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Home My WebLink AboutAir Quality Test V2 prt 3 Logged on User:scthieken Page 13 of 51 Instrument:Mikey 11/8/2022 7:44AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor 1.0 Instrument Method: Mikey Cations 12min Operator. scthieken In'.Date/Time: 07-Nov-2022' 1 16:34 Run Time: 12.00 7.00 Mikey386#13 HPLCSTDs1419#5 ECD_1 6.00 5.00 0 0 M V' U 4.00 C O C E O E CL 3.00 Q 2.00 1.00 -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS pg/mL Assigned? Ammonia 2 4.300 Ammonia 0.719 2.618 3.27227 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 cTM-09N/1�r&hA!9n021420-RT-1303 Appendix C-Page 114 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 14 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#5z Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator, scthieken In."Date/Time: 07-Nov-2022 11648 "Run Time: _ 12.00 7.00 Mikey386#14 HPLCSTDs1419#5 ECD_1 6.00 5.00 M O Cl? V' 3 4.00 N -E O C E O E In 3.00 Q a> 2.00 1.00 -0.10 2.60 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min PS*min PS pg/mL Assigned? Ammonia 2 4.303 Ammonia 0.719 2.619 3.27494 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-94 & ati9n021420-RT-1303 Appendix C-Page 115 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 15 of 51 Instrument:Mikey 11/8/2022 7:44AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSMs14l9#6 Injection,Volume: 25.00 Injection Type: Calibration Standard" Dilution Factor 1.0 Instrument Method: Mikey Cations 12min Operator.- I scthieken In".Date/Time: 07-Nov-2022 / 17:01 Run Time: 12.00 7.00 Mikey386#15 HPLCSTDs1419#6 ECD—1 0 0 6.00 M d' (9 .0 O 5.00 E Q M s 4.00 a) c O m 3.00 o' 2.00 1.00 -0.10 2.00 3.00 4.00 5.00 6.60 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS pg/mL Assigned? Ammonia 2 4.307 Ammonia 1.234 4.200 6.63227 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 IT' -O�141rueA 92-021420-RT-1303 Appendix C-Page 116 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 16 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution'Factor 1.0 Instrument Method: Mikey Cations 12min Operator, scthieken ' In."Date/Time: 07-Nov-2022 / 1715 Run Time: 12.00 7.00 Mikey386#16 HPLCSTDs1419#6 ECD_1 r` 0 6.00 M m 'c 0 5.00 E Q z 4.00 C Cn 0 0 3.00 elf 2.00 1.00 -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL. Assigned? Ammonia 2 4.307 Ammonia 1.232 4.194 6.62092 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-0JV7tlntelg7tign021420-RT-1303 Appendix C-Page 117 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 17 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#7 Injection Volume: 25.00 Injection Type: Calibration Standard I Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator: scthieken In'.Date/Time: 07-Nov-2022 / 17:29 Run Time: 12.00 7.00 Mikey386#17 HPLCSTDs1419#7 ECD_1 r- 0 m v 6.00 `a E 5.00 N cl) 4.00 a> U) c 0 m 3.00 2.00 1.00 I I I -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.307 Ammonia 1.852 5.980 11.76667 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-02N/,Ir>XeACatign021420-RT-1303 Appendix C-Page 118 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 18 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#7 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor., 1.0 Instrument Method: Mikey Cations 12min Operator: scthieken In':Date/Time: 07-Nov-2022 / 17:42 "Run Time: 12.00 7.00 Mikey386#18 HPLCSTDs1419#7 ECD_1 r` 0 Cl? rh 6.00 E 5.00 N cf) 4.00 N N G O CL 3.00 of 2.00 1.00 -0.10 �. - 2.00 3.00 4.60 5.60 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.307 Ammonia 1.858 5.988 11.83034 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTW NrIErW91-021420-RT-1303 Appendix C-Page 119 of 1178 Version 7.2.8.10783 Logged oi;.. per:scthieken - ,age 1 of 2 Instrument:Mikey 11/8/2022 7:43 AM Sequence:Mikey386 Mikey Calibration Table No. In'ection Name Iniect Time Pos. Level Ref.Amount Calibration Point Status Dil.Factor Volume pg/mL pL ECD_1 ECD_1 Ammonia Ammonia 5 HPLCSTDs1419#1 07/Nov/2022 14:45 RA1 1 0.1888 Ok 1.0000 25.00 6 HPLCSTDs1419#1 07/Nov/2022 14:58 RA1 1 0.1888 Ok 1.0000 25.00 7 HPLCSTDs1419#2 07/Nov/2022 15:12 RA2 2 0.3776 Ok 1.0000 25.00 8 'HPLCSTDs1419#2 07/Nov/2022 15:26 RA2 2' 0.3776 Ok 1.0000 25.00 9 HPLCSTDs1419#3 07/Nov/2022 1539 RA3 3' 0.7552 Ok 1.0000 25.00 10 HPLCSTDs1419#3 07/Nov/202215:53 RA3 3 0.7552 Ok 1.0000 25.00 11 HPLCSTDs1419#4 07/Nov/2022 16:07 'RA4 4 1.4160 Ok 1.0000 25.00 12 HPLCSTDs1419#4 07/Nov/2022 16:20 RA4 4 1.4160 Ok 1.0000 25.00 13 HPLCSTDs1419#5 07/Nov/2022 16:34 RA5 5 3.3040 Ok 1.0000 25.00 14 HPLCSTDs1419#5 07/Nov/2022 16:48 RA5 5 3.3040 Ok 1.0000 25.00 15 HPLCSTDs1419#6 07/Nov/202217:01 RA6 6 6.6080 Ok 1.0000 25.00 16 HPLCSTDs1419#6 07/Nov/2022 17:15 RA6 6 6.6080 Ok 1.0000 25.00 17 HPLCSTDs1419#7 07/Nov/2022 17:29 RA7 7 11.8000 Ok 1.0000 25.00 18 HPLCSTDs1419#7 07/Nov/2022 17:42 RA7 7 11.8000 Ok 1.0000 25.00 Detection Parameters Ret. Time Param. Name Param.Value Inj. Type Channel min Always Baseline Noise Auto Range Off Any All Channels Always Baseline Noise Start Time 0.231 [min] Any All Channels Always Baseline Noise End Time 1.277[min] Any All Channels Always Cobra Smoothing Width Auto Any All Channels Always Consider Void Peak Off Any All Channels 0.000 Tailing Sensitivity factor 0.100[%] Any All Channels 0.000 Rider Detection Off Any All Channels 0.000 Minimum Area Auto Any All Channels 0.000 Inhibit Integration On Any All Channels 2.900 Inhibit Integration Off Any All Channels 8.412 1 Inhibit Integration Ion An" 1AII Channels; Chromeleon(c)Dionex 1996-2009 CTM-027/Calibration Details Version 7.2.8.10783 NE01 3AS-021420-RT-1 303 Appendix C- Page 120 of 1178 Logged on User:scthieken Page 2 of 2 Instrument:Mikey 11/8/2022 7:43 AM Sequence:Mikey386 Mikey Calibration Batch Report Sequence: Mikey386 Injection Volume: 25.00 Instrument Method: Mikey Cations 12min Operator. scthieken Inv.Date/Time: 07-Nov-2022 1 19:45 Run Time: 12 Calibration Summary Peak Name Eval.Type Cal.Type Points Offset Slope Curve Coeff.Det.- CO C1 C2 % Ammonia Area Quad WithOffset 1/A 14.000 -0.021 3.450 1.575 99.996 AVERAGE: -0.0209 3.4495 1 1.5752 1 99.9964 Injection Name Ret.Time Area Height Amount 14.0 Ammonia External ECD-1 min pS'min PS pg/mL pg/mL ECD 1 ECD 1 ECD 1 ECD 1 Ammonia Ammonia Ammonia Ammonia 12.0 HPLCSTDs1419#1 4.267 0.0585 0.260 0.186 HPLCSTDs1419#1 4.270 0.0586 0.261 0.187 10.0 HPLCSTDs1419#2 4.273 0.1107 0.483 0.380 HPLCSTDs1419#2 4.273 0.1093 0.484 0.375 8.0 HPLCSTDs1419#3 4.280 0.2094 0.873 0.770 HPLCSTDs1419#3 4.280 0.2083 0.872 0.766 6.0 HPLCSTDs1419#4 4.290 0.3589 1.416 1.420 HPLCSTDs1419#4 4.290 0.3579 1.412 1.415 HPLCSTDs1419#5 4.300 0.7188 2.618 3.272 4.0 HPLCSTDs1419#5 4.303 0.7192 2.619 3.275 HPLCSTDs1419#6 4.307 1.2337 4.200 6.632 2.0 HPLCSTDs1419#6 4.307 1.2321 4.194 6.621 NS*min HPLCSTDs1419#7 4.307 1.8516 5.980 11.767 0.0 HPLCSTDs1419#7 4.307 1.8584 5.988 11.830 0.00 1.00 2.60' NN -g?d1420-RT-1303 Appendix C- ; 121 of 1178 Chromeleon(c)Dior 96-2009 CTM-OZ . r ti Versiot. _.8.10783 Logged on User:scthieken Page 19 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: ,HPLCSTDs1419#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor.- 1.0 Instrument Method: Mikey Cations 12min Operator: scthieken In'.Date/Time: 07-Nov-2022 / 17:56 Run Time: 12.00 ' 7.00 Mikey386#19 HPLCSTDs1419#RB ECD_1 6.00 5.00 )k 4.00 N c 0 0- 3.00 ry 2.00 (D N <t (6 C 1.00 E E Q -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS pg/mL Assigned? Ammonia 2 4.263 Ammonia 0.003 0.013 n.a. FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTMIN(lt1(elgati9n021420-RT-1303 Appendix C-Page 122 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 20 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor 1.0 Instrument Method: Mikey'Cations 12min Operator scthieken ln':Date/Time: 07-Nov-2022 / 18:10 Run Time: 12.00 7.00 .� Mikey386#20 HPLCSTDs1419#RB ECD_1 6.00 5.00 U 4.00 w (n c 0 Q ai 3.00 2.00 Cl) N cl' f6 C 1.00 E E Q -0.10 2.00 3.60 4.60 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS pg/mL Assigned? Ammonia 2 4.263 Ammonia 0.003 0.012 n.a. FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-NLtrue, g-'021420-RT-1303 Appendix C- Page 123 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 21 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator scthieken In".Date/Time: 07-Nov-2022 / 18:23 Run Time: 12.00 7.00 1 Mikey386#21 HPLCSTDs1419#SS ECD_1 6.00 5.00 U 4.00 Cl) N d) U) N C d: O Q u, 3.00 cm a) c 0 E E Q 2.00 1.00 i i -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS pg/mL Assigned? Ammonia 2 4.293 Ammonia 0.442 1.709 1.81201 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-O:Wnie'fq 7a 92021420-RT-1303 Appendix C- Page 124 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 22 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#SS Injection Volume: 25.00 Injection Type: Check Standard "Dilution Factor 1.0 Instrument Method. Mikey Cations 12min Operator. scthieken' In' Date/Time: 07-Nov-2022 / 18:37 Run Time: 12.00 7.00 i Mikey386#22 HPLCSTDs1419#SS ECD_1 6.00 5.00 U 4.00 M N O G Cl? O Q 3.00 c O E E Q 2.00 R� 1.00 i -0.10 i 2.60 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.303 Ammonia 0.445 1 1.707 1.82819 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-02Ntlttieq V-2021420-RT-1303 Appendix C- Page 125 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 23 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R111.OUt Injection,Volume: 25.00 Injection Type: Unknown Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator, scthieken Ini.Date/Time: 07-Nov-2022 / 18:51 Run Time: 12.00 7.00 Mikey386#23 1122-041.R111.0ut ECD_1 6.00 co co N 5.00 m c 0 E E U 4.00 `L (n C 0 O 3.00 2.00 1.00 -0.10 2.60 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.267 Ammonia 1.106 3.593 5.71783 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-OJNLIVfidtiQn021420-RT-1303 Appendix C- Page 126 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 24 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R111.Out. Injection Volume: 25.00 Injection Type: Unknown Dilution Factor. 1.0 Instrument Method: Mikey Cations`12min Operator. scthieken In'.'Date/Time: 07-Nov-2022 / 19:04 Run Time: 12.00 7.00 Mikey386#24 1122-041.R111.0ut ECD_1 6.00 M N 5.00 m 0 E E U 4.00 Q N CIO c 0 3.00 2.00 1.00 -0.10 2.00 3.60 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.273 Ammonia 1.107 3.587 5.72625 FALSE FALSE Chromeleon(c)Dionex 1996-2009 Version 7.2.8.10783 CTM-02TV7�Ir�eati�n021420-RT-1303 Appendix C-Page 127 of 1178 Logged on User:scthieken Page 25 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R111-MS.Out Injection Volume: 25.00 Injection Type: Unknown Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator scthieken In".Date/Time: 07-Nov-2022' 1 19:18 Run Time: '- 12.00 7.00 Mikey386#25 1122-041.R111-MS.Out ECD— 1 r` N V 6.00 C O E 5.00 U 4.00 c C 3.00 0_ 2.00 1.00 i -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS`min PS pg/mL Assigned? Ammonia 2 4.267 Ammonia 1.687 5.248 10.28266 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-0J49 tef iAn021420-RT-1303 Appendix C- Page 128 of 1178 version 7.2.8.10783 Logged on User:scthieken Page 26 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.11111-MS.Out Injection Volume: 25.00 Injection Type: Unknown' Dilution Factoc 1.0 Instrument Method: Mikey Cations 12min Operator: scthieken In'bate/Time: 07-Nov-2022 /`19:32 Run Time: 12.00 7.00 Mikey386#26 1122-041.R111-MS.Out ECD_1 Cl) r` N V 6.00 (6 .0 O E 5.00 U 4.00 W w c 0 W 3.00 Qf 2.00 1.00 i -0.10 -T 2.00 3.60 4.00 5.00 6.00 7.' Time[min] 001 Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.273 Ammonia 1.695 5.245 10.34818 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-02NM 92-021420-RT-1303 Appendix C- Page 129 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 27 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R111-MSD.Out Injection,Volume: 25.00 ' Injection Type: Unknown Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator scthieken Ini.Date/Time:` 07-Nov-2022 / 19:45 Run Time: 12.00 7.00 Mikey386#27 1122-041.R111-MSD.Out ECD_1 0 r` N 6.00 t0 G O E E 5.00 4.00 c C 3.00 rr 2.00 1.00 t -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.270 Ammonia 1.671 5.199 10.13870 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-02NM92021420-RT-1303 Appendix C-Page 130 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 28 of 51 Instrument:Mikey 11/8/2022 7:44AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R111-MSD.Out Injection,Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: Mikey Cations 12min Operator scthieken In":"Date/Time: 07-Nov-2022 1 19:59 Run Time: "12.00 7.00 Mikey386#28 1122-041.R111-MSD.Out ECD_1 co to N 6.00 cm C 0 E 5.00 s 4.00 aD c 0 In 3.00 o' 2.00 1.00 a -0.10 2.00 3.60 4.00 5.60 6.60 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min ps*min PS pg/mL Assigned? Ammonia 2 4.263 Ammonia 1.670 5.213 10.12896 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-02Rr>xeA 9-'021420-RT-1303 Appendix C-Page 131 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 29 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name 1122-041.R112.Out Injection Volume: 25.00 Injection Type: Unknown Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator: i scthieken Ini.Date/Time: 07-Nov-2022 / 20:13 Run Time: 12.00 7.00 Mikey386#29 1122-041.R112.Out ECD_1 6.00 5.00 4.00 a� c 0 0- aw 3.00 af 0 2.00 °O v 0 c 1.00 0 E E Q -0.10 2.60 3.00 4.00 5.60 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.180 Ammonia 0.037 0.129 0.10806 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-02N/1Er�e,�ati9n021420-RT-1303 Appendix C- Page 132 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 30 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041 R112.Out> Injection Volume: 26.00 Injection Type: Unknown Dilution Factor.