,'F Stack Customer/Facility Wt CIFL A0 — Q {Q Barometric Pressure,In.Hg Z`!. 3 Ref.Barometer ID Probe Q--4`3 Unit ID/Sample Location 112- fi Wind Speed/Direction Precipitation,Y 16 type Filter Box Run# 7-- Operator GI'� Probe/Filter Temp Range,'F Filter Exit Sampling Equipment IDs Calibration Equipment Checks Pre Mid Post Meter Outlet `S Meterbox ID S Meterbox Y 1,01051 Pilot(+),pass @ in.H2O ❑ @ ❑ @ ❑ impinger Exit Umbilical ID Meterbox AH@,in.H2O c3Lt� Pilot(-),pass @ In.H2O ❑ @ @ @ Other 3,C3 Yi Nozzle ID Nozzle diameter,On,in. Pilot visual inspection ❑ pads ❑ pass ❑ pass Ref.Thermometer ID Pitot/Probe ID Pilot coefficient,Cp •� t Nozzle visual inspection ❑ pass ❑ pass ❑ pass lContinuity Check ❑Continuity w/Proper Polarity Manometer ID 4 Manometer zero and level yes Meter,cfm @ in.Hg @ @ @ Notes: Sensitivity 0-z( IK-Factor 5.'3 Intermediate leak check volume,fe ! ! Traverse Elapsed Clock Time DGM Reading, Velocity Head, Orifice Pressure Stack Temp, Probe Temp, Filter Temp,'F Impinger Exit Dry Gas Meter j(A p Pump Point# Time 24hr Vm,it, AP in H2O Differential,An- -F 'F Temp,'F Temperature,'F l°F) Vacuum, Target Actual Box Exit Inlet I Outlet / in.Hg P 1 to 05 531®"1LI L,L ;5 2,3 5�- 5 fi =75 6 2- 1 63 cl t i 5 535,5 a�i LJ 2.33 ,3 a`l1 a 5- ;25z3 43 1 63 9 .00 13t� 53q,L 6,�)� 23� 2 251 2�3 60 -- 63 63 rn P5 3, u'Lit'( 2-33 2 g� a52. ?-53 61[q0 S b.� fJ,�I U ,t� 2_1 19 �5� a-5)- 51� 1 tKS 55i,6 t�.Lld 2.i� 2.( 2-�1 �K� �-56 59 St 6S s2 o5 �3� 2 R`�0 25 t 2 52 56S� 66 53 LO 55q.6 0"is P-3fS 2,'Y Zeta aS zs� 5;5 6� .53 °X 1 tF S6�,U DI 3 2.2 2 3 23� S�( 25� 55 5' Cr 6 561,0 ).2-- 2.3 Z6 �'52.. 2-5 a Q j 5 6,a Qay�L 7.2-- 916 �-52 2.5)- 5-+ 59 46 5-4 R3t, t� 5SO- 5 D1`2 - 2.� a.5 �-C11 9- 2= �-52, g �z 60 tS5 55q,� 0,q 2�tt 2.5 )--Olt 2-50 �s� 6 $ '4z- 6), 10 loo 589-0 rJ.� ��3 �v S3 s� 73 56 10 y t�t55`13 �- d•�� 2w3 2,K 7$1 5 52 b3 3 53 fa 0-3 1,85 t eJ fig(, 61 3 0 ( )L0 Cn 6.01, 5 0,35 t�Sf� t-`1 �S-6 S� 252 60 55� 3 S �-o G t `1 c� W . 2.! 51 4 2 �5 60 g°1 -4-5 60 o,Lt a-w® gi -+5 o a 5 0 6')-1, t 0,4a 241`9� �t-%1 2-5 6 6 2 46 d S M �3s � 11.5 6A), � 2J� 144;J X5.3 :53 GLi '3 44 66 0 629,46S — — -- -- — z Averages QA/QC Check:Completeness_Legibility_Accuracy_Specifications_Checked By Team Leader 001AS-QMS-FM-225 i ,AO NTRO S E ��� Method �- Field Datasheet(lsokinetic) Page P of a AM QUALITY SERVICES Project information Sampling Conditions ALT 011 TC ID: Ambient'F Ref.°F Date ! )—l"!-';l Project# Static Pressure,in.H2O ` Ambient Temp,'F Stack p---7— 3 Customer/Facliity �u � 17�(�—t,:bpV Mh Barometric Pressure,In.Hg o�"l, �J Ref.Barometer ID /kJu^r$ Probe Unit ID/Sample Location V — CFL'T-LtT Wind Speed/Direction Precipitation,Y,tlgtype Filter Box fib Run# '3 Operator CA"�- Probe/Filter Temp Range,°F Z 99%2-S Fitter Exit Sampling Equipment IDs Calibration Equipment Checks Pre yz Mid Post Meter outlet S Meterbox ID s Meterbox Y J,®3U 1 Pilot(+),pass @ in.H2O @ >3 u itd @ ;'3 " @�3 - Impinger Exit ` L66 4 Umbilical ID -1 Meterbox AH@,In.H2O Pitot(-),pass @ in.H2O W @ ';p'3 " [�r @ --3" EF@ 7-3 Other 6116 Nozzle ID Nozzle diameter,Dn,In. O 3l 2 Pilot visual inspection [pass Q'pass [pass Ref.Thermometer ID Pitot/Probe ID ^3 Pilot coefficlent,Cp 0-$Lj Nozzle visual inspection ["pass pass pass Continuity Check ❑Continuity wl Pro er Polarity Manometer ID Manometer zero and level kPyes Meter,cfm @ in.Hg 0-10o3 @ Ct.w3 @ 0 Notes: XAP c 6S o)c Sensitivity 0-0 l K-Factor 5.1 intermediate leak check volume,ft2 / / Orifice Pressure Dry Gas Meter Pump Traverse Elapsed Clock Time DGM Reading, Velocity Head, Stack Temp, Probe Temp, Filter Temp,'F Impinger Exit X.l�D Differential,eH Temperature,'F �, Vacuum, Point# Time 24hr Vm,fe AP in H2O Target Actual of of Box Exit Temp,°F Inlet Outlet � F, in.Hg 4 IZ9,095 6,36 �qAP /,'I ;�a6 51 o256 p/' Ll -:T.)- s`o I 633,o 0'3.. 1.11 1.1 ,a--" 95t �?-53 6,21 -IT 73- so bo b-,%7�-o 6-3 1.69 (, 2-SK 2s,2 S 77 -72- So 0 2 cS b� ,S o<3 t.6� t. �- 535 SG 55 t S/ 00 3 6R4I& Ut36 '55 a-01 U 2 51 5"1- 55 82 �2 52 c '30 6 1, 7.2- ;L"L 1 53 2-51 Sy 5 3 -43 55 9 35 65S 0<K� 2, 2.2 a �►1 2-5 � 50 5'l '99 33 56 $ m f 'o 6 5 16 0.3d 2-04 2-U ;Z-99 2-52- 25 Ll 8H T3 s� 1 5 661-7 g BSI 5L'I g5 571 Q 50 66 7 ,L 0,3 F .2<0 I .2�0 2-5 2-5 5 3 5 +3 5 y 8 Q 5 5 6f 1, d 0,35 )-.,v 1 9-1 0 -)�I 5 S6 6 SS fif 014 �. 2. `i� aS (' 5 fS6 G b5 b-`l.3 a��� a<5 s/ as3 5 �6 5 SS �( 6'83,� 01 9 �.S`i � � 2-°t2- 9-53 52 �S 62 �5 b 4sq, 6 d•�ly 9,59 2 C �-Ct2- 2-50 a-53 5� 85 6 r2- s. MC'°l •� ().`� 2.3�/ �Lll( 'LS'y :Z 51 S� SS S �( 63 c o 6 35�5 �GK,`i D��t �.3 3 2.3 Ito S� ,�5 56 8 ti 13 � � N. i� d�.0 v `l1 2;t�- �•� 2� �53 2-53 SC �6 63 1�5 �-1a, 01L(1 l 7.a- A 6 o 2_3 �-a9 V-55 '153 M 41 `l o z Averages QA/QC Check.Completeness_Legibility_Accuracy_Specifications_Checked By Team Leader 001AS-QMS-FM-225 1 .� MO N T RO S E l�Y Method Field Datashest(Isokinetic) Page of 2 AIR. QUALITY SERVICES Project Information Sampling Conditions ALT 011 TC ID: Ambient°F Ref.°F Date 10 —(`� Project# Static Pressure,in.HZO — Ambient Temp,°F Stack f w 4--3 Customer/Facility L-A) E ABMMA -'V'qH A4JMt0-YA Barometric Pressure,In.Hg 2-`'l.?"3 Ref.Barometer ID !J!~JS Probe to 14-3 Unit ID/Sample Location Ua--_ Wind Speed/Direction Precipitation,Y t&J type Filter Box Run# 3 Operator Probe/Fliter Temp Range,°F - -S Filter Exit Sampling Equipment IDs Calibration Equipment Checks Pre Mid Post Meter outlet "5 Meterbox ID � 5 Meterbox Y [-O3U[ Pilot(+),pass @ in.HZO ❑ @ @ @ Impinger Exit Umbilical ID Q - S-1 Meterbox AH@,In.HZO 2.U 6 Pitot(-),pass @ in.HaO ❑ @ ❑ ❑ @ Other d q[(7 Nozzle ID Nozzle diameter,Dn,in. Q.31 - Pilot visual inspection ❑ pass ❑ pass ❑ pass Ref.Thermometer ID Pilot/Probe ID P� -� PRot coefficient,Cp v- Nozzle visual inspection ❑ pass ❑ pass ❑ pass Continuity Check ❑Continuity w/Proper Polarity Manometer ID -5 Manometer zero and level 0 yes Meter,cfm @ in.Hg @ @ @ Notes: 6$0P Sensitiv' d to �K-Factor S Intermediate leak check volume,if / / Orifice Pressure Dry Gas Meter YAP Temeratu Vacuum, Pump Traverse Clock Time DGM Reading, Velocity Head, Differential,AH Stack Temp, Probe Temp, Filter Temp,°F Impinger Exit re,°F �� Point# Time 24hr Vm,ft9 DP in HZO of eF Box Exit Temp,"F Inlet Outlet ° in.Hg Target Actual 2,01 ;7.0 q2, -�-5-3 :5 r [�5 733Q,0 6) 3 2.07 253 1 93 00 13C 3q,' o° 2 ��� a�K � 3 E56 �sr sG 7q Zo /35 '4 3$. ( 0°q5 2.3� 2, 2-53 2-51 S� 5� S y 6� 8 0 3 a) o 1 5� SE F 0145 S ,5 2- S'T c65 44 G' f55 -:7-55,`1 0.110 2:5 q 5 2-5 x a-lD ;z-5Z ZS2- '57 5 9H GG j t6S �b�t°o d°`l� a•K a.S `90 ;25�t �51 59 9-5 62 9 )-55 lq �5 �Y sy Q f 35 ��.�( c�,�l 5 7115Y 2--K 5-9 575 t' �S i 5J 5 S J 8 51 qq6-� 0A5 �.3� �� 3 9� a s� a str 5 �[ 2.-5 2 55 5� 3 9-50 jam_ SS �sS �y S ► -494, 0�53 201U 2-53 253 li SSLf 60 9 o I d�5 4 eD 6-53 2�� at,� )-'10 2--5 2-53 56 � � 6i fp M 0153 2°1 56 53 1 s k-2 2- aOi c) --5z 5 6 to 0 °fib 1 t.S �1_Sv 5 -05K S�- K b0 l6t�.a V DS� 5� �st2 S� /o0 3v 'W� IS 0713 2�5 25� ? Sz SS 6 Q 2.550 252, s f� 3 6 !D0 �o r6'-r� a�° -- — z Averages CA/QC Check:Completeness_Legibility_Accuracy_Specifications_Checked By Team Leader OO1AS-QMS-FM-225 N Sample Recovery&Calibration ration Check Datasheet Page of L f 1 AIR QUALITY SERVICES Project Information Information 77�� 7 >� Equipment Identification Date _ Project# r��� ®Zl�Zo Ref.Thermometer Customer/Facility l'!i/VIT�'i`', , 1( .�ol/t4/1_l'/! t�1 Hygrometer Unit ID I Sample Location 6WIC2 �F aug, T Field Balance Run# Operator Check Weights Calipers Balance Audit(Field balance must be within 0.5g of check weight mass) Ambient Conditions(Mobile Lab) Date I Relative humidity, Standard mass,g U Temperature,°F Field balance mass,g -I-of-ra= Mobile lab# 26271 Moisture Determination /7/,7722 101011, Runi Run 2 Run 3 Contents Initial V&inal et Initial FlnEll Net initial Final Net Knockout ^ 1 d Impinged 160ML P If ' ^ Impinger2 oomLftzd Z Impinger 3 6 Impinger 4 Impinger 5 Impinger 6 Impinger 7 Impinger 8 Gel I U ' Train Net Gain(Vic) Nozzle Measurements(Difference between any �two �measurements must 2not �be more than 0.004 in(0.1 mm)) N.M.I diameters ���3i2 D1 Ii. :LL�D2 _Ll, 1L —D3 _Average Nozzle 2 diameters 131 D2 D3 Average Nozzle 3 diameters D1 D2 D3 Average Nozzle Material ❑ quartz glass ❑ steel ❑ titanium ❑ inconel ❑ other Probe Type heated ❑ unheated ❑ air-cooled ❑ water-cooled ❑ other Probe Liner ❑ quartz glass ❑ steel ❑ Teflon ❑ other Filter information Front Half: ❑ quartz fiber ❑ glass fiber ❑ Teflon ❑ Teflordquartz ❑ other Filter Number. Run 1: Run 2: Run 3: Run Bards Half: ❑ quartz fiber ❑ glass fiber ❑ Teflon ❑ Tefloniquartz ❑ other Reagent Information Sample Observations Type Lot Number QA/QC Check:Completeness_.Legibility_Accuracy_Specifications Checked by: Team Leader: 001AS-QMS-FM-226 NE013AS-021420-RT-1303 Appendix B- Page 80 of 98 EPA Method 3 Data Sheet Project# r) Test Date: Client/Site: U�QaLp—kr Operator: Pre-Test Leak Check: L) Pipette Fluid Level in capillaries: CO, N) 02 OCV N I- t ORSAT Analysis Audit: Date: CO2 02 Audit Gas Time of Reading Reading %02 *NOTE:Audit results must agree within Concentration Anal is A (B) (B-A) 0.5%of the audit gas concentration 0/-02 value. %CO2 Analyzer I D.-A-ORS- Audit Gas Cylinder I.D.: if Run No. Orsat Bag ID. Time: 0 Sample 1 Sample 2 Sample 3 Average CO, q' ) -- 9' ( 02+CO2 ?ts -1071 �?.1; A Net n. ID, ( 10( l/ U-)— ra>— 2 Run No. Orsat Bag ID. Time: )0 Sample 1 Sample 2 Sample 3 Average CO, L 02+CO2 LO.Net Run No. Orsat Bag ID. Time: Sample 1 Sample 2 Sample 3 Average CO2 Cf 02+CO2 ,0'Net Run No. Orsat Bag ID. Time: Sample I Sample 2 Sample 3 Average CO, 02+CO2 .02 Net Dry Gas Molecular Weight: Md=(Co,-44/100)+(02-32/100)+(Nz*28/100) Montrose Air Quality Services.LLC 2 Near Pasture Road,Unit 5-Newburyport,MA 01950--P.(978)4911-9300-F:(978)499-9303 www.montrose-env.com N EO 1 3AS-021420-RT-1303 Appendix B- Page 81 of 98 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2 Test Dates:October 18-19,2022&October 25-28,2022 Ash Sampling MONTKOSL NE01 3AS-021420-RT-1 303 Appendix B-Page 82 of 98 KU I'M I Facility; IV,A rdoy, ea- City/State: LIA Type of Sample: Et Ask Sampling Method' ADL S007 Run No. 1, Unit No: Date: 10-/A Z-Z; ;r Sampler's Name: Instructions: 1.45 minutes after the beginning of the stack sampling run,take your first shovel sample.Place the sample in a Tedlar Bag.Record sampling time. 2.Take an additional shovel sample every ten minutes afterwards,recording the sampling time. 3.Repeat steps 2 until 45 minutes AFTER the end of the stack sampling run 4.Thorougly mix combined sample in the Tedlar Bag. 5.When one sampe per run is analyzed,place a 500 ml aliquot from this total composite into a clean,labeled 500 ml sample jar. When one sample is analyzed for all three runs place 1000 ml of sample into another Tedlar bag. The three runs will then be thoroughly mixed in this bag and two 500 ml samples will be placed in two labeled.500 mi jars.One sample will be left at the facility as an archived sample. Grab No. Time of Grab Size,mL Comments 1 0 :1--) Shovel \i%/ 2 6)- L4 0 Shovel I)i v V 3 55 Shovel 4 1to Shovel 5 a!5 Shovel 6 j ail() Shovel r-IJ 7 11 ,155 Shovel Dr, \-I, / 8 1 1 D Shovel )11�1&14kn 9 J5 Shovel N 1) 10 Shovel 1)r Ay 11 X; E^ Shovel 0'rill 12 j1-: Shovel 13 Shovel 14 'f Shovel 15 Shovel 16 Shovel Uf 11 17 L Shovel 18 Shovel 19 Shovel 20 Shovel 21 Shovel 22 Shovel 23 Shovel 24 Shovel 25 Shovel 26 Shovel 27 Shovel 28 Shovel 29 Shovel 4 FE30 Shovel USE BACK OF FORM FOR ANY ADDITIONAL INFORMATION Montrose Air Quality Services,LLC 2 Now Pasture Road,Unit 6-Newburyport,MA 01960-T:(97B)499-9300•F:(978)499-9303 www.montrose-env.com N EO 1 3AS-021420-RT-1303 Appendix B- Page 83 of 98 )Ii�on `/�^' ' -^ ^ ' ' — R^~4 .( V \ /A, � \`~ Facility: r+ cmymotamo p Type wxSample: Sampling Method: &OLGunr Run No. I Unit No: Date: J0, Sampler's Nome: Instructions: 1.45 minutes after the beginning of the stack sampling run,take your first shovel sample.Place the sample-in oTedlar - Bag. Record sampling time. 2.Take on additional shovel sample every ten minutes afterwards,recording the sampling time. 3.Repeat steps 2 unfit 45 minutes AFTER the end nf the stack sampling run 4.Thonough mix combined sample im the Tedio,Bag. 5.When one sampe per run is analyzed,place a 500 ml aliquot from this total composite into a clean,labeled 500 ml - emmp|a]ar. When one sample is analyzed for all three runs place 1O00m|of sample into another Ted|orbag. ThoUhree runs will then be thoroughly mixed in this bag and two 500 ml samples will be placed in two labeled 500 ml jars.One sample will ba left ou the facility aaan archived sample. Grab No. Time of Grab Size,mL Comments 3 Shovel 5 Shovel 6 Shovel rut 7 Shovel Shovel 12 Shovel Shovel 14 Shovel 16 Shovel 17 Shovel 18 Shovel 19 Shovel 20 Shovel 21 Shovel 22 Shovel 23 Shovel 24 Shovel 25 Shovel 26 Shovel 27 Shovel 28 Shovel 29 Shovel 30 Shovel USE BACK OF FORM FOR ANY ADDITIONAL INFORMATION - Montrose Air Quality Services,Lu: o New Pasture Road,Unit s^m°°umvpo*wmmem^rmro4o9-o30o^pmru *n9-yx03 � NE013AS'U2142ORT'13O3 Appendix B-Page 84ofOD i &U, Facility: M,4kk dw Citylstate: Type of Sample: Sampling Method: ADL S007 Run No. Unit No: Date: IQ-%9 -;3— Name- Instructions: 1.45 minutes after the beginning of the stack sampling run,take your first shovel sample.Place the sample in a Tedlar Bag.Record sampling time. 2.Take an additional shovel sample every ten minutes afterwards,recording the sampling time. 3.Repeat steps 2 until 45 minutes AFTER the end of the stack sampling run 4.Thorougly mix combined sample in the Tedlar Bag. 5.When.one sampe per run is analyzed,place a 500 ml aliquot from this total composite into a clean,labeled 500 ml sample jar. When one sample is analyzed for all three runs place 1000 ml of sample into another Tedlar bag. The three runs will then be thoroughly mixed in this bag and two 500 ml samples will be placed in two labeled 500 mi jars.One sample will be left at the facility as an archived sample. Grab No. Time of Grab Size,mL Comments 1 + Shovel la 01yl 2 ShovelAiAQ 3 Shovel L,-F' 4 Shovel } 5 Q' Shovel WeDr ctwxi c' h]-t 6 Q Shovel No ` o • 7 1 3 Shovel 8 ;Q'b Shovel 9 Shovel Lj 10 3 ' Shovel 11 Shovel 1 t 12 b Shovel ) DI- 13 4 ;113 Shovel 14 Shovel 1, 15 Lq,, L(a Shovel I I- 16 +� ~ 7 Shovel 17 Shovel 18 Shovel 19 Shovel 20 Shovel 21 Shovel 22 Shovel 23 Shovel 24 Shovel 25 Shovel 26 Shovel 27 Shovel 28 Shovel 29 Shovel 30 Shovel USE BACK OF FORM FOR ANY ADDITIONAL INFORMATION Montrose Air Quality Services,LLC 2 New Pasture Road,Unit 5•Newburyport,MA 01950•T:(978)499-9300-F:(978)499-9303 www.montrose-env.com NE01 3AS-021420-RT-1 303 Appendix B- Page 85 of 98 �NILj Facility: CitylSt,te: MA of Type Sampling Method: ADLOOO7 Run No. Unit No: Date: Samples Name: Instructions: 1.45 minutes after the beginning of the stack sampling run,take your first shovel sample-Place the sample innTogla, Bag. Record sampling time. 2.Take an additional shovel sample every ten minutes aftenwondo,recording the sampling time. 3. Repeat steps 2 until 45minutes AFTER the end o[the stack sampling run 4.Thomug|y mix combined sample in the Ted|arBag. ' 5-When one sampe per run is analyzed,place a 500 ml aliquot from this total composite into a clean,labeled 500 ml sample jar. When one sample is analyzed for all three runs place 1000 ml of sample into another Tedlar bag. The three runs will then be thoroughly mixed in this bog and two 500 m|samples will be placed in two labeled 500 m|]om.One sample will bm left au the facility oaan archived sample. 4 Shovel 5 Shovel 6 Shovel Grab No. Time of Grab Size,mL Comments 15 Shovel 16 Shovel 18 Shovel 19 Shovel 20 Shovel 21 Shovel 22 Shovel 23 Shovel 24 Shovel 25 Shovel 26 Shovel 27 Shovel 28 Shovel 29 Shovel 30 Shovel USE BACK OF FORM FOR ANY ADDITIONAL INFORMATION Montrose Air Quality Sewices,uc 2 New Pasture Road,mmo^wewmuryport.wmu195m^r(9n8)499-9300^p(978)*99-9303 NEO13AS'O2142ORT'13O3 Appendix 8-Page 88ofO8 � . . " '— - rmuUwy: Atrkver coymtnte: lypeo«Sampxs Sampling Method: ADLSVU7 Run No. Unit No Data. Samplees Name: Instructions: 1.45 minutes after the beginning of the stack sampling run,take your first shovel sample.Place the sample inaTedlar Bag.Record sampling time. 2.Take an additional shovel sample every ten minutes afterwards,recording the sampling time. 3,Repeat steps 2 until 45 minutes AFTER the end uf the stack sampling run - 4.Thomugly mix combined sample in the Tod|a,Bag. 5.When one sampe per*run is analyzed,place a 500 ml aliquot from this total composite into a clean,labeled 500 ml sample jar. When one sample is analyzed for all three runs place 1000 ml of sample into another Tedlar bag. The three runs will then be thoroughly mixed in this bag and two 500 ml samples will be placed in two labeled 500 ml jars.One sample will bo left eu the facility ouan archived sample. 6 Shovel Grab No. Time of Grab Size,ml- Comments 11 Shovel 13 Shovel 14 Shovel 15 Shovel 16 Shovel 17 Shovel 19 Shovel 20 Shovel 21 Shovel 22 Shovel 23 Shovel 24 Shovel 25 Shovel 26 Shovel 27 Shovel 28 Shovel 29 Shovel 30 Shovel USE BACK OF FORM FOR ANY ADDITIONAL INFORMATION Montrose Air Quality Services,LLC . ' uNew Pasture Road,Unit o^Newburyport,MAm950^r(978)499-9300^e(978)499-9303 � NE013AS'821420RT'1303 Appendix Page 87ofQ8 5�ar� WON -�k- 10 HY - 1 ME- h4l Facility: N, AMCk()-!Qf-CIty1State: Type of Sample: 4A Sampling Method: ADL S007 Run No. Unit No: Date: Sampler's Name: 1&2 ftZrj Instructions: 1.45 minutes after the beginning of the stack sampling run,take your first shovel sample.Place the sample in a Tedlar Bag.Record sampling time. 2.Take an additional shovel sample every ten minutes afterwards,recording the sampling time. 3.Repeat steps 2 until 45 minutes AFTER the end of the stack sampling run 4.Thorougly mix combined sample in the Tedlar Bag. 5.When one sampe per run is analyzed,place a 500 ml aliquot from this total composite into a clean,labeled 500 ml sample jar. When one sample is analyzed for all three runs place 1000 ml of sample into another Tedlar bag. The three runs will then be thoroughly mixed in this bag and two 500 ml samples will be placed in two labeled 500 ml jars.One sample will be left at the facility as an archived sample. Grab No. Time of Grab Size,mL Comments 1 Shovel 2 Shovel 3 05 Shovel 4 Shovel '74 5 j 3 Shovel 6 Shovel 7 j 0 Shovel 8 ic). O Shovel 1*1 Iry 11 9 -;-5 Shovel 10 Shovel 11 Shovel rl 12 Shovel brIll, 13 Shovel c)Al 14 j r kwv SO Shovel 15 la':� L'L�f g, Shovel 16 1 a Q F oci Shovel 0�Ty I! 17 Shovel 18 Shovel 19 Shovel 20 Shovel 21 Shovel 22 Shovel 23 Shovel 24 Shovel 25 Shovel 26 Shovel 27 Shovel 28 Shovel 29 Shovel 30 Shovel <1 USE BACK OF FORM FOR ANY ADDITIONAL INFORMATION Montrose Air Quality Services,LLC 2 Now Pasture Road,Unit 5-Newburyport,MA 01960-T:(978)499-9300•F:(978)499-9303 www.montrose-env.com N EO I 3AS-021420-RT-1303 Appendix B- Page 88 of 98 ko r\ T 3 5 Ct C16 �' ';� A � J 1- L 4. j Facility: City/State:KcAp 'rw.ABf- Type of Sample:866 �- L) As(,\ Sampling Method: ADL S007 Run No. Unit No: Date: 10—2:6 samplers Name: Instructions: 1.45 minutes after the beginning of the stack sampling run,take your first shovel sample. Place the sample in a Tedlar Bag.Record sampling time. 2.Take an additional shovel sample every ten.minutes afterwards, recording the sampling time. 3. Repeat steps 2 until 45 minutes AFTER the end of the stack sampling run 4.Thorougly mix combined sample in the Tedlar Bag, 5.When one sampe per run is analyzed,place a 500 ml aliquot from this total composite into a clean,labeled 500 ml sample jar. When one sample is analyzed for all three runs place 1000 ml of sample into another Tedlar bag. The three runs will then be thoroughly mixed in this bag and two 500 ml samples will be placed in two labeled 500 ml jars.One sample will be left at the facility as an archived sample. Grab No. Time of Grab Size,ml- comments Shovel bin M&P 2 Shovel P 1440 )�.35 3 Shovel 4 O 5 Shovel 5 Shovel 6 j Shovel 7 t Shovel 8 JC)"0 Shovel 9 lot, D-0 Shovel 10 (01 1 Shovel YE� 11 104 Shovel V 12 1 05 Shovel 1)(LW411 13 a(), Shovel Of I 14 Shovel 15 CID Shovel F) VIC 16 Shovel wwo 17 1 ) Shovel 18 S 1-5 Shovel 19 Shovel 20 Shovel 21 Shovel 22 Shovel 23 Shovel 24 Shovel 25 Shovel 26 Shovel 27 Shovel 28 Shovel 29 Shovel 30 Shovel USE BACK OF FORM FOR ANY ADDITIONAL INFORMATION Montrose Air Quality Services,LLC 2 New Pasture Road,Unit 5-Newburyport,MA 01950-T(978)499-9300-F:(978)499-9303 www.montrose-env.com NE01 3AS-021420-RT-1 303 Appendix B-Page 89 of 98 Ni /� N � t � � � � � � KU )� , � �� � Fa C 11 ity:,`'^^~-~--"-~= ~~y°°^°=:m `ee ' Sampling Method: ADLOOO7 Run No. - Unit No: Date: SamRieemNmmv: Instructions: 1.45 minutes after the beginning ufthe stack sampling run,take your first shovel sample.Place the sample in a Tedlar Bag-Record sampling time. 2.Take an additional shovel sample every ten minutes afterwards, recording the sampling time. .' 3. Repeat steps 2 until 4e minutes AFTER the end uf the stack sampling run 4.ThumuQly mix combined sample in the Ted|a,Bag. 5.When one sampe per run is analyzed,place a 500 ml aliquot from this total composite into a clean,labeled 500 ml sample jar. When one sample is analyzed for all three runs place 1oD0m|of sample into another Tod|orbag. The three runs will then be thoroughly mixed in this bag and two 500 ml samples will be placed in two labeled 500 ml jars.One sample will beleft at the facility aonn archived sample. 4 Shovel oar,k' Grab No. Time of Grab Size,mL Comments 6 Shovel 7 Shovel 8 Shovel 11 Shovel 12 Shovel 14 Shovel 15 Shovel 17 Shovel 19 Shovel 20 Shovel 21 Shovel 22 Shovel 23 Shovel 24 Shovel 25 Shovel 26 Shovel 27 Shovel 28 Shovel 29 Shovel 30 Shovel USE BACK OF FORM FOR ANY ADDITIONAL INFORMATION '- -` ^.. Montrose Air Quality Services,Lu: ' - u New Pasture Road,Unit o`wo°uw»po**mmmm~r(9m)*mmx00~pmrmm9-o30u ( ^_ NE013AS'021420RT-1303 Appendix Page 00ofO8 ^ IA-0N �\ aType of Sample: Sampling Method: /V]LS807 Run No. ' Unit No: Date: Samplees Name: Instructions: 1.45minutes after the beginning ufthe stack sampling run,take your first shovel sample.Place the sample inoTodla, Bag.Record sampling time. 2 Take anadditional shovel sample every ten minutes afterwards,recording the oump||nQ time. 8.Repeat steps 2 until 45 minutes AFTER the end of the staomsomp|ing run 4.Thumugly mix combined sample m the Ted|orBag. e.When one oompe per run is analyzed,place a 5OOm|aliquot from this total composite into o clean,labeled 50om| sample jar. When one sample is analyzed for all three runs place 1UO0m\of sample into another Ted|o,bag. The three - runs will men be thoroughly mixed in this bog and two 500 m|samples will be p|unad in two labeled 500 m|]am.One sample will be left mu the facility aomn archived sample. , Grab No. Time of Grab -.Size,ml- Comments ~ 3 Shovel 4 Shovel 5 Shovel 6 Shovel 7 Shovel 8 Shovel 11 Shovel 18 Shovel 19 Shovel 20 Shovel 21 Shovel 22 Shovel 23 Shovel 24 Shovel 25 Shovel 26 Shovel 27 Shovel 28 Shovel 29 Shovel USE BACK OF FORM FOR ANY ADDIYONAL INFORMATION -_. ( / .. ` Montrose Air uuaI4 Services,un /- u New Pasture Road,Unit o^wo~umwnnummo1mm^rwru4n9-u30o^p(9room+ymm ^ NE013AS-021420RT'13O3 Appendix B- Page O1of88 pAdo it al' ov Type of Sample: MA Facility: City/State: Sampling Method: ADL S007 Run No. Unit No: Date: j0 25 Sampler's Name: lkVn A-taPl!f�S Instructions: 1.45 minutes after the beginning of the stack sampling run,take your first shovel sample. Place the sample in a Tedlar Bag.Record sampling time. 2.Take an additional shovel sample every ten minutes afterwards,recording the sampling time. 3. Repeat steps 2 until 45 minutes AFTER the end of the stack sampling run 4.Thorougly mix combined sample in the Tedlar Bag. 5.When one sampe per run is analyzed,place a 500 ml aliquot from this total composite into a clean,labeled 500 ml sample jar. When one sample is analyzed for all three runs place 1000 ml of sample into another Tedlar bag. The three runs will then be thoroughly mixed in this bag and two 500 ml samples will be placed in two labeled 500 ml jars.One sample will be left at the facility as an archived sample. Grab No. Time of Grab Size,mL Comments I rShovel bnjyl-n� 2 Shovel baub) 3 Shovel 4 C?J a Shovel Dr 11 5 C?,35 Shovel 6 Shovel /-V 7 Shovel r NY 8 r Shovel 9 Shovel DrY 10 Shovel I-V 11 Shovel I Or V 12 Shovel Nt v 13 Shovel W11 14 Shovel hrV 15 Shovel 16 Shovel 17 Shovel 18 r Shovel 19 Shovel 20 Shovel 21 Shovel 22 Shovel 23 Shovel 24 Shovel 25 Shovel 26 Shovel 27 Shovel 28 Shovel 29 Shovel 30 i� J - USE BACK OF FORM FOR ANY ADDITIONAL INFORMATION Montrose Air Quality Services,LLC 2 Now Pasture Road,Unit 5-Newburyport,MA 01950-T:(978)499-9300-F:(978)499-9303 www-montrose-env.com NE01 3AS-021420-RT-1 303 Appendix B-Page 92 of 98 ^ ��� �^-/ IWO N 1 K(- ( \ ) L ^ � 0V | - [ � r d� Facility: CU �N� aho: �l. TypemYSam�e& �T�'\ Sampling Method: ADLSuUr Run No. Unit No: Date: sammp|mes Name: 1.45 minutes after the beginning of the stack sampling run,take your first shovel sample.Place the sample in a Tedlar Bag.Record sampling time. 2.Take an additional shovel sample every ten minutes afterwards,recording the sampling time. 3.Repeat steps 2 until 4aminutes AFTER the end of the stack sampling run 4.ThommVly mix combined sample in the Tad|arBag. 5.When one sampe per run is analyzed,place a 500 ml aliquot from this total composite into a clean,labeled 500 mi sample jar- When one sample is analyzed for all three runs place 1uUom|o,sample into another Tmd|erbag. The three runs will then ba thoroughly mixed in this bag and two mODm|samples will bu placed m two labeled 50Vm|jars.One sample will ua left atthe facility as an archived sample.9 Shovel ' Time of r5rab Size,m1L Comments Grab No. 3 TO-5 Shovel V 12 1 9-0 Shovel 13 1/1-3 Shovel 18 Shovel 19 Shovel 20 Shovel 21 Shovel 22 Shovel 23 Shovel 24 Shovel 25 Shovel 26 Shovel 27 Shovel 28 Shovel 29 Shovel 30 Shovel USE BACK OF FORM FOR ANY ADDITIONAL INFORMATION ` Montrose Air Quality Services,LLC o Now Pasture Road,unxa^wewmuapoammo1mm^rmro4o9-u30o~pmro4u9-omm � � NE013AS-021420RT-1303 Appendix Page 83of9O + T35 11,LtA M-0 N I KU 6 L Facility: City/State- 1q,,qf)d()J1(2f /M TypeofSample: F t Y Sampling Method: ADL S007 Run No. Unit No: Date: Sampler's Name: yt JJA&r?