- 1.0 Instrument Method: Mikey Cations 12min Operator: scthieken ln'.Date/Time: 07-Nod-2022 / 20:26 Run Time: 12.00 7.00 Mikey386#30 1122-041.R112.Out ECD_1 6.00 5.00 U 4.00 c 0 o. 3.00 0 2.00 °ro v m .E 1.00 E E Q -0.10 2.00 3.00 4.00 5.60 6.60 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS pg/mL Assigned? Ammonia 2 4.180 Ammonia 0.036 0.128 0.10563 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-OaN(lty(e'Ig O9202 1 42 0-RT-1303 Appendix C-Page 133 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 31 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R113.Out Injection Volume: 25.00 Injection Type: Unknown Dilution Factor 1.0 Instrument Method: Mikey Cations 12min Operator scthieken In i.Date/Time: 07-Nov-2022 / 20:40 Run Time: 12.00 7.00 FJ Mikey386#31 1122-041.R113.0ut ECD_1 6.00 5.00 s 4.00 a) U) G O d ro 3.00 Df 2.00 Cl) m 1.00 0 E E Q I C�J l i -0.10 2.00 3.00 4.00 5.00 6.60 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min ps*min tis Ng/mL Assigned? Ammonia 2 4.123 Ammonia 0.003 0.011 n.a. FALSE I FALSE Chromeleon(c)Dionex 1996-2009 Version 7.2.8.10783 CTM-O�Nllntelgati�n021420-RT-1303 Appendix C-Page 134 of 1178 Logged on User:scthieken Page 32 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample i Name: 1122-041.R113.0ut Injection Volume: 25.00 Injection Type: Unknown Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator: scthieken In.Date/Time: 07-Nov-2022 / 20:54 Run'Time: 12.00 7.00 '1 Mikey386#32 1122-041.R113.Out ECD_1 6.00 5.00 s 4.00 Cn c 0 0- aNi 3.00 2.00 Cl) m c 1.00 E E Q -0.10 r--i 2.00 3.60 4.00 5.00 6.00 00 Time[min] 7. Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS pg/mL Assigned? Ammonia 2 4.143 Ammonia 0.004 0.012 n.a. FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-07Nt1nIe7tign Version 7.2.8.10783 021420-RT-1303 Appendix C- Page 135 of 1178 Logged on User:scthieken Page 33 of 51 Instrument:Mikey 11/8/2022 7:44AM Sequence:Mikey386 Peak Analysis Report Sample Name: '1122-041.R211.Out Injection Volume: L25.00 ] Injection Type: Unknown Dilution Factor.Instrument Method: Mikey Cations 12min Operator In `Date/Time: 07-Nov-2022 / 21:07 Run Time: 7.00 Mikey386#33 1122-041.R211.Out ECD_1 6.00 LO 5.00 m c 0 4.00 E 0 Q ch 0 CL 3.00 2.00 1.00 -0.10 2.60 3.60 4.00 5.00 6.60 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.257 Ammonia 1.004 3.308 5.03252 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-02N�MXti�n021420-RT-1303 Appendix C-Page 136 of 1178 version 7.2.8.10783 Logged on User:scthieken Page 34 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R211.0ut: Injection Volume: 25.00 Injection Type: Unknown Dilution Factor. 1.0 Instrument Method. Mikey Cations 12min Operator scthieken In' Date/Time: 07-Nov-2022 1 21:21 Run Time: 12.00 7.00 Mikey386#34 1122-041.R211.0ut ECD_1 6.00 LO N 5.00 ca 'c 0 E ) 4.00 E 0 0 0 0. 3.00 2.00 1.00 -0.10 r 2.00 3.00 4.00 5.00 6.00 00 Time[min] 7. Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min uS"min PS pg/mL Assigned? Ammonia 2 4.253 Ammonia 1.011 3.311 5.07787 FALSE FALSE Chromeleon(c)Dionex 1996-2009 Version 7.2.8.10783 CTM-027.t1ntegtiQn021420-RT-1303 Appendix C-Page 137 of 1178 Logged on User:scthieken Page 35 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R212.Out Injection Volume: 25.00 Injection Type: Unknown Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator. scthieken Ini.'Date/Time: 07-Now-2022 121:35 Run Time: 12.00 7.00 Mikey386#35 1122-041.R212.Out ECD_1 6.00 5.00 y 4.00 a� c 0 n 3.00 r 2.00 'n v m c 1.00 0 E E Q -0.10 2.00 3.00 4.60 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min ps*min PS pg/mL Assigned? Ammonia 2 4.157 Ammonia 0.022 0.069 0,05515 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-0Z7,/Jnte, V-2021420-RT-1303 Appendix C- Page 138 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 36 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R212.0ut Injection Volume: 25.00 Injection Type: Unknown; Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator scthieken D ate/Time: 07-Nov-2022 / 21:48 Run Time: 12.00 7.00 Mikey386#36 1122-041.R212.0ut ECD_1 6.00 5.00 4.00 a> C C a 3.00 r 2.00 d v m C 1.00 0 E E Q -0.10 �- 2.00 3.00 4.00 5.60 6.60 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.147 Ammonia 0.021 1 0.069 0.05254 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CT1-NtlnteV9-'021420-RT-1303 Appendix C- Page 139 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 37 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041R213.Out Injection Volume: 25.00 Injection Type: Unknown Dilution Factor. > 1.0 Instrument Method: Mikey Cations 12min Operator. scthieken In'.Date/Time: 07-Nov-2022 1 22:02 Run Time: 12.00 7.00 '?1 Mikey386#37 1122-041.R213.Out ECD_1 6.00 5.00 U 4.00 0 c 0 0- W 3.00 D' 2.00 0 m 1.00 0 E E Q -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS ug/mL Assigned? Ammonia 2 4.100 Ammonia 0.006 0.018 n.a. FALSE I FALSE Chromeleon(c)Dionex 1996-2009 ITM-o2N�VhXg-'021420-RT-1303 Appendix C- Page 140 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 38 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R213.Out, Injection Volume:_ 25.00 Injection Type: Unknown Dilution Factor. 1.0 Instrument Method. Mikey'Cations 12min Operator scthieken In bate/Time: 07-Nov-2022 / 22:16 Run Time: 12.00 7.00 Mikey386#38 1122-041.R213.Out ECD_1 6.00 5.00 U 4.00 a) c 0 o. GO) 3.00 0_ 2.00 0 m 'c 1.00 0 E Q -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.107 Ammonia 0.007 0.019 0.00296 FALSE FALSE Chromeleon(c)Dionex 1996-2009 Version 7.2.8.10783 CTM-O�N/1nIe �tiQn021420-RT-1303 Appendix C- Page 141 of 1178 Logged on User:scthieken Page 39 of 51 Instrument:Mikey 11/8/2022 7:44AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R311.Out Injection Volume: 25.00 Injection Type: Unknown Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator.- scthieken In'.Date/Time: 07-Nov-2022 / 22:29 Run Time: 12.00 7.00 Mikey386#39 1122-041.R311.0ut ECD—1 6.00 ti N 5.00 �r m c 0 Q 4.00 E 0 Q c �W 0 W 3.00 r� 2.00 1.00 -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.247 Ammonia 1.053 3.341 5.36108 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-0?N/IEr&M92-021420-RT-1303 Appendix C- Page 142 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 40 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R311.Out`: Injection Volume: 25.00 Injection Type: Unknown Dilution Factor 1.0 Instrument Method. Mikey Cations 12min Operator scthieken' In' Date/Time: 07-Nov-2022 / 2243 Run Time: 12.00 7.00 Mikey386#40 1122-041.R311.0ut ECD_1 6.00 co v N 5.00 v as 0 U 4.00 Q a) c R� 0 CL W 3.00 ry 2.00 1.00 -0.10 _ 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.243 Ammonia 1.064 1 3.356 5.43336 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-o?NJ�ffi7 ign021420-RT-1303 Appendix C-Page 143 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 41 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.11312.Out Injection Volume: 25.00 Injection Type: Unknown Dilution Factor 1.0 Instrument Method: Mikey Cations 12min'< Operator. scthieken In'.Date/Time: 07-Nov-2022- / 22:57- - Run Time: 12.00 7.00 1 Mikey386#41 1122-041.R312.Out ECD_1 6.00 5.00 z 4.00 0 CD c 0 0- ,u) 3.00 ry co 2.00 m c 0 E 1.00 E Q -0.10 ' 2.60 3.00 4.00 5.60 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min uS*min PS pg/mL Assigned? Ammonia 2 4.153 Ammonia 0.154 0.460 0.54752 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 1TM-0?iv7/ q 9-'021420-RT-1303 Appendix C-Page 144 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 42 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R312.Out Injection Volume: 25.00 Injection Type: Unknown Dilution Factor. 1.0 Instrument Method: Mikey Cations 12min Operator: scthieken In'I Date/Time: 07-Nov-2022 / 23:10 Run Time: 12.00 7.00 Mikey386#42 1122-041.R312.Out ECD_1 6.00 5.00 U 4.00 a> c O Q 3.00 0_ 0 2.00 c� G O E 1.00 E Q i -0.10 2.00 3.00 4.60 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS pg/mL Assigned? Ammonia 2 4.150 Ammonia 0.153 0.461 0.54460 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-OJVtlntelglgtiQn Version 7.2.8.10783 021420-RT-1303 Appendix C-Page 145 of 1178 Logged on User:scthieken Page 43 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#4 Injection Volume: LOO Injection Type: ' Check Standard Dilution Factor.Instrument Method. Mikey Cations 12min Operator. n In'.Date/Time:' 07-Nov-2022` 123:24' Run Time: _J 7.00 Mikey386#43 HPLCSTDs1419#4 ECD_1 6.00 5.00 ) 4.00 a� N o c ap O N m 3.00 0_ m c O E 2.00 Q 1.00 -0.10 2.00 3.60 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.280 Ammonia 0.354 1.424 1.39633 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 CTM-09NLIffiatign021420-RT-1303 Appendix C-Page 146 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 44 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#4 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor 1.0 Instrument Method., Mikey Cations 12min "Operator: scthieken In.Date/Time: 07-Nov-2022 / 23:38 Run Time: 12.00 7.00 i, Mikey386#44 HPLCSTDs1419#4 ECD_1 6.00 5.00 s 4.00 a� c ccoo CL N 3.00 a' cm -E 0 E 2.00 E Q 1.00 -0.10 2.60 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS pg/mL Assigned? Ammonia 2 4.280 Ammonia 0.360 1 1.429 1.42597 FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-ORe'Ig 92-021420-RT-1303 Appendix C-Page 147 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 45 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name 1122-041I.R313.0ut Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: Mikey Cations 12min `: Operator. scthieken In',Date/Time: 07-Nov-2022 / 23:51 Run Time: 12.00 7.00 Mikey386#45[manually integrated] 1122-041.R313.Out ECD 1 6.00 5.00 4.00 ro W c 0 Q aui 3.00 0_ 2.00 Cl) 0 v Cu 1.00 E E Q -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: II SJT 11/08/2022 Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min PS pg/mL Assigned? Ammonia 3 4.073 Ammonia M10 0.020 1 0.01265 FALSE I TRUE Chromeleon(c)Dionex 1996-2009 CTM-02N�e1` g'021420-RT-1303 Appendix C-Page 148 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 46 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.R313.Out" Injection Volume: 25.00 Injection Type: Unknown Dilution'Factor. 1.0 Instrument Method. Mikey Cations 12min Operator. scthieken In".`Date/Time: 08-Nov-2022 / 00:05 Run Time: 12.00 Mikey386#46 1122-041.R313.Out ECD 1 7.00 — 6.00 5.00 Q 4.00 (D c 0 o- (w 3.00 o! 2.00 Co 0 v m 1.00 E E Q -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*min 1 PS pg/mL Assigned? Ammonia 2 4.080 Ammonia 0.006 1 0.014 n.a. FALSE FALSE Chromeleon(c)Dionex 1996-2009 CTM-02N/Elr&hX9-'021420-RT-1303 Appendix C- Page 149 of 1178 version 7.2.8.10783 Logged on User:scthieken Page 47 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.Bik.NH3 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor, 1.0 Instrument Method: Mikey Cations 12min Operator scthieken In'.Date/Time: 08-Nov-2022 / 00:19 Run Time: 12.00 7.00 Mikey386#47[manually integrated] 1122-041.Bik.NH3 ECD_1 6.00 5.00 U. 4.00 ro c C Q au) 3.00 af 2.00 rn Cl) m 1.00 0 E E Q -0.10 J. 2.00 3.00 4.00 5.60 6.00 7.00 Time[min] Analyst Comment: II SJT 11/08/2022 Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min Ns*min PS Ng/mL Assigned? Ammonia 1 3.790 Ammonia 0.001 0.004 n.a. FALSE I TRUE Chromeleon(c)Dionex 1996-2009 CTM-024t1ttteAL7tign021420-RT-1303 Appendix C-Page 150 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 48 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: 1122-041.Bik.NH3 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor. 1.0 'l Instrument Method: Mikey Cations 12min Operator scthieken In:`Date/Time: 08-Nov-2022 /'00:32 Run Time. 12.00 7.00 Mikey386#48[manually integrated] 1122-041.Blk.NH3 ECD_1 6.00 5.00 � 4.00 a> c C Q u) 3.00 2.00 oN CR co m C 1.00 E E Q -0.10 2.00 3.60 4.60 5.60 6.00 7.60 Time[min] Analyst Comment: II SJT 11/08/2022 Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS*min PS lag/mL Assigned? Ammonia 1 3.820 Ammonia 0.002 0.005 n.a. FALSE TRUE Chromeleon(c)Dionex 1996-2009 CTM-02N(JtMatign021420-RT-1303 Appendix C-Page 151 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 49 of 51 Instrument:Mikey 11/8/2022 7:44 AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#5 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor. 1.0 Instrument Method., Mikey Cations 12min Operator. scthieken Inj.Date/Time: 08-Nov-2022 1 00:46 Run Time: 12.00 7.00 Mikey386#49 HPLCSTDs1419#5 ECD_1 6.00 5.00 N rf' 4.00 (6 N O E O E � a) 3.00 of 2.00 1.00 -0.10 2.00 3.00 4.00 5.60 6.60 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min NS*Min PS pg/mL Assigned? Ammonia 2 4.287 Ammonia 0.723 2.656 3.29871 FALSE I FALSE Chromeleon(c)Dionex 1996-2009 1T1-'i4!>;eA 9-'021420-RT-1303 Appendix C-Page 152 of 1178 Version 7.2.8.10783 Logged on User:scthieken Page 50 of 51 Instrument:Mikey 11/8/2022 7:44AM Sequence:Mikey386 Peak Analysis Report Sample Name: HPLCSTDs1419#5 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor 1.0 Instrument Method: Mikey Cations 12min Operator. scthieken In?'Date/Time: 08-Nov-2022 / 01:00 Run Time: 12.00 7.00 Mikey386#50 HPLCSTDs1419#5 ECD_1 6.00 5.00 0 ao N U 4.00 'c a> o E Q E au) 3.00 0' C�J 2.00 1.00 -0.10 2.00 3.00 4.00 5.00 6.00 7.00 Time[min] Analyst Comment: Peak Name No. Time Peak Name Area Height Amount Manually Manipulated? min pS"min PS pg/mL Assigned? Ammonia 2 4.280 Ammonia 0.721 1 2.647 3.28403 FALSE FALSE Chromeleon(c)Dionex 1996-2009 Version 7.2.8.10783 CTM-0?N/1nig W!92-021420-RT-1303 Appendix C- Page 153 of 1178 NE01 3AS-021420-RT-1 303 Appendix C- Page 154 of 1178 • Montrose Air ty Services, LLC — Newburyport 2 New Pasture Road Unit #5 Newburyp ort, MA 01950 Wheelabrator North Andover Client Project # POJ-02120 Analytical Report ( 1022- 157) EPA Method 2" Hydrogen Chloride EPA Method CTM-027 Ammonia Enthalpy Analytical, LLC e; Phone: (919) 850-4392 / Fax: (919) 850 -9012 / www.enthalpy.com _. 800-1 Capitola Drive Durham, NC 27713-4385 I certify that to the best of my knowledge all analytical data presented in this report: • Have been checked for completeness • Are accurate, error-free, and legible • Have been conducted in accordance with approved protocol, and that all deviations and analytical problems are summarized in the appropriate narrative(s) This analytical report was prepared in Portable Document Format (.PDF) and contains 193 pages. �f i'-% n rN _ r-r _ _r_ _ -- - -1 1- _ _ _ •r_ _ _ UM Meview P erl'u- ITIeC.1 Uy — JC(IIIIICI Bowke1 Report Issued: 11/7/2022 NE01 3AS-021420-RT-1 303 EAMWO ci e1lff(2bfl4 93 NE01 3AS-021420-RT-1 303 Appendix C-Page 157 of 1178 Enthalpy Analocal Company: Montrose Air Quality Services, LLC - Newburyport Job No.: 1022-157 EPA Method 26A Analysis Client No.: PROJ-021420 Site: Wheelabrator North Andover Summary Table Sample ID Hydrogen Chloride Catch Weight(ug) M26A R1 321,223 M26A R2 828,949 M26A R3 753,347 1022-157 EPA Method 26A 1 NE013AS-021420-RT-1303 Appendix C- Page 158 of 1178 Enthalpy Analytical Company: Montrose Air Quality Services, LLC- Newburyport Job No.: 1022-157 EPA Method 26A Analysis Client No.: PROJ-021420 Site: Wheelabrator North Andover TableSummary Sample ID Hydrogen Chloride Catch Weight(ug) M26A/CTM R1 Imp1-4 9,829 M26A/CTM R2 Imp1-4 4,753 M26A/CTM R3 Imp1-4 15,423 1022-157 EPA Method 26A 2 NE013AS-021420-RT-1303 Appendix C-Page 159 of 1178 Enthalpy Analytical Company: Montrose Air Quality Services, LLC- Newburyport Job No.: 1022-157 EPA CTM-027 Analysis Client No.: PROJ-021420 Site: Wheelabrator North Andover Summary Table Sample ID Ammonia Catch Weight(ug) M26A/CTM R1 Imp1-4 1,007 M26A/CTM R2 Imp1-4 919 M26A/CTM R3 Imp1-4 586 1022-157 EPA CTM-027 NE013AS-021420-RT-1303 Appendix C- Page 160 of 1178 NE01 3AS-021420-RT-1 303 Appendix C-Page 161 of 1178 Enthalpy Analytical Company: Montrose Air Quality Services, LLC-Newburyport Job No.: 1022-157 EPA Method 26A Analysis Client No.: PROJ-021420 Site:Wheelabrator North Andover HydrogenlChloride Filename Filename MDL Curve Curve Ret. Ret. %dill. Conc. Conc. %dill. Avg. Liquid Conv. Catch Sample ID #1 #2 (ug/mL) Min. Max. Time Time RT #1 #2 conc. Conc. DF Vol. Factor Weight Flag pH (ug/mL) (ug/mL) (min.) (min.) (ug/mL) (ug/mL) (ug/mL) (mL) (ug) M26A R1 025 026 0.0500 0.500 30.0 4.44 4.44 0.0 4.28 4.29 0.0 4.28 100 729 1.028 321,223 0 M26A R2 031 032 0.0500 0.500 30.0 4.45 4.44 0.1 11.1 11.1 0.2 11.1 100 725 1.028 828,949 0 M26A R3 033 034 0.0500 0.500 30.0 4.44 4.44 0.0 10.8 10.8 0.1 10.8 100 680 1.028 753,347 0 1022-157 EPA Method 26A 1 NE01 3AS-021420-RT-1 303 Appendix C-Page 162 of 1178 Enthalpy Analytical Company:Montrose Air Quality Services, LLC-Newburyport Job No.: 1022-157 EPA Method 26A Analysis Client No.:PROJ-021420 Site:Wheelabrator North Andover Matrixcove /o Ret. Ret. o Conc. Conc. o/o Avg. Catch Filename Filename diff. diff. Vol. Enthalpy Sample ID Compound #1 #2 Time Time RT #1 #2 conc. Conc. DF (ml-) Weight Flag (min.) (min.) (ug/mL) (ug/mL) (ug/mL) (ug) MS/M26A R1 Chloride 027 028 4.44 4.44 0.0 8.49 8.71 1.3 8.60 1 0.800 6.88 Native Amount(ug): 3.26 Mass Spiked: 4.00 Recovery(%): 90.5 MSD/M26A R1 Chloride 029 030 4.44 4.44 0.0 8.46 8.64 1.0 8.55 1 0.800 6.84 Native Amount(ug): 3.26 Mass Spiked: 4.00 Recovery(%): 89.7 1022-1 17 EPA Method 26A 1 M AS-021420-RT-1303 Appendix C- : 163 of 1178 Enthalpy Analytical Company:Montrose Air Quality Services, LLC-Newburyport Job No.: 1022-157 EPA Method 26A Analysis Client No.:PROJ-021420 Site:Wheelabrator North Andover Hydrogen1 rl as Chloride %dill.%dill Filename Filename MDL Curve Curve Ret. Ret. Conc. Conc. Avg, Liquid Conv Catch . Sample ID #1 #2 (ug/mL) Min. Max. Time Time RT. #1 #2 conc. Conc. DF Vol. Factor Weight Flag pH (ug/mL) (ug/mL) (min.) (min.) (ug/mL) (ug/mL) (ug/mL) (mL) (ug) M26A/CTM R1 Imp1 035 036 0.0500 0.500 30.0 4.44 4.44 0.0 8.05 8.03 0.1 8.04 5 226 1.028 9,341 0 M26A/CTM R1 Imp2 037 038 0.0500 0.500 30.0 4.45 4.45 0.0 0.358 0.358 0.1 0.358 5 211 1.028 388 J 0 M26A/CTM R1 Imp3 039 040 0.0500 0.500 30.0 4.52 4.51 0.1 0.0744 0.0842 6.2 0.0793 5 159 1.028 64.8 J 0 M26A/CTM R1 Imp4 041 042 0.0500 0.500 30.0 4.45 4.45 0.0 0.119 0.106 5.7 0.113 5 60.0 1.028 34.8 J 6 9,829 M26A/CTM R2 Imp1 043 044 0.0500 0.500 30.0 4.44 4.44 0.0 3.68 3.65 0.4 3.67 5 235 1.028 4,432 0 M26A/CTM R2 Imp2 047 048 0.0500 0.500 30.0 4.46 4.46 0.0 0.206 0.205 0.3 0.206 5 214 1.028 226 J 0 M26A/CTM R2 Imp3 049 050 0.0500 0.500 30.0 4.52 4.52 0.0 0.0745 0.0718 1.8 0.0732 5 164 1.028 61.7 J 0 M26A/CTM R2 Imp4 051 052 0.0500 0.500 30.0 4.44 4.45 0.1 0.117 0.115 0.7 0.116 5 56.0 1.028 33.3 J 7 4,753 M26A/CTM R3 Imp1 053 054 0.0500 0.500 30.0 4.44 4.44 0.0 13.1 13.1 0.3 13.1 5 216 1.028 14,559 0 M26A/CTM R3 Imp2 055 056 0.0500 0.500 30.0 4.44 4.45 0.0 0.557 0.552 0.5 0.555 5 245 1.028 699 0 M26A/CTM R3 Imp3 057 058 0.0500 0.500 30.0 4.48 4.48 0.0 0.116 0.109 3.4 0.113 5 199 1.028 115 J 0 M26A/CTM R3 Imp4 059 060 0.0500 0.500 30.0 4.45 4.45 0.0 0.101 0.0940 3.6 0.0975 5 100 1.028 50.1 J 6 15,423 1022-157 EPA Method 26A 2 NE013AS-021420-RT-1303 Appendix C- Page 164 of 1178 Enthalpy Analytical Company: Montrose Air Quality Services, LLC-Newburyport Job No.: 1022-157 EPA CTM-027 Analysis Client No.: PROJ-021420 Site:Wheelabrator North Andover Ammonia Filename Filename MDL /o Curve Curve Ret. Ret. o /o diff Conc. Conc. odiff. Avg. Liquid Catch Sample ID #1 #2 (ug/mL) Min. Max. Time Time RT . #1 #2 conc. Conc. DF Vol. Weight Flag pH (ug/mL) (ug/mL) (min.) (min.) (ug/mL) (ug/mL) (ug/mL) (mL) (ug) M26A/CTM R1 Imp1 022 023 0.0200 0.189 11.8 4.25 4.25 0.0 4.29 4.29 0.0 4.29 1 226 969 0 M26A/CTM R1 Imp2 028 029 0.0200 0.189 11.8 4.19 4.18 0.1 0.154 0.154 0.1 0.154 1 211 32.5 J 0 M26A/CTM R1 Imp3 030 031 0.0200 0.189 11.8 4.15 4.15 0.0 0.0359 0.0365 0.8 0.0362 1 159 5.75 J 0 M26A/CTM R1 Imp4 032 033 0.0200 0.189 11.8 N/A N/A N/A 0.0200 0.0200 N/A 0.0200 1 60.0 1.20 ND 6 1,007 M26A/CTM R2 Imp1 034 035 0.0200 0.189 11.8 4.26 4.25 0.1 3.79 3.80 0.1 3.79 1 235 891 0 M26A/CTM R2 Imp2 036 037 0.0200 0.189 11.8 4.19 4.18 0.1 0.130 0.130 0.1 0.130 1 214 27.9 J 0 M26A/CTM R2 Imp3 038 039 0.0200 0.189 11.8 N/A NIA N/A 0.0200 0.0200 N/A 0.0200 1 164 3.28 ND 0 M26A/CTM R2 Imp4 040 041 0.0200 0.189 11.8 N/A N/A N/A 0.0200 0.0200 N/A 0.0200 1 56.0 1.12 ND 7 919 M26A/CTM R3 Imp1 044 045 0.0200 0.189 11.8 4.25 4.25 0.0 2.62 2.62 0.1 2.62 1 216 566 0 M26A/CTM R3 Imp2 046 047 0.0200 0.189 11.8 4.20 4.19 0.1 0.0825 0.0820 0.3 0.0823 1 245 20.2 J 0 M26A/CTM R3 Imp3 048 049 0.0200 0.189 11.8 N/A N/A N/A 0.0200 0.0200 N/A 0.0200 1 199 3.98 ND 0 M26A/CTM R3 Imp4 050 051 0.0200 0.189 11.8 N/A N/A N/A 0.0200 0.0200 N/A 0.0200 1 100 2.00 ND 6 586 1022-1 r-7 EPA CTM-027 N. 4S-021420-RT-1303 Appendix C- ; 165 of 1178 Enthalpy Analytical Company: Montrose Air Quality Services,LLC-Newburyport Job No.: 1022-157 EPA CTM-027 Analysis Client No.: PROJ-021420 Site:Wheelabrator North Andover Matrix Spike Recovery %dill Filename Filename Ret. Ret. Conc. Conc. %dill. g' Vol.Avg. Catch Enthalpy Sample ID Compound #1 #2 Time Time RT. #1 #2 conc. Conc. DF (mL) Weight Flag (min.) (min.) (ug/mL) (ug/mL) (ug/mL) (ug) MS/M26A/CTM R1 Imp1 Ammonia 024 025 4.25 4.25 0.0 8.73 8.73 0.0 8.73 1 0.800 6.98 Native Amount(ug): 3.26 Mass Spiked: 4.00 Recovery(%): 93.1 MSD/M26A/CTM R1 Imp1 Ammonia 026 027 4.25 4.25 0.0 8.84 8.83 0.1 8.83 1 0.800 7.07 Native Amount(ug): 3.26 Mass Spiked: 4.00 Recovery(%): 95.2 1022-157 EPA CTM-027 NE01 3AS-021420-RT-1 303 Appendix C-Page 166 of 1178 NE01 3AS-021420-RT-1 303 Appendix C- Page 167 of 1178 Enthalpy Analytical Narrative Summary Job _w .___________ Company 1 Montrose Air Quality Services, LLC - Newburyport No. 1022-157 EPA Method 26AAnalysis Client ID. PROJ-021420 Site: Wheelabrator North Andover Custody Alyssa Miller received the samples on October 25, 2022 at 3.7 °C after being relinquished by Montrose Air Quality Services, LLC - Newburyport. The samples were received in good condition. I Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, LLC. Analysis The samples were analyzed for chloride using the analytical procedures in Section 11.0 of EPA Method 26A, Determination of Hydrogen Halide and Halogen Emissions from Stationary Sources Isokinetic Method. E All sample aliquots and standards are prepared, stored and analyzed using high-density polyethylene containers. Client samples are retained in the container as received. Sample catch weight results were determined using the sample volumes measured by the laboratory. The Dionex Ion Chromatograph "Raphael" equipped with a Conductivity Detector was used for these analyses_ Calibration The calibration curves are included in the Raw Data section of this report.A I quadratic curve type was used instead of the method-specified linear curve. __ ----- ___-- -____-- __-_ ------- ---- ' Chrom The acquisition method AS22 ASAP was used for the Chloride analyses and I Conditions may be made available upon request. QC Notes The samples were analyzed within the 28-day holding time specified by the f method. The analyses of the laboratory reagent blanks did not contain hydrogen chloride at concentrations greater than the LOQ. 3 Duplicate matrix spikes were prepared using aliquots of M26A R1 and met method spike recovery criteria of 80-120%. The analysis of second source standards also served as laboratory control I samples and met the laboratory acceptance criteria of±5% of the tag value. NE01 3AS-021420-RT-1 303 Appendix C- Page 168 of 1178 Enthalpy Analytical Narrative Summary Company Montrose Air Quality Services, LLC - Newburyport Job No. 1022-157 EPA Method 26AAnalysis Client ID. I PROJ-021420 Site: Wheelabrator North Andover Reporting The samples were analyzed for chloride but the results have been reported Notes i as hydrogen chloride. The results were converted using factors of 1.028 respectively to account for the additional hydrogen mass. These analyses met the requirements of the TNI Standard.Any deviations from the requirements of the reference method or TNI Standard have been stated above. The results presented in this report are representative of the samples as I provided to the laboratory. NE013AS-021420-RT-1303 Appendix C- Page 169 of 1178 Enthalpy Analytical Narrative Summary I Company Montrose Air Quality Services, LLC - Newburyport Job No. 1022-157 EPA CTM-027 Analysis Client ID. PROJ-021420 Site: Wheelabrator North Andover I Custody Alyssa Miller received the samples on October 25, 2022 at 3.6 °C after being relinquished by Montrose Air Quality Services, LLC - Newburyport. The samples were received in good condition. i I Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, LLC. Analysis I The samples were analyzed for ammonia using the analytical procedures in Section 4.2, Sample Analysis, of EPA Conditional Test Method 027, Procedure for Collection and Analysis of Ammonia in Stationary Sources. Sample catch weight results were determined using the sample volumes measured by the laboratory. 