_< Instructions: 1-45 minutes after the beginning of the stack sampling run,take your first shovel sample.Place the sample in a Tedlar Bag.Record sampling time. I 2.Take an additional shovel sample every ten minutes afterwards, recording the sampling time. 3.Repeat steps,2 until 45 minutes AFTER the end of the stack sampling run 4.Thorougly mix combined sample in the Tedlar Bag. 5.When one sampe per run is analyzed,place a 500 ml aliquot from this total composite into a clean,labeled 500 ml sample jar. When one sample is analyzed for all three runs place 1000 ml of sample into another Tedlar bag. The three runs will then be thoroughly mixed in this bag and two 500 ml samples will be placed in two labeled 500 ml jars.One sample will be left at the facility as an archived sample. Time of Grab Grab No. Size,ml- Comments 1 Shovel VV-04- 2 Shovel 3 Shovel 4 i C7 Shovel III 5 Shovel 6 Shovel 7 Shovel 8 Shovel 9 16 a Shovel 'Urvt 10 Q 3 Shovel 11 Shovel DrV 12 Shovel 13 Shovel 14 Shovel 15 Shovel 16 r j Shovel 17 Q Shovel 18 Shovel 19 Shovel 20 Shovel 21 Shovel 22 Shovel 23 Shovel 24 Shovel 25 Shovel 26 Shovel 27 Shovel 28 Shovel 29 Shovel 30 Shovel USE BACK-OF FORM FOR ANY ADDITIONAL INFORMATION I Montrose Air Quality Services,LLC 2 New Pasture Road,Unit 5-Newburyport,MA 01950-T:(978)499-9300-F:(978)499-9303 www.montrose-env.com NE01 3AS-021420-RT-1 303 Appendix B- Page 94 of 98 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2 Test Dates: October 18-19,2022&October 25-28, 2022 Fuuitive MOft!Ti OSE NEW 3AS-021420-RT-1303 Appendix B-Page 95 of 98 Company11 INS FUGITIVE OR SMOKE EMISSION INSPECTION OUTDOOR LOCATION Observer .. Locatio -TT)ya- != i M13 Affiliationo Company e . icy Conditions Wind Directiondes Precipitation WindSpeed ��. Industry Process Unit �, Sketch process unit: indicate observer position relative to source and sun, indicate potential emission points and/or actual emission points. OBSERVATIONS Observation mul. Clock period emission time duration, time, Begin Observation in:smin:sec 20 46uc C J()jtd oc(Yr- 'Da)C A aye'A.eJf 1cJ S 20 GJa(C- a\9 cJ- !Jej Av&A oSly �( End Obsie lon%er, 1 C72J�� Lt��s►T pp Figure 22-1 �aw r 4� NE01 3AS-021420-RT-1 303 Appendix B- Page 96 of 98 EMISSION OUTDOOR LOCATION C a e � Observer E — Location a��� Anil"r Mr- Affiliation Company ap. Date 10 zz2 Sky Conditions Cat in Direction @ Precipitation Wind SpeedC( Indust 0 4D r Process Unit Sketch process unit: indicate observer position relative to source and sun, indicate potential emission points and/or actual emission points. OBSERVATIONS Observation Accumulated Clock period emission time duration, time, Begin Observation min:sec min:sec I0600\j+ 170Y M52 zo f37s zo End Observation " Figure 22-1 NEW 3AS-021420-RT-1 303 Appendix B-Page 97 of 98 INSPECTIONFUGITIVE OR SMOKE EMISSION OUTDOOR LOCATION an server 1A 3 n c i L WL .ff" Affiliato } Com2any Rel?. Date y Conditions Wind Direction ��11jt Precipitation Wind Speedc� IndustryV 3 c r.- Process Unit Sketch process unit: indicate observer position relative to source and sun, indicate potential emission points and/or actual emission points. U�ase OBSERVATIONS Observation Accumulated Clock period emission time duration, time, Begin Observation in:s min:sec ICX>y 2 (v26 -- T � i�.,cy G� ( 01 S zo End Observation Figure -1 NE01 3AS-021420-RT-1 303 Appendix B-Page 98 of 98 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. I &2 Test Dates: October 18-19,2022&October 25-28, 2022 A Aploendix (%P Analytical Data C1 — Hydrogen Chloride, Ammonia, and Condensable Particulate C2 — Particulate, Metals and Mercury C3 — Flue Gas PCDDIPCDFs C4—Ash PCDDIPCDFs (Aw!`y M 0 N T ko S f Ali 001,11JI) NE01 3AS-021420-RT-1 303 Appendix C-Page 2 of 1178 Wheelabrator Environmental Systems, Inc.—Wheelabrator N.Andover, Inc. Compliance Test Program on Unit Nos. 1 &2 Test Dates: October 18-19,2022&October 25-28, 2022 1 Chloride,Hydrogen Ammonia, and Condensable Particulate NE013AS-021420-RT-1303 Appendix C- Page 3 of 1178 Montrose Air Quality Services, LLC — Newburyport 2 New Pasture Road Unit #5 Newburyport, NIA 01950 Wheelabrator North Andover Client Project # J- 21420 Analytical Report (1122-041) EPA Method 2" Hydrogen chloride EPA Method 7 Ammonia Phone: (919) 850 -4392 / Fax: (919) 850 -9012 / www.enthalpy.com 800-1 Capitola Drive Durham, NC 27713-4385 I certify that to the best of my knowledge all analytical data presented in this report: • Have been checked for completeness • Are accurate, error-free, and legible • Have been conducted in accordance with approved protocol, and that all deviations and analytical problems are summarized in the appropriate narrative(s) This analytical report was prepared in Portable Document Format (.PDF) and contains 151 pages. Digitall'y n-% r Toomrvne'YL ��-a-- Date: 2022 . 11 . 18 11% ^ 22 : 51 : 28-05luul Report Issued: 11/18/2022 EA Job# 1122-041 Page 2 of 151 NE01 3AS-021420-RT-1 303 Appendix C-Page 5 of 1178 NE01 3AS-021420-RT-1 303 Appendix C-Page 6 of 1178 Enthalpy Analytical Company: Montrose Air Quality Services, LLC - Newburyport Job No.: 1122-041 EPA M26 Analysis Client No.: PROJ-021420 Site: Wheelabrator North Andover Summary Table Sample ID Hydrogen Chloride Catch Weight(ug) U1-FF Out- R1 - Imp 1 16,291 U1-FF Out- R1 -Imp 2 862 U1-FF Out- R1 -Imp 3 8.23 ND U1-FF Out- R2 - Imp 1 28,202 U1-FF Out- R2 - Imp 2 553 U1-FF Out- R2 - Imp 3 5.30 ND U1-FF Out- R3 - Imp 1 30,566 U1-FF Out- R3 - Imp 2 4,337 U1-FF Out- R3 - Imp 3 6.43 ND U1-SDA In - R1 958,777 U1-SDA In - R2 1,123,663 U1-SDA In - R3 1,095,330 Wheelabrator-M26A- Blank 7.46 ND 1122-041 EPA M26 NE01 3AS-021420-RT-1 303 Appendix C- Page 7 of 1178 Enthalpy Analytical Company: Montrose Air Quality Services, LLC -Newburyport Job No.: 1122-041 EPA CTM-027 Analysis Client No.: PROJ-021420 Site: Wheelabrator North Andover Summary Table Sample ID Ammonia Catch Weight(ug) U1-FF Out- R1 - Imp 1 1,196 U1-FF Out- R1 - Imp 2 21.0 J U1-FF Out- R1 - Imp 3 3.20 ND U1-FF Out- R2 - Imp 1 991 U1-FF Out- R2 - Imp 2 7.22 J U1-FF Out- R2 - Imp 3 2.06 ND U1-FF Out- R3 - Imp 1 1,069 U1-FF Out- R3 - Imp 2 100 U1-FF Out- R3 - Imp 3 2.50 ND Wheelabrator-CTM-027- Blank 2.78 ND 1122-041 EPA CTM-027 NE013AS-021420-RT-1303 Appendix C-Page 8 of 1178 NE013AS-021420-RT-1303 Appendix C- Page 9 of 1178 Enthalpy Analytical Company: Montrose Air Quality Services, LLC- Newburyport Job No.: 1122-041 EPA M26 Analysis Client No.: PROJ-021420 Site:Wheelabrator North Andover Hydrogen Chloride as Chloride Filename Filename MDL Curve Curve Ret. Ret. %dill. Conc. Conc. %diff. Avg. Liquid Conv. Catch Sample ID #1 #2 (ug/mL) Min. Max. Time Time RT #1 #2 cone Conc. DF Vol. Factor Weight Flag pH (ug/mL) (ug/mL) (min.) (min.) (ug/mL) (ug/mL) (ug/mL) (ml-) (ug) U1-FF Out-R1 - Imp 1 197 198 0.0500 0.500 30.0 4.41 4.41 0.0 7.59 7.57 0.1 7.58 10 209 1.028 16,291 0 U1-FF Out-R1 - Imp 2 033 034 0.0500 0.500 30.0 4.42 4.42 0.0 4.26 4.24 0.2 4.25 1 197 1.028 862 0 U1-FF Out-R1 - Imp 3 035 036 0.0500 0.500 30.0 N/A N/A N/A 0.0500 0.0500 N/A 0.0500 1 160 1.028 8.23 ND 0 U1-FF Out-R2- Imp 1 207 208 0.0500 0.500 30.0 4A1 4.41 0.0 14.0 14.0 0.0 14.0 10 196 1.028 28,202 0 U1-FF Out-R2- Imp 2 039 040 0.0500 0.500 30.0 4.43 4.42 0.1 4.03 3.99 0.5 4.01 1 134 1.028 553 0 U1-FF Out-R2- Imp 3 041 042 0.0500 0.500 30.0 N/A N/A N/A 0.0500 0.0500 N/A 0.0500 1 103 1.028 5.30 ND 0 U1-FF Out-R3- Imp 1 209 210 0.0500 0.500 30.0 4.42 4.41 0.0 15.0 15.0 0.2 15.0 10 198 1.028 30,566 0 U1-FF Out- R3- Imp 2 045 046 0.0500 0.500 30.0 4.43 4.43 0.0 22.9 22.9 0.0 22.9 1 184 1.028 4,337 0 U1-FF Out-R3-Imp 3 049 050 0.0500 0.500 30.0 N/A N/A N/A 0.0500 0.0500 N/A 0.0500 1 125 1.028 6.43 ND 0 U1-SDA In-R1 211 212 0.0500 0.500 30.0 4.42 4.41 0.0 15.5 15.6 0.1 15.5 100 600 1.028 958,777 0 U 1-SDA In-R2 219 220 0.0500 0.500 30.0 4.41 4.41 0.0 17.5 17.5 0.1 17.5 100 624 1.028 1,123,663 0 U1-SDA In-R3 221 222 0.0500 0.500 30.0 4.42 4.41 0.0 19.4 19.4 0.0 19.4 100 550 1.028 1,095,330 0 Wheelabrator-M26A-Blank 061 062 0.0500 0.500 30.0 N/A N/A N/A 0.0500 0.0500 N/A 0.0500 1 145 1.028 7.46 ND 0 1122-041 EPA M26 NE01 3AS-021420-RT-1 303 Appendix C- Page 10 of 1178 Enthalpy Analytical Company:Montrose Air Quality Services, LLC-Newburyport Job No.: 1122-041 EPA M26 Analysis Client No.: PROJ-021420 Site:Wheelabrator North Andover Matrix1 %dill.%diff Vol Filename Filename Ret. Ret. Conc. Conc. Avg. Catch Enthalpy Sample ID Compound #1 #2 Time Time RT. #1 #2 conc. Conc. DF (ml-) Weight Flag (min.) (min.) (ug/mL) (ug/mL) (ug/mL) (ug) 1122-041.R111-MS.HCI Chloride 199 200 4.41 4.41 0.0 12.1 12.0 0.6 12.1 1 0.8 9.65 Native Amount(ug): 5.76 Mass Spiked: 4.00 Recovery(%): 97.3 1122-041.R111-MSD.HCI Chloride 201 202 4.41 4.41 0.0 12.5 12.5 0.1 12.5 1 0.8 10.00 Native Amount(ug): 5.76 Mass Spiked: 4.00 Recovery(%): 106 1122-041.In R1-MS.HCI Chloride 213 214 4.41 4.41 0.0 20.2 20.2 0.0 20.2 1 0.8 16.2 Native Amount(ug): 11.8 Mass Spiked: 4.00 Recovery(%): 109 1122-041.In R1-MSD.HCI Chloride 217 218 4.41 4.41 0.0 20.4 20.2 0.4 20.3 1 0.8 16.3 Native Amount(ug): 11.8 Mass Spiked: 4.00 Recovery(%): 111 1122-041 EPA M26 NE01 3AS-021420-RT-1 303 Appendix C-Page 11 of 1178 EnthMpy AnMy.UCM Company: Montrose Air Quality Services, LLC-Newburyport Job No.: 1122-041-3 EPA Method CTM-027(4 Frac)Analysis Client No.: PROJ-021420 Site:Wheelabrator North Andover AmmonEa Sample ID Filename Filename MDL Curve Curve Ret. Ret. %dill. Conc. Conc. %dill. Avg. DF Liquid Catch Flag pH #1 #2 (ug/mL) Min. Max. Time Time RT #1 #2 conc. Conc. Vol. Weight (ug/mL) (ug/mL) (min.) (min.) (ug/mL) (ug/mL) (ug/mL) (ml-) (ug) U1-FF Out-R1 -Imp 1 023 024 0.0200 0.189 11.8 4.27 4.27 0.1 5.72 5.73 0.1 5.72 1 209 1,196 0 U1-FF Out-R1 -Imp 2 029 030 0.0200 0.189 11.8 4.18 4.18 0.0 0.108 0.106 1.1 0.107 1 197 21.0 J 0 U1-FF Out-R1 -Imp 3 031 032 0.0200 0.189 11.8 N/A N/A N/A 0.0200 0.0200 N/A 0.0200 1 160 3.20 ND 0 U1-FF Out-R2-Imp 1 033 034 0.0200 0.189 11.8 4.26 4.25 0.0 5.03 5.08 0A 5.06 1 196 991 0 U1-FF Out-R2-Imp 2 035 036 0.0200 0.189 11.8 4.16 4.15 0.1 0.0552 0.0525 2.4 0.0538 1 134 7.22 J 0 U1-FF Out-R2-Imp 3 037 038 0.0200 0.189 11.8 N/A N/A N/A 0.0200 0.0200 N/A 0.0200 1 103 2.06 ND 0 U1-FF Out-R3-Imp 1 039 040 0.0200 0.189 11.8 4.25 4.24 0.0 5.36 5.43 0.7 5A0 1 198 1,069 0 U1-FF Out-R3-Imp 2 041 042 0.0200 0.189 11.8 4.15 4.15 0.0 0.548 0.545 0.3 0.546 1 184 100 0 U1-FF Out-R3-Imp 3 045 046 0.0200 0.189 11.8 N/A N/A N/A 0.0200 0.0200 N/A 0.0200 1 125 2.50 ND 0 Wheelabrator-CTM-027-Blank 047 048 0.0200 0.189 11.8 N/A N/A N/A 0.0200 0.0200 N/A 0.0200 1 139 2.78 ND 0 1122-041-3-M26 NE013AS-021420-RT-1303 Appendix C-Page 12 of 1178 Enthalpy Analytical Company: Montrose Air Quality Services, LLC-Newburyport Job No.: 1122-041 EPA CTM-027 Analysis Client No.: PROJ-021420 Site:Wheelabrator North Andover Matrix Spike Ret. Ret. Conc. Conc. %diffAvg. VolCatch #1 #2 Enthalpy Sample ID Compound Filename Filename Time Time %dill. #1 #2 conc.. ons. Conc. DF mL Weight Flag (min.) (min.) RT (ug/mL) (ug/mL) conc. (ug/mL) ( ) (ug) 1122-041.R111-MSD.Out Ammonia 027 028 4.27 4.26 0.1 10.1 10.1 0.0 10.1 1 0.8 8.11 Native Amount(ug): 4.35 Mass Spiked: 4.00 Recovery(%): 94.0 1122-041.R111-MS.Out Ammonia 025 026 4.27 4.27 0.1 10.3 10.3 0.3 10.3 1 0.8 8.25 Native Amount(ug): 4.35 Mass Spiked: 4.00 Recovery(%): 97.6 1122-041 EPA CTM-027 NE01 3AS-021420-RT-1 303 Appendix C-Page 13 of 1178 NEW 3AS-021420-RT-1 303 Appendix C- Page 14 of 1178 Enthalpy Analytical Narrative Summary Company Montrose Air Quality Services, LLC - Newburyport Job No. 1 1122-041 EPA M26 Analysis Client ID. PROJ-021420 Site: Wheelabrator North Andover ---- ------------ Custody 1 Matt Loftis received the samples on November 04, 2022 at 3.9 °C after being relinquished by Montrose Air Quality Services, LLC - Newburyport. The 1 samples were received in good condition. Prior to, during, and after analysis, the samples were kept under lock with JT access only to authorized personnel by Enthalpy Analytical, LLC. Analysis The samples were analyzed for chloride using the analytical procedures in i Section 11.0 of EPA Method 26, Determination of Hydrogen Halide and Halogen Emissions from Stationary Sources Non-Isokinetic Method. i All sample aliquots and standards are prepared, stored and analyzed using high-density polyethylene containers. Client samples are retained in the container as received. Sample catch weight results were determined using the sample volumes measured by the laboratory. The Dionex Ion Chromatograph "Raphael' equipped with a Conductivity Detector was used for these analyses. Calibration The calibration curves are included in the Raw Data section of this report.A quadratic curve type was used instead of the method-specified linear curve. Chrom. The acquisition method AS22 ASAP was used for the chloride analyses and Conditions may be available upon request. QC Notes The samples were analyzed within the 28-day holding time specified by the method. ;i The analyses of the field and laboratory reagent blanks did not contain chloride at concentrations greater than the MDL. Duplicate matrix spikes were prepared using aliquots of U1-FF Out- R1 - Imp 1 and U1-SDA In - R1 and met method spike recovery criteria of 80-120%. The analysis of second source standards also served as laboratory control samples and met the laboratory acceptance criteria of±5% of the tag value. ____------------ --_ ____._ _ _-----._____ NE013AS-021420-RT-1303 Appendix C- Page 15 of 1178 Enthalpy Analytical Narrative Summary Company Montrose Air Quality Services, LLC - Newburyport �W Job No. 1122-041 EPA M26 Analysis Client ID. PROJ-021420 Site: Wheelabrator North Andover Reporting 1The samples were analyzed for chloride but the results have been reported Notes as hydrogen chloride. The results were converted using factors of 1.028 respectively to account for the additional hydrogen mass. These analyses met the requirements of the TNI Standard.Any deviations from the requirements of the reference method or TNI Standard have been stated above. i The results presented in this report are representative of the samples as provided to the laboratory. NE01 3AS-021420-RT-1 303 Appendix C- Page 16 of 1178 Enthalpy Analytical Narrative Summary Company Montrose Air Quality Services, LLC - Newburyport Job No. ; 1122-041 EPA CTM-027 Analysis Client IDS PROJ-021420 Site:_Wheelabrator North Andover Custody Matt Loftis received the samples on November 04, 2022 at 3.9 °C after being relinquished by Montrose Air Quality Services, LLC - Newburyport. The samples were received in good condition. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnelby Enthalpy Analytical, LLC_ - — --- _--------------- ---- - -- Analysis The samples were analyzed for ammonia using the analytical procedures in Section 4.2, Sample Analysis, of EPA Conditional Test Method 027, Procedure for Collection and Analysis of Ammonia in Stationary Sources. Sample catch weight results were determined using the sample volumes measured by the laboratory. The sample fractions were not brought up to the method-specified volume of t 250 mL. This preserves lower detection limits and removes a possible source of contamination. I The Thermo Ion Chromatograph "Mikey" equipped with a Conductivity i Detector was used for these analyses. Calibration The calibration curves are included in the Raw Data section of this report. -� Chrom. i The Instrument Method Mikey Cations 12mm was used for the ammonia Conditions analyses and may be available upon request. I QC Notes The samples were analyzed within the 14-day holding time specified by the method. i The analyses of the field and laboratory reagent blanks did not contain ammonia at concentrations greater than the MDL. I Duplicate matrix spikes were prepared using aliquots of U1-FF Out- R1 - Imp 1 and met method spike recovery criteria of 80-120%. The analysis of second source standards also served as laboratory control samples and^met the laboratory acceptance criteria of±10% of the tag value. Reporting These analyses met the requirements of the TNI Standard.Any deviations Notes from the requirements of the reference method or TNI Standard have been I stated above. The results presented in this report are representative of the samples as i provided to the laboratory. NE01 3AS-021420-RT-1 303 Appendix C-Page 17 of 1178 General Reporting Notes The following are general reporting notes that are applicable to all Enthalpy Analytical, LLC data reports,unless specifically noted otherwise. • Any analysis which refers to the method as "Type" represents a planned deviation from the reference method. For instance a Hydrogen Sulfide assay from a Tedlar bag would be labeled as "EPA Method 16-Type" because Tedlar bags are not mentioned as one of the collection options in EPA Method 16. • The acronym MDL represents the Minimum Detection Limit. Below this value the laboratory cannot determine the presence of the analyte of interest reliably. • The acronym LOQ represents the Limit of Quantification. Below this value the laboratory cannot quantitate the analyte of interest within the criteria of the method. • The acronym ND following a value indicates a non-detect or analytical result below the MDL. • The letter J in the Qualifier or Flag column in the results indicates that the value is between the MDL and the LOQ. The laboratory can positively identify the analyte of interest as present, but the value should be considered an estimate. • The letter E in the Qualifier or Flag column indicates an analytical result exceeding 100% of the highest calibration point. The associated value should be considered as an estimate. • Sample results are presented `as measured' for single injection methodologies, or an average value if multiple injections are made. If all injections are below the MDL, the sample is considered non-detect and the ND value is presented. If one, but not all, are below the MDL, the MDL value is used for any injections that are below the MDL. For example, if the MDL is 0.500 and LOQ is 1.00, and the instrument measures 0.355, 0.620, and 0.442 - the result reported is the average of 0.500, 0.620, and 0.500 - - - i.e. 0.540 with a J flag. • When a spike recovery (Bag Spike, Collocated Spike Train, or liquid matrix spike) is being calculated, the native (unspiked) sample result is used in the calculations, as long as the value is above the MDL. If a sample is ND, then 0 is used as the native amount (not the MDL value). • The acronym DF represents Dilution Factor. This number represents dilution of the sample during the preparation and/or analysis process. The analytical result taken from a laboratory instrument is multiplied by the DF to determine the final undiluted sample results. • The addition of MS to the Sample ID represents a Matrix Spike. An aliquot of an actual sample is spiked with a known amount of analyte so that a percent recovery value can be determined. The MS analysis indicates what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample matrix interferes with the analysis of the analyte(s). NE013AS-021420-RT-1303 Appendix C-Page 18 of 1178 General Reporting Notes (continued) • The addition of MSD to the Sample ID represents a Matrix Spike Duplicate. Prepared in the same manner as a MS, the use of duplicate matrix spikes allows further confirmation of laboratory quality by showing the consistency of results gained by performing the same steps multiple times. • The addition of LD to the Sample ID represents a Laboratory Duplicate. The analyst prepares an additional aliquot of sample for testing and the results of the duplicate analysis are compared to the initial result. The result should have a difference value of within 10% of the initial result(if the results of the original analysis are greater than the LOQ). • The addition of AD to the Sample ID represents an Alternate Dilution. The analyst prepares an additional aliquot at a different dilution factor (usually double the initial factor). This analysis helps confirm that no additional compound is present and coeluting or sharing absorbance with the analyte of interest, as they would have a different response/absorbance than the analyte of interest. • The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample matrix, prepared and analyzed by the laboratory using the same reagents, spiking standards and procedures used for the client samples. The LCS is used to assess the control of the laboratory's analytical system. Whenever spikes are prepared for our client projects, two spikes are retained as LCSs. The LCSs are labeled with the associated project number and kept in-house at the appropriate temperature conditions. When the project samples are received for analysis, the LCSs are analyzed to confirm that the analyte could be recovered from the media, separate from the samples which were used on the project and which may have been affected by source matrix, sample collection, and/or sample transport. • Significant Figures: Where the reported value is much greater than unity (1.00) in the units expressed, the number is rounded to a whole number of units, rather than to 3 significant figures. For example, a value of 10,456.45 ug catch is rounded to 10,456 ug. There are five significant digits displayed, but no confidence should be placed on more than two significant digits. In the case of small numbers, generally 3 significant figures are presented, but still only 2 should be used with confidence. Many neat materials are only certified to 3 digits, and as the mathematically correct final result is always 1 digit less than all its pre-cursors - 2 significant figures are what are most defensible. • Manual Integration: The data systems used for processing will flag manually integrated peaks with an "M". There are several reasons a peak may be manually integrated. These reasons will be identified by the following two letter designations on sample chromatograms, if provided in the report. The peak was not integrated by the software "NI", the peak was integrated incorrectly by the software "II" or the wrong peak was integrated by the software "WP" These codes will accompany the analyst's manual integration stamp placed next to the compound name on the chromatogram. NE013AS-021420-RT-1303 Appendix C-Page 19 of 1178 NE01 3AS-021420-RT-1 303 Appendix C-Page 20 of 1178 Chain - Source Page_1_of A ANALYSIS REQUESTED Company Name: Montrose Air Quality Services CLIENT Project Manager: Michael Bruni w INFORMATION e-mail: mbrunikmontrase-env.com ¢ Address: 2 New Pasture Road o d SECTION Newburyport,MA 01950 g z U S Phone: (978)499-9300 Fax: (978)499-9303 N Cell: 339-026-2376 m Sampled by: Michael Bruni Initial Impinger Collection Charge Field Sam le ID #Bottles Collection Date Time volumes tmLp Fraction Ut-FF Out-M2t3AlCTM-027-R1-Imp 1 1 1 DJ27/2022 50 X Imp1 Contents&Rinse 1,11-FF Out-M26AICTM-027-R1-Imp 2 1 10/27/2022 100 X Imp 2 Contents&Rinse Ui-FF Out-M26NCTM-027-R1-Imp 3 1 10/27/2022 100 X Imp 3 Contents&Rinse U1-FF Out-M26A/CTM-027-R1-Imp 4 1 10/2712022 0 X Imp 4 Contents&Rinse U1-FF Out-M26AACTM-027-R2-Imp 1 1 10/27/2022 50 X Imp 1 Contents&Rinse Ui-FF Out-M26AJCTM-027-R2-Imp 2 1 10/27/2022 100 X Imp 2 Contents&Rinse U 1-FF Out-M26A/CTM-027-R2-Imp 3 1 10/27/2022 100 X Imp 3 Contents&Rinse Ut-FF Out-M26AJCTM-027-R2-Imp 4 1 10/27/2022 0 X Im 4 Contents&Rinse u1-FF Out-M26ArcTM-027-R3-Imp 1 1 10/27/2022 50 X Imp1 Contents&Rinse U1-FF Out-M26A ICTM-027-R3-Imp 2 1 10127/2022 100 X Imp 2 Contents&Rinse u1-FF Out-M26A/CTM-027-R3-Imp 3 1 10/2712022 100 X Imp 3 Contents&Rinse f, U1-FF Out-M26AVCTM-027-R3-Imp 4 1 10/27/2022 0 X im 4 Contents&Rinse Y � it 1 liY � TAT Requirement PROJECT INFORMATION REPORTING REQUIREMENTS PROJECT SPECIFIC COMMENTS STD 10 Business day ❑ Project : PROJ-021420 Summary Report only ❑ Method 26A/CTM-027 Analysis(Wheelabroator N.Andover) Rush 5 Business day ❑ Name: Wheelabrator North Andover Summary Report & ❑ Please hold Impinger 4 for analysis. Only analyze if it meets Rush 2 Business day ❑ PO it: Full Data Package breakthrough criteria for CTM-027. Rush 1 Business day ❑ EDD 121 Other sea 'Initial Impinger charge volumes are required before the following analysis can be started:Method 26,CTM-027&Method 8 Relinquished By Date/Time . 2 l`IICV Received by Method 231 T09A Relinquished By Date>rme Received by NATO TEF ❑ TEF x DL ❑ TEF x 0 DL ❑ Relinquished By Date/Time Received by WHO TEF ❑ TEF x 0.5 DL ❑ N. AS-021420-RT-1303 Appendix C rR 7 0 1178t` Chair - Source Page_1_of_1_ ANALYSIS REQUESTED `o Company Name: Montrose Air Quality Services CLIENT n Project Manager: Michael Bruni 2 INFORMATION e-mail: _ mbruni�tmontrose env, _rrr Address: 2 New Pasture Road SECTION Newburyport,MA 01950 Cq Q Phone: (978)499-9300 Fax: (978)499-9303I i U Cell: 339-206-2376 a Sampled by: Michael Bruni i 6 < m 2z 1 Y �; Y77tz InitialImpinger ;YC i�fY Y;t�jY �,YYYz Collection C9iePgt Field Sample ID #Bottles Collection Date Time votuanes tmLr Fraction u1-SDA In-M26A-R1 1 10/27/2022 250 X Y Y 1-4 IM2 Contents&Rinse Y Y YY ut-SDA in-M26A-R2 1 10/27/2022 250 X 14 Imp Contents&Rinse F4, YYftY " u1-SDAIn-M26A-R3 1 10/27/2022 250 X 1-4 Imp Contents&Rinse— V l Y r t j iY �L t 4Wheeiabrator-M26A-Blank 1 10/2712022 100 X 0.1 N H2SO4 Wheeiabrefor-CTM-027-Blank 1 10127/2022 100 X 0.1 N H2SO4 IY�Y ;Y�t Y R. tY,': ti Yi Y�1z,4 i r a \ Y '�311ti1 }b�l Yt }Ye 1 {d 13 k - (`�-Y�}} TAT Requirement PROJECT INFORMATION REPORTING REQUIREMENTS PROJECT SPECIFIC COMMENTS STD 10 Business day ❑ Project#: PROJ-021420 Summary Report only ❑ Method 26A Analysis (Wheelabroator N.Andover) Rush 5 Business day ❑ Name: Wheelabrator North Andover Summary Report & ❑ Method CTM-027 Analysis (W heelabroator N.Andover) Rush 2 Business day ❑ PO#: Full Data Package Rush 1 Business day ❑ EDD O Other s ec . «Initial Impinger charge volumes are required before the following analysis can be started:Method 26,CTM-027&Method 8 Relinquished By Datf 00 Received by Method 23/T09A Relinquished By Date/Time Received by NATO TEF ❑ TEF x DL ❑ TEF x 0 DL ❑ Relinquished By Date/Time Received by WHO TEF ❑ TEF x 0.5 DL ❑ f� -z 2 0=yv Z- NE01 3AS-021420-RT-1 303 AppendiX4�14age M6 Raw Data I , NE01 3AS-021420-RT-1 303 Appendix C-Page 23 of 1178 Logged on User:scthieken Page 11 of 235 Instrument:Raphael 11/14/2022 11:08 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 10-Nov-2022 / 16:18 Run Time: 14.50 36.0 Raphael1245#11 [manually integrated] ECD_1 PS c~o 0 N d' d 30.0 a> 0 25.0 U M i 20.0 m 0 c 0 Uc 15.0 10.0 5.0 0.0 min -2.0 2.00 3.60 4.60 5.60 6.60 7.60 8.00 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Cone Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.17 Fluoride 7.955 28.724 29.56110 FALSE TRUE 2 4.42 Chloride 5.753 21.819 29.80408 FALSE TRUE FSR13AS-021420-RT-1303 Appendix C-Page 24 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 12 of 235 Instrument:Raphael 11/14/2022 11:08 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In. Date/Time: 10-Nov-2022 / 16:34 Run Time: 14.50 36.0 Raphael1245#12 [manually integrated] ECD 1 FPS (.0 cri 30.0 L 0 25.0 U 20.0 a> Cn c 0 C 15.0 tY 10.0 5.0 0.0 min -2.0 2.00 3.60 4.00 5.00 6.60 7.00 8.00 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.16 Fluoride 8.023 29.410 29.78786 FALSE TRUE 2 4.42 Chloride 5.802 22.056 30.03630 FALSE TRUE MER13AS-021420-RT-1303 Appendix C-Page 25 of 1178 Chromeleon(c)Dionex 1996-2009 Version 7.2.8.10783 Logged on User:scthieken Page 13 of 235 Instrument:Raphael 11/14/2022 11:08 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 10-Nov-2022 / 16:50 Run Time: 14.50 36.0 Raphael1245#13 [manually integrated] ECD 1 PS 30.0 25.0 r` LO 17 ri o = 20.0 r a) 0 a) y 15.0 u_ o U 10.0 C�J 5.0 0.0 _ — --._____. min -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.60 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min pS pg/mL 1 3.16 Fluoride 3.911 13.107 14.96830 FALSE TRUE 2 4.41 Chloride 2.848 10.090 15.10529 FALSE TRUE gR13AS-021420-RT-1303 Appendix C-Page 26 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 14 of 235 Instrument:Raphael 11/14/2022 11:08 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 10-Nov-2022 / 17:06 Run Time: 14.50 36.0 Raphael1245#14 [manually integrated] ECD_1 PS 30.0 25.0 M CO =L 20.0 v N O O O C 15.0 LL o � � U 10.0 5.0 0.0 min -2.0 2.00 3.60 4.60 5.60 6.60 7.60 8.00 Time[min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.16 Fluoride 3.930 13.260 15,04340 FALSE TRUE 2 4.41 Chloride 2.848 10.039 15.10394 FALSE TRUE fNER13AS-021420-RT-1303 Appendix C- Page 27 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:scthieken Page 15 of 235 Instrument:Raphael 11/14/2022 11:08 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 10-Nov-2022 / 17:23 Run Time: 14.50 36.0 Raphael1245#15 [manually integrated] ECD 1 PS 30.0 25.0 =-20.0 a� LOo o CY d N 15.0 tY a) o 10.0 L` V RJ 5.0 0.0 min -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 1 111 1/2022 No. Time Peak Name Area Height Conc Manually Assigned? ITRUE ated? min pS*min PS pg/mL 1 3.16 Fluoride 2.579 8.234 9.67627 FALSE 2 4.41 Chloride 1.887 6.440 9.83360 FALSE UE NFn13AS-021420-RT-1303 Appendix C-Page 28 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/IntegratiSfS Version 7.2.8.10783 Logged on User:scthieken Page 16 of 235 Instrument:Raphael 11/14/2022 11:08 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 10-Nov-2022 / 17:39 Run Time: 14.50 36.0 Raphael1245#16 [manually integrated] ECD_1 PS 30.0 25.0 20.0 M a) LO w ti C M O v 15.0 Cn c o o $ 10.0 u o U 5.0 0.0 -2.0 min 2.00 3.00 4.00 5.60 6.60 7.00 8.00 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.15 Fluoride 2.631 8.359 9.88480 FALSE TRUE 2 4.41 Chloride 1.913 6.466 9.97876 FALSE TRUE ER13AS-021420-RT-1303 Appendix C- Page 29 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:scthieken Page 17 of 235 Instrument:Raphael 11/14/2022 11:08 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In. Date/Time: 10-Nov-2022 / 17:55 Run Time: 14.50 36.0 Raphael1245#17 [manually integrated] ECD— 1 PS 30.0 25.0 �20.0 a) c 0 N 15.0 0 d: cli d 10.0 o 0 0 LL U 5.0 cr � 0.0 -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.16 Fluoride 1.431 3.909 4.91922 FALSE TRUE 2 4.41 Chloride 1.032 3.224 4.98264 FALSE TRUE g %Rl3AS-021420-RT-1303 Appendix C- Page 30 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inte ra i Version 7.2.8.10783 Logged on User:scthieken Page 18 of 235 Instrument:Raphael 11/14/2022 11:08 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 10-Nov-2022 / 18:11 Run Time: 14.50 36.0 Raphael1245#18 [manually integrated] ECD_1 PS 30.0 25.0 20.0 m c 0 0 15.0 ch r tY 7 ri a 10.0 0 0 u_ U 5.0 0.0 -2.0 2.00 3.60 4.60 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min uS pg/mL 1 3.16 Fluoride 1.412 3.928 4.83915 FALSE TRUE 2 4A1 Chloride 1.034 3.201 4.99199 FALSE TRUE f�E�13AS-021420-RT-1303 Appendix C-Page 31 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:scthieken Page 19 of 235 Instrument:Raphael 11/14/2022 11:08 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 10-Nov-2022 / 18:27 Run Time: 14.50 36.0 Raphael1245#19 [manually integrated] ECD 1 PS 30.0 25.0 �20.0 a� c 0 w 15.0 a) O 10.0 17 co a) a) 5.0 `o 0 :3 2 U U 0.0 -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.20 Fluoride 0.518 0.886 1.01002 FALSE TRUE 2 4.41 Chloride 0.353 0.772 1.01421 FALSE TRUE gRl3AS-021420-RT-1303 Appendix C-Page 32 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 20 of 235 Instrument:Raphael 11/14/2022 11:08 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In. Date/Time: 10-Nov-2022 / 18:43 Run Time: 14.50 36.0 Raphael1245#20 [manually integrated] ECD_1 PS 30.0 25.0 20.0 Cn a> c 0 n 15.0 a� M O 10.0 C6 a) 0 5.0 `0 0 L U 0.0 min -2.0 2.00 3.60 4.00 5.00 6.60 7.60 8.60 Time[min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conic Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.19 Fluoride 0.511 0.881 0.97657 FALSE TRUE 2 4.41 Chloride 0.354 0.771 1.01876 FALSE TRUE ER13AS-021420-RT-1303 Appendix C-Page 33 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:scthieken Page 21 of 235 Instrument:Raphael 11/14/2022 11:08 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken In.Date/Time: 10-Nov-2022 / 18:59 Run Time: 14.50 36.0 Raphael1245#21 [manually integrated] ECD 1 PS 30.0 25.0 =20.0 a) c 0 15.0 a) 0 0 10.0 N cM a) a) 5.0 0 0 LL U 0.0 i min -2.0 2.00 3.60 4.00 5.00 6.00 7.60 8.00 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conic Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.22 Fluoride 0.402 0.553 0.50322 FALSE TRUE 2 4.41 Chloride 0.264 0.478 0.48491 FALSE TRUE ERl3AS-021420-RT-1303 Appendix C-Page 34 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 22 of 235 Instrument:Raphael 11/14/2022 11:08 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In Date/Time: 10-Nov-2022 / 19:15 Run Time: 14.50 36.0 Raphael1245#22 [manually integrated] ECD_1 PS 30.0 25.0 s 20.0 (D U) c 0 N 15.0 a� O O 10.0 N ri d a� a) 5.0 0 0 ti U 0.0 -2.0 min 2.00 3.60 4.60 5.60 6.60 7.00 8.00 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.22 Fluoride 0.405 0.555 0.51575 FALSE TRUE 2 4.41 Chloride 0.265 0.481 0.48881 FALSE TRUE ME�13AS-021420-RT-1303 Appendix C-Page 35 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:scthieken Page 23 of 235 Instrument:Raphael 11/14/2022 11:08 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 10-Nov-2022 119:31 Run Time: 14.50 36.0 Raphael1245#23 [manually integrated] ECD_1 PS 30.0 25.0 =20.0 C co O CO- 15.0 (D 10.0 O LL s U 5.0 0.0 min -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.60 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.15 Fluoride 1.986 6.603 7.23888 FALSE TRUE 2 4.40 Chloride 1.477 5.745 7.52768 FALSE TRUE gRl3AS-021420-RT-1303 Appendix C-Page 36 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 24 of 235 Instrument:Raphael 11/14/2022 11:08 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 10-Nov-2022 / 19:48 Run Time: 14.50 36.0 J,`" Raphael1245#24 [manually integrated] ECD_1 PS 30.0 25.0 s 20.0 U) o 0 17 M O 0 (n 15.0 M d Of v U> v 10.0 o LL 17 U 5.0 CN 0.0 min -2.0 2.00 3.60 4.00 5.00 6.60 7.00 8.00 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conic Manually Assigned. Manipulated? min NS*min PS pg/mL 1 3.15 Fluoride 2.012 6.648 7.34780 FALSE TRUE 2 4.40 Chloride 1.445 4.858 7.34919 FALSE TRUE ER13AS-021420-RT-1303 Appendix C-Page 37 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:SWilson Page 15 of 28 Instrument:Raphael 11/18/2022 3:58 PM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: SWilson In'.Date/Time: 10-Nov-2022 120:04 Run Time: 14.50 36.0 Raphael1245#25 HPLCStdsl433#RB ECD_1 {PS 30.0 25.0 20.0 c 0 Q 15.0 10.0 5.0 0.0 --�� min -2.0 1. 2.00 3.60 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS Ng/mL n.a. n.a. Fluoride n.a. n.a. n.a. n.a. n.a. n.a. n.a. Chloride n.a. n.a. n.a. n.a. n.a. tFd�13AS-021420-RT-1303 Appendix C- Page 38 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra i Version 7.2.8.10783 Logged on User:SWilson Page 16 of 28 Instrument:Raphael 11/18/2022 3:58 PM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: SWilson In. Date/Time: 10-Nov-2022 / 20:20 Run Time: 14.50 36.0 Raphael1245#26 HPLCStds1433#RB ECD_1 PS 30.0 25.0 20.0 m c 0 w 15.0 (D 10.0 5.0 0.0 -2.01 min 2.60 3.60 4.60 5.00 6.60 7.00 8.60 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL n.a. n.a. Fluoride n.a. n.a. n.a. n.a. n.a. n.a. n.a. Chloride n.a. n.a. n.a. n.a. n.a. I�E(�13AS-021420-RT-1303 Appendix C-Page 39 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:r ken Page 1 of 2 Instrument Rap! '2022 11:00 AM Sequence:Raph: Calibration Table Pos. Level Ref.Amount Calibration Amount Cal Point Ref.Amount Calibration Dil.Factor Volume No. In'ection Name Inlect Time Point Status Status Point Status Ng/mL Ng/mL dig/mL ECD_1 ECD 1, ECD_1 ECD_1 ECD 1 ECD 1 Fluoride Fluoride Fluoride' Fluoride Chloride Chloride 11 HPLCStds1433#6 10/Nov/2022 16:18 RA6 06 30.0000 Ok 30.0000 Ok 30.0000 Ok 1:0000 25.00 12 HPLCStds1433#6 10/Nov/2022 16:34 RA6 06 30,0000 Ok 30.0000 Ok 30.0000 Ok' 1.0000 25.00 13 HPLCStds1433#5 10/Nov/2022"16:50 RA5 05 15.0000 Ok 15.0000 Ok 15.0000 Ok` 1.0000 25.00 14 HPLCStds1433#5 ' 10/Nov/2022 17:06 RA5 05 15,0000 Ok 15.0000 Ok 15.0000 Ok 1,0000 25.00 ' 15 HPLCStds1433#4' 10/Nov/2022 17:23 RA4 04 10.0000 Ok 10.0000 Ok 10.0000 Ok' 1.0000 25.00 16 HPLCStds1433#4 10/Nov/2022 17:39 RA4 04 10.0000 Ok 10.0000 Ok 10.0000 Ok 1.0000 25.00 -17 HPLCStds1433#3" 10/Nov/2022 17:55 RA3 03 5.0000 Ok 5.0000` Ok 5.0000 Ok 1:0000 25.00 18 HPLCStds1433#3 10/Nov/2022 18:11 RA3 03 5.0000 Ok 5.0000 Ok 5.0000 Ok; 1.0000 25.00 19 HPLCStds1433#2; 10/Nov/2022 18:27 RA2 02 1.0000 Ok 1.0000 Ok 1.0000 Ok 1.0000 25.00 20 HPLCStds1433#2 10/Nov/2022`18:43 RA2 02 1.0000 Ok 1.0000 Ok 1.0000 Ok' 10000 25.00 21 HPLCStds1433#1 10/Nov/2022`18:59 RA1 01 0.5000 Ok 0,5000 Ok 0.5000 Ok 1.0000 25,00 22 HPLCStds1433#1 10/Nov/2022 19:15 RA1 01 0.5000 Ok 0.5000 Ok 0.5000 Ok 1.0000 25.00 223 HPLCStds1433#6 13/Nov/2022 01:14 RA6 06 30,0000 Ok 30.0000 Ok ' 30.0000 Ok 1.0000 25.00 224 HPLCStds1433#6 13/Nov/2022 01:30 RA6 06 30.0000 Ok 30.0000` Ok 30.0000 Ok 1.0000 25.00 225 HPLCStds1433#5 13/Nov/2022 01:46 RA5 05 15.0000 Ok 15.0000 Ok 150000 Ok 1.0000 25,00 226 HPLCStds1433#5 13/Nov/2022 02:02 RA5 05 15.0000 Ok '15.0000 Ok 15.0000 Ok 1.0000 25.00 227 HPLCStds1433#4' 13/Nov/2022 02:18 RA4 04 10.0000 Ok 10.0000 Ok 10.0000 Ok 1.0000 25.00 228 HPLCStds1433#4 13/Nov/2022 02:34 RA4 04 10.0000 Ok 10.0000 Ok 10.0000 Ok 1.0000 25.00 229 HPLCStds1433#3 13/Nov/2022 02:51 RA3 03 5.0000 Ok 5.0000` Ok 5.0000 Ok 1.0000 25.00 230 HPLCStds1433#3 13/Nov/2022 03:07 RA3 03 5.0000 Ok 5.0000 Ok 5.0000 Ok 1.0000 25.00 231 HPLCStds1433#2. 131Nov/2022'03:23 RA2 02 1.0000 Ok 1.0000; Ok 1.0000 Ok 1.0000 25.00 232 HPLCStds1433#2 13/Nov/2022 03:39 RA2 02 1.0000 Ok 1.0000 Ok 1.0000 Ok 1.0000 25.00 233 HPLCStds1433#1 13/Nov/2022 03:55 RA1 01 0.5000 Ok 0.5000 Ok 0.5000 Ok 1.0000 25.00 234 HPLCStds1433#1 113/Nov/2022 04:11 1 RA1 1 01 1 0.5000 1 Ok 1 0.5000 1 Ok 1 0.5000 1 Ok 1 1.0000 1 25.00 Detection Parameters Ret.Time Param.Name Param.Value Inj.Type Channel min Always Baseline Noise Auto Range Off Any All Channels Always Baseline Noise Start Time 1.621 [min] Any All Channels Always Baseline Noise End Time 2.175[min] Any All Channels Always ' Cobra Smoothing Width Auto Any All Channels Always ` Consider Void Peak Off Any All Channels 0.000 Fronting Sensitivity Factor 0.500[%] Any All Channels 0.000 Maximum Rider Ratio 10[%] Any All Channels 0.000 Tailing Sensitivity Factor 0.500[%] Any All Channels 0.000 Inhibit lntegration On Any All Channels 0.000 Minimum Area Auto Any All Channels' 2.755 Inhibit'Integration Off` Any All Channels 5.850 Inhibit Integration IOn IAny jAll Channels NE01 3AS-021420-RT-1 303 Appendix C-Page 40 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Calibration Details Version 7.2.8.10783 Logged on User:scthieken Page 2 of 2 Instrument:Raphael 11/14/2022 11:00AM Sequence:Raphael1245 Calibration Batch Report Sequence: Raphael1245 Injection Volume: 25.00 Instrument Method: AS22'ASAP Operator. scthieken Inj.Date/Time: 10-Nov-2022 / 19:31 Run Time: 14.6 Calibration Summary Peak Name Eval.Typez Cal.Type Points Offset Slope Curve Coeff.Det. CO C1 C2 %, Fluoride Area Quad,WithOffset,1/A 24.000 -1.260 4.415 -0.068 99.976 Chloride Area Quad WithOffset 1/A 24.000 -1,090 5.995 -0.109 99.994 AVERAGE: 1.1751 5.2053 -0.0884 99.9850 Injection Name Ret.Time - Area Height Amount 35.0 Fluoride External ECD-1 min NS'min PS pg/mL: pg/mL ECD 1 ECD 1 ECD 1 ECD 1 Fluoride Fluoride Fluoride Fluoride HPLCStds1433#6 3.167 7.955 28.724 29.561 30.0 HPLCStds1433#6 3.163 8.023 29.410 29.788 HPLCStds1433#5 3.157 3.911 13.107 14.968 HPLCStds1433#5 3.157 3.930 13.260 15.043 25.0 HPLCStds1433#4 3.157 2.579 8.234 9.676 HPLCStds1433#4 3.153 2.631 8.359 9.885 HPLCStds1433#3 3.160 1.431 3.909 4.919 HPLCStdsl433#3 3.163 1.412 3.928 4.839 20.0 HPLCStds1433#2 3.197 0.518 0.886 1.010 HPLCStds1433#2 3.193 0.511 0.881 0.977 HPLCStds1433#1 3.220 0.402 0.553 0.503 HPLCStds1433#1 3.220 0.405 0.555 0.516 15.0 HPLCStds1433#6 3.153 8.104 34.375 30.055 HPLCStds1433#6 3.153 8.195 34.524 30.357 HPLCStds1433#5 3.143 4.008 15.809 15.345 10.0 HPLCStds1433#5 3.143 4.007 15.821 15.340 HPLCStds1433#4 3.143 2.688 9.859 10.116 HPLCStds1433#4 3.140 2.657 9.840 9.991 HPLCStds1433#3 3.143 1.454 4.601 5.015 5.0 HPLCStds1433#3 3.143 1.462 4.608 5.049 HPLCStds1433#2 3.167 0.514 0.971 0.992 HPLCStds1433#2 3.167 0.515 0.966 0.996 Wmin HPLCStds1433#1 3.193 0.402 0.580 0.505 0.0 HPLCStds1433#1 3.190 0.402 0.580 0.504 0.00 2.50 5.00 7.50 9.00 Injection Name Ret,Time Area Height Amount 35.0 Chloride External ECD_1 min NS`min PS pg/mL ' pg/mL ECD 1 ECD 1 ECD 1`: ECD 1 Chloride Chloride Chloride Chloride HPLCStds1433#6 4.420 5.753 21.819 29.804 30.0 HPLCStds1433#6 4.417 5.802 22.056 30.036 HPLCStds1433#5 4.410 2.848 10.090 15.105 HPLCStds1433#5 4.413 2.848 10.039 15.104 HPLCStds1433#4 4.410 1.887 6.440 9.834 25.0 HPLCStds1433#4 4.407 1.913 6.466 9.979 HPLCStds1433#3 4.407 1.032 3.224 4.983 HPLCStds1433#3 4.407 1.034 3.201 4.992 20.0 HPLCStds1433#2 4.410 0.353 0.772 1.014 HPLCStds1433#2 4.410 0.354 0.771 1.019 HPLCStds1433#1 4.410 0.264 0.478 0.485 HPLCStds1433#1 4.410 0.265 0.481 0.489 15.0 HPLCStds1433#6 4.420 5.787 22.724 29.961 HPLCStds1433#6 4.413 5.823 22.837 30.136 HPLCStds1433#5 4.413 2.838 10.276 15.048 HPLCStds1433#5 4.410 2.840 10.361 15.057 10.0 HPLCStds1433#4 4.413 1.917 6.579 10.001 HPLCStds1433#4 4.410 1.891 6.587 9.859 HPLCStds1433#3 4.410 1.037 3.281 5.010 5.0 HPLCStds1433#3 4.410 1.046 3.312 5.063 HPLCStds1433#2 4.403 0.351 0.783 U. HPLCStds1433#2 4.407 0.350 0.783 0.997 NS'min HPLCStds1433#1 4.417 0.266 0.483 0.496 0.0 HPLCStds1433#1 1 4.407 0.270 0.486 0.518 0.00 2.00 4.00 6.00 7.00 NE01 3AS-021420-RT-1 303 Appendix C-Page 41 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Calibration Version 7.2.8.10783 Logged on User:scthieken Page 23 of 235 Instrument:Raphael 11/14/2022 11:08 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In. Date/Time: 10-Nov-2022 / 19:31 Run Time: 14.50 36.0 nr Raphael1245#23 [manually integrated] ECD_1 PS 30.0 25.0 =.20.0 d o o P 0 15.0 c� a> 10.0 ° L U 5.0 0.0 _ min -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.15 Fluoride 1.986 6.603 7.23888 FALSE TRUE 2 4.40 Chloride 1.477 5.745 7.52768 FALSE TRUE MgRl3AS-021420-RT-1303 Appendix C- Page 42 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 24 of 235 Instrument:Raphael 11/14/2022 11:08 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken /I Date/Time: 10-Nov-2022 / 19:48 Run Time: 14.50 36.0 1,14 Raphael1245#24 [manually integrated] ECD_1 PS 30.0 25.0 20.0 o O LO O M W 15.0 0 ai ry v a> , •� m 10.0 o W 1 U 5.0 0.0 -2.0 min 2.00 3.60 4.60 5.60 6.60 7.60 8.60 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.15 Fluoride 2.012 6.648 7.34780 FALSE TRUE 2 4.40 Chloride 1 A45 4.858 7.34919 FALSE TRUE MRl3AS-021420-RT-1303 Appendix C- Page 43 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 25 of 235 Instrument: Raphael 11/14/2022 11:08 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 10-Nov-2022 / 20:04 Run Time: 14.50 36.0 l Raphael1245#25 HPLCStds1433#RB ECD_1 PS 30.0 25.0 ZL 20.0 a) c 0 N 15.0 a) 10.0 5.0 0.0 min -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS"min PS pg/mL %R 13AS-021420-RT-1303 Appendix C- Page 44 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra i Version 7.2.8.10783 Logged on User:scthieken Page 26 of 235 Instrument:Raphael 11/14/2022 11:08 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 10-Nov-2022 / 20:20 Run Time: 14.50 36.0 io Raphael1245#26 HPLCStds1433#RB ECD_1 PS 30.0 25.0 20.0 a) w c 0 n 15.0 a) 10.0 5.0 0.0 min -2.0 2.60 3.00 4.00 5.60 6.60 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pig/mL fNER13AS-021420-RT-1303 Appendix C-Page 45 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:scthieken Page 33 of 235 Instrument:Raphael 11/14/2022 11:08 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R112.HC1 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken 11 Date/Time: 10-Nov-2022 / 22:13 Run Time: 14.50 36.0 Raphael1245#33 [manually integrated] ECD_1 PS 30.0 25.0 �20.0 m c 15.0 10.0 .c 0 U 5.0 17 0.0 min -2.0 2.00 3.00 4.60 5.00 6.60 7.00 8.60 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.42 Chloride 0.908 3.412 4.26243 FALSE TRUE gRl3AS-021420-RT-1303 Appendix C-Page 46 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 34 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R112.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 10-Nov-2022 / 22:29 Run Time: 14.50 36.0 Raphael1245#34 [manually integrated] ECD_1 PS 30.0 25.0 20.0 m c 0 5 15.0 ti m 10.0 0 U 5.0 rr 0.0 o _ I min -2.0 2.00 3.60 4.00 5.00 6.60 7.00 8.00 Time[min] Analyst Comment: II SJT 11/11/2022 E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL. 4.42 Chloride 0.905 3.415 4.24433 FALSE TRUE N E�13AS-021420-RT-1303 Appendix C-Page 47 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:scthieken Page 35 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R113.HC1 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 10-Nov-2022 / 22:45 Run Time: 14.50 36.0 Raphael1245#35 [manually integrated] ECD_1 PS 30.0 25.0 =.20.0 0 c 0 cc 15.0 a� 0 M 10.0 d a) 5.0 `o s= U 0.0 min -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS"min PS pg/mL 1 4.43 Chloride 0.031 0.111 n.a. FALSE TRUE gRl3AS-021420-RT-1303 Appendix C-Page 48 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 36 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R113.HC1 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 10-Nov-2022 / 23:01 Run Time: 14.50 36.0 Raphael1245#36 [manually integrated] ECD_1 PS 30.0 25.0 z 20.0 (D U) c 0 N 15.0 ti 10.0 aD 5.0 0 U 0.0 `7 min -2.0 2.00 3.60 4.60 5.60 6.00 7.60 8.60 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.43 Chloride 0.030 0.110 n.a. FALSE TRUE ER13AS-021420-RT-1303 Appendix C- Page 49 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/integr io Version 7.2.8.10783 Logged on User:scthieken Page 39 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R212.HC1 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 10-Nov-2022 / 23:49 Run Time: 14.50 36.0 17 Raphael1245#39 [manually integrated) ECD_1 PS 30.0 25.0 �20.0 a) w c 0 15.0 N a d- 10.0 0 0 U 5.0 0.0 min -2.0 2.00 3.00 4.00 5.00 6.60 7.00 8.00 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.43 Chloride 0.868 3.195 4.03236 FALSE TRUE bRl3AS-021420-RT-1303 Appendix C-Page 50 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 40 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R212.HC1 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 11-Nov-2022 / 00:05 Run Time: 14.50 36.0 Raphael1245#40 [manually integrated] ECD_1 PS 30.0 25.0 =L 20.0 a> w c 0 N 15.0 0 a) C14 10.0 0 5.0 U 0.0 r min -2.0 2.00 3.60 4.60 5.60 6.60 7.60 8.00 Time [min] Analyst Comment: II SJT 11/11/2022 ETime Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL No. 1 4.42 Chloride 0.861 3.183 3.99170 FALSE TRUE gRl3AS-021420-RT-1303 Appendix C- Page 51 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 41 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R213.HC1 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 11-Nov-2022 100:21 Run Time: 14.50 36.0 Raphael1245#41 [manually integrated] ECD_1 PS 30.0 25.0 a 20.0 am c 0 N 15.0 aD 0 cM 10.0 d 5.0 0 U 0.0 `T min -2.0 2.00 3.00 4.60 5.00 6.60 7.60 8.60 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.43 Chloride 0.032 0.113 n.a. FALSE TRUE g M,dR13AS-021420-RTA 303 Appendix C- Page 52 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 42 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R213.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 11-Nov-2022 / 00:38 Run Time: 14.50 36.0 71 Raphael1245#42 [manually integrated] ECD_1 PS 30.0 25.0 20.0 m c 0 Cc 15.0 lY 0 10.0 d- a> 5.0 0 U 0.0 `' min -2.0 2.00 3.60 4.60 5.00 6.00 7.00 8.60 Time [min] Analyst Comment: II SJT 1 111 1/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.43 Chloride 0.033 0.114 n.a. FALSE TRUE f ,ER13AS-021420-RT-1303 Appendix C-Page 53 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra i Version 7.2.8.10783 Logged on User:scthieken Page 45 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R312.HC1 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In".Date/Time: 11-Nov-2022 / 01:26 Run Time: 14.50 36.0 Raphael1245#45 [manually integrated] ECD_1 PS 30.0 0 M �P d' 25.0 a) 0 =L 20.0 U am c � 0 N 15.0 0 10.0 5.0 0.0 _— min -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conic Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.43 Chloride 4.346 17.030 22.91297 FALSE TRUE MFSR13AS-021420-RT-1303 Appendix C-Page 54 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 46 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R312.HC1 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In Date/Time: 11-Nov-2022 / 01:42 Run Time: 14.50 36.0 Raphael1245#46 [manually integrated] ECD_1 PS 30.0 cY) c) v Nr 25.0 a> L O a 20.0 U N V) 17 G O ( 15.0 m 10.0 5.0 0.0 i min -2.0 2.00 3.00 4.00 5.00 6.60 7.00 8.00 Time [min] Analyst Comment: II SJT 11/11/2022 ENo. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.43 Chloride 4.349 17.086 22.92682 FALSE TRUE faER13AS-021420-RT-1303 Appendix C-Page 55 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:scthieken Page 47 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken to Date/Time: 11-Nov-2022 / 01:58 Run Time: 14.50 36.0 Raphael1245#47 HPLCStds1433#4 ECD_1 PS 30.0 25.0 �20.0 a) ``' o et Q- 15.0 _0 d 0 a) 0 a) iZ 10.0 U 5.0 0.0 min -2.0 2.00 3.60 4.00 5.60 6.60 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min pS pg/mL 1 3.14 Fluoride 2.660 9.568 10.00335 FALSE FALSE 2 4A0 Chloride 1.889 6.615 9.84819 FALSE FALSE MgR13AS-021420-RT-1303 Appendix C- Page 56 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 48 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 11-Nov-2022 / 02:14 Run Time: 14.50 36.0 Raphael1245#48 HPLCStds1433#4 ECD_1 PS 30.0 25.0 �20.0 a) Cl) o C) C 15.0 a) 0 I 0 10.0 CIO 1 5.0 0.0 n min -2.0 2.00 3.60 4.60 5.60 6.60 7.00 8.00 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.14 Fluoride 2.659 9.612 10.00030 FALSE FALSE 2 4.40 Chloride 1.881 6.611 9.80180 FALSE FALSE gRl3AS-021420-RT-1303 Appendix C-Page 57 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 49 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R313.HC1 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 11-Nov-2022 / 02:30 Run Time: 14.50 36.0 Raphael1245#49 [manually integrated] ECD_1 PS 30.0 25.0 =20.0 aD co c 0 N 15.0 a> af 0 M 10.0 v 0 5.0 `o U 0.0 min -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time[min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.43 Chloride 0.043 0.157 n.a. FALSE TRUE NN t113AS-021420-RT-1303 Appendix C-Page 58 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr�t � Version 7.2.8.10783 Logged on User:scthieken Page 50 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R313.HC1 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 11-Nov-2022 102:46 Run Time: 14.50 36.0 Raphael1245#50 [manually integrated] ECD_1 PS 30.0 25.0 20.0 m W c 0 in 15.0 m 10.0 dN a� 5.0 0 U 0.0 •r -2.0 min 2.00 3.00 4.00 5.00 6.00 7.60 8.60 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4A3 Chloride 0.042 0.154 n.a. FALSE TRUE f�ER13AS-021420-RT-1303 Appendix C-Page 59 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra 10 Version 7.2.8.10783 Logged on User:scthieken Page 61 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.M26A BIk.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 11-Nov-2022 / 05:44 Run Time: 14.50 36.0 Raphael1245#61 [manually integrated] ECD_1 PS 30.0 25.0 �.20.0 a> w c 0 N 15.0 a) tY r` 10.0 d- a) 5.0 `o U 0.0 min -2.0 2.00 3.00 4.00 5.00 6.60 7.00 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4A3 Chloride 0.099 0.293 n.a. FALSE TRUE MgR13AS-021420-RT-1303 Appendix C-Page 60 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr Version 7.2.8.10783 Logged on User:scthieken Page 62 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.M26A BIk.