1 The sample fractions were not brought up to the method-specified volume of i 250 mL. This preserves lower detection limits and removes a possible source of contamination. The Thermo Ion Chromatograph "Mikey" equipped with a Conductivity ( Detector was used for these analyses. Calibration The calibration curves are included in the Raw Data section of this report Chrom. The Instrument Method Mikey Cations 9min was used for the ammonia i Conditions analyses and may be made available upon request. j QC Notes The samples were analyzed within the 14-day holding time specified by the method. i The analyses of the laboratory reagent blanks did not contain ammonia at concentrations greater than the LOQ. } i Duplicate matrix spikes were prepared using aliquots of M26A/CTM R1 Imp1 and met method spike recovery criteria of 80-120%. E The analysis of second source standards also served as laboratory control samples and met the laboratory acceptance criteria of±10% of the tag value. Reporting' These analyses met the requirements of the TNI Standard.Any deviations Notes from the requirements of the reference method or TNI Standard have been stated above. i The results presented in this report are representative of the samples as provided to the laboratory. NE013AS-021420-RT-1303 Appendix C-Page 170 of 1178 General Reporting es The following are general reporting notes that are applicable to all Enthalpy Analytical, LLC data reports, unless specifically noted otherwise. • Any analysis which refers to the method as "Type" represents a planned deviation from the reference method. For instance a Hydrogen Sulfide assay from a Tedlar bag would be labeled as "EPA Method 16-Type" because Tedlar bags are not mentioned as one of the collection options in EPA Method 16. • The acronym MDL represents the Minimum Detection Limit. Below this value the laboratory cannot determine the presence of the analyte of interest reliably. • The acronym LOQ represents the Limit of Quantification. Below this value the laboratory cannot quantitate the analyte of interest within the criteria of the method. • The acronym ND following a value indicates a non-detect or analytical result below the MDL. • The letter J in the Qualifier or Flag column in the results indicates that the value is between the MDL and the LOQ. The laboratory can positively identify the analyte of interest as present, but the value should be considered an estimate. • The letter E in the Qualifier or Flag column indicates an analytical result exceeding 100% of the highest calibration point. The associated value should be considered as an estimate. • Sample results are presented `as measured' for single injection methodologies, or an average value if multiple injections are made. If all injections are below the MDL, the sample is considered non-detect and the ND value is presented. If one, but not all, are below the MDL, the MDL value is used for any injections that are below the MDL. For example, if the MDL is 0.500 and LOQ is 1.00, and the instrument measures 0.355, 0.620, and 0.442 - the result reported is the average of 0.500, 0.620, and 0.500 - - - i.e. 0.540 with a J flag. • When a spike recovery (Bag Spike, Collocated Spike Train, or liquid matrix spike) is being calculated, the native (unspiked) sample result is used in the calculations, as long as the value is above the MDL. If a sample is ND, then 0 is used as the native amount (not the MDL value). • The acronym DF represents Dilution Factor. This number represents dilution of the sample during the preparation and/or analysis process. The analytical result taken from a laboratory instrument is multiplied by the DF to determine the final undiluted sample results. • The addition of MS to the Sample ID represents a Matrix Spike. An aliquot of an actual sample is spiked with a known amount of analyte so that a percent recovery value can be determined. The MS analysis indicates what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample matrix interferes with the analysis of the analyte(s). NE013AS-021420-RT-1303 Appendix C- Page 171 of 1178 Generala rtNotes (continued) • The addition of MSD to the Sample ID represents a Matrix Spike Duplicate. Prepared in the same manner as a MS, the use of duplicate matrix spikes allows further confirmation of laboratory quality by showing the consistency of results gained by performing the same steps multiple times. • The addition of LD to the Sample ID represents a Laboratory Duplicate. The analyst prepares an additional aliquot of sample for testing and the results of the duplicate analysis are compared to the initial result. The result should have a difference value of within 10% of the initial result(if the results of the original analysis are greater than the LOQ). • The addition of AD to the Sample ID represents an Alternate Dilution. The analyst prepares an additional aliquot at a different dilution factor (usually double the initial factor). This analysis helps confirm that no additional compound is present and coeluting or sharing absorbance with the analyte of interest, as they would have a different response/absorbance than the analyte of interest. • The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample matrix, prepared and analyzed by the laboratory using the same reagents, spiking standards and procedures used for the client samples. The LCS is used to assess the control of the laboratory's analytical system. Whenever spikes are prepared for our client projects, two spikes are retained as LCSs. The LCSs are labeled with the associated project number and kept in-house at the appropriate temperature conditions. When the project samples are received for analysis, the LCSs are analyzed to confirm that the analyte could be recovered from the media, separate from the samples which were used on the project and which may have been affected by source matrix, sample collection, and/or sample transport. • Significant Figures: Where the reported value is much greater than unity (1.00) in the units expressed, the number is rounded to a whole number of units, rather than to 3 significant figures. For example, a value of 10,456.45 ug catch is rounded to 10,456 ug. There are five significant digits displayed, but no confidence should be placed on more than two significant digits. In the case of small numbers, generally 3 significant figures are presented, but still only 2 should be used with confidence. Many neat materials are only certified to 3 digits, and as the mathematically correct final result is always 1 digit less than all its pre-cursors - 2 significant figures are what are most defensible. • Manual Integration: The data systems used for processing will flag manually integrated peaks with an "M". There are several reasons a peak may be manually integrated. These reasons will be identified by the following two letter designations on sample chromatograms, if provided in the report. The peak was not integrated by the software "NI", the peak was integrated incorrectly by the software "II" or the wrong peak was integrated by the software " P". These codes will accompany the analyst's manual integration stamp placed next to the compound name on the chromatogram. l vJ f i NE013AS-021420-RT-1303 Appendix C- Page 172 of 1178 { (t NE013AS-021420-RT-1303 Appendix C- Page 173 of 1178 Chain Custody Form - Source Page_1_of l Z ANALYSIS REQUESTED `o Company Name: Montrose Air Quality Services Q CLIENT m Project Manager Michael Brunt w INFORMATION e-mail: mbruni&amontrose-env.com m c Address: 2 New Pasture Road SECTION Newburyport, MA 01950 m o a Phone: (978)499-9300 Fax (978)499-9303 < v Cell: 339-206-2376 v 'o Sampled by: Michael Bruni t C = 6 d � z � Initial Impinger Collection Charge Laboratory use only! Field Sample ID #Bottles Collection Date Time volumes tmLi' Fraction U2-SDA In-M26A-R1 1 10/18/2022 1 250 X 14 Imp Contents&Rinse - U2-SDA In-M26A-R2 1 10/18/2022 250 X 1-4 Imp Contents&Rinse U2-SDA In-M26A-R3 1 10/19/2022 250 X I 1 1 A Imp Contents&Rinse TAT Requirement PROJECT INFORMATION REPORTING REQUIREMENTS PROJECT SPECIFIC COMMENTS STD 10 Business day ❑ Project#: C 21420 Summary Report only ❑ Method 26A Analysis (Wheelabroator N.Andover) Rush 5 Business day ❑ Name: Wheelabrator North Andover Summary Report & ❑ Method CTM-027 Analysis (Wheelabroator N.Andover) Rush 2 Business day ❑ PO#: Full Data Package Rush 1 Business day ❑ EDD E Other(specify): 'Initial Impinger charge volumes are required before the following analysis t4';'?2 can be started:Method 26,CTM-027&Method 8 Relinquished By DateiTime it j� �"' Received byap MALaj, Method 231 T09A Relinquished By Datellime Received by NATO TEF ❑ TEF x DL ❑ TEF x 0 DL ❑ Relinquished By Date/Time Received by WHO TEF ❑ TEF x 0.5 DL ❑ NE013AS-021420-RT-1303 Appendix C-Page 174 of 1178 Chain of CustodyFor - Source Page_2_of_2_ ANALYSIS REQUESTED Company Name: Montrose Air Quality Services CLIENT m Project Manager: Michael Bruni T INFORMATION e-mail: mbrunilMmontrose-env.com a o Address: 2 New Pasture Road N c o SECTION Newburyport,MA 01950 z ~ o Phone: (978)499-9300 Fax: (978)499-9303 2 Cell: 339-206-2376 v m Sampled by: Michael Bruni t Initial Impinger Collection Charge Laboratory use only Field Sample ID #Bottles Collection Date Time volumes(mi)* Fraction U2-FF Out-M26A/CTM-027-R1-Imp 1 1 10/18/2022 50 1 X Imp 1 Contents&Rinse U2-FF Out-M26A/CTM-027-Rt-Imp 2 1 10/18/2022 100 X Imp 2 Contents&Rinse U2-FF Out-M26A/CTM-027-R1-Imp 3 1 10/18/2022 100 X I Imp 3 Contents&Rinse U2-FF Out-M26A/CTM-027-R1-Imp 4 1 10/18/2022 0 X Imp 4 Contents&Rinse U2-FF Out-M26AICTM-027-R2-Imp 1 1 10/18/2022 50 X Imp 1 Contents&Rinse U2-FF Out-M26A/CTM-027-R2-Imp 2 1 10/18/2022 100 X Imp 2 Contents&Rinse U2-FF Out-M26A/CTM-027-R2-Imp 3 1 10/18/2022 100 X Imp 3 Contents&Rinse U2-FF Out-M26A/CTM-027-R2-Imp 4 1 10/18/2022 0 X Imp 4 Contents&Rinse U2-FF Out-M26A]CTM-027-R3-Imp 1 1 10/19/2022 50 X Imp 1 Contents&Rinse U2-FF Out-M26A/CTM-027-R3-Imp 2 1 10/19/2022 100 X Imp 2 Contents&Rinse U2-FF Out-M26AJCTM-027-R3-Imp 3 1 10/19/2022 1 100 X Imp 3 Contents&Rinse U2-FF Out-M26A/CTM-027-R3-Imp 4 1 10/19/2022 0 X Imp 4 Contents&Rinse O TAT Requirement PROJECT INFORMATION REPORTING REQUIREMENTS PROJECT SPECIFIC COMMENTS STD 10 Business day 2 Project#: PROJ-021420 Summary Report only ❑ Method 26A/CTM-027 Analysis(Wheelabroator N.Andover) Rush 5 Business day ❑ Name: Wheelabrator North Andover Summary Report & ❑ Please hold Impinger 4 for analysis. Only analyze if it meets Rush 2 Business day ❑ PO#: Full Data Package breakthrough criteria for CTM-027. Rush 1 Business day D EDD 01 Other(specify): •Initial Impinger charge volumes are required before the following analysis Q Zi can be started: Method 26,CTM-027&Method 8 Relinquished By '• ` yc �j y �QQ�t,. Method 231 T09A r Daterrime } t ; �< ate; Received b , Relinquished By DatefTime Received by V NATO TEF ❑ TEF x DL ❑ TEF x 0 DL ❑ Relinquished By Date/Time Received by WHO TEF ❑ TEF x 0.5 DL ❑ bampvX 2 � t 2bN Ct Ylrl Ga i� C,br� dix y L t NE01 3AS-021420-RT-1 303 Appendix C- Page 176 of 1178 Logged on User:scthieken Page 9 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 15:36 Run Time: 14.50 30.0 Raphael1239#9 HPLCStds1433#6 ECD_1 PS � d- 25.0 0 2= U 20.0 v0i 15.0 0 a a) a! 10.0 5.0 min 2.60 3.00 4.00 5.00 6.00 7.00 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 1 4.46 Chloride 5.173 19.961 29,89029 FALSE FALSE ER13AS-021420-RT-1303 Appendix C-Page 177 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:scthieken Page 10 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Irj.Date/Time: 28-Oct-2022 / 15:52 Run Time: 14.50 Raphael1239#10 HPLCStds1433#6 ECD_1 30.0 PS LO �r 25.0 0 U 20.0 `7 uoi 15.0 c 0 n 10.0 5.0 min -1.0 2.00 3.00 4.60 5.60 6.60 7.60 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS Ng/mL 1 4.45 Chloride 5.093 19.471 29.51490 FALSE FALSE F6�13AS-021420-RT-1303 Appendix C-Page 178 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/[ntegr i Version 7.2.8.10783 Logged on User:scthieken Page 11 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-00-2022 / 16:08 Run Time: 14.50 30.0 Raphael1239#11 HPLCStds1433#5 ECD_1 PS 25.0 20.0 CY) rt 15.0 o CL o ro -C O U 10.0 ' m 5.0 min 2.00 3.60 4.60 5.60 6.00 7.00 8.00 Time [min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.44 Chloride 2.374 8.864 15,15172 FALSE FALSE f�E�13AS-021420-RT-1303 Appendix C-Page 179 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:scthieken Page 12 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Inj.Date/Time: 28-Oct-2022 / 16:24 Run Time: 14.50 Raphae11239#12 HPLCStds1433#5 ECD 1 30.0 pS 25.0 20.0 .J v 15.0 o •` Q- o � U 10.0 5.0 min 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS"min NS pg/mL 1 4.45 Chloride 2.368 8.925 15.11496 FALSE FALSE g M,;R13AS-021420-RT-1303 Appendix C- Page 180 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 13 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken /2L.Date/Time: 28-Oct-2022 / 16:40 Run Time: 14.50 Raphael1239#13 HPLCStdsl433#4 ECD_1 30.0 pS 25.0 20.0 c 15.0 Cl)0 v C � o 10.0 L 0 U 17 5.0 min 2.00 3.00 4.60 5.60 6.60 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.499 5.645 9.85450 FALSE FALSE g MER13AS-021420-RT-1303 Appendix C-Page 181 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter io Version 7.2.8.10783 Logged on User:scthieken Page 14 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method. AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 16:57 Run Time: 14.50 30.0 ^` Raphael1239#14 HPLCStds1433#4 ECD_1 PS 25.0 20.0 c 15.0 o En a �r 10.0 0 U 5.0 i min 2.60 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 1 4.44 Chloride 1.502 5.646 9.87479 FALSE FALSE gFs�13AS-021420-RT-1303 Appendix C-Page 182 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 15 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStdsl433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 28-Oct-2022 / 17:13 Run Time: 14.50 30.0 Raphaell239#15 HPLCStdsl433#3 ECD_1 PS 25.0 20.0 ch 15.0 c 0 n 0 a� d. � d- 10.0 v a> 0 5.0 U 17 min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 0.712 2.713 4.81636 FALSE FALSE gFa�13AS-021420-RT-1303 Appendix C- Page 183 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 16 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 17:29 Run Time: 14.50 30.0 Raphael1239#16 HPLCStds1433#3 