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In. Date/Time: 11-Nov-2022 / 06:00 Run Time: 14.50 36.0 71 Raphael1245#62 [manually integrated] ECD_1 PS 30.0 25.0 �20.0 a� c 0 ( 15.0 a) 0 10.0 N d- a� 5.0 0 V 0.0 7 min -2.0 2.00 3.60 4.00 5.00 6.00 7.60 8.00 Time[min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.42 Chloride 0.038 0.106 n.a. FALSE TRUE & R13AS-021420-RT-1303 Appendix C- Page 61 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 69 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 11-Nov-2022 / 07:52 Run Time: 14.50 36.0 !,,41 Raphael1245#69 [manually integrated] ECD 1 PS 30.0 25.0 =.20.0 c — co O ri o CO- 15.0 er a) (D ry o a) 10.0 u- `o U , 5.0 0.0 min -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.60 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.14 Fluoride 2.045 7.238 7.48291 FALSE TRUE 2 4A0 Chloride 1.428 4.878 7.25199 FALSE TRUE gRl3AS-021420-RT-1303 Appendix C- Page 62 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 70 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 11-Nov-2022 / 08:09 Run Time: 14.50 36.0 n- Raphael1245#70 [manually integrated] ECD 1 PS 30.0 25.0 s 20.0 a c o ai o � 15.0 0 m 10.0 .7 0 u- •r U , 5.0 CIN 0.0 min -2.0 2.00 3.60 4.60 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.14 Fluoride 2.052 7.259 7.51299 FALSE TRUE 2 4.40 Chloride 1.434 4.889 7.28346 FALSE TRUE fNER13AS-021420-RT-1303 Appendix C-Page 63 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:scthieken Page 71 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken 12L.Date/Time: 11-Nov-2022 / 08:25 Run Time: 14.50 36.0 Raphaell245#71 [manually integrated] ECD_1 PS 30.0 25.0 �20.0 a> 0 c 0 N 15.0 a> 0 LO 10.0 d: v a) 5.0 0 s= U 0.0 min -2.0 2.00 3.00 4.60 5.00 6.60 7.60 8.60 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 0.003 0.012 n.a. FALSE TRUE NFn 13AS-021420-RT-1303 Appendix C- Page 64 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/IntegratfC� Version 7.2.8.10783 Logged on User:scthieken Page 72 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 11-Nov-2022 / 08:41 Run Time: 14.50 Raphael1245#72 [manually integrated] ECD 1 36.0 — PS 30.0 25.0 20.0 a> C 0 15.0 a> LO 0 10.0 d: V- a� 5.0 0 U 0.0 min -2.0 2.00 3.60 4.00 5.60 6.60 7.60 8.00 Time [min] Analyst Comment: II SJT 11/11/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 0.003 0.012 n.a. FALSE TRUE f�E�13AS-021420-RT-1303 Appendix C- Page 65 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:scthieken Page 185 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken /2L.Date/Time: 12-Nov-2022 / 15:02 Run Time: 14.50 36.0 Raphael1245#185 [manually integrated] ECD 1 PS 30.0 25.0 �20.017 v m ri o o a) c 15.0 7 m o a) 0 10.0 U 5.0 0.0 min -2.0 2.00 3.60 4.60 5.00 6.60 7.60 8.60 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min pS pg/mL 1 3.15 Fluoride 2.635 9.453 9.90065 FALSE TRUE 2 4A1 Chloride 1.880 6.470 9.79597 FALSE TRUE fEa�13AS-021420-RT-1303 Appendix C- Page 66 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra i Version 7.2.8.10783 Logged on User:scthieken Page 186 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 12-Nov-2022 / 15:18 Run Time: 14.50 36.0 Raphael1245#186 [manually integrated] ECD— 1 PS 30.0 25.0 20.0 v cM O O N C 15.0 a d 0 L 10.0 U 5.0 0.0 —� -2.0 min 2.00 3.60 4.00 5.60 6.60 7.00 8.60 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.14 Fluoride 2.685 9.646 10.10522 FALSE TRUE 2 4.41 Chloride 1.902 6.557 9.92090 FALSE TRUE ME�13AS-021420-RT-1303 Appendix C- Page 67 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:scthieken Page 197 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R111.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 10.0 Instrument Method: AS22 ASAP Operator: scthieken In". Date/Time: 12-Nov-2022 / 18:15 Run Time: 14.50 36.0 Raphael1245#197 [manually integrated] ECD_1 PS 30.0 25.0 =L 20.0 a) N o c o d CO- 15.0 4 m a) -o 10.0 U M 5.0 0.0 min -2.0 2.00 3.60 4.60 5.00 6.60 7.60 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 2 4.41 Chloride 1.487 5.693 7.58583 FALSE TRUE MgRl3AS-021420-RT-1303 Appendix C-Page 68 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 198 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R1l1.HCl Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 10.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 12-Nov-2022 / 18:31 Run Time: 14.50 36.0 ',?J Raphael1245#198 [manually integrated] ECD_1 PS 30.0 25.0 20.0 co 0 O n d 15.0 d a� 10.0 0 U 5.0 0.0 - min -2.0 2.00 3.60 4.60 5.60 6.00 7.60 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 E2 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.41 Chloride 1.485 5.694 7.57234 FALSE TRUE MER1 3AS-021420-RT-1 303 Appendix C- Page 69 of 1178 Chromeleon(c)Dionex 1996-2009 Version 7.2.8.10783 Logged on User:scthieken Page 199 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R111-MS.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 12-Nov-2022 / 18:47 Run Time: 14.50 36.0 Raphael1245#199 [manually integrated, 1 peak(s) manually assigned] ECD_1 PS 30.0 25.0 =L 20.0 0 am �r w N 15.0 (D o U 10.0 5.0 0.0 min -2.0 2.00 3.00 4.60 5.00 6.60 7.60 8.60 Time [min] Analyst Comment: *10 II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 2 4.41 Chloride 2.303 8.964 12.13867 FALSE TRUE Rl3AS-021420-RT-1303 Appendix C-Page 70 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 200 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R111-MS.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 12-Nov-2022 / 19:03 Run Time: 14.50 36.0 Raphael1245#200 [manually integrated, 1 peak(s) manually assigned] ECD_1 PS 30.0 25.0 20.0 ~0 c C 15.0 a) o U 10.0 5.0 0.0 - min -2.0 2.00 3.60 4.00 5.00 6.00 7.00 8.60 Time [min] Analyst Comment: *10 II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 2 4.41 Chloride 2.277 9.031 11.99545 FALSE TRUE 1 pp 3AS-021420-RT-1303 Appendix C-Page 71 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr ioER Version 7.2.8.10783 Logged on User:scthieken Page 201 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R1 III-MSD.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 12-Nov-2022 / 19:19 Run Time: 14.50 36.0 Raphael1245#201 [manually integrated, 1 peak(s) manually assigned] ECD_1 PS 30.0 25.0 0 =L 20.0 d am c o o � 15.0 L 0 0 U 10.0 c� 5.0 0.0 min -2.0 2.00 3.60 4.00 5.00 6.60 7.00 8.00 Time [min] Analyst Comment: *10 II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 2 4.41 Chloride 2.366 9.272 12.48801 FALSE TRUE MR13AS-021420-RT-1303 Appendix C- Page 72 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 202 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R111-MSD.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 12-Nov-2022 / 19:36 Run Time: 14.50 36.0 Raphaell245#202 [manually integrated, 1 peak(s) manually assigned] ECD_1 PS 30.0 25.0 r` 20.0 0 v a) �r c 0 0 15.0 a) o U 10.0 c� 5.0 0.0 min -2.0 2.00 3.00 4.60 5.60 6.60 7.60 8.00 Time [min] Analyst Comment: *10 II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS Ng/mL 2 4A1 Chloride 2.369 1 9.280 12.50388 FALSE TRUE ER13AS-021420-RT-1303 Appendix C-Page 73 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:scthieken Page 203 of 235 Instrument: Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken In. Date/Time: 12-Nov-2022 / 19:52 Run Time: 14.50 36.0 Raphael1245#203 [manually integrated] ECD 1 PS 30.0 25.0 =,20.0 co (n d C C)0 M .- 15.0 a o a) 10.0 w o �r c� 5.0 C 0.0 min -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.14 Fluoride 2.076 7.325 7.61317 FALSE TRUE 2 4.41 Chloride 1.466 4.937 7.46282 FALSE TRUE M,;Rl3AS-021420-RT-1303 Appendix C- Page 74 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 204 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 12-Nov-2022 / 20:08 Run Time: 14.50 36.0 Raphael1245#204 [manually integrated] ECD 1 PS 30.0 25.0 20.0 coc v o M Q. 15.0 a� a� `o 10.0 L o , 5.0 M 0.0 min -2.0 2.00 3.60 4.00 5.00 6.00 7.00 8.00 Time[min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated. min pS*min PS pg/mL 1 3.14 Fluoride 2.081 7.329 7.63335 FALSE TRUE 2 4.41 Chloride 1.468 4.920 7.47426 FALSE TRUE ,;R13AS-021420-RT-1303 Appendix C- Page 75 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 205 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In Date/Time: 12-Nov-2022 / 20:24 Run Time: 14.50 36.0 Raphael1245#205 [manually integrated] ECD_1 PS 30.0 25.0 �20.0 a) c 0 15.0 eM It 10.0 �r m 5.0 0 2= U 0.0 I `� min -2.0 2.00 3.60 4.60 5.60 6.60 7.00 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.003 0.013 n.a. FALSE TRUE R13AS-021420-RT-1303 Appendix C-Page 76 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr iFd Version 7.2.8.10783 Logged on User:scthieken Page 206 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 12-Nov-2022 / 20:40 Run Time: 14.50 36.0 JoRaphael1245#206 [manually integrated] ECD 1 PS 30.0 25.0 20.0 a> c 0 R 15.0 a> n 10.0 a> 5.0 0 U 0.0 i -2.0 min 2.00 3.60 4.60 5.60 6.60 7.00 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 0.003 0.012 n.a. FALSE TRUE ER13AS-021420-RT-1303 Appendix C-Page 77 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:scthieken Page 207 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R211.HC1 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 10.0 Instrument Method: AS22 ASAP Operator: scthieken /I Date/Time: 12-NOV-2022 / 20:56 Run Time: 14.50 36.0 Raphael1245#207 [manually integrated] ECD_1 PS 30.0 25.0 o_ �20.0 14: a) C 0 c 15.0 0 O U 10.0 5.0 0.0 min -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 2 4.41 Chloride 2.641 10.284 13.98551 FALSE TRUE gRl3AS-021420-RT-1303 Appendix C-Page 78 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 208 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R211.HC1 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 10.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 12-Nov-2022 / 21:12 Run Time: 14.50 36.0 Raphael1245#208 [manually integrated] ECD_1 PS 30.0 25.0 _o 20.0 aD w C 0 N 15.0 0 � U 10.0 5.0 0.0 min 2.00 3.00 4.00 5.00 6.00 7.60 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 E2 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.41 Chloride 2.643 10.392 13.99687 FALSE TRUE f�E�13AS-021420-RT-1303 Appendix C-Page 79 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:scthieken Page 209 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R311.HC1 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 10.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 12-Nov-2022 / 21:28 Run Time: 14.50 36.0 Raphaell245#209 [manually integrated] ECD_1 PS 30.0 25.0 r` =-20.0 �t (n a) c O O CO-15.0 r U 10.0 5.0 0.0 min -2.0 2.00 3.00 4.00 5.00 6.00 7.60 8.60 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 2 4.42 Chloride 2.826 11.086 14.98452 FALSE TRUE g NgR13AS-021420-RT-1303 Appendix C- Page 80 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inte ra i Version 7.2.8.10783 Logged on User:scthieken Page 210 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.R311.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 10.0 Instrument Method: AS22 ASAP Operator: scthieken In. Date/Time: 12-Nov-2022 / 21:44 Run Time: 14.50 36.0 Raphaell245#210 [manually integrated] ECD_1 PS 30.0 25.0 M =L 20.0 Cn N C � O O 5 15.0 tY U CIO 10.0 5.0 0.0 -2.0 min 2.00 3.60 4.00 5.60 6.60 7.60 8.60 Time[min] Analyst Comment: II SJT 11/14/2022 E2 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.41 Chloride 2.836 11.177 15.03701 FALSE TRUE ER13AS-021420-RT-1303 Appendix C-Page 81 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/integr io Version 7.2.8.10783 Logged on User:scthieken Page 211 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.In R1.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 100.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 12-Nov-2022 / 22:01 Run Time: 14.50 36.0 Raphael1245#211 [manually integrated, 1 peak(s) manually assigned] ECD_1 PS 30.0 25.0 r d- _,20.0 � m o a 15.0 U a> W cg> 10.0 5.0 0.0 - — min -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 3 4.42 Chloride 2.926 11.438 15.52382 FALSE TRUE MIaR13AS-021420-RT-1303 Appendix C-Page 82 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 212 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.In R1.HC1 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 100.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 12-Nov-2022 / 22:17 Run Time: 14.50 36.0 Raphael1245#212 [manually integrated, 1 peak(s) manually assigned] ECD_1 PS 30.0 25.0 CM 20.0 N (D C 'C O O N 15.0 c U Mi 10.0 5.0 0.0 -2.0 J min 2.00 3.60 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: 11 SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 3 4.41 Chloride 2.932 11.427 15.55192 FALSE TRUE E�13AS-021420-RT-1303 Appendix C-Page 83 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:scthieken Page 213 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.In RI-MS.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken Date/Time: 12-Nov-2022 / 22:33 Run Time: 14.50 36.0 Raphael1245#213 [manually integrated, 1 peak(s) manually assigned] ECD_1 PS 30.0 M 25.0 a� Z.20.0 0 0 c U 0 N 15.0 a� 10.0 5.0 i 0.0 min -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: *100 II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 2 4.41 Chloride 3.816 14.486 20.20248 FALSE TRUE FR'3AS-021420-RT-1303 Appendix C- Page 84 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 214 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.In R1-MS.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 12-Nov-2022 / 22:49 Run Time: 14.50 36.0 Raphael1245#214 [manually integrated, 1 peak(s) manually assigned] ECD_1 PS 30.0 0 25.0 a> 20.0 � o c U CL 15.0 N 10.0 5.0 i 0.0 _ min -2.0 2.00 3.00 4.60 5.00 6.60 7.00 8.00 Time [min] Analyst Comment: *100 11 SJT 11/14/2022 E2 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.41 Chloride 3.818 14.456 20.21545 FALSE TRUE ER13AS-021420-RT-1303 Appendix C-Page 85 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:scthieken Page 215 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In".Date/Time: 12-Nov-2022 / 23:05 Run Time: 14.50 36.0 nr Raphaell245#215 [manually integrated] ECD_1 PS 30.0 25.0 C') 20.0 O M O C i r O N 15.0 a) o` L 0 10.0 U 5.0 0.0 min -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time[min] Analyst Comment: 11 SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.14 Fluoride 2.683 9.954 10.09596 FALSE TRUE 2 4.41 Chloride 1.900 6.649 9.90982 FALSE TRUE ME6R13AS-021420-RT-1303 Appendix C-Page 86 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 216 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 12-Nov-2022 / 23:21 Run Time: 14.50 36.0 ni' Raphael1245#216 [manually integrated] ECD_1 PS 30.0 25.0 20.0 M M C N 15.0 d L 1 Q LL 10.0 rr U 5.0 0.0 min -2.0 2.00 3.00 4.00 5.00 6.00 7.60 8.00 Time[min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.14 Fluoride 2.695 9.920 10.14407 FALSE TRUE 2 4.41 Chloride 1.906 6.568 9.94429 FALSE TRUE f�ER13AS-021420-RT-1303 Appendix C-Page 87 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra 10 Version 7.2.8.10783 Logged on User:scthieken Page 217 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.In R1-MSD.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method. AS22 ASAP Operator: scthieken Irj.Date/Time: 12-Nov-2022 / 23:37 Run Time: 14.50 36.0 Raphael1245#217 [manually integrated, 1 peak(s) manually assigned] ECD_1 PS 30.0 M 25.0 d- a� �20.0 0 a) � U c 0 c 15.0 10.0 5.0 0.0 �--� min -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: *100 II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL. 2 4.41 Chloride 3.858 14.801 20.41984 FALSE TRUE JM,gR13AS-021420-RT-1303 Appendix C-Page 88 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 218 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.In R1-MSD.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 12-Nov-2022 / 23:53 Run Time: 14.50 36.0 Raphael1245#218 [manually integrated, 1 peak(s) manually assigned] ECD_1 PS 30.0 M 25.0 v a� 20.0 0 En � U 0 15.0 c� W 10.0 5.0 0.0 min -2.0 2.00 3.60 4.60 5.60 6.60 7.60 8.60 Time [min] Analyst Comment: *100 II SJT 11/14/2022 E2 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.41 Chloride 3.824 14.616 20.24589 FALSE I TRUE f gR13AS-021420-RT-1303 Appendix C-Page 89 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra i Version 7.2.8.10783 Logged on User:scthieken Page 219 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.In R2.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 100.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 13-Nov-2022 / 00:09 Run Time: 14.50 36.0 Raphael1245#219 [manually integrated, 1 peak(s) manually assigned] ECD_1 PS 30.0 25.0 M �.20.0 m � •c Cn _o o N 15.0 U am Mi W 10.0 5.0 0 min .0 -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS lag/mL 3 4.41 Chloride 3.298 12.975 17.49880 FALSE TRUE N R13AS-021420-RT-1303 Appendix C- Page 90 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integrstietf Version 7.2.8.10783 Logged on User:scthieken Page 220 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.In R2.HCl Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 100.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 13-Nov-2022 100:26 Run Time: 14.50 36.0 Raphael1245#220 [manually integrated, 1 peak(s) manually assigned] ECD_1 PS 30.0 25.0 M v v 20.0 a) (D W o c s o U R 15.0 , Mi 10.0 5.0 0.0 min -2.0 2.00 3.60 4.60 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 E3 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min PS*min PS pg/mL 4.41 Chloride 3.302 1 13.014 17.52044 FALSE TRUE f�ER13AS-021420-RT-1303 Appendix C-Page 91 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:scthieken Page 221 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.In R3.HC1 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 100.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 13-Nov-2022 / 00:42 Run Time: 14.50 36.0 Raphael1245#221 [manually integrated, 1 peak(s) manually assigned] ECD_1 PS 30.0 25.0 v a> 20.0 0 N L c U 0 W 15.0 CIP a) W 10.0 5.0 0.0 -2.0 min 2.00 3.60 4.60 5.60 6.60 7.60 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 3 4.42 Chloride 3.654 14.341 19.36748 FALSE TRUE NgR13AS-021420-RT-1303 Appendix C- Page 92 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra i Version 7.2.8.10783 Logged on User:scthieken Page 222 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: 1122-041.In R3.HC1 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 100.0 Instrument Method: AS22 ASAP Operator: scthieken In. Date/Time: 13-Nov-2022 / 00:58 Run Time: 14.50 36.0 Raphael1245#222 [manually integrated, 1 peak(s) manually assigned] ECD_1 PS 30.0 co 25.0 m =.20.0 0 a) U c 0 W 15.0 Mi a) 10.0 5.0 0.0 mm -2.0 2.00 3.60 4.60 5.00 6.60 7.00 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 3 4.41 Chloride 3.653 14.484 19.36162 FALSE TRUE ER13AS-021420-RT-1303 Appendix C-Page 93 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/integr io Version 7.2.8.10783 Logged on User:scthieken Page 223 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 13-Nov-2022 / 01:14 Run Time: 14.50 36.0 Raphael1245#223 [manually integrated] ECD— 1 PS L o N 30.0 `o o 25.0 U =.20.0 m c 0 U 15.0 10.0 5.0 0.0 — — min -2.0 2.00 3.60 4.60 5.60 6.60 7.60 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pgtmL 1 3.15 Fluoride 8.104 34.375 30.05528 FALSE TRUE 2 4.42 Chloride 5.787 22.724 29.96128 FALSE TRUE MR13AS-021420-RT-1303 Appendix C-Page 94 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 224 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Ll Date/Time: 13-Nov-2022 / 01:30 Run Time: 14.50 36.0 Raphael1245#224 [manually integrated] ECD_1 PS r) 30.0 0 O 'C O O 25.0 U =L 20.0 a) c 0 c 15.0 a) 10.0 5.0 0.0 min -2.0 2.00 3.60 4.60 5.00 6.00 7.60 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.15 Fluoride 8.195 34.524 30.35727 FALSE TRUE 2 4.41 Chloride 5.823 22.837 30.13563 FALSE TRUE I�ER13AS-021420-RT-1303 Appendix C- Page 95 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:scthieken Page 225 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 13-Nov-2022 101:46 Run Time: 14.50 36.0 Raphael1245#225 [manually integrated] ECD 1 PS 30.0 M d' 25.0 17 M O M 8 �.20.0 O O � u- a I a) O N 15.0 `o a> c w U 10.0 0� 5.0 0.0 min -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 1 3.14 Fluoride 4.008 15.809 15.34467 FALSE TRUE 2 4.41 Chloride 2.838 10.276 15.04811 FALSE TRUE MgRl3AS-021420-RT-1303 Appendix C- Page 96 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 226 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In Date/Time: 13-Nov-2022 / 02:02 Run Time: 14.50 36.0 Raphael1245#226 [manually integrated] ECD_1 PS 30.0 M d' 25.0 cl" O Co 20.0 `O L O N O c 15.0 o a) ij 10.0 5.0 0.0 __ min -2.0 2.00 3.60 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min NS pg/mL 1 3.14 Fluoride 4.007 15.821 15.34013 FALSE TRUE 2 4.41 Chloride 2.840 10.361 15.05727 FALSE TRUE NgR13AS-021420-RT-1303 Appendix C-Page 97 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra i Version 7.2.8.10783 Logged on User:scthieken Page 227 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 13-Nov-2022 / 02:18 Run Time: 14.50 36.0 Raphael1245#227 [manually integrated] ECD 1 PS 30.0 25.0 �20.0 a> cli o er 0 15.0 a) `o LL L 0 10.0 �r U 5.0 0.0 min -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 1 3.14 Fluoride 2.688 9.859 10.11584 FALSE TRUE 2 4.41 Chloride 1.917 6.579 10.00148 FALSE TRUE ]MgR13AS-021420-RT-1303 Appendix C-Page 98 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 228 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 13-Nov-2022 / 02:34 Run Time: 14.50 36.0 Raphael1245#228 [manually integrated] ECD 1 PS 30.0 25.0 20.0 M o Cn C 15.0 d I"L L Q 10.0 m U CIO 5.0 0.0 — min -2.0 2.00 3.00 4.00 5.00 6.00 7.60 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.14 Fluoride 2.657 9.840 9.99086 FALSE TRUE 2 4.41 Chloride 1.891 6.587 9.85904 FALSE TRUE MER1 3AS-021420-RT-1 303 Appendix C- Page 99 of 1178 Chromeleon(c)Dionex 1996-2009 Version 7.2.8.10783 Logged on User:scthieken Page 229 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 13-Nov-2022 / 02:51 Run Time: 14.50 36.0 Raphael1245#229 [manually integrated] ECD 1 PS 30.0 25.0 �20.0 a� c 0 � 15.0 p a) c� a) 10.0 0 0 L 0 5.0 U rr' CIO 0.0 min -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min NS pg/mL 1 3.14 Fluoride 1.454 4.601 5.01531 FALSE TRUE 2 4.41 Chloride 1.037 3.281 5.00961 FALSE TRUE gRl3AS-021420-RT-1303 Appendix C-Page 100 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 230 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken /I Date/Time: 13-Nov-2022 / 03:07 Run Time: 14.50 36.0 Raphael1245#230 [manually integrated] ECD— 1 PS 30.0 25.0 20.0 a> co c 0 15.0 v O cr) d v a> 10.0 a a� o =3 `o u_ -F 5.0 U 0.0 min -2.0 2.00 3.60 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: 11 SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.14 Fluoride 1.462 4.608 5.04872 FALSE TRUE 2 4.41 Chloride 1.046 3.312 5.06281 FALSE TRUE ER13AS-021420-RT-1303 Appendix C- Page 101 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:scthieken Page 231 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In. Date/Time: 13-Nov-2022 / 03:23 Run Time: 14.50 36.0 Raphael1245#231 [manually integrated] ECD_1 PS 30.0 25.0 �20.0 a) c 0 �15.0 a) Co 10.0 ri d' a) a) 5.0 0 ti U 0.0 min -2.0 2.00 3.00 4.00 5.00 6.00 7.60 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.17 Fluoride 0.514 0.971 0.99155 FALSE TRUE 2 4.40 Chloride 0.351 0.783 0.99926 FALSE TRUE g f ,;Rl3AS-021420-RT-1303 Appendix C-Page 102 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inte ra i Version 7.2.8.10783 Logged on User:scthieken Page 232 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 13-Nov-2022 / 03:39 Run Time: 14.50 36.0 Raphael1245#232 [manually integrated] ECD_1 PS 30.0 25.0 20.0 a> c 0 w 15.0 a> r � o 10.0 M 5.0 0 U U 0.0 � min -2.0 2.00 3.60 4.00 5.60 6.00 7.00 8.60 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conic Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.17 Fluoride 0.515 0.966 0.99604 FALSE TRUE 2 4.41 Chloride 0.350 0.783 0.99674 FALSE TRUE f ,ER13AS-021420-RT-1303 Appendix C- Page 103 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra i Version 7.2.8.10783 Logged on User:scthieken Page 233 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken In Date/Time: 13-Nov-2022 / 03:55 Run Time: 14.50 36.0 Raphael1245#233 [manually integrated] ECD 1 PS 30.0 25.0 s 20.0 a) c 0 15.0 a) M 10.0 cri d a) a> 5.0 0 `o � s= LL U 0.0 min -2.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.19 Fluoride 0.402 0.580 0.50522 FALSE TRUE 2 4.42 Chloride 0.266 0.483 0.49566 FALSE TRUE N ER13AS-021420-RT-1303 Appendix C-Page 104 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:scthieken Page 234 of 235 Instrument:Raphael 11/14/2022 11:09 AM Sequence:Raphael1245 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 instrument Method. AS22 ASAP Operator: scthieken Ll Date/Time: 13-Nov-2022 / 04:11 Run Time: 14.50 36.0 Raphael1245#234 [manually integrated] ECD_1 PS 30.0 25.0 20.0 a> c 0 15.0 a� 0 CD 10.0 '7 d ci d' a) 0 7 5.0 0 0 L v � r i m i n -2.0 2.00 3.00 4.00 5.00 6.60 7.60 8.00 Time [min] Analyst Comment: II SJT 11/14/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 3.19 Fluoride 0.402 0.580 0.50385 FALSE TRUE 2 4.41 Chloride 0.270 0.486 0.51834 FALSE TRUE INER13AS-021420-RT-1303 Appendix C- Page 105 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra 10 Version 7.2.8.10783 Logged on User:scthieken Page 5 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator. scthieken Ini.Date/Time: 07-Nov-2022 / 14:45` Run Time: 12.00 7.00 Mikey386#5 HPLCSTDs1419#1 ECD_1 6.00 5.00 Q 4.00 a> 0 0 o_ 3.00 r 2.00 N m 0 1.00 E E Q RJ -0.10 r 2.00 3.60 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.267 Ammonia 0.059 0.260 0.18635 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-02NIlrelgati�n021420-RT-1303 Appendix C- Page 106 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 6 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#1> Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator. scthieken In Date/Time: 07-Nov-2022 / 14:58 Run Time: 12.00 7.00 Mikey386#6 HPLCSTDs1419#1 ECD_1 6.00 5.00 U 4.00 a� c 0 o_ 3.00 0 r` 2.00 N v m 0 1.00 E E Q -0.10 2.60 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS Ng/mL Assigned? Ammonia 2 4.270 Ammonia 0.059 0.261 0.18667 FALSE FALSE Chromeleon(c)Dionex 1996-2009 Version 7.2.8.10783 CTM-0?N/EU�eati�n021420-RT-1303 Appendix C- Page 107 of 1178 Logged on User:scthieken Page 7 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator: scthieken Ini.Date/Time: ' 07-Nov-2022` 115:12 Run Time: 12.00 7.00 Mikey386#7 HPLCSTDs1419#2 ECD_1 ` 6.00 5.00 = 4.00 (D c 0 0- 3.00 ry Cl) r• N 2.00 (D 0 O E 1.00 Q M -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time [min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.273 Ammonia 0.111 0.483 0.38040 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-0?7,UnieACati�n021420-RT-1303 Appendix C-Page 108 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 8 of 51 Instrument:Mikey 11/8/2022 7:44AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor. 1.0 Instrument Method., MikeyCations 12min Operator. scthieken In`Date/Time: 07-Nov-2022 / 15:26 Run Time: 12.00 7.00 Mikey386#8 HPLCSTDs1419#2 ECD_1 6.00 5.00 U 4.00 a� c 0 o_ In 3.00 M t` N 2.00 (6 C O E 1.00 E Q i e -0.10 - 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.273 Ammonia 0.109 1 0.484 0.37489 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-Oz7,M 92-021420-RT-1303 Appendix C-Page 109 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 9 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator.- scthieken In'.Date/Time: 07-Nov-2022` 1 15:39 Run Time: 12.00 7.00 Mikey386#9 HPLCSTDs1419#3 ECD_1 6.00 5.00 U 4.00 U) C G 0 n In 3.00 a) 00 ry N V (0 2.00 E E Q 1.00 cy� -0.10 2.00 3.60 4.60 5.60 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min uS*min PS pg/mL Assigned? Ammonia 2 4.280 Ammonia 0.209 0.873 0.77041 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-04Nf�M 92021420-RT-1303 Appendix C-Page 110 of 1178 version 7.2.8.10783 Logged on User:scthieken Page 10 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor 1.0 Instrument Method. Mikey Cations`12min Operator.- scthieken Date/Time: 07-Nov-2022 / 15:53 Run Time: 12.00 7.00 Mikey386#10 HPLCSTDs1419#3 ECD_1 6.00 5.00 U) 4.00 a> U) c 0 0- 3.00 0 a� ao � N V (6 2.00 C O E E Q 1.00 c� -0.10 2.00 3.00 4.00 5.00 6.00 7.60 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS pg/mL Assigned? Ammonia 2 4.280 Ammonia 0.208 0.872 0.76603 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-02NflrueM92021420-RT-1303 Appendix C- Page 111 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 11 of 51 Instrument:Mikey 11/8/2022 7:44AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor, 1.0 Instrument Method: Mikey Cations 12min` Operator. scthieken In'.Date/Time 07-Nov-2022 116:07 Run Time: 12.00 7.00 Mikey386#11 HPLCSTDs1419#4 ECD 1 6.00 5.00 U 4.00 a> 0 3.00 � m .F 0 E 2.00 E Q 1.00 -0.10 2.00 3.00 4.00 5.00 6.60 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min uS*min PS pg/mL Assigned? Ammonia 2 4.290 Ammonia 0.359 1.416 1,42021 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-0;JtlNatiAn021420-RT-1303 Appendix C-Page 112 of 1178 version 7.2.8.10783 Logged on User:scthieken Page 12 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#4, Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor 1.0 Instrument Method: Mikey Cationsf12min Operator scthieken In Date/Time: 07-Nov-2022 t 16:20 Run Time: 12.00 7.00 Mikey386#12 HPLCSTDs1419#4 ECD_1 6.00 5.00 s 4.00 aD o c 07) O N 0- ai 3.00 d m -E 0 E 2.00 Q 1.00 -0.10 2.00 3.60 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min NS pg/mL Assigned? Ammonia 2 4.290 Ammonia 0.358 1.412 1.41540 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-027./1nIeALgtiQn Version 7.2.8.10783 021420-RT-1303 Appendix C-Page 113 of 1178 Logged on User:scthieken Page 13 of 51 Instrument:Mikey 11/8/2022 7:44AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator. scthieken In'.Date/Time: 07-Nov-2022 116:34 Run Time: 12.00 7.00 Mikey386#13 HPLCSTDs1419#5 ECD_1 6.00 5.00 0 0 m rr C 4.00 a� o c E o E 3.00 Q 2.00 1.00 -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.300 Ammonia 0.719 2.618 3.27227 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-0:NLInle atiQn021420-RT-1303 Appendix C- Page 114 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 14 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: Mikey Cations 12min Operator scthieken In.Date/Time: 07-Nov-2022 /'16i48 Run Time: 12.00 7.00 Mikey386#14 HPLCSTDs1419#5 ECD_1 6.00 5.00 M O Cl? d' U 4.00 a) c 0 c E 0 E CL 3.00 Q o 2.00 1.00 -0.10 �. _.. 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.303 Ammonia 0.719 2.619 3.27494 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-02Nt1nte g-'021420-RT-1303 Appendix C- Page 115 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 15 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator scthieken Ini.Date/Time: 07-Nov-2022 1 17:01 Run Time: ' 12.00 7.00 Mikey386#15 HPLCSTDs1419#6 ECD_1 r 0 6.00 Cl? v m c 0 5.00 E Q R� U 4.00 a> U) G O 3.00 a! 2.00 1.00 -0.10 2.00 3.60 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount I Manually Manipulated? min NS*min PS pg/mL Assigned? Ammonia 2 4.307 Ammonia 1.234 4.200 6.63227 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 Version 7.2.8.10783 CTM-O�N(tt)xeACatiRn021420-RT-1303 Appendix C- Page 116 of 1178 Logged on User:scthieken Page 16 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution'Factor 1.0 Instrument Method. Mikey Cations 12min Operator scthieken In'.`Date/Time: 07-Nov-2022 / 17:15 Run Time: 12.00 7.00 Mikey386#16 HPLCSTDs1419#6 ECD_1 r` 0 6.00 v� m 0 5.00 E Q 4.00 a> 0 0 aw 3.00 2.00 1.00 -0.10 T - 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS pg/mL Assigned? Ammonia 2 4.307 Ammonia 1.232 4.194 6.62092 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-0 N/lErM9n-021420-RT-1303 Appendix C- Page 117 of 1178 version 7.2.8.10783 Logged on User:scthieken Page 17 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#7 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min ` Operator, scthieken In'.'Date/Time: 07-Nov-2022 I'17:29 Run Time: 12.00 7.00 Mikey386#17 HPLCSTDs1419#7 ECD 1 C) 0 a? 6.00 O E 5.00 N y 4.00 N C O aaw 3.00 a! 2.00 1.00 -0.10 2.60 3.60 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS'min PS pg/mL Assigned? Ammonia 2 4.307 Ammonia 1.852 5.980 11.76667 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-02NMatign021420-RT-1303 Appendix C- Page 118 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 18 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#7a Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator. scthieken In.Date/Time: 07-Nov-2022 / 17:42 Run Time: 12.00 7.00 Mikey386#18 HPLCSTDs1419#7 ECD_1 r 0 Cl? 6.00 f° E 5.00 N z 4.00 c CW 3.00 0' 2.00 1.00 -0.10 -- 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.307 Ammonia 1.858 1 5.988 11.83034 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-09TV7Llttie'Ig §n-021420-RT-1303 Appendix C-Page 119 of 1178 Version 7.2.8.10783 Logged o,, per:scthieken age 1 of 2 Instrument:Mikey 11/8/2022 7:43 AM Sequence:Mikey386 Mikey Calibration Table No. In'ection Name Iniect Time Pos. Level Ref.Amount Calibration Point Status Dil.Factor Volume ug/mL pL ECD_1 ECD_1 Ammonia Ammonia 5 HPLCSTDs1419#1 07/Nov/2022 14:45 RA1 1 0.1888 Ok 1.0000 25.00 6 HPLCSTDs1419#1 07/Nov/2022 14:58 RA1 1 0.1888 Ok 1.0000 25.00 7 HPLCSTDs1419#2 07/Nov/2022 15:12 RA2 2 - 0.3776 Ok 1.0000 25.00 8 HPLCSTDs1419#2 07/Nov/2022 15:26 RA2 2 0.3776 Ok 1.0000 25.00 9 HPLCSTDs1419#3 07/Nov/2022 15:39 RA3 3 0.7552 Ok 1.0000 25.00 10 HPLCSTDs1419#3 07/Nov/2022 15:53 RA3 3 0.7552 Ok 1.0000 25.00 11 HPLCSTDs1419#4 07/Nov/2022 16:07 RA4 4 1.4160 Ok 1.0000 25.00 12 HPLCSTDs1419#4 07/Nov/2022 16:20 RA4 4 1.4160 Ok 1.0000 25.00 13 HPLCSTDs1419#5 07/Nov/2022 16:34 RA5 5 3.3040 Ok 1.0000 25.00 14 HPLCSTDs1419#5 07/Nov/2022 16:48 RA5 5 3.3040 Ok 1.0000 25.00 15 HPLCSTDs1419#6 07/Nov/2022 17:01 RA6 6 6.6080 Ok 1.0000 25.00 16 HPLCSTDs1419#6 07/Nov/2022 17:15 RA6 6 6.6080 Ok 1.0000 25.00 17 " HPLCSTDs1419#7 07/Nov/2022 17:29 RA7 7 11.8000 Ok 1.0000 25.00 18 HPLCSTDs1419#7 07/Nov/2022 17:42 RA7 7 11.8000 Ok 1.0000 25.00 Detection Parameters Ret. Time Param. Name Param.Value Inj. Type Channel min Always Baseline Noise Auto Range Off Any All Channels Always Baseline Noise Start Time 0.231 [min]; Any All Channels Always Baseline Noise End Time 1.277 [min]' Any All Channels Always Cobra Smoothing Width Auto Any All Channels Always Consider Void Peak Off Any All Channels 0000 Tailing Sensitivity Factor 0.100 [%] ; Any All Channels 0.000 Rider Detection Off Any All Channels 0.000 Minimum Area Auto Any All Channels 0.000 Inhibit Integration On Any All Channels 2.900 Inhibit Integration Off Any All Channels 8.412 1 Inhibit Integration jOn JAny 1AII'Channels Chromeleon(c)Dionex 1996-2009 CTM-027/Calibration Details Version 7.2.8.10783 NE01 3AS-021420-RT-1 303 Appendix C- Page 120 of 1178 Logged on User:scthieken Page 2 of 2 Instrument:Mikey 11/8/2022 7:43 AM Sequence:Mikey386 Mikey Calibration Batch Report Sequence: Mikey386 Injection Volume: - 25.00 Instrument Method., Mikey Cations 12min Operator: scthieken Inj:Date/Time: 07-Nov-2022 / 19:46 Run Time: 12 Calibration Summary Peak Name Eval.Type Cal.Type Points Offset Slope Curve Coeff.Det. CO C1 C2 % Ammonia Area Quad WithOffset 1/A 14.000 -0.021 3.450 1.575 99.996 AVERAGE: -0.0209 3.4495 1.5752 99.9964 Injection Name Ret.Time Area Height Amount 14.0 Ammonia External ECD-1 min pS"min PS pg/mL pg/mL ECD 1 ECD 1 ECD 1 ECD 1 Ammonia Ammonia Ammonia Ammonia 12.0 HPLCSTDs1419#1 4.267 0.0585 0.260 0.186 HPLCSTDs1419#1 4.270 0.0586 0.261 0.187 10.0 HPLCSTDs1419#2 4.273 0.1107 0.483 0.380 HPLCSTDs1419#2 4.273 0.1093 0.484 0.375 8.0 HPLCSTDs1419#3 4.280 0.2094 0.873 0.770 HPLCSTDs1419#3 4.280 0.2083 0.872 0.766 6.0 HPLCSTDs1419#4 4.290 0.3589 1.416 1.420 HPLCSTDs1419#4 4.290 0.3579 1.412 1.415 HPLCSTDs1419#5 4.300 0.7188 2.618 3.272 4.0 HPLCSTDs1419#5 4.303 0.7192 2.619 3.275 HPLCSTDs1419#6 4.307 1.2337 4.200 6.632 2.0 HPLCSTDs1419#6 4.307 1.2321 4.194 6.621 pS*min HPLCSTDs1419#7 4.307 1.8516 5.980 11.767 0.0. HPLCSTDs1419#7 4.307 1.8584 5.988 11.830 0.00 1.60 2.60' NN Chromeleon( �, g?�1420-RT-1303 Appendix C- ; 121 of 1178 c)Dior 96-2009 CTM-02 . r ti Versioi. _.8.10783 Logged on User:scthieken Page 19 of 51 Instrument:Mikey 11/8/2022 7:44AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: Co Instrument Method: Mikey Cations 12min Operator: scthieken Id.Date/Time: 07-Nov-2022 / 17:56 Run Time: 12.00 7.00 17 Mikey386#19 HPLCSTDs1419#RB ECD 1 6.00 5.00 s 4.00 a� c 0 a a) 3.00 2.00 Cl) N V' t6 C 1.00 0 E Q 0� -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS Ng/mL Assigned? Ammonia 2 4.263 Ammonia 0.003 0.013 n.a. FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-02NLInieAiati�n021420-RT-1303 Appendix C-Page 122 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 20 of 51 Instrument:Mikey 11/8/2022 7:44AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#RB "Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor; 1.0 Instrument Method. MikeyCations 12min Operator scthieken> In'Date/Time: 07-Nov-2022 / 18:10 Run Time: 12.00 7 00 Mikey386#20 HPLCSTDsl419#RB ECD_1 6.00 5.00 s 4.00 a) c C Q 3.00 2.00 CO N N 1.00 0 E E Q -0.10 2.00 3.00 4.00 5.60 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.263 Ammonia 0.003 0.012 n.a. FALSE FALSE Chromeleon(c)Dionex 1996-2009 Version 7.2.8.10783 CTM-02N/JnteACati�n021420-RT-1303 Appendix C- Page 123 of 1178 Logged on User:scthieken Page 21 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor.- 1.0 Instrument Method: Mikey Cations 12min Operator. scthieken In',Date/Time: 07-Nov-2022' "l 18:23 Run Time: 12.00 7.00 Mikey386#21 HPLCSTDs1419#SS ECD_1 6.00 5.00 U 4.00 Cl) d7 (n N G O Q 2 3.00 o E E Q 2.00 1.00 i -0.10 2.00 3.60 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min pS pg/mL Assigned? Ammonia 2 4.293 Ammonia 0.442 1.709 1.81201 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-0?N/lM 92021420-RT-1303 Appendix C- Page 124 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 22 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#SS Injection Volume: 26.00 Injection Type: Check Standard Dilution Factor 1.0 Instrument Method: Mikey Cations 12min Operator. scthieken ' In Date/Time: 07-Nov-2022 / 18i37 Run Time: 12.00 7.00 Mikey386#22 HPLCSTDs1419#SS ECD_1 6.00 5.00 U 4.00 r) N o 0 0 o_ 0 3.00 m Q c elf o E E 2.00 M 1.00 i i -0.10 2.00 3.00 4.00 5.60 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.303 Ammonia 0.445 1.707 1.82819 FALSE FALSE Chromeleon(c)Dionex 1996-2009 Version 7.2.8.10783 CTM-O7N/lttte�Cati�n021420-RT-1303 Appendix C-Page 125 of 1178 Logged on User:scthieken Page 23 of 51 Instrument:Mikey 11/8/2022 7:44AM Sequence:Mikey386 Peak Analysis Report Sample Name. 1122-041.R111.Out Injection Volume: 25.00 Injection Type: ' Unknown Dilution Factor, 1.0 Instrument Method: Mikey Cations 12min Operator scthieken Ini.Date/Time: 07-Nov-2022 / 18:51 Run Time: 12.00 Mikey386#23 1122-041.R111.0ut ECD_1 7.00 6.00 r` N 5.00 c 0 E E ) 4.00 Q En 0 0 in 3.00 D' 2.00 1.00 -0.10 2.60 3.00 4.00 5.60 6.00 7.00 Time [min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS Ng/ml- Assigned? Ammonia 2 4.267 Ammonia 1.106 3.593 5.71783 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CT1-0'RM9'-021420-RT-1303 Appendix C-Page 126 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 24 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041:R111.Out Injection.Volume 25.00 Injection Type: Unknown Dilution`Factor. 1.0 Instrument Method: Mikey Cations 12min Operator. scthieken In1 Date/Time: 07-Nov-2022 /'19:04 Run Ti— 12.00 7.00 1 Mikey386#24 1122-041.R111.0ut ECD_1 6.00 M r` N 5.00 m 0 E E CO 4.00 Q 0 c 0 CL 3.00 2.00 1.00 s i i -0.10 2.00 3.00 4.00 5.00 6.60 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.273 Ammonia 1.107 3.587 5.72625 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-02NJnte �pn021420-RT-1303 Appendix C- Page 127 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 25 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R111-MS.Out Injection Volume: 25.00 `. Injection Type: Unknown Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator scthieken In'.Date/Time:`- 07-Nov-2022 / 19:18 Run Time: ` 12.00 7.00 Mikey386#25 1122-041.R111-MS.Out ECD 1 r co N d' 6.00 Cc c 0 E 5.00 C 4.00 m c 0 CL 3.00 2.00 1.00 i -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time(min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS Ng/ml- Assigned? Ammonia 2 4.267 Ammonia 1.687 5.248 10.28266 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-02NLtnte'ptW-021420-RT-1303 Appendix C- Page 128 of 1178 version 7.2.8.10783 Logged on User:scthieken Page 26 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R111-MS.Out Injection Volume Y 25.00 Injection Type: Unknown Dilution Factor 1.0 Instrument Method: Mikey Cations 12min Operator. scthieken`1 In'`Date/Time: 07-Nov-2022 I 19:32 Run Time: 12.00 7.00 '1? Mikey386#26 1122-041.R111-MS.Out ECD_1 Cl) t` N V' 6.00 C O E 5.00 s 4.00 a) in c 0 W 3.00 2.00 1.00 i -0.10 2.00 3.00 4.60 5.60 6.60 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min uS*min PS pg/mL Assigned? Ammonia 2 4.273 Ammonia 1.695 5.245 10.34818 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-N/1ffift'021420-RT-1303 Appendix C-Page 129 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 27 of 51 Instrument:Mikey 11/8/2022 7:44AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R111-MSMOut Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: Mikey Cations 12min Operator scthieken In.Date/Time:` 07-Nov-2022 "/ 19:45 Run Time: 12.00 7.00 � Mikey386#27 1122-041.R111-MSD.Out ECD_1 0 N V 6.00 (6 G O E E 5.00 r) 4.00 0 CW 3.00 2.00 1.00 i -0.10 2.00 3.60 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min NS pg/mL Assigned? Ammonia 2 4.270 Ammonia 1.671 5.199 10.13870 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-0;JUnYeAtati�n021420-RT-1303 Appendix C- Page 130 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 28 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R111-MSD.Out Injection Volume:: 25.00 Injection Type: Unknown Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator scthieken Date/Time: 07-Nov-2022 l 19:59 Run Time: 12.00 7.00 Mikey386#28 1122-041.R111-MSD.Out ECD_1 Cl) N 6.00 O E 5.00 Q 4.00 N c O CL (0 3.00 2.00 1.00 i -0.10 _ i 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS pg/mL Assigned? Ammonia 2 4.263 Ammonia 1.670 5.213 10.12896 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-O7NLInieAi 92021420-RT-1303 Appendix C-Page 131 of 1178 version 7.2.8.10783 Logged on User:scthieken Page 29 of 51 Instrument:Mikey 11/8/2022 7:44AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R112.Out Injection Volume: 25.00 Injection Type: Unknown Dilution Factor 1.0 Instrument Method: Mikey Cations 12min Operator.- scthieken In'.Date/Time:` 07-Nov-2022 120:13 Run Time: 12.00 7.00 '1? Mikey386#29 1122-041.R112.Out ECD_1 6.00 5.00 )k 4.00 aD c 0 Q aui 3.00 0_ 0 2.00 v 0 0 1.00 E E Q I I I C�J I I -0.10 � 2.00 3.00 4.00 5.00 6.00 7.00 Time [min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.180 Ammonia 0.037 0.129 0.10806 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-02N(tr)Zeh 92 02 1 42 0-RT-1303 Appendix C-Page 132 of 1178 version 7.2.8.10783 Logged on User:scthieken Page 30 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R112.Out Injection Volume: 25.00 Injection Type: Unknown Dilution Factor 1.0 Instrument Method. Mikey Cations 12min Operator scthieken In'.'Date/Time: 07-Nov-2022 / 20:26 "Run Time: 12.00 7.00 Mikey386#30 1122-041.R112.Out ECD_1 6.00 5.00 4.00 a> w c O Q au) 3.00 of 0 2.00 °ro v _m G O 1.00 E E Q -0.10 2.00 3.00 4.00 5.60 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS pg/mL Assigned? Ammonia 2 4.180 Ammonia 0.036 0.128 0.10563 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-OJV/1ntgACgtign Version 7.2.8.10783 021420-RT-1303 Appendix C-Page 133 of 1178 Logged on User:scthieken Page 31 of 51 Instrument:Mikey 11/8/2022 7:44AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.11113.Out Injection Volume: 25.00 Injection Type: Unknown Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator scthieken Ini.Date/Time: 07-Nov-2022 "/ 20:40 - Run Time: 12.00 7.00 ��J Mikey386#31 1122-041.R113.Out ECD_1 6.00 5.00 4.00 a) in c 0 a 3.00 af 2.00 CY) v co c 1.00 E E Q I I i -0.10 _I M 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min Ns*min PS pg/mL Assigned? Ammonia 2 4.123 Ammonia 0.003 0.011 n.a. FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-0?N/,lM 92021420-RT-1303 Appendix C- Page 134 of 1178 version 7.2.8.10783 Logged on User:scthieken Page 32 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 11122-041;R713.Out r Injection Volume: 25.00 Injection Type: Unknown i Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator: scthieken In7Date/Time: 07-Nov-2022 / 20:54 Run Time: 12.00 7.00 Mikey386#32 1122-041.R113.0ut ECD_1 6.00 5.00 U 4.00 a> c 0 0_ (n 3.00 or 2.00 y v as 1.00 E E Q -0.10 2.00 3.00 4.00 5.00 6.bO 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS pg/mL Assigned? Ammonia 2 4.143 Ammonia 0.004 0.012 ma. FALSE FALSE Chromeleon(c)Dionex 1996-2009 Version 7.2.8.10783 CTM-O7NleACati�n021420-RT-1303 Appendix C-Page 135 of 1178 Logged on User:scthieken Page 33 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R211.0ut Injection Volume: 25.00 Injection Type: Unknown Dilution Factor 1.0 Instrument Method: Mikey Cations 12min Operator. scthieken In'.Date/Time: 07-Nov-2022 / 21:07 Run Time: 12.00 7.00 Mikey386#33 1122-041.R211.0ut ECD_1 6.00 LO t` N 5.00 m c 0 U 4.00 a) Q U) o m 3.00 o' 2.00 1.00 -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min ps*min PS pg/mL Assigned? Ammonia 2 4.257 Ammonia 1.004 3.308 5.03252 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-07NLItiteAl 91-021420-RT-1303 Appendix C- Page 136 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 34 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R211.Out Injection Volume: 25.00 Injection Type: Unknown Dilution Factor. 1.0 Instrument Method. Mikey'Cations 12min Operator: scthieken In"Date/Time: 07-Nov-2022 I'21:21 Run Time: 12.00 7.00 1 Mikey386#34 1122-041.R211.Out ECD_1 6.00 LO co 5.00 N v m 'c 0 � 4.00 E (D Q 0 (n 3.00 2.00 1.00 -0.10 - T_ 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/ml- Assigned? Ammonia 2 4.253 Ammonia 1.011 3.311 5.07787 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-0:Re, 9'-021420-RT-1303 Appendix C- Page 137 of 1178 version 7.2.8.10783 Logged on User:scthieken Page 35 of 51 Instrument:Mikey 11/8/2022 7:44AM Sequence:Mikey386 Peak Analysis Report Sample Name 1122-041.R212.Out Injection Volume: 25.00 Injection Type: Unknown Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator: scthieken Inj.Date/Time: 07-Nov-2022 / 21:35 Run Time: `' 12.00 ' 7.00 17 Mikey386#35 1122-041.R212.Out ECD_1 6.00 5.00 U 4.00 0 0 c 0 0- T 3.00 2.00 v m 1.00 0 E Q -0.10 2.00 3.00 4.00 5.00 6.60 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.157 Ammonia 0.022 0.069 0.05515 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-027,/1nteA g-'021420-RT-1303 Appendix C- Page 138 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 36 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R212.Out Injection Volume: 25.00 Injection Type: Unknown Dilution Factor 1.0 Instrument Method. Mikey Cations 12min Operator. scthieken In.Date/Time: 07-Nov-2022 / 21:48 Run Time: 12.00 7.00 Mikey386#36 1122-041.R212.Out ECD_1 6.00 5.00 = 4.00 a� c 0 Q 3.00 r` 2.00 d v m C 1.00 0 E E Q �I I -0.10 I 2.00 3.00 4.00 5.00 6.00 7.60 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS pglmL Assigned? Ammonia 2 4.147 Ammonia 0.021 0.069 0.05254 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-02NtlM 92021420-RT-1303 Appendix C-Page 139 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 37 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R213.Out Injection Volume: 25.00 Injection Type: Unknown Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min ` Operator scthieken Ini.Date/Time: 07-Nov-2022 / 22:02 Run Time: 12.00 7.00 Mikey386#37 1122-041.R213.Out ECD_1 6.00 5.00 ) 4.00 a> c 0 0- W 3.00 0' 2.00 _o �r m c 1.00 0 E E Q -0.10 r 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS"rrtin PS pg/mL Assigned? Ammonia 2 4.100 Ammonia 0.006 0.018 n.a. FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-0?i4�ffi7 ign021420-RT-1303 Appendix C- Page 140 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 38 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R213.Out Injection Volume: 25.00 Injection Type: Unknown Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator sethieken In":`Date/Time: 07-Nov-2022 / 22:16 Run Time: 12.00 7.00 Mikey386#38 1122-041.R213.Out ECD_1 6.00 5.00 U 4.00 a> c C a � 3.00 G% 2.00 0 v 1.00 E E a S 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS pg/mL Assigned? Ammonia 2 4.107 Ammonia 0.007 0.019 0.00296 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 1TM-02N/VW9-'021420-RT-1303 Appendix C-Page 141 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 39 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R311.0ut Injection Volume: 25.00 Injection Type: Unknown Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator scthieken Irj.Date/Time: 07-Nov-2022 1 22:29' Run Time: 12.00 7.00 Mikey386#39 1122-041.R311.0ut ECD_1 6.00 r` v N 5.00 ca c 0 U 4.00 Q am c � 0 CL 3.00 2.00 1.00 -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.247 Ammonia 1.053 3.341 5.36108 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-02NM 92021420-RT-1303 Appendix C- Page 142 of 1178 version 7.2.8.10783 Logged on User:scthieken Page 40 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R311.0ut Injection Volume: 25.00 Injection Type: Unknown` Dilution Factor 1.0 Instrument Method: Mikey Cations 12min Operator: scthieken In.Date/Time: 07-Nov-2022 / 22:43 Run Time: 12.00 7.00 Mikey386#40 1122-041.R311.0ut ECD_1 6.00 M d' N 5.00 v m �c 0 = 4.00 E 0 Q c rN 0 In 3.00 0_ 2.00 1.00 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS pg/mL Assigned? Ammonia 2 4.243 Ammonia 1.064 3.356 5.43336 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-N/,UM92-021420-RT-1303 Appendix C- Page 143 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 41 of 51 Instrument:Mikey 11/8/2022 7:44AM Sequence:Mikey386 Peak Analysis Report Sample Name: ` 1122-041.R3I2.Out Injection Volume: 25.00 Injection Type: Unknown Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator.- scthieken Ini.Date/Time: 07-Nov-2022 1 22:57` Run Time: 12.00 7.00 Mikey386#41 1122-041.R312.Out ECD_1 6.00 5.00 � 4.00 nn Cn O o. 3.00 M u7 2.00 (9 c O E 1.00 Q -0.10 2.00 3.00 4.00 5.60 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.153 Ammonia 0.154 0.460 0.54752 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-OJ7, ffi�gn021420-RT-1303 Appendix C-Page 144 of 1178 version 7.2.8.10783 Logged on User:scthieken Page 42 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R312.Out Injection Volume: 25.00 Injection Type: Unknown l Dilution Factor. 