ECD 1 PS 25.0 20.0 05 15.0 c 0 Q- N Cl) N Nr O 10.0 d a� 0 2= 5.0 U min -1.0 2.00 3.60 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.715 2.728 4.83878 FALSE FALSE g �13AS-021420-RT-1303 Appendix C- Page 184 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 17 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 17:45 Run Time: 14.50 30.0 Raphael1239#17 HPLCStds1433#2 ECD 1 PS 25.0 20.0 obi 15.0 c 0 CL a� o! 10.0 �t m 5.0 -0 L _Q .L U min -1.0 2.00 3.00 4.00 5.00 6.00 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS Ng/mL 1 4.44 Chloride 0.136 0.523 0.96515 FALSE FALSE g MER13AS-021420-RT-1303 Appendix C-Page 185 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter io Version 7.2.8.10783 Logged on User:scthieken Page 18 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 118:01 Run Time: 14.50 30.0 Raphael1239#18 H1PLCStds1433#2 ECD_1 PS 25.0 20.0 u�i 15.0 c 0 0_ 0 a� a! 10.0 d a) 5.0 -0 0 U min -1.0 2.60 3.00 4.60 5.00 6.00 7.00 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 0.135 0.524 0.95797 FALSE FALSE g MgR13AS-021420-RT-1303 Appendix C- Page 186 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 19 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken L2L.Date/Time: 28-Oct-2022 / 18:17 Run Time: 14.50 30.0 Raphael1239#19 HPLCStds1433#1 ECD_1 PS 25.0 20.0 con 15.0 c 0 (D 10.0 ti v a) 5.0 0 U min 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 0.071 0.270 0.51828 FALSE FALSE gR13AS-021420-RT-1303 Appendix C-Page 187 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/integr i Version 7.2.8.10783 Logged on User:scthieken Page 20 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In Date/Time: 28-Oct-2022 / 18:33 Run Time: 14.50 _ Raphael1239#20 HPLCStds1433#1 ECD_1 30.0 pS 25.0 20.0 voi 15.0 c 0 Q W a) 10.0 co v m 5.0 70 0 s= U min 2.00 3.00 4.00 5.00 6.60 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.070 0.267 0.51523 FALSE FALSE MgR g l3AS-021420-RT-1303 Appendix C-Page 188 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter I Version 7.2.8.10783 Logged on User:scthieken Page 21 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 18:49 Run Time: 14.50 30.0 . Raphael1239#21 [manually integrated] ECD 1 PS 25.0 20.0 vWi 15.0 c n a`) 10.0 L U 5.0 rr i min -1.0 2.60 3.60 4.00 5.00 6.60 7.60 8.00 Time [min] Analyst Comment: II SJT 10/31/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min ea PS pg/mL 1 4.44 Chloride 1.076 4.148 7.18111 FALSE TRUE fNER13AS-021420-RT-1303 Appendix C-Page 189 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:scthieken Page 22 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 19:05 Run Time: 14.50 30.0 ' ' Raphael1239#22 [manually integrated] ECD_1 PS 25.0 20.0 voi 15.0 c 0 aa) tY � 10.0 a) 0 s U 5.0 '- min -1.0 2.60 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 10/31/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.073 4.147 7.16292 FALSE TRUE gFeR13AS-021420-RT-1303 Appendix C-Page 190 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 23 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 19:22 Run Time: 14.50 30.0 04 Raphael1239#23 HPLCStds1433#RB ECD_1 PS 25.0 20.0 of 15.0 c 0 n C0 a) 10.0 0 rn v 5.0 a) L O U `7 I min -1.0 2.60 3.60 4.60 5.00 6.00 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 1 4.49 Chloride 0.007 0.022 0.07927 FALSE FALSE g MFa�13AS-021420-RT-1303 Appendix C-Page 191 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 24 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 19:38 Run Time: 14.50 30.0 Raphael1239#24 HPLCStds1433#RB ECD— 1 PS 25.0 20.0 uoi 15.0 c 0 a 0 a� 10.0 M rn 5.0 0 U I I I min 2.00 3.60 4.00 5.00 6.60 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS Ng/mL 2 4.49 Chloride 0.006 0.023 0.07739 FALSE FALSE g MFe913AS-021420-RT-1303 Appendix C-Page 192 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter I Version 7.2.8.10783 Logged on User:scthieken Page 95 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 29-Oct-2022 / 14:42 Run Time: 14.50 Raphael1239#95 HPLCStds1433#6 ECD_1 30.0 CD PS 25.0 L O U 20.0 s 15.0 c 0 CL W 10.0 5.0 min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 5.209 19.932 30.05767 FALSE FALSE g MER13AS-021420-RT-1303 Appendix C- Page 193 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter io Version 7.2.8.10783 Logged on User:scthieken Page 96 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 29-Oct-2022 / 14:58 Run Time: 14.50 30.0 Raphael1239#96 HPLCStds1433#6 ECD_1 PS LO 25.0 0 .c 0 U P 20.0 u0i 15.0 c 0 o_ 0 10.0 5.0 min 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min NS pg/mL 1 4.45 Chloride 5.239 20.345 30.19689 FALSE FALSE g MgR13AS-021420-RT-1303 Appendix C- Page 194 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 97 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 29-Oct-2022 / 15:14 Run Time: 14.50 30.0 Raphael1239#97 HPLCStds1433#5 ECD_1 PS 25.0 20.0 ti d- � d: v(Di 15.0 c -0 0 N o a) U 10.0 5.0 min 2.60 3.00 4.00 5.00 6.60 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min NS pg/mL 1 4.45 Chloride 2.410 9.186 15.36067 FALSE FALSE g M,dR13AS-021420-RT-1303 Appendix C- Page 195 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 98 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken In•. Date/Time: 29-Oct-2022 / 15:30 Run Time: 14.50 30.0 Raphael1239#98 HPLCStds1433#5 ECD_1 PS 25.0 20.0 M obi 15.0 a� c � 0 N o � U 10.0 5.0 min -1.0 2.00 3.00 4.60 5.00 6.60 7.00 8.00 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4A4 Chloride 2.410 9.129 15.35737 FALSE FALSE ,;Rl3AS-021420-RT-1303 Appendix C-Page 196 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 99 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 29-00-2022 / 15:46 Run Time: 14.50 30.0 Raphael1239#99 HPLCStds1433#4 ECD_1 PS 25.0 20.0 s c 15.0 o C aD 10.0 0 U er 5.0 i min 2.00 3.60 4.00 5.00 6.00 7.00 8.60 Time[min] Analyst Comment: No. Time Peak Name Area Height Conic Manually Assigned? Manipulated? min pS*min PS lag/mL 1 4.44 Chloride 1.530 5.809 10.04927 FALSE FALSE M,dR13AS-021420-RT-1303 Appendix C- Page 197 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 100 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In Date/Time: 29-Oct-2022 / 16:02 Run Time: 14.50 30.0 Raphael1239#100 HPLCStds1433#4 ECD_1 PS 25.0 20.0 s 15.0 a`) 10.0 O U R 5.0 'IL-4-- min -1.0 2.00 3.00 4.00 5.00 6.60 7.60 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.528 5.810 10.03723 FALSE FALSE g MgR13AS-021420-RT-1303 Appendix C-Page 198 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 101 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 29-Oct-2022 / 16:18 Run Time: 14.50 30.0 Raphael1239#101 HPLCStds1433#3 ECD_1 PS 25.0 20.0 va)i 15.0 c 0 o 10.0 d aD v `o 5.0 U i min -1.0 2.00 3.60 4.60 5.00 6.00 7.00 8.00 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.726 2.799 4.91302 FALSE FALSE f�E�13AS-021420-RT-1303 Appendix C-Page 199 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:scthieken Page 102 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 29-Oct-2022 / 16:34 Run Time: 14.50 Raphael1239#102 HPLCStds1433#3 ECD_1 30.0 PS 25.0 20.0 u0i 15.0 c 0 n CM 01� d 10.0 d aD _o s 5.0 U '7 min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS lag/mL 1 4.44 Chloride 0.729 2.795 4.93367 FALSE FALSE gRl3AS-021420-RT-1303 Appendix C-Page 200 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 103 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 29-Oct-2022 / 16:51 Run Time: 14.50 30.0 Raphael1239#103 HPLCStds1433#2 ECD_1 PS 25.0 20.0 15.0 c 0 a aD 10.0 0 m 5.0 L 0 J-- U min -1.0 2.60 3.60 4.00 5.60 6.60 7.60 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.140 0.541 0.99426 FALSE FALSE FdR13AS-021420-RT-1303 Appendix C-Page 201 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 104 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In. Date/Time: 29-00-2022 / 17:07 Run Time: 14.50 Raphael1239#104 HPLCStds1433#2 ECD_1 30.0 pS 25.0 20.0 15.0 c 0 Q co m of 10.0 d- a) 5.0 0 U i m in -1.0 2.60 3.60 4.00 5.00 6.60 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS Ng/mL 1 4.44 Chloride 0.139 0.540 0.98638 FALSE FALSE F6R13AS-021420-RT-1303 Appendix C-Page 202 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 105 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 29-00-2022 / 17:23 Run Time: 14.50 Raphael1239#105 HPLCStds1433#1 ECD_1 30.0 NS 25.0 20.0 s 15.0 c 0 n W a� 10.0 M d- d- m 5.0 L _0 U min -1.0 2.60 3.60 4.60 5.00 6.60 7.60 8.00 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.071 0.275 0.52137 FALSE FALSE g MEdR13AS-021420-RT-1303 Appendix C-Page 203 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 106 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In. Date/Time: 29-00-2022 / 17:39 Run Time: 14.50 30.0 Raphael1239#106 HPLCStds1433#1 ECD_1 PS 25.0 20.0 uoi 15.0 c 0 n a� 10.0 M v v 0 5.0 0 U f 1 I I min 2.00 3.00 4.00 5.00 6.00 7.00 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.072 0.275 0.52511 FALSE FALSE g MRl3AS-021420-RT-1303 Appendix C-Page 204 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter I Version 7.2.8.10783 Logged on User:scthieken Page 1 of 2 Instrument:Raphael 10/31/2022 7:55 AM Sequence:Raphael1239 Calibration Table Pos. Level Ref.Amount Calibration Dil.Factor Volume No. Iniection Name In'ect Time Point Status pg/m L ECD_1 ECD_1 Chloride Chloride 9 HPLCStds1433#6 28/Oct/2022 15:36 BA6 06 30.0000 Ok 1.0000 25.00 10 HPLCStds1433#6 28/Oct/2022 15:52 BA6 06 30.0000 Ok 1.0000- 25.00 11 HPLCStds1433#5 28/Oct/2022 16:08 BA5 05 15.0000 Ok 1.0000 25.00 12 HPLCStds1433#5` 28/Oct/2022 16:24 BA5 05 15.0000 Ok 1.0000 25.00 13 HPLCStds1433#4 28/Oct/2022 16:40 BA4 04 10.0000 Ok 1.0000 25.00 14 HPLCStds1433#4 28/Oct/2022 16:57 BA4 04 10.0000 Ok 1.0000 25.00 15 HPLCStds1433#3' 28/Oct/2022 17:13 BA3 03 5.0000 Ok 1.0000 25.00 16 HPLCStds1433#3 28/Oct/2022 17:29 BA3 03 5.0000 Ok 1.0000 25.00 17 HPLCStds1433#2' 28/Oct/2022 17:45 BA2 02 1.0000 Ok 1.0000 25.00 18 HPLCStds1433#2' 28/Oct/2022 18:01' BA2 02 1.0000 Ok 1.0000 25`.00 19 HPLCStds1433#1 28/Oct/2022 18:17 BA1 01 0.5000 Ok 1.0000 25.00 20 HPLCStds1433#1 28/Oct/2022 18:33 BA1 01 0.5000 Ok 1.0000' 2500 95 HPLCStds1433#6 29/Oct/2022 14:42 BA6 06 30.0000 Ok 1.0000 2500 96 HPLCStds1433#6 29/Oct/2022 14:58 BA6 06 30.0000 Ok 1.0000 25.00 97 HPLCStds1433#5 29/Oct/2022 15:14 BA5 05 15.0000 Ok 1.0000 2500 98 HPLCStds1433#5 29/Oct/202215:30 BA5 05 15.0000 Ok 1.0000 25.00 99 HPLCStds1433#4 29/Oct/2022 15:46 BA4 04 10.0000 Ok 1.0000' 25;00 100 HPLCStds1433#4 29/Oct/2022 16:02 BA4 04 10.0000 Ok 1.0000 25.00 101 HPLCStds1433#3 29/Oct/2022 16:18 BA3 03 5.0000 Ok 1.0000 25.00 102 HPLCStds1433#3 29/Oct/2022 16:34 BA3 03 5.0000 Ok 1.0000 25.00 103 HPLCStds1433#2 29/Oct/2022 16:51 BA2 02 1.0000 Ok 1.0000 25.00 104 HPLCStds1433#2 29/Oct/202217:07 BA2 02 1.0000 Ok 1.0000 25.00 105 HPLCStds1433#1 29/Oct/2022 17:23 BA1 01 0.5000 Ok 1.0000 25.00 106 HPLCStds1433#1 29/Oct/2022 17:39 1 BA1 01 1 0.5000 Ok 1.0000` 25.00 Detection Parameters Ret.Time Param. Name Param.Value Inj.Type Channel min Always Baseline Noise Auto Range Off Any All Channels Always Baseline Noise Start Time 0.400[min] Any All Channels Always Baseline Noise End Time 0.700[min] Any All Channels Always Cobra Smoothing Width Auto Any All Channels Always Consider Void Peak Off Any All Channels 0.000 Maximum Rider Ratio 10[%] Any All Channels 0.000 Tailing Sensitivity Factor 0.500[%]' Any ` All Channels 0.000 Inhibit Integration On Any All Channels 0.000 Minimum Area Auto Any All Channels 4.018 Inhibit Integration Off Any All Channels 6.225 lInhibit Integration On lAny lAll Channels NIL aS-021420-RT-1303 Appendix C- 205 of 1178 Chromeleon(c) .1996-2009 9Anions/Calir-oon Details Verb-17.2.8.10783 Logged on User:scthieken Page 2 of 2 Instrument:Raphael 10/31/2022 7:55 AM Sequence:Raphael1239 Calibration Batch Report ince: Raphael1239 Injection Volume: 25.00 �. ment Method. AS22 ASAP Operator: scth eken Inj.Date/Time: 29-Oct-2022 114:09 Run Time: 14.5 Calibration iSummary Peak Name Eval.Type Cal.Type Points Offset Slope Curve Coeff.Det. CO (Cl) C2 % Chloride Area Quad WithOffset 1/A 24.000 0.034 6.872 -0.213 99.973 AVERAGE: 1 0.0341 6.8719 -0.2127 99.9734 Injection Name Ret.Time Area Height Amount 35.0 Chloride External ECD-1 min pS*min PS pg/mL pg/mL ECD 1 ECD 1 ECD 1 ECD 1 Chloride Chloride Chloride Chloride HPLCStds1433#6 4.460 5.173 19.961 29.890 30.0 HPLCStds1433#6 4.450 5.093 19.471 29.515 HPLCStds1433#5 4.443 2.374 8.864 15.152 HPLCStds1433#5 4.447 2.368 8.925 15.115 25.0 HPLCStds1433#4 4.443 1.499 5.645 9.855 HPLCStds1433#4 4.440 1.502 5.646 9.875 HPLCStds1433#3 4.447 0.712 2.713 4.816 HPLCStds1433#3 4.443 0.715 2.728 4.839 20.0 HPLCStds1433#2 4.443 0.136 0.523 0.965 HPLCStds1433#2 4.447 0.135 0.524 0.958 HPLCStds1433#1 4.447 0.071 0.270 0.518 HPLCStds1433#1 4.443 0.070 0.267 0.515 15.0 HPI CStds1433#6 4.450 5.209 19.932 30.058 Stds1433#6 4.450 5.239 20.345 30.197 hr CStds1433#5 4.447 2.410 9.186 15.361 10.0 HPLCStds1433#5 4.443 2.410 9.129 15.357 HPLCStds1433#4 4.443 1.530 5.809 10.049 ! HPLCStds1433#4 4.440 1.528 5.810 10.037 HPLCStds1433#3 4.440 0.726 2.799 4.913 5.0 HPLCStds1433#3 4.443 0.729 2.795 4.934 HPLCStds1433#2 4.440 0.140 0.541 0.994 HPLCStds1433#2 4.437 0.139 0.540 0.986 pS*min HPLCStds1433#1 4.443 0.071 0.275 0.521 0.0 HPLCStds1433#1 1 4.443 