1.0 Instrument Method. >Mikey Cations 12min Operator: scthieken In.Date/Time: 07-Nov-2022 I 23:10 Run Time: 12.00 7.00 Mikey386#42 1122-041.R312.Out ECD_1 6.00 5.00 U) 4.00 a> c 0 Q 3.00 0 2.00 m 0 E 1.00 E Q M -0.10 i 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min pS pg/ml- Assigned? Ammonia 2 4.150 Ammonia 0.153 0.461 0.54460 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-04NM 92021420-RT-1303 Appendix C- Page 145 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 43 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#4 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator scthieken In'.Date/Time:' 07-Nov-2022 / 23:24 Run Time: 12.00 7.00 Mikey386#43 HPLCSTDs1419#4 ECD_1 6.00 5.00 U 4.00 m c o 0 w d N 0) 3.00 0_ m 0 E 2.00 E Q 1.00 -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.280 Ammonia 0.354 1.424 1.39633 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-02N(1q(egC g,021420-RT-1303 Appendix C- Page 146 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 44 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#4 Injection Volume: 25.00 Injection Type: 'Check Standard Dilution Factor- 1.0 Instrument Method: Mikey Cations 12min Operator. scthieken In.,Date/Time: 07-Nov-2022 / 23:38 Run Time: 12.00 7.00 Mikey386#44 HPLCSTDs1419#4 ECD_1 6.00 5.00 4.00 a> c a0o d N In 3.00 `n Of m C O E 2.00 E Q 1.00 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount--]- mount Manually Manipulated? min pS*min pS pg/mL Assigned? Ammonia 2 4.280 Ammonia 0.360 1.429 1.42597 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-N/lnte'Iq 9-2021420-RT-1303 Appendix C-Page 147 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 45 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R313.Out Injection Volume: 25.00 Injection Type: Unknown Dilution Factor 1.0 Instrument Method: Mikey Cations 12min Operator. scthieken In'.Date/Time: 07-Nov-2022` / 23:51 Run Time: 12.00 7.00 Mikey386#45[manually integrated] 1122-041.R313.Out ECD_1 6.00 5.00 U) 4.00 a> 0 0 n 3.00 2.00 ca c 1.00 0 E E Q -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: II SJT 11/08/2022 Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS Ng/mL Assigned? Ammonia 3 4.073 Ammonia 0.010 0.020 0.01265 FALSE I TRUE Chromeleon(c)Dionex 1996-2009 cTM-o7N/t�t�eti�n021420-RT-1303 Appendix C- Page 148 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 46 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R313.Out> Injection Volume:_ 25.00 Injection Type: Unknown Dilution Factor 1.0 Instrument Method: Mikey Cations 12min Operator. scthieken In'`bate/Time: 08-Nov-2022 / 00:05 Run Time: 12.00 7 00 � Mikey386#46 1122-041.R313.Out ECD_1 6.00 5.00 y 4.00 Cn C c 0 0- In 3.00 o_ 2.00 000 0 .Cu c 1.00 E E Q -0.10 2.00 3.00 4.00 5.60 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min pS pg/mL Assigned? Ammonia 2 4.080 Ammonia 0.006 0.014 ma. FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-ORMW-021420-RT-1303 Appendix C-Page 149 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 47 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.BIk.NH3 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator. scthieken In'.Date/Time: 08-Nov-2022 / 00:19 Run Time: 12.00 7.00 Mikey386#47[manually integrated] 1122-041.Blk.NH3 ECD_1 6.00 5.00 � 4.00 a� c C a In 3.00 2.00 rn Cl) ca c 1.00 E E Q -0.10 2.00 3.60 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: II SJT 11/08/2022 Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS pg/mL Assigned? I i Ammonia 1 3.790 Ammonia 0.001 0.004 n.a. FALSE I TRUE Chromeleon(c)Dionex 1996-2009 CTM-O7NtlnMW'021420-RT-1303 Appendix C-Page 150 of 1178 version 7.2.8.10783 Logged on User:scthieken Page 48 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample;Name: 1122-041.BIk.NH3 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: Mikey Cations 12min Operator: scthieken In Date/Time: 08-Nov-2022 t 00:32 Run Time: 12.00 7.00 Mikey386#48[manually integrated] 1122-041.BIk.NH3 ECD_1 6.00 5.00 Q 4.00 a� w c 0 a En 3.00 D' 2.00 N Cq ri c� 'c 1.00 E E Q -0.10 _..... __.._�,.._ .. 2.00 3.60 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: 11 SJT 11/08/2022 Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 1 3.820 Ammonia 0.002 0.005 n.a. FALSE TRUE Chromeleon(c)Dionex 1996-2009 CTM-02N�&ftn Version 7.2.8.10783 021420-RT-1303 Appendix C-Page 151 of 1178 Logged on User:scthieken Page 49 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#5 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor 1.0 Instrument Method: Mikey Cations 12min Operator scthieken In.Date/Time: 08-Nov-2022 / 00:46 - Run Time: 12.00 7.00 " , Mikey386#49 HPLCSTDs1419#5 ECD_1 6.00 5.00 00 N d' 4.00 (0 -E O O E O E W 3.00 Q a tY 2.00 1.00 -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.287 Ammonia 0.723 2.656 3.29871 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-O NM 92021420-RT-1303 Appendix C- Page 152 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 50 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#5 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min "Operator- scthieken In'.'Date/Time: 08-Nov-2022 / 01:00 Run Time: 12.00 '']' 7.00 Mikey386#50 HPLCSTDs1419#5 ECD_1 6.00 5.00 0 N V = 4.00ca E a� o c E o E (n 3.00 Q a) ry- CIO 2.00 1.00 -0.10 2.60 3.00 4.00 5.60 6.60 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS lag/mL Assigned? Ammonia 2 4.280 Ammonia 0.721 2.647 3.28403 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-0zVtlnte'Ig g'-021420-RT-1303 Appendix C-Page 153 of 1178 Version 7.2.8.10783 NE01 3AS-021420-RT-1 303 Appendix C- Page 154 of 1178 • Montrose Air ty Services, LLC — Newburyport 2 New Pasture Road Unit #5 Newburyport, MA 01950 Wheelabrator North Andover Client Project # P J-0242 Analytical Report ( 1022- 157) EPA Method 2" Hydrogen Chloride Ammonia x Phone: (919) 850-4392 / Fax: (919) 850 -9012 / www.enthalpy.com 800-1 Capitola Drive Durham, NC 27713-4385 I certify that to the best of my knowledge all analytical data presented in this report: • Have been checked for completeness • Are accurate, error-free, and legible • Have been conducted in accordance with approved protocol, and that all deviations and analytical problems are summarized in the appropriate narrative(s) This analytical report was prepared in Portable Document Format (.PDF) and contains 193 pages. H Review Per for tneu Uy — vefj011er ®vwker Report Issued: 11/7/2022 NE01 3AS-021420-RT-1 303 EXQPgbd#01T29ellff 1 193 NE01 3AS-021420-RT-1 303 Appendix C- Page 157 of 1178 Enthalpy Analytical Company: Montrose Air Quality Services, LLC- Newburyport Job No.: 1022-157 EPA Method 26A Analysis Client No.: PROJ-021420 Site: Wheelabrator North Andover TableSummary Sample ID Hydrogen Chloride Catch Weight(ug) M26A R1 321,223 M26A R2 828,949 M26A R3 753,347 1022-157 EPA Method 26A 1 NE013AS-021420-RT-1303 Appendix C- Page 158 of 1178 Enthalpy Analytical Company: Montrose Air Quality Services, LLC - Newburyport Job No.: 1022-157 EPA Method 26A Analysis Client No.: PROJ-021420 Site: Wheelabrator North Andover Summary Table Sample ID Hydrogen Chloride Catch Weight(ug) M26A/CTM R1 Imp1-4 9,829 M26A/CTM R2 Imp1-4 4,753 M26A/CTM R3 Imp1-4 15,423 1022-157 EPA Method 26A 2 NE013AS-021420-RT-1303 Appendix C- Page 159 of 1178 Enthalpy Analytical Company: Montrose Air Quality Services, LLC- Newburyport Job No.: 1022-157 EPA CTM-027 Analysis Client No.: PROJ-021420 Site: Wheelabrator North Andover Summary Table Sample ID Ammonia Catch Weight(ug) M26A/CTM R1 Imp1-4 1,007 M26A/CTM R2 Imp1-4 919 M26A/CTM R3 Imp1-4 586 1022-157 EPA CTM-027 NE01 3AS-021420-RT-1 303 Appendix C-Page 160 of 1178 NE01 3AS-021420-RT-1 303 Appendix C-Page 161 of 1178 Enthalpy Analytical Company: Montrose Air Quality Services, LLC-Newburyport Job No.: 1022-157 EPA Method 26A Analysis Client No.: PROJ-021420 Site:Wheelabrator North Andover HydrogenIr' Chloride Filename Filename MDL /o Curve Curve Ret. Ret. o /o diff. Conc. Conc. odiff. Conv.Avg. Liquid Catch Sample ID #1 #2 (ug/mL) Min. Max. Time Time RT #1 #2 conc. Conc. DF Vol. Factor Weight Flag pH (ug/mL) (ug/mL) (min.) (min.) (ug/mL) (ug/mL) (ug/mL) (mL) (ug) M26A R1 025 026 0.0500 0.500 30.0 4.44 4.44 0.0 4.28 4.29 0.0 4.28 100 729 1.028 321,223 0 M26A R2 031 032 0.0500 0.500 30.0 4.45 4.44 0.1 11.1 11.1 0.2 11.1 100 725 1.028 828,949 0 M26A R3 033 034 0.0500 0.500 30.0 4.44 4.44 0.0 10.8 10.8 0.1 10.8 100 680 1.028 753,347 0 1022-157 EPA Method 26A 1 NE01 3AS-021420-RT-1 303 Appendix C-Page 162 of 1178 Enthalpy Analytical Company:Montrose Air Quality Services, LLC-Newburyport Job No.: 1022-157 EPA Method 26A Analysis Client No.:PROJ-021420 Site:Wheelabrator North Andover Matrix iRecovery Vol.%dill.%dill Filename Filename Ret. Ret. Conc. Conc. Avg. Catch Enthalpy Sample ID Compound #1 #2 Time Time RT. #1 #2 conc. Conc. DF (mL) Weight Flag (min.) (min.) (ug/mL) (ug/mL) (ug/mL) (ug) MS/M26A R1 Chloride 027 028 4.44 4.44 0.0 8.49 8.71 1.3 8.60 1 0.800 6.88 Native Amount(ug): 3.26 Mass Spiked: 4.00 Recovery(%): 90.5 MSD/M26A R1 Chloride 029 030 4.44 4.44 0.0 8.46 8.64 1.0 8.55 1 0.800 6.84 Native Amount(ug): 3.26 Mass Spiked: 4.00 Recovery(%): 89.7 1022-11-7 EPA Method 26A 1 U AS-021420-RT-1303 Appendix C- :163 of 1178 Enthalpy Analytical Company: Montrose Air Quality Services, LLC-Newburyport Job No.: 1022-157 EPA Method 26A Analysis Client No.: PROJ-021420 Site:Wheelabrator North Andover HydrogenI ri Chloride %dill.%dill Filename Filename MDL Curve Curve Ret. Ret. Conc. Conc. Avg. Liquid Conv Catch . Sample ID #1 #2 (ug/mL) Min. Max. Time Time RT #1 #2 conc. Conc. DF Vol. Factor. Weight Flag pH (ug/mL) (ug/mL) (min.) (min.) (ug/mL) (ug/mL) (ug/mL) (ml-) (ug) M26A/CTM R1 Imp1 035 036 0.0500 0.500 30.0 4.44 4.44 0.0 8.05 8.03 0.1 8.04 5 226 1.028 9,341 0 M26A/CTM R1 Imp2 037 038 0.0500 0.500 30.0 4.45 4.45 0.0 0.358 0.358 0.1 0.358 5 211 1.028 388 J 0 M26A/CTM R1 Imp3 039 040 0.0500 0.500 30.0 4.52 4.51 0.1 0.0744 0.0842 6.2 0.0793 5 159 1.028 64.8 J 0 M26A/CTM R1 Imp4 041 042 0.0500 0.500 30.0 4.45 4.45 0.0 0.119 0.106 5.7 0.113 5 60.0 1.028 34.8 J 6 9,829 M26A/CTM R2 Imp1 043 044 0.0500 0.500 30.0 4.44 4.44 0.0 3.68 3.65 0.4 3.67 5 235 1.028 4,432 0 M26A/CTM R2 Imp2 047 048 0.0500 0.500 30.0 4.46 4.46 0.0 0.206 0.205 0.3 0.206 5 214 1.028 226 J 0 M26A/CTM R2 Imp3 049 050 0.0500 0.500 30.0 4.52 4.52 0.0 0.0745 0.0718 1.8 0.0732 5 164 1.028 61.7 J 0 M26A/CTM R2 Imp4 051 052 0.0500 0.500 30.0 4.44 4.45 0.1 0.117 0.115 0.7 0.116 5 56.0 1.028 33.3 J 7 4,753 M26A/CTM R3 Imp1 053 054 0.0500 0.500 30.0 4.44 4.44 0.0 13.1 13.1 0.3 13.1 5 216 1.028 14,559 0 M26A/CTM R3 Imp2 055 056 0.0500 0.500 30.0 4.44 4.45 0.0 0.557 0.552 0.5 0.555 5 245 1.028 699 0 M26A/CTM R3 Imp3 057 058 0.0500 0.500 30.0 4.48 4.48 0.0 0.116 0.109 3.4 0.113 5 199 1.028 115 J 0 M26A/CTM R3 Imp4 059 060 0.0500 0.500 30.0 4.45 4.45 0.0 0.101 0.0940 3.6 0.0975 5 100 1.028 50.1 J 6 15,423 1022-157 EPA Method 26A 2 NE01 3AS-021420-RT-1 303 Appendix C- Page 164 of 1178 Enthalpy Analytical Company: Montrose Air Quality Services, LLC-Newburyport Job No.: 1022-157 EPA CTM-027 Analysis Client No.: PROJ-021420 Site:Wheelabrator North Andover Ammonia %dill Filename Filename MDL %dill. Curve Curve Ret. Ret. Conc. Conc. Avg. Liquid Catch Sample ID #1 #2 (ug/mL) Min. Max. Time Time RT . #1 #2 conc. Conc. DF Vol. Weight Flag pH (ug/mL) (ug/mL) (min.) (min.) (ug/mL) (ug/mL) (ug/mL) (ml-) (ug) M26A/CTM R1 Imp1 022 023 0.0200 0.189 11.8 4.25 4.25 0.0 4.29 4.29 0.0 4.29 1 226 969 0 M26A/CTM R1 Imp2 028 029 0.0200 0.189 11.8 4.19 4.18 0.1 0.154 0.154 0.1 0.154 1 211 32.5 J 0 M26A/CTM R1 Imp3 030 031 0.0200 0.189 11.8 4.15 4.15 0.0 0.0359 0.0365 0.8 0.0362 1 159 5.75 J 0 M26A/CTM R1 Imp4 032 033 0.0200 0.189 11.8 N/A N/A N/A 0.0200 0.0200 N/A 0.0200 1 60.0 1.20 ND 6 1,007 M26A/CTM R2 Imp1 034 035 0.0200 0.189 11.8 4.26 4.25 0.1 3.79 3.80 0.1 3.79 1 235 891 0 M26A/CTM R2 Imp2 036 037 0.0200 0.189 11.8 4.19 4.18 0.1 0.130 0.130 0.1 0.130 1 214 27.9 J 0 M26A/CTM R2 Imp3 038 039 0.0200 0.189 11.8 N/A N/A N/A 0.0200 0.0200 N/A 0.0200 1 164 3.28 ND 0 M26A/CTM R2 Imp4 040 041 0.0200 0.189 11.8 N/A N/A N/A 0.0200 0.0200 N/A 0.0200 1 56.0 1.12 ND 7 919 M26A/CTM R3 Imp'! 044 045 0.0200 0.189 11.8 4.25 4.25 0.0 2.62 2.62 0.1 2.62 1 216 566 0 M26A/CTM R3 Imp2 046 047 0.0200 0.189 11.8 4.20 4.19 0.1 0.0825 0.0820 0.3 0.0823 1 245 20.2 J 0 M26A/CTM R3 Imp3 048 049 0.0200 0.189 11.8 N/A N/A N/A 0.0200 0.0200 N/A 0.0200 1 199 3.98 ND 0 M26A/CTM R3 Imp4 050 051 0.0200 0.189 11.8 N/A N/A N/A 0.0200 0.0200 N/A 0.0200 1 100 2.00 ND 6 586 1022-1 r-7 EPA CTM-027 N. 8tS-021420-RT-1303 Appendix C- 165 of 1178 Enthalpy Analytical Company: Montrose Air Quality Services, LLC-Newburyport Job No.: 1022-157 EPA CTM-027 Analysis Client No.: PROJ-021420 Site:Wheelabrator North Andover MatrixaRecovery Filename Filename /o Ret. Ret. o Conc. Conc. o/odiff. Vol.Avg. Catch diff. Enthalpy Sample ID Compound #1 #2 Time Time RT #1 #2 conc. Conc. DF (ml-) Weight Flag (min.) (min.) (ug/mL) (ug/mL) (ug/mL) (ug) MS/M26A/CTM R1 Imp1 Ammonia 024 025 4.25 4.25 0.0 8.73 8.73 0.0 8.73 1 0.800 6.98 Native Amount(ug): 3.26 Mass Spiked: 4.00 Recovery(%): 93.1 MSD/M26A/CTM R1 Imp1 Ammonia 026 027 4.25 4.25 0.0 8.84 8.83 0.1 8.83 1 0.800 7.07 Native Amount(ug): 3.26 Mass Spiked: 4.00 Recovery(%): 95.2 1022-157 EPA CTM-027 NE013AS-021420-RT-1303 Appendix C- Page 166 of 1178 NE01 3AS-021420-RT-1 303 Appendix C- Page 167 of 1178 Enthalpy Analytical Narrative Summary j Company Montrose Air Quality Services, LLC - Newburyport j Job No. 1022-157 EPA Method 26AAnalysis Client ID. PROJ-021420 Site: Wheelabrator North Andover -------._________-__-__-_ -.-.____-. ------------____-- Custody Alyssa Miller received the samples on October 25, 2022 at 3.7 °C after being relinquished by Montrose Air Quality Services, LLC - Newburyport. The samples were received in good condition. I Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, LLC. ------___ �------- Analysis The samples were analyzed for chloride using the analytical procedures in Section 11.0 of EPA Method 26A, Determination of Hydrogen Halide and Halogen Emissions from Stationary Sources Isokinetic Method. All sample aliquots and standards are prepared, stored and analyzed using high-density polyethylene containers. Client samples are retained in the fr container as received. Sample catch weight results were determined using the sample volumes measured by the laboratory. The Dionex Ion Chromatograph "Raphael" equipped with a Conductivity { Detector was used for these analyses. Calibration The calibration curves are included in the Raw Data section of this report.A quadratic curve type was used instead of the method-specified linear curve. _.__...._._ __, __._._.___.. _ _.._._ _ _,-__.__._ _---__-- -___ Chrom. The acquisition method AS22 ASAP was used for the Chloride analyses and ` Conditions I may be made available upon request. ------------ - ----------- ---------- — QC Notes The samples were analyzed within the 28-day holding time specified by the method. 1 3 The analyses of the laboratory reagent blanks did not contain hydrogen i chloride at concentrations greater than the LOQ. Duplicate matrix spikes were prepared using aliquots of M26A R1 and met method spike recovery criteria of 80-120%. I f The analysis of second source standards also served as laboratory control f samples and met the laboratory acceptance criteria of±5% of the tag value. NE01 3AS-021420-RT-1 303 Appendix C- Page 168 of 1178 Enthalpy Analytical Narrative Summary Company I Montrose Air Quality Services, LLC - Newburyport Job No. 1022-157 EPA Method 26AAnalysis Client ID. PROJ-021420 Site: Wheelabrator North Andover Reporting The samples were analyzed for chloride but the results have been reported Notes as hydrogen chloride. The results were converted using factors of 1.028 respectively to account for the additional hydrogen mass. These analyses met the requirements of the TNI Standard.Any deviations from the requirements of the reference method or TNI Standard have been stated above. The results presented in this report are representative of the samples as provided to the laboratory. NE01 3AS-021420-RT-1 303 Appendix C- Page 169 of 1178 Enthalpy Analytical Narrative Summary Company Montrose Air Quality Services, LLC - Newburyport Job No. 1022-157 EPA CTM-027 Analysis Client ID. PROJ-021420 Site: Wheelabrator North Andover Custody Alyssa Miller received the samples on October 25, 2022 at 3.6 °C after being relinquished by Montrose Air Quality Services, LLC - Newburyport. The samples were received in good condition. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, LLC. Analysis `- __i The samples were analyzed for ammonia using the analytical procedures in Section 4.2, Sample Analysis, of EPA Conditional Test Method 027, Procedure for Collection and Analysis of Ammonia in Stationary Sources. Sample catch weight results were determined using the sample volumes measured by the laboratory. The sample fractions were not brought up to the method-specified volume of 250 mL. This preserves lower detection limits and removes a possible source of contamination. The Thermo Ion Chromatograph "Mikey" equipped with a Conductivity 1, Detector was used for these analyses. Calibration The calibration curves are included in the Raw Data section of this report. Chrom. The Instrument Method Mikey Cations 9min was used for the ammonia Conditions analyses and may be made available upon request. QC Notes The samples were analyzed within the 14-day holding time specified by the method. The analyses of the laboratory reagent blanks did not contain ammonia at f concentrations greater than the LOQ. Duplicate matrix spikes were prepared using aliquots of M26A/CTM R1 Imp1 ( and met method spike recovery criteria of 80-120%. The analysis of second source standards also served as laboratory control samples and met the laboratory acceptance criteria of±10% of the tag value. Reporting These analyses met the requirements of the TNI Standard.Any deviations Notes from the requirements of the reference method or TNI Standard have been j stated above. x The results presented in this report are representative of the samples as l provided to the laboratory. ------------- NE013AS-021420-RT-1303 Appendix C- Page 170 of 1178 GeneralCl Reporting Notes The following are general reporting notes that are applicable to all Enthalpy Analytical, LLC data reports, unless specifically noted otherwise. • Any analysis which refers to the method as "Type" represents a planned deviation from the reference method. For instance a Hydrogen Sulfide assay from a Tedlar bag would be labeled as "EPA Method 16-Type" because Tedlar bags are not mentioned as one of the collection options in EPA Method 16. • The acronym MDL represents the Minimum Detection Limit. Below this value the laboratory cannot determine the presence of the analyte of interest reliably. • The acronym LOQ represents the Limit of Quantification. Below this value the laboratory cannot quantitate the analyte of interest within the criteria of the method. • The acronym ND following a value indicates a non-detect or analytical result below the MDL. • The letter J in the Qualifier or Flag column in the results indicates that the value is between the MDL and the LOQ. The laboratory can positively identify the analyte of interest as present, but the value should be considered an estimate. • The letter E in the Qualifier or Flag column indicates an analytical result exceeding 100% of the highest calibration point. The associated value should be considered as an estimate. • Sample results are presented `as measured' for single injection methodologies, or an average value if multiple injections are made. If all injections are below the MDL, the sample is considered non-detect and the ND value is presented. If one, but not all, are below the MDL, the MDL value is used for any injections that are below the MDL. For example, if the MDL is 0.500 and LOQ is 1.00, and the instrument measures 0.355, 0.620, and 0.442 - the result reported is the average of 0.500, 0.620, and 0.500 - - - i.e. 0.540 with a J flag. • When a spike recovery (Bag Spike, Collocated Spike Train, or liquid matrix spike) is being calculated, the native (unspiked) sample result is used in the calculations, as long as the value is above the MDL. If a sample is ND, then 0 is used as the native amount (not the MDL value). • The acronym DF represents Dilution Factor. This number represents dilution of the sample during the preparation and/or analysis process. The analytical result taken from a laboratory instrument is multiplied by the DF to determine the final undiluted sample results. • The addition of MS to the Sample ID represents a Matrix Spike. An aliquot of an actual sample is spiked with a known amount of analyte so that a percent recovery value can be determined. The MS analysis indicates what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample matrix interferes with the analysis of the analyte(s). r,, r NE013AS-021420-RT-1303 Appendix C-Page 171 of 1178 eneral Reportings (continued) • The addition of MSD to the Sample ID represents a Matrix Spike Duplicate. Prepared in the same manner as a MS, the use of duplicate matrix spikes allows further confirmation of laboratory quality by showing the consistency of results gained by performing the same steps multiple times. • The addition of LD to the Sample ID represents a Laboratory Duplicate. The analyst prepares an additional aliquot of sample for testing and the results of the duplicate analysis are compared to the initial result. The result should have a difference value of within 10% of the initial result (if the results of the original analysis are greater than the LOQ). • The addition of AD to the Sample ID represents an Alternate Dilution. The analyst prepares an additional aliquot at a different dilution factor (usually double the initial factor). This analysis helps confirm that no additional compound is present and coeluting or sharing absorbance with the analyte of interest, as they would have a different response/absorbance than the analyte of interest. • The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample matrix, prepared and analyzed by the laboratory using the same reagents, spiking standards and procedures used for the client samples. The LCS is used to assess the control of the laboratory's analytical system. Whenever spikes are prepared for our client projects, two spikes are retained as LCSs. The LCSs are labeled with the associated project number and kept in-house at the appropriate temperature conditions. When the project samples are received for analysis, the LCSs are analyzed to confirm that the analyte could be recovered from the media, separate from the samples which were used on the project and which may have been affected by source matrix, sample collection, and/or sample transport. • Significant Figures: Where the reported value is much greater than unity (1.00) in the units expressed, the number is rounded to a whole number of units, rather than to 3 significant figures. For example, a value of 10,456.45 ug catch is rounded to 10,456 ug. There are five significant digits displayed, but no confidence should be placed on more than two significant digits. In the case of small numbers, generally 3 significant figures are presented, but still only 2 should be used with confidence. Many neat materials are only certified to 3 digits, and as the mathematically correct final result is always 1 digit less than all its pre-cursors - 2 significant figures are what are most defensible. • Manual Integration: The data systems used for processing will flag manually integrated peaks with an "M". There are several reasons a peak may be manually integrated. These reasons will be identified by the following two letter designations on sample chromatograms, if provided in the report. The peak was not integrated by the software "NI", the peak was integrated incorrectly by the software "II" or the wrong peak was integrated by the software " P" These codes will accompany the analyst's manual integration stamp placed next to the compound name on the chromatogram. NE01 3AS-021420-RT-1 303 Appendix C- Page 172 of 1178 � f' NE01 3AS-021420-RT-1 303 Appendix C-Page 173 of 1178 Chain Custody Form - Source Page_1_of_ . Z_ ANALYSIS REQUESTED `o Company Name Montrose Air Quality Services Q CLIENT Project Manager Michael Bruni � y INFORMATION e-mail: mbruni@montrose-env.com m Address: 2 New Pasture Road Q SECTION Newburyport, MA 01950 o a` Phone: (978)499-9300 Fax (978)499-9303 m U Cell: 339-206-2376 v 'oD o Sampled by: Michael Bruni C t a) < am 2 z Initial Impinger Collection Charge Laboratory use oni' Field Sample ID #Bottles Collection Date Time volumes(mt-(• Fraction 1.12-SDA In-M26A-R1 1 10/18/2022 250 X 1-4 Imp Contents&Rinse U2-SDA In-M26A-R2 1 10/18/2022 250 x 1 A Imp Contents&Rinse U2-SDA In-M26A-R3 1 10/19/2022 250 X 1A Imp Contents&Rinse ,Q` TAT Requirement PROJECT INFORMATION REPORTING REQUIREMENTS PROJECT SPECIFIC COMMENTS STD 10 Business day 121 Project `,,21420 Summary Report only ❑ Method 26A Analysis (Wheelabroator N.Andover) Rush 5 Business day ❑ Name: Wheelabrator North Andover Summary Report & ❑ Method CTM-027 Analysis (Wheelabroator N-Andover) Rush 2 Business day ❑ PO#: Full Data Package Rush 1 Business day ❑ EDD EI Other(specify): "Initial Impinger charge volumes are required before the following analysis 14 •72 can be started:Method 26,CTM-027&Method 8 Relinquished By �� Date/Time Received by e Method 231 T09A Relinquished By Date/Time Received by NATO TEF ❑ TEF x DL ❑ TEF x 0 DL ❑ Relinquished By Date/Time Received by WHO TEF ❑ TEF x 0.5 DL ❑ NE01 3AS-021420-RT-1 303 Appendix C-Page 174 of 1178 Chain of Custody For _ Source Page_2_of_2_ ANALYSIS REQUESTED Company Name: Montrose Air Quality Services CLIENT Project Manager: Michael Bruni a INFORMATION e-mail: mbruni0montrose-env.com a o Address: 2 New Pasture Road N SECTION Newburyport,MA 01950 z ~ o Phone: (978)499-9300 Fax: (978)499-9303 2 Cell: 339-206-2376 m Sampled by: Michael Bruni Initial Impinger Collection Charge Laboratog use only Field Sample ID #Bottles Collection Date Time volumes(mL)• Fraction U2-FF Out-M26AICTM-027-R1-Imp 1 1 10/18/2022 50 X Imp 1 Contents&Rinse U2-FF out-M26A/CTM-027-R1-imp 2 1 10/18/2022 100 X Imp 2 Contents&Rinse U2-FF Out-M26A/CTM-027-R1-Imp 3 1 10/18/2022 100 X Imp 3 Contents&Rinse U2-FF Out-M26A/CTM-027-R1-Imp 4 1 10/18/2022 0 X Imp 4 Contents&Rinse U2-FF Out-M26A/CTM-027-R2-Imp 1 1 10/18/2022 50 X Imp 1 Contents&Rinse U2-FF Out-M26A/CTM-027-R2-Imp 2 1 10/18/2022 100 X Imp 2 Contents&Rinse U2-FF Out-M26A/CTM-027-R2-Imp 3 1 10/18/2022 100 X Imp 3 Contents&Rinse U2-FF Out-M26A/CTM-027-R2-Imp 4 1 10/18/2022 0 X Imp 4 Contents&Rinse ,W U2-FF Out-M26A/CTM-027-R3-Imp 1 1 10/19/2022 50 X Imp 1 Contents&Rinse U2-FF Out-M26A/CTM-027-R3-Imp 2 1 10/19/2022 100 X Imp 2 Contents&Rinse U2-FF Out-M26A/CTM-027-R3-Imp 3 1 10/19/2022 100 X Imp 3 Contents&Rinse "'. U2-FF Out-M26A/CTM-027-R3-Imp 4 1 10/19/2022 0 X Imp 4 Contents&Rinse d ftYA -2 'V TAT Requirement PROJECT INFORMATION REPORTING REQUIREMENTS PROJECT SPECIFIC COMMENTS STD 10 Business day El Project#: PROJ-021420 Summary Report only ❑ Method 26A/CTM-027 Analysis(Wheelabroator N.Andover) Rush 5 Business day ❑ Name: Wheelabrator North Andover Summary Report & ❑ Please hold Impinger 4 for analysis. Only analyze if it meets Rush 2 Business day ❑ PO#: Full Data Package breakthrough criteria for