0.0721 0.2751 1 0.5251 0.00 2.00 4.00 6.001 NE013AS-021420-RT-1303 Appendix C-Page 206 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Calibration Version 7.2.8.10783 Logged on User:scthieken Page 21 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 18:49 Run Time: 14.50 30.0 Raphael1239#21 [manually integrated] ECD— 1 PS 25.0 20.0 ch 15.0 c n � Cni 10.0 0 U 5.0 17 i min -1.0 2.60 3.00 4.60 5.00 6.00 7.00 8.00 Time[min] Analyst Comment: II SJT 10/31/2022 E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min p�S*min PS pig/mL 4.44 Chloride 1.076 4.148 7.18111 FALSE TRUE j MgRl3AS-021420-RT-1303 Appendix C- Page 207 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 22 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-Oct-2022 / 19:05 Run Time: 14.50 30.0 40 Raphael1239#22 [manually integrated] ECD_1 PS 25.0 20.0 voi 15.0 a v m � 10.0 0 s U 5.0 min 2.00 3.60 4.00 5.00 6.60 7.00 8.00 Time [min] Analyst Comment: II SJT 10/31/2022 No. Time Peak Name Area Height Conic Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.073 4.147 7.16292 FALSE TRUE g MF�R13AS-021420-RT-1303 Appendix C- Page 208 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 23 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In. Date/Time: 28-Oct-2022 / 19:22 Run Time: 14.50 30.0 tle Raphae11239#23 HPLCStds1433#RB ECD_1 PS 25.0 20.0 obi 15.0 c 0 n a> IY 10.0 0 rn 5.0 L U �\ I `T I min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.49 Chloride 0.007 0.022 0.07927 FALSE FALSE g NER13AS-021420-RT-1303 Appendix C-Page 209 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter io Version 7.2.8.10783 Logged on User:scthieken Page 24 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken /I Date/Time: 28-Oct-2022 / 19:38 Run Time: 14.50 30.0 no Raphael1239#24 HPLCStds1433#RB ECD_1 PS 25.0 20.0 uoi 15.0 c 0 n w 0 10.0 M 0) d' d' 5.0 0 U C I I min -1.0 2.60 3.00 4.60 5.60 6.60 7.60 8.60 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 2 4.49 Chloride 0.006 0.023 0.07739 FALSE FALSE NNgFR(1l3AS-021420-RT-1303 Appendix C-Page 210 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr3trbtf Version 7.2.8.10783 Logged on User:scthieken Page 25 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R1.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 100.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 19:54 Run Time: 14.50 30.0 Raphael1239#25 1022-157.R1.HCI ECD_1 PS 25.0 20.0 u) 15.0 c 0 CL 10.0 v as `o 5.0 i; min -1.0 2.60 3.60 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS tag/mL 1 4.44 Chloride 0.631 2.359 4.28381 FALSE FALSE ER13AS-021420-RT-1303 Appendix C-Page 211 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr io Version 7.2.8.10783 Logged on User:scthieken Page 26 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R1.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 100.0 Instrument Method., AS22 ASAP Operator: scthieken ln.Date/Time: 28-Oct-2022 / 20:10 Run Time: 14.50 30.0 Raphael1239#26 1022-157.R1.HC1 ECD_1 PS 25.0 20.0 in 15.0 c 0 Cn 10.0 d- a) -0 `o 5.0 U ' min 2.00 3.00 4.00 5.00 6.00 7.00 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min pS pg/mL 1 4.44 Chloride 0.631 2.373 4.28527 FALSE FALSE gFb�13AS-021420-RT-1303 Appendix C-Page 212 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 27 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R1-MS.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 20:26 Run Time: 14.50 30.0 Raphael1239#27 1022-157.R1-MS.HCI ECD_1 PS 25.0 20.0 of 15.0 0 ' W tY 10.0 L 0 U 5.0 min 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: *100 E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min NS pg/mL 4.44 Chloride 1.281 4.794 8.48558 FALSE FALSE g N,ER13AS-021420-RT-1303 Appendix C- Page 213 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inte ra i Version 7.2.8.10783 Logged on User:scthieken Page 28 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R1-MS.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In. Date/Time: 28-00-2022 / 20:42 Run Time: 14.50 30.0 Raphael1239#28 1022-157.R1-MS.HCI ECD_1 PS 25.0 20.0 c 15.0 0 0 ch a� 10.0 0 U 5.0 min -1.0 2.00 3.60 4.60 5.60 6.00 7.00 8.00 Time [min] Analyst Comment: *100 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.315 4.919 8.70510 FALSE FALSE NNFF(�13AS-021420-RT-1303 Appendix C-Page 214 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/IntegrMgR Version 7.2.8.10783 Logged on User:scthieken Page 29 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R1-MSD.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 28-Oct-2022 / 20:58 Run Time: 14.50 30.0 Raphael1239#29 1022-157.R1-MSD.HCI ECD_1 PS 25.0 20.0 in uoi 15.0 oCD a) d 10.0 0 s= U 5.0 min 2.60 3.60 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: *100 No. Time Peak Name Area Height Conic Manually Assigned? Manipulated? min pS*min PS lag/mL 1 4.44 Chloride 1.277 4.791 8.46413 FALSE FALSE ,;R13AS-021420-RT-1303 Appendix C-Page 215 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 30 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R1-MSD.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In. Date/Time: 28-Oct-2022 / 21:14 Run Time: 14.50 30.0 Raphael1239#30 1022-157.R1-MSD.HCI ECD_1 PS 25.0 20.0 15.0 co Q c1' N N 10.0 O O U 5.0 min 2.00 3.60 4.60 5.00 6.60 7.00 8.60 Time [min] Analyst Comment: *100 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.305 4.900 8.64229 FALSE FALSE ME6R g 13AS-021420-RT-1303 Appendix C-Page 216 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 31 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R2.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 100.0 Instrument Method., AS22 ASAP Operator: scthieken IL.Date/Time: 28-Oct-2022 / 21:30 Run Time: 14.50 30.0 Raphaell239#31 1022-157.R2.HC1 ECD_1 PS 25.0 20.0 z 0 15.0 LO o Q 10.0 0 U 5.0 ' min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 1 4.45 Chloride 1.706 6.306 11.14103 FALSE FALSE f�ER13AS-021420-RT-1303 Appendix C- Page 217 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:scthieken Page 32 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R2.HC1 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 100.0 Instrument Method: AS22 ASAP Operator: scthieken In Date/Time: 28-Oct-2022 / 21:47 Run Time: 14.50 30.0 Raphael1239#32 1022-157.R2.HC1 ECD_1 PS 25.0 20.0 c 15.0 o a w 10.0 0 s U 5.0 min 2.00 3.00 4.00 5.00 6.60 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.699 6.282 11.09438 FALSE FALSE gRl3AS-021420-RT-1303 Appendix C-Page 218 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 33 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R3.HCI Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 100.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 22:03 Run Time: 14.50 30.0 Raphael1239#33 1022-157.R3.HC1 ECD_1 PS 25.0 20.0 15.0 c � o U a) W 10.0 0 U '7 5.0 min 2.00 3.00 4.00 5.00 6.00 7.60 8.00 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.646 6.097 10.76642 FALSE FALSE Fa�13AS-021420-RT-1303 Appendix C- Page 219 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 34 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R3.HC1 Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 100.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 22:19 Run Time: 14.50 30.0 Raphael1239#34 1022-157.R3.HCI ECD_1 PS 25.0 20.0 CD 15.0 dM o 0- �r C 10.0 _o U 5.0 min -1.0 2.60 3.60 4.60 5.60 6.60 7.00 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.648 6.106 10.77833 FALSE FALSE gR13AS-021420-RT-1303 Appendix C-Page 220 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter iFa Version 7.2.8.10783 Logged on User:scthieken Page 45 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 29-Oct-2022 / 01:16 Run Time: 14.50 30.0 Raphaell239#45 HPLCStdsl433#4 ECD_1 PS 25.0 20.0 c 15.0 M d- o CL Cn a) 10.0 0 U 5.0 min -1.0 2.60 3.60 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 4.44 Chloride 1.509 5.670 9.91766 FALSE FALSE g MER13AS-021420-RT-1303 Appendix C-Page 221 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter io Version 7.2.8.10783 Logged on User:scthieken Page 46 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 29-Oct-2022 / 01:32 Run Time: 14.50 30.0 Raphael1239#46 H1PLCStds1433#4 ECD_1 PS 25.0 20.0 c 15.0 o d V- m 10.0 0 r U 5.0 i min 2.00 3.00 4.00 5.00 6.00 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.512 5.678 9.93694 FALSE FALSE FdR13AS-021420-RT-1303 Appendix C- Page 222 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Raw ij ta {u NE01 3AS-021420-RT-1 303 Appendix C-Page 223 of 1178 Logged on User:scthieken Page 9 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 15:36 Run Time: 14.50 Raphael1239#9 HPLCStdsl433#6 ECD_1 30.0 pS m v 25.0 a 0 U 20.0 in 15.0 c 0 n of 10.0 5.0 min 2.60 3.00 4.60 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated. min pS*min PS pg/mL 1 4.46 Chloride 5.173 19.961 29.89029 FALSE FALSE g MgR13AS-021420-RT-1303 Appendix C-Page 224 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 10 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-Oct-2022 / 15:52 Run Time: 14.50 Raphael1239#10 HPLCStds1433#6 ECD_1 30.0 pS d- 25.0 0 s U 20.0 u0i 15.0 c 0 Q 10.0 5.0 min -1.0 2.60 3.60 4.00 5.60 6.00 7.00 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 5.093 19.471 29.51490 FALSE FALSE g MER13AS-021420-RT-1303 Appendix C-Page 225 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter io Version 7.2.8.10783 Logged on User:scthieken Page 11 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-Oct-2022 116:08 Run Time: 14.50 30.0 Raphael1239#11 HPLCStds1433#5 ECD_1 PS 25.0 20.0 _ M eJ' 15.0 o n o (D c [r U 10.0 rr 5.0 -1.0 min 2.60 3.60 4.00 5.60 6.60 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 1 4.44 Chloride 2.374 8.864 15.15172 FALSE FALSE gR13AS-021420-RT-1303 Appendix C-Page 226 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 12 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-Oct-2022 / 16:24 Run Time: 14.50 Raphael1239#12 30.0 HPLCStds1433#5 ECD_1 PS 25.0 20.0 r• V c 15.0 L i1 p Zn a � U 10.0 rr 5.0 min 2.00 3.00 4.00 5.00 6.00 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS tag/mL 1 4.45 Chloride 2.368 8.925 15,11496 FALSE FALSE g M,;R13AS-021420-RT-1303 Appendix C- Page 227 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 13 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-00-2022 / 16:40 Run Time: 14.50 Raphael1239#13 HPLCStds1433#4 ECD_1 30.0 PS 25.0 20.0 c 15.0 M d- o a �r a`) ' Of a> 10.0 0 U 5.0 min -1.0 2.00 3.00 4.60 5.60 6.00 7.60 8.60 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 1 4.44 Chloride 1.499 5.645 9.85450 FALSE FALSE NNFF(113AS-021420-RT-1303 Appendix C-Page 228 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr�tia� Version 7.2.8.10783 Logged on User:scthieken Page 14 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 16:57 Run Time: 14.50 30.0 Raphaell239#14 HPLCStdsl433#4 ECD_1 PS 25.0 20.0 s 15.0 0 v C � o 10.0 0 U rr 5.0 min 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.502 5.646 9.87479 FALSE FALSE g M,aRUAS-021420-RT-1303 Appendix C-Page 229 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 15 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-00-2022 / 17:13 Run Time: 14.50 Raphael1239#15 HPLCStds1433#3 ECD_1 30.0 pS 25.0 20.0 ch 15.0 c 0 Q Cl) ti 10.0 v m 0 5.0 U min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 0.712 2.713 4.81636 FALSE FALSE gFa�13AS-021420-RT-1303 Appendix C- Page 230 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 16 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 17:29 Run Time: 14.50 30.0 Raphael1239#16 HPLCStds1433#3 ECD_1 PS 25.0 20.0 v7 can 15.0 c 0 n. En cM 0! � 10.0 a) a 0 5.0 U min -1.0 J. 