CTM-027. Rush 1 Business day ❑ EDD 2 Other(specify): 'Initial Impinger charge volumes are required before the following analysis can be started Method 26,CTM-027&Method 8 Relinquished By Date/Time j �' :%. a~ Received by 3ai.1 Method 23/T09A Relinquished By Date/Time Received by NATO TEF ❑ TEF x DL ❑ TEF x 0 DL ❑ Relinquished _[B�y� � Date/Time Repceeiived by WHO TEF ElTEF x 0.5 DL ❑ ` T "O 'O- q�%2 100 ['eV_,t qr«M YlVi _0 '�.i� l,,'1 Ix j L t NE01 3AS-021420-RT-1 303 Appendix C- Page 176 of 1178 Logged on User:scthieken Page 9 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-Oct-2022 / 15:36 Run Time: 14.50 30.0 Raphael1239#9 HPLCStds1433#6 ECD 1 PS � d- 25.0 0 U 20.0 v0i 15.0 c 0 n. 10.0 5.0 min 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS Ng/mL 1 4.46 Chloride 5.173 19.961 29.89029 FALSE FALSE E�13AS-021420-RT-1303 Appendix C- Page 177 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:scthieken Page 10 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 15:52 Run Time: 14.50 30.0 Raphael1239#10 HPLCStds1433#6 ECD_1 PS Lo v d- 25.0 oa 0 U 20.0 uoi 15.0 c 0 Cn a) tr 10.0 5.0 min 2.00 3.00 4.60 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS"min PS pg/mL 1 4.45 Chloride 5.093 19.471 29.51490 FALSE FALSE bR13AS-021420-RT-1303 Appendix C- Page 178 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 11 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-Oct-2022 / 16:08 Run Time: 14.50 30.0 Raphael1239#11 HPLCStdsl433#5 ECD_1 PS 25.0 20.0 _ M �Y 15.0 o CL `o � U 10.0 m 5.0 min 2.00 3.00 4.00 5.60 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 1 4.44 Chloride 2.374 8.864 15.15172 FALSE FALSE 9 Anions/Integra gR13AS-021420-RT-1303 Appendix C-Page 179 of 1178 Chromeleon(Version 71996 2009 Logged on User:scthieken Page 12 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 16:24 Run Time: 14.50 Raphael1239#12 HPLCStds1433#5 ECD_1 30.0 pS 25.0 20.0 ti c 15.0 o Q- o c � V 10.0 5.0 min 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conic Manually Assigned? Manipulated? min NS*min PS pg/mL 1 4.45 Chloride 2.368 8.925 15.11496 FALSE FALSE g MgR13AS-021420-RT-1303 Appendix C-Page 180 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 13 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In Date/Time: 28-Oct-2022 / 16:40 Run Time: 14.50 30.0 Raphael1239#13 HPLCStds1433#4 ECD_1 PS 25.0 20.0 c 15.0 M o d W a) 10.0 0 U 1- 5.0 min 2.60 3.00 4.00 5.00 6.60 7.60 8.60 Time [min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 4.44 Chloride 1.499 5.645 9.85450 FALSE FALSE 9 Anions/Integ rMgRl 3AS-021420-RT-1 303 Appendix C- Page 181 of 1178 Chromeleon(Verson 1996 20009 Logged on User:scthieken Page 14 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 28-Oct-2022 / 16:57 Run Time: 14.50 30.0 Raphael1239#14 HPLCStds1433#4 ECD_1 PS 25.0 20.0 s c 15.0 0 a c a> a) a 10.0 0 2= U 5.0 i min 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.502 5.646 9.87479 FALSE FALSE g MFaR13AS-021420-RT-1303 Appendix C- Page 182 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 15 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 28-Oct-2022 / 17:13 Run Time: 14.50 30.0 Raphael1239#15 HPLCStds1433#3 ECD_1 PS 25.0 20.0 in 15.0 c 0 a W 10.0 �r a> `o 5.0 U rr min -1.0 2.00 3.00 4.60 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.45 Chloride 0.712 2.713 4.81636 FALSE FALSE g MR13AS-021420-RT-1303 Appendix C-Page 183 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 16 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken l21.Date/Time: 28-Oct-2022 / 17:29 Run Time: 14.50 ; Raphael1239#16 HPLCStds1433#3 ECD_1 30.0 PS 25.0 20.0 s uu) 15.0 c 0 Q tr � 10.0 d a 0 5.0 U min -1.0 2.00 3.60 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.715 2.728 4.83878 FALSE FALSE MRl3AS-021420-RT-1303 Appendix C-Page 184 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 17 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 17:45 Run Time: 14.50 30.0 Raphael1239#17 HPLCStds1433#2 ECD_1 PS 25.0 20.0 ch 15.0 c 0 n a� 10.0 Cl) v a) 5.0 0 U min 2.00 3.60 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.136 0.523 0.96515 FALSE FALSE MEdR13AS-021420-RT-1303 Appendix C- Page 185 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 18 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-Oct-2022 / 18:01 Run Time: 14.50 30.0 Raphael1239#18 HPLCStds1433#2 ECD_1 PS 25.0 20.0 in 15.0 c 0 0- w a) tY 10.0 a) 5.0 0 s= U min 2.60 3.60 4.00 5.00 6.60 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 0.135 0.524 0.95797 FALSE FALSE M,FRl3AS-021420-RT-1303 Appendix C- Page 186 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 19 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 18:17 Run Time: 14.50 30.0 Raphael1239#19 HPLCStds1433#1 ECD_1 PS 25.0 20.0 s (n 15.0 c 0 0_ 0 a) Of 10.0 ti �t a) 5.0 0 U min 2.60 3.00 4.00 5.60 6.60 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min PS*min PS lag/mL 1 4.45 Chloride 0.071 0.270 0,51828 FALSE FALSE gR13AS-021420-RT-1303 Appendix C-Page 187 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 20 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method. AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 18:33 Run Time: 14.50 30.0 Raphaell239#20 HPLCStds1433#1 ECD 1 PS 25.0 20.0 z uoi 15.0 c 0 a 0 a> 10.0 co v v a> 5.0 0 U m i n 2.60 3.60 4.60 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.070 0.267 0.51523 FALSE FALSE gRl3AS-021420-RT-1303 Appendix C- Page 188 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 21 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 18:49 Run Time: 14.50 30.0 tZ Raphael1239#21 [manually integrated] ECD 1 PS 25.0 20.0 obi 15.0 c Q 10.0 L U 5.0 i min 2.60 3.00 4.00 5.60 6.60 7.00 8.00 Time [min] Analyst Comment: II SJT 10/31/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 1 4.44 Chloride 1.076 4.148 7.18111 FALSE TRUE MEdR13AS-021420-RT-1303 Appendix C- Page 189 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 22 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken In".Date/Time: 28-Oct-2022 / 19:05 Run Time: 14.50 30.0 Raphae11239#22 [manually integrated] ECD_1 PS 25.0 20.0 uoi 15.0 c a Cl) aa) 10.0 m 0 U 5.0 '7 J - min 2.00 3.00 4.00 5.00 6.00 7.60 8.00 Time [min] Analyst Comment: 11 SJT 10/31/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.073 4.147 7.16292 FALSE TRUE MgRUAS-021420-RT-1303 Appendix C-Page 190 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 23 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 19:22 Run Time: 14.50 30.0 04 Raphael1239#23 HPLCStds1433#RB ECD_1 PS 25.0 20.0 co 15.0 c 0 0_ in m 10.0 0 rn v 5.0 0 U -1.0 2.00 3.60 4.60 5.60 6.60 7.00 8.00 Time [min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min uS*min PS pg/mL 4.49 Chloride 0.007 0.022 0.07927 FALSE FALSE MRl3AS-021420-RT-1303 Appendix C-Page 191 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 24 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 28-Oct-2022 / 19:38 Run Time: 14.50 30.0 Raphaell239#24 HPLCStdsl433#RB ECD_1 PS 25.0 20.0 v7 uoi 15.0 c 0 a 0 a) af 10.0 co d' 5.0 0 U I I C*9 1 min -1.0 2.00 3.00 4.00 5.00 6.60 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 2 4.49 Chloride 0.006 0.023 0.07739 FALSE FALSE g MgR13AS-021420-RT-1303 Appendix C-Page 192 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 95 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In. Date/Time: 29-Oct-2022 / 14:42 Run Time: 14.50 Raphael1239#95 HPLCStds1433#6 ECD_1 30.0 pS LO v 25.0 0 2= U 20.0 `1 s con 15.0 c 0 a Of 10.0 5.0 min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 5.209 19.932 30.05767 FALSE FALSE ME13AS-021420-RT-1303 Appendix C-Page 193 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr ]ORVersion 7.2.8.10783 Logged on User:scthieken Page 96 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In".Date/Time: 29-Oct-2022 / 14:58 Run Time: 14.50 Raphael1239#96 HPLCStds1433#6 ECD_1 30.0 PS U) Nt �r 25.0 -0 0 U f 20.0 uoi 15.0 c 0 a. CD a> 10.0 5.0 min -1.0 __J T-- 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Co Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 5.239 20.345 30.19689 FALSE FALSE MgRl3AS-021420-RT-1303 Appendix C-Page 194 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 97 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 29-Oct-2022 / 15:14 Run Time: 14.50 Raphael1239#97 HPLCStds1433#5 ECD 1 30.0 — pS 25.0 20.0 va)i 15.0 a� c -� 0 N o a> � U 10.0 5.0 min 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 2.410 9.186 15.36067 FALSE FALSE gR13AS-021420-RT-1303 Appendix C-Page 195 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 98 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Inj.Date/Time: 29-Oct-2022 / 15:30 Run Time: 14.50 30.0 Raphael1239#98 HPLCStds1433#5 ECD_1 PS 25.0 20.0 M c 15.0 "D 0 a o ZA 10.0 5.0 min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min NS Ng/mL 1 4.44 Chloride 2.410 9.129 15.35737 FALSE FALSE MgRl3AS-021420-RT-1303 Appendix C- Page 196 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 99 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 29-Oct-2022 / 15:46 Run Time: 14.50 30.0 Raphael1239#99 HPLCStds1433#4 ECD_1 PS 25.0 20.0 N s c 15.0 M d o Q m 10.0 0 U 5.0 min 2.00 3.00 4.00 5.00 6.00 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min pS pg/mL 1 4.44 Chloride 1.530 5.809 10.04927 FALSE I FALSE f gR13AS-021420-RT-1303 Appendix C-Page 197 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra i Version 7.2.8.10783 Logged on User:scthieken Page 100 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken Ir j, Date/Time: 29-Oct-2022 / 16:02 Run Time: 14.50 Raphael1239#100 HPLCStds1433#4 ECD_1 30.0 pS 25.0 20.0 c 15.0 o `r n v m 10.0 0 U 5.0 ' min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.528 5.810 10.03723 FALSE FALSE FaR13AS-021420-RT-1303 Appendix C- Page 198 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 101 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 29-Oct-2022 1 16:18 Run Time: 14.50 Raphael1239#101 HPLCStds1433#3 ECD_1 30.0 pS 25.0 20.0 of 15.0 c 0 n CO) 0 a> r 10.0 d a� v `o 5.0 U i I min 2.00 3.00 4.60 5.60 6.60 7.60 8.60 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.726 2.799 4.91302 FALSE FALSE MgRl3AS-021420-RT-1303 Appendix C- Page 199 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 102 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 29-Oct-2022 / 16:34 Run Time: 14.50 Raphael1239#102 HPLCStds1433#3 ECD_1 30.0 pS 25.0 20.0 15.0 c 0 n � M 10.0 d m a `o 5.0 U rr min -1.0 2.00 3.60 4.00 5.00 6.00 7.00 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.729 2.795 4.93367 FALSE FALSE NFn13AS-021420-RT-1303 Appendix C-Page 200 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integrati��i Version 7.2.8.10783 Logged on User:scthieken Page 103 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 29-Oct-2022 / 16:51 Run Time: 14.50 Raphael1239#103 HPLCStds1433#2 ECD 1 30.0 pS 25.0 20.0 ch 15.0 c 0 a w a) 10.0 0 a) 5.0 0 s= U rr ' min -1.0 2.60 3.60 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.140 0.541 0.99426 FALSE FALSE gRl3AS-021420-RT-1303 Appendix C-Page 201 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 104 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 29-Oct-2022 117:07 Run Time: 14.50 30.0 Raphael1239#104 HPLCStds1433#2 ECD_1 " PS 25.0 20.0 ch 15.0 c 0 a Cn a) tY 10.0 co m 5.0 .L 0 U min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.139 0.540 0.98638 FALSE FALSE gr i �13AS-021420-RT-1303 Appendix C-Page 202 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inte Version 7.2.8.10783 Logged on User:scthieken Page 105 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 29-Oct-2022 / 17:23 Run Time: 14.50 Raphael1239#105 HPLCStds1433#1 ECD_1 30.0 pS 25.0 20.0 in 15.0 c 0 n 0 a) 10.0 M �r v v a> 5.0 0 2= C.� -1.0 2.60 3.60 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.071 0.275 0.52137 FALSE FALSE M1�R13AS-021420-RT-1303 Appendix C- Page 203 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 106 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 29-Oct-2022 / 17:39 Run Time: 14.50 30.0 Raphael1239#106 HPLCStds1433#1 ECD_1 PS 25.0 20.0 vo, 15.0 c 0 a a� 10.0 v 5.0 0 s U 1.0 �—� I I I r min - 2.00 3.00 4.00 5.00 6.00 7.00 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.072 0.275 0.52511 FALSE FALSE MgRl3AS-021420-RT-1303 Appendix C-Page 204 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr I Version 7.2.8.10783 Logged on User:scthieken Page 1 of 2 Instrument:Raphael 10/31/2022 7:55AM Sequence:Raphael1239 Calibration Table Pos. Level Ref.Amount Calibration Dil.Factor Volume No. Injection Name Inject Time Point Status pg/mL ECD_1 ECD_1 Chloride Chloride 9 HPLCS1ds1433#6 28/Oct/2022 15:36 BA6 06 30.0000 Ok 1.0000 25.00 10 HPLCStds1433#6 28/Oct/202215:52 BA6 06 30.0000 Ok 1.0000 25.00 11 HPLCStds1433#5 28/Oct/2022 16:08' BA5 05 15.0000 Ok 1.0000 25.00 12 HPLCStds1433#5 28/Oct/2022 16:24' BA5 05 15.0000 Ok 1.0000 25.00 13 HPLCStds1433#4 28/Oct/2022 16:40 BA4 04 10.0000 Ok 1.0000 25.00 14 HPLCStds1433#4 28/Oct/2022 16:57 BA4' 04 10.0000 Ok 1.0000 25.00 15 HPLCStds1433#3 28/Oct/2022 17:13 BA3 03 5.0000 Ok 1.0000' 25.00 16 HPLCStds1433#3 28/Oct/2022 17:29 BA3 03 5.0000 Ok 1.0000 25.00 17 HPLCStds1433#2 28/Oct/2022 17:45> BA2 02 1.0000 Ok 1.0000 25.00 18 HPLCStds1433#2 28/Oct/2022 18:01 BA2' 02 1.0000 Ok 1.0000 25.00 19 HPLCStds1433#1 28/Oct/2022 18:17' BA1 01 0.5000 Ok 1.0000 25.00 20 HPLCStds1433#1 28/Oct/2022 18:33 BA1 01 0.5000 Ok 1.0000 25.00 95 HPLCStds1433#6 29/Oct/2022 14:42' BA6 06 30.0000 Ok 1.0000 25.00 96 HPLCStds1433#6 29/Oct/2022 14:58 BA6 06 30.0000 Ok 1.0000 25.00 97 HPLCStds1433#5 29/Oct/2022 15:14 BA5 05 15.0000 Ok 1.0000 25.00 98 HPLCStds1433#5 29/Oct/2022 15:30 BA5 05 15.0000 Ok 1.0000 25.00 99 HPLCS1ds1433#4 29/Oct/2022 15:46' BA4 04 10.0000 Ok 1.0000 25.00 100 HPLCStds1433#4 29/Oct/2022 16:02 BA4 04 10.0000 Ok 1.0000 25.00 101 HPLCStds1433#3 29/Oct/202216:18` BA3 03 5.0000 Ok 1.0000 25.00 102 HPLCStds1433#3 29/Oct/2022 16:34 BA3 03 5.0000 Ok 1.0000 25.00 103 HPLCStds1433#2 29/Oct/2022 16:51 BA2 02 1.0000 Ok 1.0000 25.00 104 HPLCStds1433#2 29/Oct/2022 17:07 BA2' 02 1.0000 Ok 1.0000' 25.00 105 HPLCStds1433#1 29/Oct/2022 17:23 BA1 01 0.5000 Ok 1.0000 25.00 106 HPLCStds1433#1 29/Oct/2022 17:39 1 BA1 1 01 1 0.5000 Ok 1.0000 25.00 Detection Parameters Ret.Time Param. Name Param.Value Inj.Type Channel min Always Baseline Noise Auto Range Off Any All Channels Always Baseline Noise Start Time 0.400[min] Any All Channels Always Baseline Noise End Time 0.700[min] Any All Channels Always Cobra Smoothing:Width s Auto Any All Channels Always Consider Void Peak Off Any All Channels 0.000 Maximum Rider Ratio 10[%] Any All Channels 0.000 Tailing Sensitivity Factor 0.500[%] Any All Channels' 0.000 Inhibit Integration On Any All Channels 0.000 Minimum Area Auto Any All Channels 4.018 Inhibit Integration Off Any All Channels 6.225 Inhibit Integration On 1Any 1All Channels NL. aS-021420-RT-1303 Appendix C- 205 of 1178 Chromeleon(c) .1996-2009 9 Anions/Calir,,-ion Details Vera-o 7.2.8.10783 Logged on User:scthieken Page 2 of 2 Instrument:Raphael 10/31/2022 7:55 AM Sequence:Raphael1239 Calibration Batch Report ance: Raphae11239 Injection Volume: 25.00 meet Method: AS22 ASAP Operator scthieken Inj.Date/Time: 29-Oct-2022 / 1409 Run Time: 14.5> Calibration Summary Peak Name Eval.Type Cal.Type Points Offset SlopeE05 Coeff.Det. CO C1 % Chloride Area Quad WithOffset 1/A 24.000 0.034 6.872 99.973 AVERAGE: 0.0341 6.8719 99.9734 Injection Name Ret.Time Area Height Amount` 35.0 Chloride External ECD-1 min pS*min PS pg/mL pg/mL ECD 1 ECD 1 ECD 1 ECD 1 Chloride Chloride Chloride Chloride HPLCStds1433#6 4.460 5.173 19.961 29.890 30.0 HPLCStds1433#6 4.450 5.093 19.471 29.515 HPLCStds1433#5 4.443 2.374 8.864 15.152 . HPLCStds1433#5 4.447 2.368 8.925 15.115 25.0 HPLCStds1433#4 4.443 1.499 5.645 9.855 HPLCStds1433#4 4.440 1.502 5.646 9.875 HPLCStds1433#3 4.447 0.712 2.713 4.816 HPLCStds1433#3 4.443 0.715 2.728 4.839 20.0 HPLCStds1433#2 4.443 0.136 0.523 0.965 HPLCStds1433#2 4.447 0.135 0.524 0.958 HPLCStds1433#1 4.447 0.071 0.270 0.518 HPLCStds1433#1 4.443 0.070 0.267 0.515 15.0 Hp'CStds1433#6 4.450 5.209 19.932 30.058 Stds1433#6 4.450 5.239 20.345 30.197 I-hr -(-Stds1433#5 4.447 2.410 9.186 15.361 10.0 HPLCStds1433#5 4.443 2.410 9.129 15.357 HPLCStds1433#4 4.443 1.530 5.809 10.049 HPLCStds1433#4 4.440 1.528 5.810 10.037 HPLCStds1433#3 4.440 0.726 2.799 4.913 5.0 HPLCStds1433#3 4.443 0.729 2.795 4.934 HPLCStds1433#2 4.440 0.140 0.541 0.994 HPLCStds1433#2 4.437 0.139 0.540 0.986 pS*min HPLCStds1433#1 4.443 0.071 0.275 0.521 0.0 HPLCStds1433#1 4.443 0.072 0.275 0.525 0.DO 2.00 4.00 6.00 NE01 3AS-021420-RT-1 303 Appendix C-Page 206 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Calibration Version 7.2.8.10783 Logged on User:scthieken Page 21 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 18:49 Run Time: 14.50 30.0 Raphael1239#21 [manually integrated] ECD— 1 PS 25.0 20.0 ch 15.0 c 0- a`) 4 10.0 v L 5.0 i min -1.0 2.00 3.00 4.00 5.60 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 10/31/2022 No. Time Peak Name Area Height Conic Manually Assigned? Manipulated? min pS*min pS pg/mL 1 4.44 Chloride 1.076 4.148 7.18111 FALSE TRUE gR'3AS-021420-RT-1303 Appendix C- Page 207 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 22 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken In'. Date/Time: 28-Oct-2022 / 19:05 Run Time: 14.50 30.0 Raphael1239#22 [manually integrated] ECD_1 PS 25.0 20.0 uoi 15.0 c a co 10.0 a� -a 0 5.0 IT min 2.00 3.00 4.00 5.00 6.60 7.00 8.00 Time [min] Analyst Comment: II SJT 10/31/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.073 4.147 7.16292 FALSE TRUE R13AS-021420-RT-1303 Appendix C-Page 208 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 23 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 28-Oct-2022 / 19:22 Run Time: 14.50 30.0 Raphael1239#23 HPLCStds1433#RB ECD_1 PS 25.0 20.0 s (h 15.0 c 0 Q a� 10.0 0 rn 5.0 L U min 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.49 Chloride 0.007 0.022 0.07927 FALSE FALSE ER13AS-021420-RT-1303 Appendix C- Page 209 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:scthieken Page 24 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-Oct-2022 / 19:38 Run Time: 14.50 30.0 Raphael1239#24 HPLCStds1433#RB ECD_1 PS 25.0 20.0 c 15.0 0 0- 0 a> 10.0 Cl) el' 5.0 .c _o V -1.0 2.00 3.60 4.00 5.60 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 2 4.49 Chloride 0.006 0.023 0.07739 FALSE FALSE N n13AS-021420-RT-1303 Appendix C- Page 210 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/IntegrMg Version 7.2.8.10783 Logged on User:scthieken Page 25 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R1.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 100.0 Instrument Method., AS22 ASAP Operator: scthieken In.Date/Time: 28-Oct-2022 / 19:54 Run Time: 14.50 30.0 Raphael1239#25 1022-157.R1.HC1 ECD_1 PS 25.0 20.0 u7 15.0 c 0 D w tr v 10.0 v m `o 5.0 U 17 min 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.631 2.359 4.28381 FALSE FALSE ER13AS-021420-RT-1303 Appendix C-Page 211 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:scthieken Page 26 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R1.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 100.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 20:10 Run Time: 14.50 30.0 Raphael1239#26 1022-157.R1.HCI ECD_1 PS 25.0 20.0 ch 15.0 c 0 C. 10.0 V' a) `o 5.0 U R min -1.0 2.60 3.00 4.60 5.00 6.00 7.00 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.631 2.373 4.28527 FALSE FALSE g MgR13AS-021420-RT-1303 Appendix C-Page 212 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 27 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R1-MS.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken /I Date/Time: 28-Oct-2022 / 20:26 Run Time: 14.50 30.0 Raphael1239#27 1022-157.R1-MS.HCI ECD_1 PS 25.0 20.0 a 15.0 o Nt C 10.0 0 U 5.0 min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: *100 E1 NoConicTime Peak Name Area Height Conic Manually Assigned? Manipulated? min pS*min PS pg/mL 4.44 Chloride 1.281 4.794 8.48558 FALSE FALSE N ER13AS-021420-RT-1303 Appendix C-Page 213 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/in teg ra io Version 7.2.8.10783 Logged on User:scthieken Page 28 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R1-MS.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-Oct-2022 / 20:42 Run Time: 14.50 30.0 Raphael1239#28 1022-157.R1-MS.HCI ECD_1 PS 25.0 20.0 15.0 0 0 V- a� 10.0 0 U 5.0 min -1.0 J. 2.00 3.00 4.00 5.60 6.00 7.00 8.00 Time [min] Analyst Comment: *100 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.315 4.919 8.70510 FALSE FALSE MF;R13AS-021420-RT-1303 Appendix C- Page 214 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 29 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R1-MSD.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 20:58 Run Time: 14.50 30.0 ? Raphael1239#29 1022-157.R1-MSD.HCI ECD_1 PS 25.0 20.0 uu) 15.0 o 10.0 L .0 U 5.0 -1.0 n 2.60 3.60 4.60 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: *100 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.277 4.791 8.46413 FALSE FALSE ME�13AS-021420-RT-1303 Appendix C-Page 215 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:scthieken Page 30 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R1-MSD.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 28-00-2022 121:14 Run Time: 14.50 30.0 Raphael1239#30 1022-157.R1-MSD.HCI ECD_1 PS 25.0 20.0 c 15.0 M C N N 10.0 O L U 5.0 `T min 2.00 3.00 4.00 5.60 6.00 7.00 8.00 Time [min] Analyst Comment: *100 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.305 4.900 8.64229 FALSE FALSE M,;Rl3AS-021420-RT-1303 Appendix C-Page 216 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 31 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R2.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 100.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 28-Oct-2022 / 21:30 Run Time: 14.50 30.0 Raphael1239#31 1022-157.R2.HC1 ECD_1 PS 25.0 20.0 0 15.0 ,La, o a cn 10.0 0 U 5.0 min 2.60 3.60 4.00 5.60 6.60 7.00 8.00 Time [min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 4.45 Chloride 1.706 6.306 11.14103 FALSE FALSE ER13AS-021420-RT-1303 Appendix C-Page 217 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:scthieken Page 32 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R2.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 100.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 21:47 Run Time: 14.50 30.0 17 Raphael1239#32 1022-157.R2.HCI ECD_1 PS 25.0 20.0 a ua)i v 15.0 c Q d a> a> .L 10.0 0 V 5.0 min -1.0 2.60 3.00 4.60 5.00 6.60 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.699 6.282 11.09438 FALSE FALSE Ea�13AS-021420-RT-1303 Appendix C-Page 218 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 33 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R3.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 100.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-Oct-2022 / 22:03 Run Time: 14.50 30.0 ? Raphael1239#33 1022-157.R3.HCI ECD_1 PS 25.0 20.0 c 15.0 o d a c O 10.0 0 t U 5.0 ' min -1.0 2.60 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.646 6.097 10.76642 FALSE FALSE EdR13AS-021420-RT-1303 Appendix C-Page 219 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 34 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R3.