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time[min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.44 Chloride 0.715 2.728 4.83878 FALSE FALSE g MgR13AS-021420-RT-1303 Appendix C-Page 231 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 17 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-Oct-2022 117:45 Run Time: 14.50 Raphae11239#17 HPLCStdsl433#2 ECD_1 30.0 NS 25.0 20.0 u) 15.0 c 0 n 0) 0 10.0 d- m 5.0 0 s= U min 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.136 0.523 0.96515 FALSE FALSE f�F6�13AS-021420-RT-1303 Appendix C-Page 232 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra I Version 7.2.8.10783 Logged on User:scthieken Page 18 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-Oct-2022 / 18:01 Run Time: 14.50 30.0 Raphaell239#18 HPLCStdsl433#2 ECD_1 PS 25.0 20.0 uui 15.0 c 0 0- U) aD 10.0 m 5.0 .L 0 U rr i min 2.60 3.60 4.60 5.00 6.60 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 1 4.45 Chloride 0.135 0.524 0.95797 FALSE FALSE g NER13AS-021420-RT-1303 Appendix C- Page 233 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter io Version 7.2.8.10783 Logged on User:scthieken Page 19 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 18:17 Run Time: 14.50 Raphael1239#19 HPLCStds1433#1 ECD_1 30.0 pS 25.0 20.0 a con 15.0 c 0 n 0 am 10.0 �t v� 5.0 0 L U n 2.60 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 0.071 0.270 0.51828 FALSE FALSE g MFcR13AS-021420-RT-1303 Appendix C- Page 234 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter I Version 7.2.8.10783 Logged on User:scthieken Page 20 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 18:33 Run Time: 14.50 30.0 Raphael1239#20 HPLCStds1433#1 ECD— 1 PS 25.0 20.0 z uu) 15.0 c 0 a W a� 10.0 M d- �I' aD 5.0 L 0 U 17 I min 2.60 3.60 4.60 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated. min pS*min NS Ng/mL 1 4A4 Chloride 0.070 0.267 0.51523 FALSE FALSE f�E�13AS-021420-RT-1303 Appendix C- Page 235 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra to Version 7.2.8.10783 Logged on User:scthieken Page 21 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Inj.Date/Time: 28-Oct-2022 / 18:49 Run Time: 14.50 30.0 .04 Raphael1239#21 [manually integrated] ECD_1 PS 25.0 20.0 uoi 15.0 c CL � v 10.0 a) a .c 0 U 5.0 i min 2.60 3.00 4.00 5.60 6.00 7.00 8.60 Time [min] Analyst Comment: II SJT 10/31/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.076 4.148 7.18111 FALSE TRUE F��13AS-021420-RT-1303 Appendix C-Page 236 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr Version 7.2.8.10783 Logged on User:scthieken Page 22 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 19:05 Run Time: 14.50 30.0 Raphael1239#22 [manually integrated] ECD— 1 PS 25.0 20.0 vi 15.0 c a`) 10.0 .L 0 U 5.0 min -1.0 2.00 3.00 4.60 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: II SJT 10/31/2022 E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min uS*min PS pg/mL 4.44 Chloride 1.073 4.147 7.16292 FALSE TRUE ER13AS-021420-RT-1303 Appendix C-Page 237 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/integr io Version 7.2.8.10783 Logged on User:scthieken Page 23 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 19:22 Run Time: 14.50 30.0 Raphael1239#23 HPLCStds1433#RB ECD 1 PS 25.0 20.0 N uu) 15.0 c 0 a am 10.0 0 rn 5.0 0 U min 2.60 3.60 4.60 5.00 6.60 7.60 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS"min PS pg/mL 1 4.49 Chloride 0.007 0.022 0.07927 FALSE FALSE NNFF(113AS-021420-RT-1303 Appendix C- Page 238 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integratr6tS Version 7.2.8.10783 Logged on User:scthieken Page 24 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 19:38 Run Time: 14.50 30.0 Raphael1239#24 HPLCStds1433#RB ECD_1 PS 25.0 20.0 ai 15.0 c 0 Q U) a) w 10.0 M 0) V' cf' 5.0 0 U CIO min 2.60 3.60 4.00 5.00 6.00 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 2 4.49 Chloride 0.006 0.023 0.07739 FALSE FALSE f�ER13AS-021420-RT-1303 Appendix C-Page 239 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra 10 Version 7.2.8.10783 Logged on User:scthieken Page 95 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 29-Oct-2022 / 14:42 Run Time: 14.50 30.0 Raphael1239#95 HPLCStds1433#6 ECD— 1 PS LO 25.0 0 U 20.0 ch 15.0 c 0 n. Cn m 10.0 5.0 min 2.00 3.00 4.00 5.60 6.60 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conic Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 5.209 19.932 30.05767 FALSE FALSE FaR13AS-021420-RT-1303 Appendix C-Page 240 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 96 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#6 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken /2. Date/Time. 29-Oct-2022 / 14:58 Run Time: 14.50 30.0 Raphael1239#96 HPLCStds1433#6 ECD_1 PSLO v v 25.0 a L U P 20.0 ch 15.0 c 0 co 10.0 5.0 -1.01 J T-- min 2.00 3.00 4.60 5.00 6.60 7.60 8.60 Time [min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 4.45 Chloride 5.239 20.345 30.19689 FALSE FALSE g MEdR13AS-021420-RT-1303 Appendix C-Page 241 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 97 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In. Date/Time: 29-Oct-2022 / 15:14 Run Time: 14.50 30.0 Raphael1239#97 HPLCStds1433#5 ECD_1 PS 25.0 20.0 0) 15.0 a) c Q L NQ O IL 10.0 5.0 min 2.60 3.60 4.00 5.00 6.00 7.00 8.00 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS"min PS pg/mL 1 4.45 Chloride 2.410 9.186 15.36067 FALSE FALSE gF��13AS-021420-RT-1303 Appendix C- Page 242 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 98 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#5 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken In Date/Time: 29-Oct-2022 / 15:30 Run Time: 14.50 Raphael1239#98 HPLCStds1433#5 ECD_1 30.0 NS 25.0 20.0 M ch 15.0 c v O L (n O a) O � U 10.0 5.0 min -1.0 2.00 3.60 4.60 5.00 6.60 7.60 8.00 Time(min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.44 Chloride 2.410 9.129 15.35737 FALSE FALSE ,;Rl3AS-021420-RT-1303 Appendix C-Page 243 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 99 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 29-Oct-2022 / 15:46 Run Time: 14.50 30.0 Raphaell239#99 HPLCStds1433#4 ECD 1 PS 25.0 20.0 c 15.0 o Q. .4 aa) o' 0 10.0 0 U IT 5.0 i ' min 2.00 3.00 4.00 5.00 6.00 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.530 5.809 10.04927 FALSE FALSE NF(1 13AS-021420-RT-1303 Appendix C- Page 244 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/IntegrN�it Version 7.2.8.10783 Logged on User:scthieken Page 100 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 29-Oct-2022 / 16:02 Run Time: 14.50 30.0 Raphael1239#100 HPLCStds1433#4 ECD_1 PS 25.0 20.0 s c 15.0 Nr It a 4 aWi 10.0 0 U rr- 5.0 min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.528 5.810 10.03723 FALSE FALSE N ER13AS-021420-RT-1303 Appendix C-Page 245 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/in teg ra io Version 7.2.8.10783 Logged on User:scthieken Page 101 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Inj.Date/Time: 29-Oct-2022 / 16:18 Run Time: 14.50 30.0 Raphael1239#101 HPLCStds1433#3 ECD_1 PS 25.0 20.0 v0i 15.0 c 0 Q U) o � v 10.0 d m `o 5.0 C i min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS ug/mL 1 4A4 Chloride 0.726 2.799 4.91302 FALSE FALSE g MRl3AS-021420-RT-1303 Appendix C- Page 246 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 102 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#3 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 29-Oct-2022 / 16:34 Run Time: 14.50 30.0 Raphael1239#102 HPLCStds1433#3 ECD— 1 PS 25.0 20.0 in 15.0 c 0 a U) Cl) 10.0 d a� 0 5.0 C� min 2.00 3.00 4.60 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min pS pg/mL 1 4.44 Chloride 0.729 2.795 4.93367 FALSE I FALSE f ,FR13AS-021420-RT-1303 Appendix C-Page 247 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra i Version 7.2.8.10783 Logged on User:scthieken Page 103 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken /I Date/Time: 29-Oct-2022 / 16:51 Run Time: 14.50 30.0 Raphael1239#103 HPLCStds1433#2 ECD_1 PS 25.0 20.0 uu) 15.0 c 0 a 0 a) 10.0 v m 5.0 �0 0 U min 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.140 0.541 0.99426 FALSE FALSE gFb�13AS-021420-RT-1303 Appendix C-Page 248 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 104 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#2 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 29-Oct-2022 / 17:07 Run Time: 14.50 30.0 Raphael1239#104 HPLCStds1433#2 ECD_1 PS 25.0 20.0 in 15.0 c 0 a Cn a> af 10.0 M �t a) 5.0 -a 0 U i min -1.0 2.60 3.60 4.60 5.60 6.60 7.00 8.00 Time [min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.44 Chloride 0.139 0.540 0.98638 FALSE FALSE g MFd�13AS-021420-RT-1303 Appendix C-Page 249 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 105 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken Date/Time: 29-Oct-2022 / 17:23 Run Time: 14.50 30.0 Raphael1239#105 HPLCStds1433#1 ECD_1 PS 25.0 20.0 con 15.0 c 0 n 0 0 10.0 M 0 5.0 -0 0 U min 2.60 3.60 4.00 5.00 6.00 7.00 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.071 0.275 0.52137 FALSE I FALSE g MRl3AS-021420-RT-1303 Appendix C-Page 250 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter I Version 7.2.8.10783 Logged on User:scthieken Page 106 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#1 Injection Volume: 25.00 Injection Type: Calibration Standard Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken In Date/Time: 29-Oct-2022 / 17:39 Run Time: 14.50 30.0 Raphael1239#106 HPLCStds1433#1 ECD_1 PS 25.0 20.0 15.0 0 0 10.0 M m 5.0 L _0 U min -1.0 2.60 3.60 4.60 5.60 6.00 7.00 8.00 Time[min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.44 Chloride 0.072 0.275 0.52511 FALSE FALSE g MER13AS-021420-RT-1303 Appendix C-Page 251 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter io Version 7.2.8.10783 Logged on I' -cthieken Page 1 of 2 Instrument: el 1i 22 7:55AM Sequence:F,_,_:,dell239 Calibration Table Pos, Level Ref.Amount Calibration Dil.Factor Volume No. Injection Name Inject Time Point Status pg/mL ECD_1 ECD_1 Chloride Chloride 9 HPLCStds1433#6 28/Oct/2022 15:36 BA6 06 30.0000 Ok 1.0000 25.00 10 HPLCStds1433#6 28/Oct/2022 15:52 BA6 06 30.0000 Ok 1.0000 25.00 11 HPLCStds1433#5" 28/Oct/2022 16:08 BA5 05 15.0000 Ok 1.0000 25.00 12 HPLCStds1433#5 28/Oct/2022 16:24 BA5 05 15.0000 Ok 1.0000 25.00 13 HPLCStds1433#4' 28/Oct/2022 16:40 BA4 04 10.0000 ` Ok 1.0000 25.00 14 HPLCStds1433#4' 28/Oct/2022 16:57 BA4 04 10.0000 Ok 1.0000 25.00 15 HPLCStds1433#3' 28/Oct/2022 17:13 BA3 03 50000 Ok 1.0000 25.00 16 HPLCStds1433#3 28/Oct/2022 17:29 BA3 03 50000 Ok 1.0000 25.00 17 HPLCStds1433#2 28/Oct/2022 17:45 BA2 02 10000 Ok 1.0000 25.00 18 HPLCStds1433#2 28/Oct/2022 18:01 BA2 02 1.0000 Ok 1.0000 25.00 19 HPLCStds1433#1 28/Oct/2022 18:17 BA1 01 0.5000 Ok 1.0000 25.00 20 HPLCStds1433#1' 28/Oct/2022 18:33 BA1 01 0.5000 Ok 1.0000 25.00 95 HPLCStds1433#6' 29/Oct/2022 14:42 BA6 06 30.0000 Ok 1.0000 25.00 96 HPLCStds1433#6' 29/Oct/2022 14:58 BA6 06 30.0000 Ok 1.0000 25.00 97 HPLCStds1433#5' 29/Oct/2022 15:14 BA5 05 15.0000 Ok 1.0000 25.00 98 HPLCStds1433#5' 29/Oct/2022 15:30 BA5 05 15`.0000 Ok 1.0000 25.00 99 HPLCStds1433#4' 29/Oct/2022 15:46 BA4 04 10.0000 Ok 1.0000 25.00 100 HPLCStds1433#4 29/Oct/202216:02 BA4 04 10,0000 Ok 1.0000 25.00 101 HPLCStds1433#3' 29/Oct/2022 16:18 BA3 03 50000 Ok 1.0000 25.00 102 HPLCStds1433#3 29/Oct/2022 16:34 BA3 03 50000 Ok 1.0000 25.00 103 HPLCStds1433#2` 29/Oct/2022 16:51 BA2 02 10000 Ok 1.0000 25.00 104 HPLCStds1433#2 29/Oct/2022 17:07 BA2 02 1.0000 Ok 1.0000 25.00 105 HPLCStds1433#1 29/Oct/2022 17:23 BA1 01 0.5000 Ok 1.0000 25.00 106 HPLCStds1433#1' 29/Oct/2022 17:39 BA1 01 0.5000 Ok 1.0000 25.00 Detection Parameters Ret.Time Param. Name Param.Value Inj.Type Channel min Always Baseline Noise Auto Range Off Any All Channels` Always Baseline Noise Start Time 0400[min] Any All Channels' Always Baseline Noise End Time 0700[min] Any ; All Channels` Always Cobra Smoothing Width Auto Any All Channels Always Consider Void Peak Off Any All Channels 0.000 Maximum Rider Ratio 10[%] Any ` All Channels 0.000 Tailing Sensitivity Factor 0500[%] Any All Channels' 0.000 Inhibit Integration On Any All Channels' 0.000 Minimum Area Auto Any All Channels 4.018 Inhibit Integration Off Any , All Channels 6.225 IInhibit Integration IOn Any 1All Channels NE013AS-021420-RT-1303 Appendix C-Page 252 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Calibration Details Version 7.2.8.10783 Logged on User:scthieken Page 2 of 2 Instrument:Raphael 10/31/2022 7:55 AM Sequence:Raphael1239 Calibration Batch Report Sequence: Raphael1239 Injection Volume: 25.00 Instrument Method.• AS22 ASAP Operator- scthieken' Inj.Date/Time: 29-Oct-2022 I'14:09 Run Time: 14.5 Calibration Summary' Peak Name Eval.Type Cal.Type Points Offset Slope Curve Coeff.Det. CO C1 C2 % Chloride Area Quad WithOffset 1/A 24.000 0.034 6.872 -0.213 99.973 AVERAGE: 0.0341 6.8719 -0.2127 99.9734 Injection Name Ret.Time Area Height Amount 35.0 Chloride External ECD_1 min` pS*min PS pg/mL pg/mL ECD 1 ECD 1 ECD 1 ECD 1 Chloride Chloride Chloride Chloride HPLCStds1433#6 4.460 5.173 19.961 29.890 30.0 HPLCStds1433#6 4.450 5.093 19.471 29.515 HPLCStds1433#5 4.443 2.374 8.864 15.152 HPLCStds1433#5 4.447 2.368 8.925 15.115 25.0 HPLCStds1433#4 4.443 1.499 5.645 9.855 HPLCStds1433#4 4.440 1.502 5.646 9,875 HPLCStds1433#3 4.447 0.712 2.713 4.816 HPLCStds1433#3 4.443 0.715 2.728 4.839 20.0 HPLCStds1433#2 4.443 0.136 0.523 0.965 HPLCStds1433#2 4.447 0.135 0.524 0.958 HPLCStds1433#1 4.447 0.071 0.270 0.518 HPLCStds1433#1 4.443 0.070 0.267 0.515 I 15.0 HPLCStds1433#6 4.450 5.209 19.932 30.058 HPLCStds1433#6 4.450 5.239 20.345 30.197 HPLCStds1433#5 4.447 2.410 9.186 15.361 10.0 HPLCStds1433#5 4.443 2.410 9.129 15.357 HPLCStds1433#4 4.443 1.530 5.809 10.049 HPLCStds1433#4 4.440 1.528 5.810 10.037 HPLCStds1433#3 4.440 0.726 2.799 4.913 5.0 HPLCStds1433#3 4.443 0.729 2.795 4.934 HPLCStds1433#2 4.440 0.140 0.541 0.994 HPLCStds1433#2 4.437 0.139 0.540 0.986 pS*min HPLCStds1433#1 4.443 0.071 0.275 0.521 0.0 HPLCStds1433#1 4.443 0.072 0.275 0,525 0.00 2.00 4.60 6.00 NE013AS-021420-RT-1303 Appendix C- Page 253 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Calibration Version 7.2.8.10783 Logged on User:scthieken Page 21 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method., AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 18:49 Run Time: 14.50 30.0 Raphael1239#21 [manually integrated] ECD_1 PS 25.0 20.0 z voi 15.0 c n 't W of 10.0 a> .L 0 U 5.0 i min 2.00 3.00 4.00 5.00 6.00 T 0 8.00 Time [min] Analyst Comment: II SJT 10/31/2022 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.076 4.148 7.18111 FALSE TRUE g MgR'3AS-021420-RT-1303 Appendix C-Page 254 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 22 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#SS Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-Oct-2022 / 19:05 Run Time: 14.50 30.0 ' Raphael1239#22 [manually integrated] ECD_1 PS 25.0 20.0 uoi 15.0 c CL m 10.0 a 0 2= U 5.0 R mi -1.0 n 2.60 3.00 4.60 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: 11 SJT 10/31/2022 No. Time Peak Name Area Height Conic Manually Assigned? Manipulated? min pS*min PS lag/mL 1 4.44 Chloride 1.073 4.147 7.16292 FALSE TRUE M,;Rl3AS-021420-RT-1303 Appendix C-Page 255 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 23 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-Oct-2022 / 19:22 Run Time: 14.50 30.0 tol Raphael1239#23 HPLCStds1433#RB ECD_1 PS 25.0 20.0 s u�i 15.0 c 0 a w a� 10.0 0 rn d- 5.0 0 U m 2.60 3.60 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.49 Chloride 0.007 0.022 0.07927 FALSE FALSE g FdR13AS-021420-RT-1303 Appendix C- Page 256 of 1178 Chmmeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 24 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#RB Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 28-Oct-2022 / 19:38 Run Time: 14.50 30.0 Raphael1239#24 HPLCStds1433#RB ECD— 1 PS 25.0 20.0 rn 15.0 c 0 n a) 10.0 Cl) rn v v 5.0 0 U 1� I I I I I I min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 2 4A9 Chloride 0.006 0.023 0.07739 FALSE FALSE g MR13AS-021420-RT-1303 Appendix C-Page 257 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 35 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R111.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken /I Date/Time: 28-Oct-2022 / 22:35 Run Time: 14.50 30.0 Raphael1239#35 1022-157.R111.M26A ECD_1 PS 25.0 20.0 ch 15.0 0 o o �. Q � 10.0 a) 0 U 5.0 ' min -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS lag/mL 1 4.44 Chloride 1.212 4.509 8.04871 FALSE FALSE g MgR13AS-021420-RT-1303 Appendix C-Page 258 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 36 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R111.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 28-Oct-2022 / 22:51 Run Time: 14.50 30.0 Raphael1239#36 1022-157.R111.M26A ECD_1 PS 25.0 20.0 15.0 O M O It a 10.0 m 0 U 5.0 1- ' min 2.60 3.60 4.60 5.00 6.60 7.00 8.00 Time (min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min pS pg/mL 1 4.44 Chloride 1.208 4.533 8.02756 FALSE FALSE N ER13AS-021420-RT-1303 Appendix C- Page 259 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:scthieken Page 37 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R112.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 23:07 Run Time: 14.50 30.0 Raphaell239#37 1022-157.R112.M26A ECD_1 PS 25.0 20.0 v0i 15.0 c 0 o_ a) 10.0 0 LO a) 5.0 -o 0 U i'� min -1.0 2.60 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS Ng/mL 1 4.45 Chloride 0.047 0.178 0.35823 FALSE FALSE g �13AS-021420-RT-1303 Appendix C-Page 260 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 38 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R112.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 28-Oct-2022 / 23:23 Run Time: 14.50 30.0 Raphael1239#38 1022-157.R112.M26A ECD_1 PS 25.0 20.0 ch 15.0 c 0 n c m 10.0 0 v v a) 5.0 L U -1.0 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time[min] Analyst Comment: E1 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 4.45 Chloride 0.047 0.177 0.35764 FALSE FALSE g MgRl3AS-021420-RT-1303 Appendix C-Page 261 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 39 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R113.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 23:39 Run Time: 14.50 30.0 Raphael1239#39 1022-157.R113.M26A ECD_1 PS 25.0 20.0 uoi 15.0 c 0 Q m 10.0 5.0 -0 0 U 1 `T 1 1 1 I min -1.0 2.60 3.60 4.00 5.00 6.60 7.60 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.52 Chloride 0.006 0.022 0.07440 FALSE FALSE gR13AS-021420-RT-1303 Appendix C-Page 262 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 40 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R113.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 28-Oct-2022 / 23:55 Run Time: 14.50 30.0 Raphael1239#40 1022-157.R113.M26A ECD_1 PS 25.0 20.0 u) 15.0 c 0 n a� 10.0 0 v 5.0 L min -1.0 2.60 3.60 4.00 5.60 6.60 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.51 Chloride 0.007 0.024 0.08418 FALSE FALSE g N,FRl3AS-021420-RT-1303 Appendix C-Page 263 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inte ra i Version 7.2.8.10783 Logged on User:scthieken Page 41 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R114.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 29-Oct-2022 / 00:12 Run Time: 14.50 30.0 Raphael1239#41 1022-157.R114.M26A ECD_1 PS 25.0 20.0 15.0 c 0 ,Z a� af 10.0 5.0 0 U m i 2.00 3.60 4.60 5.60 6.60 7.00 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 0.012 0.038 0.11943 FALSE FALSE gFc�13AS-021420-RT-1303 Appendix C- Page 264 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter I Version 7.2.8.10783 Logged on User:scthieken Page 42 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R114.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 29-Oct-2022 / 00:28 Run Time: 14.50 30.0 J? Raphael1239#42 1022-157.Rl l4.M26A ECD_1 PS 25.0 20.0 va)i 15.0 c 0 n a) 10.0 0 LO 5.0 0 s= V `N min 2.60 3.60 4.00 5.60 6.00 7.00 8.00 Time [min] Analyst Comment: E2 No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 4.45 Chloride 0.011 0.039 0.10646 FALSE FALSE g MgR'3AS-021420-RT-1303 Appendix C-Page 265 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 43 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R2i9.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In". Date/Time: 29-Oct-2022 / 00:44 Run Time: 14.50 30.0 Raphael1239#43 1022-157.R211.M26A ECD_1 PS 25.0 20.0 15.0 c 0 Q o �r 10.0 a� :a `o 5.0 U ' min -1.0 2.00 3.60 4.60 5.60 6.00 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 1 4.44 Chloride 0.540 2.042 3.68409 FALSE FALSE NNFFnn13AS-021420-RT-1303 Appendix C- Page 266 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integrattbit Version 7.2.8.10783 Logged on User:scthieken Page 44 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R211.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 29-Oct-2022 / 01:00 Run Time: 14.50 30.0 Raphael1239#44 1022-157.R211.M26A ECD_1 PS 25.0 20.0 a i 15.0 c 0 n Cn W CM d' 10.0 d v a> 5.0 c U ' mm -1.0 2.00 3.60 4.60 5.60 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.535 2.047 3.65117 FALSE FALSE g MER13AS-021420-RT-1303 Appendix C-Page 267 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter io Version 7.2.8.10783 Logged on User:scthieken Page 45 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method. AS22 ASAP Operator: scthieken In'.Date/Time: 29-Oct-2022 / 01:16 Run Time: 14.50 30.0 Raphael1239#45 HPLCStds1433#4 ECD_1 PS 25.0 20.0 c 15.0. M o Q a`) a) 10.0 0 U 5.0 i ' min -1.0 2.00 3.00 4.60 5.00 6.60 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS"min PS pg/mL 1 4.44 Chloride 1.509 5.670 9.91766 FALSE FALSE MF6R g pp 13AS-021420-RT-1303 Appendix C- Page 268 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 46 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: HPLCStds1433#4 Injection Volume: 25.00 Injection Type: Check Standard Dilution Factor: 1.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 29-Oct-2022 / 01:32 Run Time: 14.50 30.0 04 Raphael1239#46 HPLCStds1433#4 ECD_1 PS 25.0 20.0 15.0 d- o 10.0 0 U 5.0 ' min 2.00 3.00 4.00 5.00 6.00 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 1.512 5.678 9.93694 FALSE FALSE g N,;R13AS-021420-RT-1303 Appendix C-Page 269 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inte ra i Version 7.2.8.10783 Logged on User:scthieken Page 47 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R212.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In'.Date/Time: 29-00-2022 / 01:48 Run Time: 14.50 30.0 Raphael1239#47 1022-157.R212.M26A ECD_1 PS 25.0 20.0 voi 15.0 c 0 n 0 a� 10.0 Cl) 5.0 0 U `r I I min -1.0 2.60 3.60 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.46 Chloride 0.025 0.091 0.20635 FALSE FALSE F6R13AS-021420-RT-1303 Appendix C-Page 270 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr I Version 7.2.8.10783 Logged on User:scthieken Page 48 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R212.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 29-Oct-2022 / 02:04 Run Time: 14.50 30.0 Raphae11239#48 1022-157.R212.M26A ECD_1 PS 25.0 20.0 in 15.0 c 0 n a) 10.0 0 co v 5.0 0 J- U 1 min 2.60 3.60 4.60 5.60 6.00 T00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min pS pg/mL 1 4.46 Chloride 0.025 0.090 0.20496 FALSE FALSE g M,;R13AS-021420-RT-1303 Appendix C-Page 271 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 49 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R213.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In". Date/Time: 29-Oct-2022 / 02:21 Run Time: 14.50 30.0 Raphael1239#49 1022-157.R213.M26A ECD_1 PS 25.0 20.0 uu) 15.0 c 0 0- U) a> 10.0 5.0 0 s= min— 2.00 3.60 4.00 5.60 6.00 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS"min PS pg/mL 1 4.52 Chloride 0.006 0.021 0.07449 FALSE FALSE NNFF((1�13AS-021420-RT-1303 Appendix C- Page 272 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integrafi�ti Version 7.2.8.10783 Logged on User:scthieken Page 50 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R213.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 29-Oct-2022 / 02:37 Run Time: 14.50 30.0 J� Raphael1239#50 1022-157.R213.1%4126A ECD_1 PS 25.0 20.0 N uoi 15.0 c 0 Q a) 10.0 r- L9 Nr 5.0 0 U min 2.00 3.60 4.60 5.00 6.60 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min NS pg/mL 1 4.52 Chloride 0.005 0.020 0.07184 FALSE FALSE fNER13AS-021420-RT-1303 Appendix C- Page 273 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integra io Version 7.2.8.10783 Logged on User:scthieken Page 51 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R214.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method., AS22 ASAP Operator: scthieken In'. Date/Time: 29-Oct-2022 / 02:53 Run Time: 14.50 30.0 Raphael1239#51 1022-157.R214.M26A ECD_1 PS 25.0 20.0 u0i 15.0 c 0 Q rn a> 10.0 M d' d' 5.0 0 U I `T I I I I -1.0 2.60 3.60 4.60 5.60 6.60 7.00 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 0.012 0.040 0.11654 FALSE FALSE NgR13AS-021420-RT-1303 Appendix C- Page 274 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integratibts Version 7.2.8.10783 Logged on User:scthieken Page 52 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R214.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In'. Date/Time: 29-Oct-2022 / 03:09 Run Time: 14.50 30.0 Raphael1239#52 1022-157.R214.M26A ECD_1 PS 25.0 20.0 s (h 15.0 c 0 CL W a) 10.0 LO eO d' d' 5.0 0 U I II 00 ( I min 2.60 3.60 4.60 5.00 6.00 7.60 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 2 4.45 Chloride 0.012 0.041 0.11489 FALSE FALSE MgR g 13AS-021420-RT-1303 Appendix C-Page 275 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter I Version 7.2.8.10783 Logged on User:scthieken Page 53 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R311.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In.Date/Time: 29-Oct-2022 / 03:25 Run Time: 14.50 30.0 Raphael1239#53 1022-157.R311.M26A ECD_1 PS 25.0 20.0 c) v c 15.0 CL � •c o 10.0 U 5.0 I L min 2.00 3.00 4.00 5.00 6.00 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 1 4.44 Chloride 2.025 7.575 13.07440 FALSE FALSE NFn13AS-021420-RT-1303 Appendix C-Page 276 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integrati�r� Version 7.2.8.10783 Logged on User:scthieken Page 54 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R311.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken 12L.Date/Time: 29-Oct-2022 / 03:41 Run Time: 14.50 30.0 Raphael1239#54 1022-157.R311.M26A ECD_1 PS 25.0 20.0 o s � �t c 15.0 o (n -0 a) `o 10.0 U 5.0 ' min -1.0 2.00 3.60 4.00 5.60 6.60 7.00 8.00 Time[min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.44 Chloride 2.036 7.599 13.14130 FALSE FALSE g MEcR13AS-021420-RT-1303 Appendix C-Page 277 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Inter i Version 7.2.8.10783 Logged on User:scthieken Page 55 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R312.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken Date/Time: 29-Oct-2022 / 03:57 Run Time: 14.50 30.0 Raphael1239#55 1022-157.R312.M26A ECD_1 PS 25.0 20.0 uoi 15.0 c 0 n am 10.0 M 5.0 0 s U min -1.0 2.60 3.00 4.60 5.60 6.60 7.60 8.60 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min NS*min PS pg/mL 1 4.44 Chloride 0.076 0.292 0.55747 FALSE FALSE EcR13AS-021420-RT-1303 Appendix C- Page 278 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783 Logged on User:scthieken Page 56 of 107 Instrument:Raphael 10/31/2022 7:56 AM Sequence:Raphael1239 Peak Analysis Report Sample Name: 1022-157.R312.M26A Injection Volume: 25.00 Injection Type: Unknown Dilution Factor: 5.0 Instrument Method: AS22 ASAP Operator: scthieken In. Date/Time: 29-Oct-2022 / 04:13 Run Time: 14.50 30.0 Raphael1239#56 1022-157.R312.M26A ECD_1 PS 25.0 20.0 c 15.0 0 a w aD 10.0 v a> 5.0 0 U min 2.60 3.00 4.60 5.60 6.60 7.00 8.00 Time [min] Analyst Comment: No. Time Peak Name Area Height Conc Manually Assigned? Manipulated? min pS*min PS pg/mL 1 4.45 Chloride 0.076 0.290 0.55246 FALSE FALSE gRl3AS-021420-RT-1303 Appendix C-Page 279 of 1178 Chromeleon(c)Dionex 1996-2009 9 Anions/Integr i Version 7.2.8.10783