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 100.0 Instrument Method., AS22 ASAP Operator: scthieken Inj.Date/Time: 28-Oct-2022 / 22:19 Run Time: 14.50 30.0 Raphael1239#34 1022-157.R3.HC1 ECD_1 PS 25.0 20.0 v7 of 15.0 o a � Of 10.0 `o C� 5.0 ' min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 1 4.44 Chloride 1.648 6.106 10.77833 FALSE FALSE g MF, 913AS-021420-RT-1303 Appendix C- Page 220 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 45 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 29-Oct-2022 / 01:16 Run Time: 14.50 30.0 Raphael1239#45 HPLCStds1433#4 ECD_1 PS 25.0 20.0 c 15.0 M v o w m 10.0 0 U rr 5.0 min -1.0 2.00 3.00 4.60 5.60 6.60 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.509 5.670 9.91766 FALSE I FALSE ER13AS-021420-RT-1303 Appendix C- Page 221 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:scthieken Page 46 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 29-Oct-2022 / 01:32 Run Time: 14.50 30.0 Raphael1239#46 HPLCStds1433#4 ECD_1 PS 25.0 20.0 c 15.0 It o d N v a) a 10.0 0 U 5.0 min 2.00 3.00 4.60 5.60 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.512 5.678 9.93694 FALSE FALSE NF((1113AS-021420-RT-1303 Appendix C-Page 222 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integratib�i Version 7.2.8.10783 NE013AiS-021420-RT-1303 Appendix C- Page 223 of 1178 Logged on User:scthieken Page 9 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Irj,Date/Time: 28-Oct-2022 / 15:36 Run Time: 14.50 Raphael1239#9 HPLCStds1433#6 ECD_1 30.0 pS v 25.0 0 U 20.0 voi 15.0 c 0 n 10.0 5.0 min -1.0 2.00 3.00 4.00 5.00 6.60 7.60 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.46 Chloride 5.173 19.961 29.89029 FALSE FALSE MF�R13AS-021420-RT-1303 Appendix C-Page 224 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 10 of 107 Instrument:Raphael 10/31/2022 7:56AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 15:52 Run Time: 14.50 30.0 Raphael1239#10 HPLCStds1433#6 ECD_1 PS LO d- 25.0 0 U 20.0 u0i 15.0 c 0 C Cn 10.0 5.0 min 2.60 3.60 4.60 5.60 6.60 7.00 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 5.093 19.471 29.51490 FALSE FALSE gR13AS-021420-RT-1303 Appendix C- Page 225 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 11 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken 12.Date/Time: 28-Oct-2022 / 16:08 Run Time: 14.50 Raphael1239#11 HPLCStds1433#5 ECD_1 30.0 pS 25.0 20.0 M _. c 15.0 o Q- `o 0 10.0 ' 5.0 min 2.00 3.60 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min NS pg/mL 1 4.44 Chloride 2.374 8.864 15.15172 FALSE FALSE J MgR13AS-021420-RT-1303 Appendix C-Page 226 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 12 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 16:24 Run Time: 14.50 30.0 Raphael1239#12 HPLCStds1433#5 ECD_1 PS 25.0 20.0 ti d- 15.0 o CL `o (D c Of U 10.0 ' 5.0 min -1.0 ------------- 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time[min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.45 Chloride 2.368 8.925 15.11496 FALSE FALSE M,dR13AS-021420-RT-1303 Appendix C- Page 227 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 13 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 16:40 Run Time: 14.50 Raphaell239#13 HPLCStds1433#4 ECD_1 30.0 pS 25.0 20.0 c 15.0 M �r o d a d m m 10.0 0 U 5.0 ,_Jmin -1.0 2.00 3.00 4.60 5.00 6.60 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.499 5.645 9.85450 FALSE FALSE gR13AS-021420-RT-1303 Appendix C-Page 228 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 14 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 16:57 Run Time: 14.50 30.0 Raphael1239#14 HPLCStds1433#4 ECD_1 PS 25.0 20.0 c 15.0 o d U m a) 10.0 0 U yr 5.0 i min 2.00 3.00 4.60 5.60 6.60 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.502 5.646 9,87479 FALSE FALSE gR'3AS-021420-RT-1303 Appendix C- Page 229 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 15 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-Oct-2022 / 17:13 Run Time: 14.50 30.0 Raphael1239#15 HPLCStds1433#3 ECD_1 PS 25.0 20.0 s va)i 15.0 c 0 n C 10.0 rf am 0 5.0 U rr min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 0.712 2.713 4.81636 FALSE FALSE g MgR13AS-021420-RT-1303 Appendix C-Page 230 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 16 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-00-2022 / 17:29 Run Time: 14.50 30.0 Raphae11239#16 HPLCStds1433#3 ECD 1 PS 25.0 20.0 con 15.0 c 0 n N M 10.0 0 0 5.0 C� 17 min -1.0 2.60 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.715 2.728 4.83878 FALSE FALSE gR13AS-021420-RT-1303 Appendix C- Page 231 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 17 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken 12L. Date/Time: 28-Oct-2022 / 17:45 Run Time: 14.50 Raphael1239#17 HPLCStds1433#2 ECD_1 30.0 pS 25.0 20.0 of 15.0 c 0 n a� 10.0 � v a) 5.0 0 U min -1.0 2.00 3.60 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.136 0.523 0.96515 FALSE FALSE g MgR13AS-021420-RT-1303 Appendix C-Page 232 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 18 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-Oct-2022 / 18:01 Run Time: 14.50 30.0 Raphael1239#18 HPLCStds1433#2 ECD_1 PS 25.0 20.0 ch 15.0 c 0 n a� Of 10.0 d- m 5.0 0 U rr � min 2.60 3.60 4.60 5.60 6.00 7.00 8.00 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 1 4.45 Chloride 0.135 0.524 0.95797 FALSE FALSE fNER13AS-021420-RT-1303 Appendix C-Page 233 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:scthieken Page 19 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 18:17 Run Time: 14.50 30.0 Raphael1239#19 HPLCStdsl433#1 ECD 1 PS 25.0 20.0 uoi 15.0 c 0 0_ 0 am 10.0 a> 5.0 $ 0 s U min 2.60 3.60 4.60 5.00 6.60 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? =FALSE min pS*min PS pg/mL 1 4.45 Chloride 0.071 0.270 0.51828 FALSE ]M,I Rl3AS-021420-RT-1303 Appendix C-Page 234 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr I Version 7.2.8.10783 Logged on User:scthieken Page 20 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 18:33 Run Time: 14.50 Raphael1239#20 HPLCStds1433#1 ECD 1 30.0 PS 25.0 20.0 s u) 15.0 c 0 0- Cn m af 10.0 M v 0 5.0 L V `7 -1.0 2.60 3.60 4.00 5.00 6.60 7.00 8.60 Time [min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.44 Chloride 0.070 0.267 0.51523 FALSE FALSE f�E�13AS-021420-RT-1303 Appendix C-Page 235 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:scthieken Page 21 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 28-Oct-2022 / 18:49 Run Time: 14.50 30.0 Raphael1239#21 [manually integrated] ECD_1 PS 25.0 20.0 (n 15.0 c a C1 aa) `r Of dt 10.0 a) 0 U 5.0 i min 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 10/31/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.076 4.148 7.18111 FALSE TRUE MgR13AS-021420-RT-1303 Appendix C-Page 236 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 22 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 19:05 Run Time: 14.50 30.0 Raphae11239#22 [manually integrated] ECD_1 PS 25.0 20.0 ch 15.0 c aW a) w 10.0 0 2= U 5.0 rr mi -1.0 n 2.60 3.60 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 10/31/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 1 4.44 Chloride 1.073 4.147 7.16292 FALSE TRUE Ec�13AS-021420-RT-1303 Appendix C- Page 237 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 23 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In Date/Time: 28-Oct-2022 / 19:22 Run Time: 14.50 30.0 Raphael1239#23 HPLCStds1433#RB ECD_1 PS 25.0 20.0 uoi 15.0 c 0 n a� 10.0 0 rn v 5.0 0 U min -1.0 2.00 3.00 4.00 5.00 6.60 7.00 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.49 Chloride 0.007 0.022 0.07927 FALSE FALSE F6�13AS-021420-RT-1303 Appendix C-Page 238 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 24 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In. Date/Time: 28-Oct-2022 / 19:38 Run Time: 14.50 30.0 04 Raphael1239#24 HPLCStds1433#RB ECD_1 PS 25.0 20.0 ai 15.0 c 0 a a> Of 10.0 M 0) mot' d' 5.0 L 0 U `N min 2.60 3.00 4.00 5.00 6.00 7.00 8.00 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 2 4.49 Chloride 0.006 0.023 0.07739 FALSE FALSE fNER13AS-021420-RT-1303 Appendix C-Page 239 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:scthieken Page 95 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 29-Oct-2022 / 14:42 Run Time: 14.50 Raphael1239#95 HPLCStds1433#6 ECD_1 30.0 pS LO �r 25.0 .L 0 U 20.0 uoi 15.0 c 0 n 0 10.0 5.0 min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 5.209 19.932 30.05767 FALSE FALSE gR13AS-021420-RT-1303 Appendix C- Page 240 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 96 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken ln'. Date/Time: 29-Oct-2022 / 14:58 Run Time: 14.50 30.0 Raphael1239#96 HPLCStds1433#6 ECD_1 PS LO �r 25.0 0 U r 20.0 s c 15.0 0 n w 10.0 5.0 min 2.60 3.60 4.60 5.60 6.60 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 5.239 20.345 30.19689 FALSE FALSE gR13AS-021420-RT-1303 Appendix C-Page 241 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 97 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken 12L.Date/Time: 29-Oct-2022 / 15:14 Run Time: 14.50 Raphael1239#97 HPLCStds1433#5 ECD_1 30.0 pS 25.0 20.0 c 15.0 -0 Q o N L U 10.0 1- 5.0 min -1.0 2.00 3.00 4.60 5.00 6.60 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 2.410 9.186 15.36067 FALSE FALSE gR13AS-021420-RT-1303 Appendix C- Page 242 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 98 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 29-Oct-2022 / 15:30 Run Time: 14.50 30.0 Raphael1239#98 HPLCStds1433#5 ECD_1 PS 25.0 20.0 co Z � ch 15.0 a> c � O L N O U 10.0 5.0 min -1.0 2.60 3.60 4.60 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: EiTime Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4A4 Chloride 2.410 9.129 15.35737 FALSE FALSE gFa�13AS-021420-RT-1303 Appendix C- Page 243 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 99 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken Date/Time: 29-00-2022 / 15:46 Run Time: 14.50 30.0 Raphael1239#99 HPLCStds1433#4 ECD_1 PS 25.0 20.0 15.0 v a v aa) 10.0 O U rr 5.0 i min 2.00 3.00 4.00 5.00 6.60 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min pS pg/mL 1 4.44 Chloride 1.530 5.809 10.04927 FALSE FALSE NNFFn13AS-021420-RT-1303 Appendix C-Page 244 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integratl�� Version 7.2.8.10783 Logged on User:scthieken Page 100 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken I2L.Date/Time: 29-Oct-2022 / 16:02 Run Time: 14.50 30.0 Raphael1239#100 HPLCStds1433#4 ECD_1 PS 25.0 20.0 s c 15.0 � o C v v 10.0 0 t C.) 1- 5.0 min 2.60 3.00 4.60 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.44 Chloride 1.528 5.810 10.03723 FALSE FALSE g MgRl3AS-021420-RT-1303 Appendix C-Page 245 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 101 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 29-Oct-2022 / 16:18 Run Time: 14.50 30.0 Raphael1239#101 HPLCStds1433#3 ECD_1 PS 25.0 20.0 (A 15.0 0 0 n o � v 10.0 d a) `o 5.0 U cr i min 2.00 3.60 4.00 5.00 6.00 7.00 8.00 Time[min] Analyst Comment: No. Time Peak Name Area Height Conic Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.726 2.799 4.91302 FALSE FALSE gR13AS-021420-RT-1303 Appendix C-Page 246 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 102 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 29-Oct-2022 / 16:34 Run Time: 14.50 30.0 Raphael1239#102 HPLCStds1433#3 ECD_1 PS 25.0 20.0 15.0 c 0 Q Nr N M N 10.0 d a� `o 5.0 C� Tr min 2.00 3.00 4.60 5.60 6.00 7.60 8.00 Time(min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.729 2.795 4.93367 FALSE FALSE gR'3AS-021420-RT-1303 Appendix C-Page 247 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 103 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type. Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 29-Oct-2022 / 16:51 Run Time: 14.50 30.0 Raphael1239#103 HPLCStds1433#2 ECD_1 PS 25.0 20.0 ch 15.0 c 0 Q a� 10.0 C) �r �r a) 5.0 0 U min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS"min PS pg/mL 1 4.44 Chloride 0.140 0.541 0.99426 FALSE FALSE MR13AS-021420-RT-1303 Appendix C- Page 248 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 104 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 29-Oct-2022 / 17:07 Run Time: 14.50 30.0 Raphael1239#104 HPLCStds1433#2 ECD_1 PS 25.0 20.0 va)i 15.0 c 0 0- 0 m Of 10.0 M v a> 5.0 0 U rr � min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time[min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.44 Chloride 0.139 0.540 0.98638 FALSE I FALSE F��13AS-021420-RT-1303 Appendix C-Page 249 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 105 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In. Date/Time: 29-00-2022 / 17:23 Run Time: 14.50 Raphael1239#105 HPLCStds1433#1 ECD 1 30.0 pS 25.0 20.0 in 15.0 c 0 Cn a> tY 10.0 M d- a) 5.0 0 U -1.0 2.60 3.60 4.00 5.60 6.60 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS Ng/mL 1 4.44 Chloride 0.071 0.275 0.52137 FALSE FALSE g MgR13AS-021420-RT-1303 Appendix C-Page 250 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 106 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 29-Oct-2022 / 17:39 Run Time: 14.50 30.0 Raphael1239#106 HPLCStds1433#1 ECD_1 PS 25.0 20.0 uai 15.0 c 0 Cn a) af 10.0 M d- �r v 5.0 0 U f i rr i _�min -1.0 2.60 3.60 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.072 0.275 0.52511 FALSE FALSE ER13AS-021420-RT-1303 Appendix C-Page 251 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on I' -cthieken Page 1mu Instrument: el x 227:55mw Sequence:R^,-*ul239 Calibration Table Pos. Level Ref.Amount Calibration DiI.Factor Volume No. Iniection Name Inlect Time Point Status Chloride Chloride Detection Parameters Ret.Time Param. Name Param.Value I nj.Type Channel min I Always Baseline Noise Auto Range Off Any All Channels Always Baseline Noise Start Time 0.400[min] Any All Channels Always Baseline Noise End Time 0.700[min] Any All Channels Always Cobra Smoothing Width Auto Any All Channels Always Consider Void Peak Off Any All Channels 0.000 Maximum Rider Ratio 10 Any All Channels 0,000 Tailing Sensitivity Factor 0.500 Any All Channels 0.000 Inhibit Integration On Any All Channels 0.000 Minimum Area Auto Any All Channels 4.018 Inhibit Integration Off Any All Channels 16.225 Inhibit Integration 1On Any All Channels NE013AS-021420RT-1303 Appendix Page 252nf1178 cmmmvleu 1996-2009 eAnmnstou/mrau noem/m vommn/.u.o.m/ou Logged on User:scthieken Page 2 of 2 Instrument:Raphael 10/31/2022 7:55 AM Sequence:Raphael1239 Calibration Batch Report Sequencer Raphaei1239 Injection Volume: 25.00 Instrument Method. AS22 ASAP Operator.• scthieken> Inj.Date/`Time: 29-00-2022 / 14:09 Run Time: 14.5 Calibration Summary Peak Name Eval.Type Cal.Type Points Offset Slope; Curve Coeff.Det. CO (Cl) C2 % Chloride Area Quad WithOffset 1/A 24.000 0.034 6.872 -0.213 99.973 AVERAGE: 0.0341 6.8719 1 -0.2127 99.9734 Injection Name Ret.Time Area Height Amount 35.0 Chloride External ECD-1 min pS*min US pg/mL ug/mL ECD ;1 ECD 1 ECD 1 ECD i'1 Chloride Chloride Chloride Chloride HPLCStds1433#6 4.460 5.173 19.961 29.890 30.0 HPLCStds1433#6 4A50 5.093 19.471 29.515 HPLCStds1433#5 4.443 2.374 8.864 15.152 HPLCStds1433#5 4.447 2.368 8.925 15.115 25.0 HPLCStds1433#4 4.443 1.499 5.645 9.855 HPLCStds1433#4 4.440 1.502 5.646 9.875 HPLCStds1433#3 4.447 0.712 2.713 4.816 HPLCStds1433#3 4.443 0.715 2.728 4.839 20.0 HPLCStds1433#2 4.443 0.136 0.523 0.965 HPLCStds1433#2 4.447 0.135 0.524 0.958 HPLCStds1433#1 4.447 0.071 0.270 0.518 HPLCStds1433#1 4.443 0.070 0.267 0.515 15.0 HPLCStds1433#6 4.450 5.209 19.932 30.058 HPLCStds1433#6 4.450 5.239 20.345 30.197 HPLCStds1433#5 4.447 2.410 9.186 15.361 10.0 HPLCStds1433#5 4.443 2.410 9.129 15.357 HPLCStds1433#4 4.443 1.530 5.809 10.049 HPLCStds1433#4 4.440 1.528 5.810 10.037 HPLCStds1433#3 4.440 0.726 2.799 4.913 5.0 HPLCStds1433#3 4.443 0.729 2.795 4.934 HPLCStds1433#2 4.440 0.140 0.541 0.994 HPLCStds1433#2 4.437 0.139 0.540 0.986 pS*min HPLCStds1433#1 4.443 0.071 0.275 0.521 0.0 HPLCStds1433#1 4.443 0.072 0.275 0.525 0.00 2.00 4.00 6.00 NE01 3AS-021420-RT-1 303 Appendix C- Page 253 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Calibration Version 7.2.8.10783 Logged on User:scthieken Page 21 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 18:49 Run Time: 14.50 30.0 !,41 Raphael1239#21 [manually integrated] ECD_1 PS 25.0 20.0 N uoi 15.0 c n Cn 10.0 a> .L 0 U 5.0 17 i min 2.60 3.00 4.00 5.00 6.00 7.00 8.60 Time [min] Analyst Comment: II SJT 10/31/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.076 4.148 7.18111 FALSE TRUE IaR13AS-021420-RT-1303 Appendix C-Page 254 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 22 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 19:05 Run Time: 14.50 30.0 tjo Raphael1239#22 [manually integrated] ECD 1 PS 25.0 20.0 in 15.0 c n a`) 10.0 0 U 5.0 min 2.60 3.60 4.60 5.60 6.60 7.60 8.60 Time [min] Analyst Comment: II SJT 10/31/2022 E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.44 Chloride 1.073 4.147 7.16292 FALSE TRUE f ,FR13AS-021420-RT-1303 Appendix C-Page 255 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra i Version 7.2.8.10783 Logged on User:scthieken Page 23 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken Inj.Date/Time: 28-Oct-2022 / 19:22 Run Time: 14.50 30.0 Raphael1239#23 HPLCStds1433#RB ECD_1 PS 25.0 20.0 ch 15.0 c 0 Q U) 0 10.0 0 rn m 5.0 0 s U min -1.0 2.60 3.00 4.00 5.60 6.60 7.60 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.49 Chloride 0.007 0.022 0.07927 FALSE FALSE g MR13AS-021420-RT-1303 Appendix C-Page 256 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 24 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In". Date/Time: 28-Oct-2022 / 19:38 Run Time: 14.50 30.0 Raphaell239#24 HPLCStds1433#RB ECD— 1 PS 25.0 20.0 uoi 15.0 c 0 Q (D w 10.0 cf) rn d- 5.0 0 U I I I min -1.0 I —- 2.00 3.60 4.60 5.60 6.60 7.60 8.60 Time [min] Analyst Comment: E2 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.49 Chloride 0.006 0.023 0.07739 FALSE FALSE ,dR13AS-021420-RT-1303 Appendix C-Page 257 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr I Version 7.2.8.10783 Logged on User:scthieken Page 35 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R111.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In Date/Time: 28-Oct-2022 / 22:35 Run Time: 14.50 30.0 Raphael1239#35 1022-157.R111.M26A ECD_1 PS 25.0 20.0 ch 15.0 0 0 0 a- CA a 10.0 a) .L 0 U 5.0 ' min -1.0 2.60 3.00 4.60 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.212 4.509 8.04871 FALSE FALSE NNFF((1113AS-021420-RT-1303 Appendix C-Page 258 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integratia�i Version 7.2.8.10783 Logged on User:scthieken Page 36 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R111.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 22:51 Run Time: 14.50 30.0 Raphael1239#36 1022-157.R111.M26A ECD_1 PS 25.0 20.0 va)i 15.0 O M O d (n d <Y 10.0 O L U 5.0 min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.44 Chloride 1.208 4.533 8.02756 FALSE FALSE R13AS-021420-RT-1303 Appendix C-Page 259 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 37 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R112.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In". Date/Time: 28-Oct-2022 / 23:07 Run Time: 14.50 30.0 Raphaell239#37 1022-157.R112.M26A ECD_1 PS 25.0 20.0 ch 15.0 c 0 0. Cn m 10.0 0 LO v a> 5.0 min 2= U �\ 2.60 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min uS*min PS pg/mL 1 4.45 Chloride 0.047 0.178 0.35823 FALSE FALSE NNFF((�� 13AS-021420-RT-1303 Appendix C-Page 260 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/IntegrUgR Version 7.2.8.10783 Logged on User:scthieken Page 38 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R112.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 23:23 Run Time: 14.50 30.0 Raphael1239#38 1022-157.R112.M26A ECD_1 PS 25.0 20.0 v7 ai 15.0 c 0 o_ CD a> 10.0 0 LO 5.0 0 U min 2.60 3.60 4.00 5.00 6.00 7.60 8.00 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 0.047 0.177 0.35764 FALSE FALSE g M,bRl3AS-021420-RT-1303 Appendix C-Page 261 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter I Version 7.2.8.10783 Logged on User:scthieken Page 39 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R113.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-00-2022 / 23:39 Run Time: 14.50 30.0 Raphael1239#39 1022-157.R113.M26A ECD_1 PS 25.0 20.0 ch 15.0 c 0 a a) 10.0 5.0 0 U `T min 2.60 3.00 4.00 5.00 6.60 7.60 8.00 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS Ng/mL 1 4.52 Chloride 0.006 0.022 0.07440 FALSE FALSE g MEaR13AS-021420-RT-1303 Appendix C- Page 262 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 40 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R113.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In".Date/Time: 28-Oct-2022 / 23:55 Run Time: 14.50 30.0 Raphael1239#40 1022-157.R113.M26A ECD_1 PS 25.0 20.0 co 15.0 c 0 Q. W a� 10.0 0 v 5.0 L _O U min -1.0 2.60 3.60 4.00 5.00 6.60 7.00 8.60 Time [min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS lag/mL 4.51 Chloride 0.007 0.024 0.08418 FALSE FALSE g MEdR13AS-021420-RT-1303 Appendix C- Page 263 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter Version 7.2.8.10783 Logged on User:scthieken Page 41 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R114.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 29-Oct-2022 / 00:12 Run Time: 14.50 30.0 17 Raphael1239#41 1022-157.R114.M26A ECD_1 PS 25.0 20.0 s voi 15.0 c 0 a m 10.0 v a> 5.0 a 0 s= U ml 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 1 4.45 Chloride 0.012 0.038 0.11943 FALSE FALSE MgR13AS-021420-RT-1303 Appendix C-Page 264 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken IPage 42 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R114.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 29-Oct-2022 / 00:28 Run Time: 14.50 30.0 Raphael1239#42 1022-157.R114.M26A ECD_1 PS 25.0 20.0 in 15.0 c 0 o_ w aD 10.0 0 5.0 a 0 U -1.0 2.60 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: E2 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.45 Chloride 0.011 0.039 0.10646 FALSE FALSE g MgR13AS-021420-RT-1303 Appendix C- Page 265 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 43 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R211.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In".Date/Time: 29-Oct-2022 / 00:44 Run Time: 14.50 30.0 Raphae11239#43 1022-157.R211.M26A ECD_1 PS 25.0 20.0 vi 15.0 c 0 a a) o Of0 10.0 a) o` 5.0 U ' min -1.0 2.60 3.60 4.60 5.00 6.00 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.540 2.042 3.68409 FALSE FALSE g MgRl3AS-021420-RT-1303 Appendix C- Page 266 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 44 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R211.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 29-Oct-2022 101:00 Run Time: 14.50 30.0 Raphael1239#44 1022-157.R211.M26A ECD_1 PS 25.0 20.0 in 15.0 c 0 n 0 Cl) d' 10.0 d a� `o 5.0 -C U rr ' mm -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.44 Chloride 0.535 2.047 3.65117 FALSE FALSE ER13AS-021420-RT-1303 Appendix C-Page 267 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:scthieken Page 45 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In".Date/Time: 29-Oct-2022 / 01:16 Run Time: 14.50 30.0 Raphael1239#45 HPLCStds1433#4 ECD_1 PS 25.0 20.0 c 15.0 M o a �r aCni ' 10.0 0 2= U 5.0 i min 2.00 3.00 4.60 5.00 6.60 7.00 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.509 5.670 9.91766 FALSE FALSE Fc�13AS-021420-RT-1303 Appendix C- Page 268 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 46 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 29-Oct-2022 / 01:32 Run Time: 14.50 30.0 tjo Raphael1239#46 HPLCStds1433#4 ECD_1 PS 25.0 20.0 15.0 Vt o � v a) ry 10.0 0 s= V 5.0 min 2.00 3.00 4.60 5.00 6.00 7.00 8.00 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.512 5.678 9.93694 FALSE FALSE g Mgpll3AS-021420-RT-1303 Appendix C- Page 269 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 47 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R212.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 29-Oct-2022 101:48 Run Time: 14.50 30.0 Raphael1239#47 1022-157.R212.M26A ECD_1 CIS 25.0 20.0 uoi 15.0 c 0 m 10.0 M a) 5.0 -a min U -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min NS pg/mL 1 4.46 Chloride 0.025 0.091 0.20635 FALSE FALSE g MgRl3AS-021420-RT-1303 Appendix C-Page 270 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 48 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R212.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method. AS22 ASAP Operator: scthieken In'.Date/Time: 29-Oct-2022 / 02:04 Run Time: 14.50 30.0 Raphael1239#48 1022-157.R212.M26A ECD_1 PS 25.0 20.0 u0i 15.0 c 0 Q 0 as 10.0 0 0 �r 5.0 0 U min -1.0 2.00 3.60 4.00 5.00 6.00 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS lag/mL 1 4A6 Chloride 0.025 0.090 0.20496 FALSE FALSE g MgR13AS-021420-RT-1303 Appendix C-Page 271 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 49 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R213.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken Ini.Date/Time: 29-Oct-2022 / 02:21 Run Time: 14.50 30.0 Raphael1239#49 1022-157.R213.M26A ECD_1 PS 25.0 20.0 in 15.0 c 0 n w a� 10.0 ti 5.0 a 0 U min 2.60 3.00 4.00 5.00 6.60 T 0 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.52 Chloride 0.006 0.021 0.07449 FALSE FALSE F6R13AS-021420-RT-1303 Appendix C-Page 272 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 50 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R213.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 29-Oct-2022 / 02:37 Run Time: 14.50 30.0 Raphael1239#50 1022-157.R213.M26A ECD_1 PS 25.0 20.0 ai 15.0 c 0 ❑. w aD 10.0 v 5.0 L 0 U I et I i min 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.52 Chloride 0.005 0.020 0.07184 FALSE FALSE INIaR13AS-021420-RT-1303 Appendix C-Page 273 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra i Version 7.2.8.10783 Logged on User:scthieken Page 51 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R214.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken Inj. Date/Time: 29-Oct-2022 / 02:53 Run Time: 14.50 30.0 Raphaell239#51 1022-157.R214.M26A ECD_1 PS 25.0 20.0 voi 15.0 c 0 n a) 10.0 m �r d- 5.0 a 0 U -1.0 2.60 3.60 4.60 5.60 6.60 7.60 8.00 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.012 0.040 0.11654 FALSE FALSE g MgRl3AS-021420-RT-1303 Appendix C-Page 274 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter I Version 7.2.8.10783 Logged on User:scthieken Page 52 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R214.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 29-Oct-2022 / 03:09 Run Time: 14.50 30.0 Raphael1239#52 1022-157.R214.M26A ECD_1 PS 25.0 20.0 voi 15.0 0 n 0 m 10.0 co u7LO d' 5.0 0 U RO i m i n 2.60 3.60 4.00 5.60 6.60 7.60 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS lag/mL 2 4.45 Chloride 0.012 0.041 0.11489 FALSE FALSE g MgR13AS-021420-RT-1303 Appendix C-Page 275 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 53 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R311.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken /I Date/Time: 29-Oct-2022 / 03:25 Run Time: 14.50 30.0 Raphael1239#53 1022-157.R311.M26A ECD_1 PS 25.0 20.0 = M 15.0 a m ry o 10.0 U R 5.0 min 2.60 3.60 4.00 5.60 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS"min PS pg/mL 1 4.44 Chloride 2.025 7.575 13.07440 FALSE FALSE MR13AS-021420-RT-1303 Appendix C-Page 276 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 54 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R311.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 29-Oct-2022 / 03:41 Run Time: 14.50 30.0 JJ Raphael1239#54 1022-157.R311.M26A ECD_1 PS 25.0 20.0 o u�i 15.0 d 0 U � o 10.0 U rr- 5.0 min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 2.036 7.599 13.14130 FALSE FALSE M913AS-021420-RT-1303 Appendix C-Page 277 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 55 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R312.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken /2L.Date/Time: 29-Oct-2022 103:57 Run Time: 14.50 30.0 Raphael1239#55 1022-157.R312.M26A ECD_1 PS 25.0 20.0 uoi 15.0 c 0 Q a) 10.0 M 5.0 0 U rr i min 2.00 3.00 4.00 5.60 6.00 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.076 0.292 0.55747 FALSE I FALSE M,aR13AS-021420-RT-1303 Appendix C- Page 278 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 56 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R312.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method., AS22 ASAP Operator: scthieken In'.Date/Time: 29-Oct-2022 / 04:13 Run Time: 14.50 30.0 Raphael1239#56 1022-157.R312.M26A ECD_1 CIS 25.0 20.0 ch 15.0 c 0 fl. a� 10.0 ti �r v v a� 5.0 0 U I I min 2.60 3.00 4.60 5.60 6.60 7.00 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS Ng/mL 1 4.45 Chloride 0.076 0.290 0.55246 FALSE FALSE gR13AS-021420-RT-1303 Appendix C- Page 279 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783